Summary of the invention
The present invention, mainly for the problems referred to above, provides a kind of and can strengthen outside batteries structure, avoids cell deformation, prevented combustion-supporting gas from entering and slow down the flame-proof explosion-proof battery that electric current increases, reduces inside battery heat, prevents cells burst and blast at battery during acupuncture.
Object of the present invention is mainly achieved by following proposal: a kind of flame-proof explosion-proof battery, comprise naked battery core and outer copper foil, coat of metal is provided with between described naked battery core and outer copper foil, containing cavity is provided with between coat of metal and outer copper foil, spacer is provided with in containing cavity, spacer is insulator, spacer is the double-deck sleeve-like structure of inner hollow, outer copper foil inner surface is provided with dielectric film, coat of metal is provided with unidirectional valve, containing cavity is communicated with naked battery core by unidirectional valve, the direction of unidirectional valve is towards containing cavity by naked battery core, the low-pressure gas of air pressure lower than a standard atmospheric pressure is filled with in containing cavity, spacer inside is filled with fire retardant matter.Between naked battery core and outer copper foil, coat of metal is set; there is between coat of metal and outer copper foil gap and form containing cavity; spacer is provided with in containing cavity; spacer is the double-deck sleeve-like structure of inner hollow; namely spacer inside is the cavity of sealing, fills fire retardant matter, in containing cavity, fill low-pressure gas in cavity; low-pressure gas is the gas of air pressure lower than a standard atmospheric pressure, makes the pressure in containing cavity be less than pressure in naked battery core.Spacer can support outer copper foil, strengthens outer copper foil structural strength, makes outer copper foil coaxial with coat of metal all the time, avoid cell deformation.After battery uses a period of time, naked battery core inside produces reacted waste gas.Due to coat of metal being provided with unidirectional valve; containing cavity is communicated with naked battery core by unidirectional valve; and the direction of unidirectional valve is towards containing cavity by naked battery core; waste gas in naked battery core enters in the lower containing cavity of air pressure by unidirectional valve; it is the mist of waste gas and low-pressure gas in cavity now between containing cavity and spacer; containing cavity uses the waste gas produced as container collection battery, avoid battery bulging, prevent battery explosion.After containing cavity absorbs battery generation waste gas, be the mist of waste gas and low-pressure gas between containing cavity and spacer, and in spacer, be fire retardant matter.When battery is subject to acupuncture, acupuncture is through outer copper foil, and enter the moment of containing cavity, the waste gas in containing cavity and the mist of low-pressure gas leak, and the extraneous combustion-supporting gas of air can be stoped to enter.Along with metal needle acupuncture penetrates in spacer, the fire retardant matter in spacer leaks, and jointly stop combustion-supporting gas to enter battery, and fire retardant matter can prevent cells burst with waste gas and low-pressure gas.When metal needle runs through battery; outer copper foil inner surface is provided with dielectric film; outer copper foil, between coat of metal and metal needle formed a current circuit; a current circuit is formed between naked battery core and metal needle; slow down current collection, reduce the temperature amount of increase of metal needle, the fire retardant matter in spacer can be followed metal needle and be entered inside battery; can not only cool metal needle, and cells burst and blast can be prevented.Battery is not yielding when normal use, and the fire retardant matter in spacer can not cause interference to the use of battery, and the low pressure in containing cavity can absorb in naked battery core and produce waste gas, makes containing cavity as container collection waste gas, avoids battery bulging.When battery sudden huge profits use causes acupuncture, many current circuits slow down current collection, reduce temperature and raise, the combustion-supporting gases such as air can be stoped to enter, prevent battery spontaneous combustion further, make cell safety reliable when fire retardant matter leaks.
As preferably, described spacer inside is provided with parting bead, and parting bead is centered around spacer inside in the shape of a spiral.Spacer inside is provided with parting bead, by the side wall support of parting bead to spacer both sides, the pressure avoiding spacer to be subject to waste gas causes spacer to be out of shape, parting bead is centered around in spacer in the shape of a spiral, make cavity in spacer in the shape of a spiral, when outer copper foil is pierced, fire retardant matter in spacer leaks, spiral helicine spacer inside can increase the path of fire retardant matter movement, and then control outer discharge, fire retardant matter is slowly flowed out, extend the time that fire retardant matter leaks, and then extend the time intercepting air and enter, after ensureing that metal needle runs through battery completely, still can have fire retardant matter leak out intercept combustion-supporting gas enter, prevent cells burst.
