CN105462343B - Using beta-cyclodextrin and rare earth β-diketone complex complex composite solution micro-contact printing application - Google Patents

Using beta-cyclodextrin and rare earth β-diketone complex complex composite solution micro-contact printing application Download PDF

Info

Publication number
CN105462343B
CN105462343B CN201510999271.7A CN201510999271A CN105462343B CN 105462343 B CN105462343 B CN 105462343B CN 201510999271 A CN201510999271 A CN 201510999271A CN 105462343 B CN105462343 B CN 105462343B
Authority
CN
China
Prior art keywords
complex
rare earth
beta
cyclodextrin
solution
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201510999271.7A
Other languages
Chinese (zh)
Other versions
CN105462343A (en
Inventor
苏炜
李培源
庞锦英
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhejiang Donghe Printing Packaging Co ltd
Nanning Normal University
Original Assignee
Guangxi Teachers College
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guangxi Teachers College filed Critical Guangxi Teachers College
Priority to CN201510999271.7A priority Critical patent/CN105462343B/en
Publication of CN105462343A publication Critical patent/CN105462343A/en
Application granted granted Critical
Publication of CN105462343B publication Critical patent/CN105462343B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/025—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet
    • B41M5/04—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet using solvent-soluble dyestuffs on the master sheets, e.g. alcohol-soluble
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/14—Printing inks based on carbohydrates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Molecular Biology (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemically Coating (AREA)
  • Polysaccharides And Polysaccharide Derivatives (AREA)

Abstract

The invention discloses it is a kind of using beta cyclodextrin and rare earth β-diketone complex complex composite solution micro-contact printing application, using beta cyclodextrin and rare earth β-diketone complex complex solution as the print paste of micro-contact printing, the pattern of PDMS seals is transferred to the PET substrate of carboxylated, obtain exquisite metal pattern on PET substrate by the method for chemical plating again, by regarding beta cyclodextrin and rare earth β-diketone complex complex composite solution as micro-contact printing ink metal pattern is prepared on the common PET substrate surface of electronics industry, new approaches are provided for micro-contact printing industry.

Description

Using beta-cyclodextrin and rare earth β-diketone complex complex composite solution micro-contact printing application
Technical field
The invention belongs to modern electronic technology field, more particularly to it is a kind of using beta-cyclodextrin and rare earth β-diketone complex complex as Application of the composite green Environment-friendlyink ink in micro-contact printing.
Background technology
The micro- constructing technology in surface is just gradually being embodied in significant application value, especially microcontact printing techniques, can The micro-patterning in small size is of great significance in multiple fields especially modern electronic technology field.It is available at present Micro-contact printing ink it is less, also limited to the material that surface can carry out micro-contact printing, a large amount of material can not be connect with micro- The method for touching printing prepares picture on surface.Ink that is new, stablizing thus is developed to have a very big significance.
In order to adapt to requirement of the ink of new generation for environmental protection and health, it is necessary to which further exploitation cyclodextrin is micro- Application in contact printing.Cyclodextrin is nontoxic, has good human compatibility.Beta-cyclodextrin and rare earth β-diketone complex complex are compound molten Fluidity can be stablized, and quality of forming film is high, and the micro-contact printing of surfaces of various materials can be applied to as a kind of ink of stabilization.Mesh Preceding beta-cyclodextrin and rare earth β-diketone complex complex composite solution have not been reported as the application of micro-contact printing ink.
Invention content
The object of the present invention is to provide a kind of using beta-cyclodextrin and rare earth β-diketone complex complex composite solution in micro-contact printing Application the pattern of PDMS seals is turned using beta-cyclodextrin and rare earth β-diketone complex complex solution as the print paste of micro-contact printing Move to the PET substrate of carboxylated, then by the method for chemical plating in polyethylene terephthalate Exquisite metal pattern is obtained in substrate.
In order to realize purposes and other advantages according to the present invention, provide multiple using beta-cyclodextrin and rare earth β-diketone complex complex Application of the solution in micro-contact printing is closed, including：
Beta-cyclodextrin is obtained the beta-cyclodextrin aqueous solution of a concentration of 3-6g/L by step 1 with water dissolution, and in gained β- Rare earth β-diketone complex complex is added in cyclodextrin aqueous solution, 20KHz ultrasonic vibration 30-60min obtain beta-cyclodextrin and rare earth β-diketone complex cooperation Object composite solution；
PDMS seals are soaked in 30-40s in beta-cyclodextrin and rare earth β-diketone complex complex composite solution, after taking-up by step 2 In N2Dry 30-60s, carboxylated is placed on by the PDMS seals for being coated with beta-cyclodextrin and rare earth β-diketone complex complex composite solution in air-flow PET substrate on, gently press 10-20s, PDMS seal designs be transferred to poly terephthalic acid second two Alcohol ester substrate surface obtains printing figuratum PET substrate；
Step 3 will print figuratum PET substrate and be soaked in 0.1g/L PdCl2In solution 10-30s is put into the solution for electroless copper after taking-up and carries out chemical plating, time 1-10min, by poly terephthalic acid After glycol ester substrate is taken out, you can obtain metal copper pattern on PET substrate.
Preferably, it is described using beta-cyclodextrin and rare earth β-diketone complex complex composite solution micro-contact printing application, The rare earth β-diketone complex complex is that 1- biphenyl -1,3- diacetyl closes dysprosium, and structural formula is as follows：
Preferably, it is described using beta-cyclodextrin and rare earth β-diketone complex complex composite solution micro-contact printing application, Beta-cyclodextrin aqueous solution and the usage ratio of rare earth β-diketone complex complex are in step 1, and 0.8g is added in every liter of beta-cyclodextrin aqueous solution Rare earth β-diketone complex complex.
Preferably, it is described using beta-cyclodextrin and rare earth β-diketone complex complex composite solution micro-contact printing application, It is by the method that PET substrate carries out carboxylated：By PET substrate in 45- 55% isopropanol water solution impregnates 30-60min, then impregnates 15-20min under the conditions of 55-65 DEG C with 2-3mol/L sulfuric acid, 60-65 DEG C of vacuum drying, obtains carboxylated PET substrate.
Preferably, it is described using beta-cyclodextrin and rare earth β-diketone complex complex composite solution micro-contact printing application, In step 3, for electroless copper