As preferably, parting bead thickness is 2 times of spacer wall thickness to 3 times.The excessive spacer internal volume that easily causes of parting bead thickness is excessively taken, under guarantee spacer internal volume obtains the condition of Appropriate application, parting bead thickness is 2 times of spacer thickness to 3 times, the contact area of parting bead and spacer can be increased, and then strengthen parting bead to the support of spacer, avoid parting bead flexural deformation simultaneously.
As preferably, the axial distance between adjacent two layers parting bead is 1.5 times of parting bead thickness to 3 times.Parting bead around the number of turns more, the volume that spacer inside is taken by parting bead is larger, under guarantee spacer internal volume obtains the condition of Appropriate application, the axial distance between adjacent two layers parting bead is 1.5 times of parting bead thickness to 3 times, can strengthen the support of parting bead to spacer.
As preferably, between coat of metal and naked battery core, be provided with barrier film.
As preferably, the ratio shared by volume shared by fire retardant matter and low-pressure gas between volume is between 0.5:1 to 2:1.Fire retardant matter is used for being subject at battery stoping combustion-supporting gas to enter battery when leaking after the violences such as acupuncture use, and stops the effect of battery spontaneous combustion simultaneously; Low-pressure gas is for reducing the air pressure in containing cavity, the power absorbing waste gas is provided, and a part for volume shared by low-pressure gas is intended for container collection waste gas, the amount of fire retardant matter and the amount of low-pressure gas all have specific function, ratio shared by volume shared by fire retardant matter and low-pressure gas between volume is between 0.5:1 to 2:1, can ensure that battery uses the waste gas produced when 10,000 times can obtain the absorption of containing cavity, and battery is subject to acupuncture when leaking, fire retardant matter slowly can leak all the time and organize cells burst.
As preferably, described low-pressure gas is thin nitrogen.Low-pressure gas is thin nitrogen; thin nitrogen can reduce the air pressure in containing cavity; be convenient to waste gas and suck; simultaneously nitrogen can be fire-retardant; when battery be subject to acupuncture leak time; nitrogen can be followed fire retardant matter and together be leaked, and stops the combustion-supporting gases such as air to enter battery, prevents battery spontaneous combustion further.
As preferably, fire retardant matter is dry powder or sodium-chloride water solution.Fire retardant matter can be dry powder, and when acupuncture runs through, dry powder can be fire-retardant, even extinguishes naked light in the moment producing fragmentary Mars.Fire retardant matter can also to be sodium-chloride water solution, and sodium-chloride water solution can be attached on metal needle when metal needle passes, and to metal needle cooling, can play effect that is fire-retardant and extinguishing naked light simultaneously.
As preferably, the two ends up and down of coat of metal are provided with unidirectional valve.The two ends up and down of coat of metal are provided with unidirectional valve, and no matter anode is at upper or negative pole upper, and no matter fire retardant matter sinks to the bottom still swims in lower, at least ensures have a unidirectional valve not blocked between containing cavity and naked battery core.
A kind of flame-proof explosion-proof battery, it is characterized in that, comprise naked battery core and outer copper foil, naked battery core is by negative electrode, spacer, anode winding forms, coat of metal is provided with between naked battery core and outer copper foil, barrier film is provided with between coat of metal and naked battery core, containing cavity is provided with between coat of metal and outer copper foil, spacer is provided with in containing cavity, spacer is insulator, spacer is the double-deck sleeve-like structure of inner hollow, spacer inside is provided with parting bead, parting bead is centered around spacer inside in the shape of a spiral, parting bead thickness is 2.5 times of spacer wall thickness, axial distance between adjacent two layers parting bead is 2 times of parting bead thickness, outer copper foil inner surface is provided with dielectric film, the two ends up and down of coat of metal outer wall are provided with unidirectional valve, containing cavity is communicated with naked battery core by unidirectional valve, the direction of unidirectional valve is towards containing cavity by naked battery core, the low-pressure gas of air pressure lower than a standard atmospheric pressure is filled with in containing cavity, spacer inside is filled with fire retardant matter, low-pressure gas is thin nitrogen, fire retardant matter is sodium-chloride water solution, ratio shared by volume shared by fire retardant matter and low-pressure gas between volume is 1:1.
Therefore, flame-proof explosion-proof battery of the present invention possesses following advantage: 1, between naked battery core and outer copper foil, coat of metal is set, there is between coat of metal and outer copper foil gap and form containing cavity, spacer is provided with in containing cavity, spacer is the double-deck sleeve-like structure of inner hollow, namely spacer inside is the cavity of sealing, fire retardant matter is filled in cavity, low-pressure gas is filled in containing cavity, low-pressure gas is the gas of air pressure lower than a standard atmospheric pressure, the pressure in containing cavity is made to be less than pressure in naked battery core, spacer can support outer copper foil, strengthen outer copper foil structural strength, make outer copper foil coaxial with coat of metal all the time, avoid cell deformation, 2, after battery uses a period of time, naked battery core inside produces reacted waste gas, due to coat of metal being provided with unidirectional valve, containing cavity is communicated with naked battery core by unidirectional valve, and the direction of unidirectional valve is towards containing cavity by naked battery core, waste gas in naked battery core enters in the lower containing cavity of air pressure by unidirectional valve, it is the mist of waste gas and low-pressure gas in cavity now between containing cavity and spacer, containing cavity uses the waste gas produced as container collection battery, avoid battery bulging, prevent battery explosion, 3, when battery is subject to acupuncture, acupuncture is through outer copper foil, enter the moment of containing cavity, waste gas in containing cavity and the mist of low-pressure gas leak, the extraneous combustion-supporting gas of air can be stoped to enter, and along with metal needle acupuncture penetrates in spacer, the fire retardant matter in spacer leaks, jointly stop combustion-supporting gas to enter battery with waste gas and low-pressure gas, and fire retardant matter can prevent cells burst, 4, when metal needle runs through battery, outer copper foil inner surface is provided with dielectric film, outer copper foil, between coat of metal and metal needle formed a current circuit, a current circuit is formed between naked battery core and metal needle, slow down current collection, reduce the temperature amount of increase of metal needle, the fire retardant matter in spacer can be followed metal needle and be entered inside battery, can not only cool metal needle, and cells burst and blast can be prevented.
Embodiment 1: as shown in Figure 1,2,3, 4, a kind of flame-proof explosion-proof battery, comprises naked battery core 01 and outer copper foil 04, and naked battery core is reeled formed by negative electrode 011, spacer 013, anode 012.Be provided with coat of metal 02 between naked battery core and outer copper foil, between coat of metal and naked battery core, be provided with barrier film 03, between coat of metal and outer copper foil, be provided with containing cavity 05.Be provided with spacer 07 in containing cavity, spacer is insulator, and spacer is the double-deck sleeve-like structure of inner hollow, and spacer inside is provided with parting bead 071, and parting bead is centered around spacer inside in the shape of a spiral.Parting bead thickness is 2.5 times of spacer wall thickness, and the axial distance between adjacent two layers parting bead is 2 times of parting bead thickness.Outer copper foil inner surface is provided with dielectric film, and the two ends up and down of coat of metal outer wall are provided with unidirectional valve 08, and containing cavity is communicated with naked battery core by unidirectional valve, and the direction of unidirectional valve is towards containing cavity by naked battery core.Be filled with the low-pressure gas of air pressure lower than a standard atmospheric pressure in containing cavity, spacer inside is filled with fire retardant matter 06.Low-pressure gas is thin nitrogen, and fire retardant matter is sodium-chloride water solution, and the ratio shared by volume shared by fire retardant matter and low-pressure gas between volume is 1:1.
Between naked battery core and outer copper foil, coat of metal is set; there is between coat of metal and outer copper foil gap and form containing cavity; spacer is provided with in containing cavity; spacer is the double-deck sleeve-like structure of inner hollow; namely spacer inside is the cavity of sealing, fills fire retardant matter, in containing cavity, fill low-pressure gas in cavity; low-pressure gas is the gas of air pressure lower than a standard atmospheric pressure, makes the pressure in containing cavity be less than pressure in naked battery core.Spacer can support outer copper foil, strengthens outer copper foil structural strength, makes outer copper foil coaxial with coat of metal all the time, avoid cell deformation.After battery uses a period of time, naked battery core inside produces reacted waste gas.Due to coat of metal being provided with unidirectional valve; containing cavity is communicated with naked battery core by unidirectional valve; and the direction of unidirectional valve is towards containing cavity by naked battery core; waste gas in naked battery core enters in the lower containing cavity of air pressure by unidirectional valve; it is the mist of waste gas and low-pressure gas in cavity now between containing cavity and spacer; containing cavity uses the waste gas produced as container collection battery, avoid battery bulging, prevent battery explosion.After containing cavity absorbs battery generation waste gas, be the mist of waste gas and low-pressure gas between containing cavity and spacer, and in spacer, be fire retardant matter.When battery is subject to acupuncture, as shown in Figure 5, the acupuncture of metal needle 09 is through outer copper foil, and enter the moment of containing cavity, the waste gas in containing cavity and the mist of low-pressure gas leak, and the extraneous combustion-supporting gas of air can be stoped to enter.Along with metal needle acupuncture penetrates in spacer, the fire retardant matter in spacer leaks, and jointly stop combustion-supporting gas to enter battery, and fire retardant matter can prevent cells burst with waste gas and low-pressure gas.When metal needle runs through battery; outer copper foil inner surface is provided with dielectric film; outer copper foil, between coat of metal and metal needle formed a current circuit; a current circuit is formed between naked battery core and metal needle; slow down current collection, reduce the temperature amount of increase of metal needle, the fire retardant matter in spacer can be followed metal needle and be entered inside battery; can not only cool metal needle, and cells burst and blast can be prevented.Battery is not yielding when normal use, and the fire retardant matter in spacer can not cause interference to the use of battery, and the low pressure in containing cavity can absorb in naked battery core and produce waste gas, makes containing cavity as container collection waste gas, avoids battery bulging.When battery sudden huge profits use causes acupuncture, many current circuits slow down current collection, reduce temperature and raise, the combustion-supporting gases such as air can be stoped to enter, prevent battery spontaneous combustion further, make cell safety reliable when fire retardant matter leaks.Spacer inside is provided with parting bead, by the side wall support of parting bead to spacer both sides, the pressure avoiding spacer to be subject to waste gas causes spacer to be out of shape, parting bead is centered around in spacer in the shape of a spiral, make cavity in spacer in the shape of a spiral, when outer copper foil is pierced, fire retardant matter in spacer leaks, spiral helicine spacer inside can increase the path of fire retardant matter movement, and then control outer discharge, fire retardant matter is slowly flowed out, extend the time that fire retardant matter leaks, and then extend the time intercepting air and enter, after ensureing that metal needle runs through battery completely, still can have fire retardant matter leak out intercept combustion-supporting gas enter, prevent cells burst.The excessive spacer internal volume that easily causes of parting bead thickness is excessively taken, under guarantee spacer internal volume obtains the condition of Appropriate application, parting bead thickness is 2.5 times of spacer thickness, the contact area of parting bead and spacer can be increased, and then strengthen parting bead to the support of spacer, avoid parting bead flexural deformation simultaneously.Parting bead around the number of turns more, the inner volume taken by parting bead of spacer is larger, and under ensureing that spacer internal volume obtains the condition of Appropriate application, the axial distance between adjacent two layers parting bead is 2 times of parting bead thickness, can strengthen the support of parting bead to spacer.Fire retardant matter is used for being subject at battery stoping combustion-supporting gas to enter battery when leaking after the violences such as acupuncture use, and stops the effect of battery spontaneous combustion simultaneously; Low-pressure gas is for reducing the air pressure in containing cavity, the power absorbing waste gas is provided, and a part for volume shared by low-pressure gas is intended for container collection waste gas, the amount of fire retardant matter and the amount of low-pressure gas all have specific function, ratio shared by volume shared by fire retardant matter and low-pressure gas between volume is 1:1, can ensure that battery uses the waste gas produced when 10,000 times can obtain the absorption of containing cavity, and battery is subject to acupuncture when leaking, fire retardant matter slowly can leak all the time and organize cells burst.Low-pressure gas is thin nitrogen; thin nitrogen can reduce the air pressure in containing cavity; be convenient to waste gas and suck; simultaneously nitrogen can be fire-retardant; when battery be subject to acupuncture leak time; nitrogen can be followed fire retardant matter and together be leaked, and stops the combustion-supporting gases such as air to enter battery, prevents battery spontaneous combustion further.Fire retardant matter is sodium-chloride water solution, and sodium-chloride water solution can be attached on metal needle when metal needle passes, and to metal needle cooling, can play effect that is fire-retardant and extinguishing naked light simultaneously.The two ends up and down of coat of metal are provided with unidirectional valve, and no matter anode is at upper or negative pole upper, and no matter fire retardant matter sinks to the bottom still swims in lower, at least ensures have a unidirectional valve not blocked between containing cavity and naked battery core.
Should be understood that this embodiment is only not used in for illustration of the present invention to limit the scope of the invention.In addition should be understood that those skilled in the art can make various changes or modifications the present invention, and these equivalent form of values fall within the application's appended claims limited range equally after the content of having read the present invention's instruction.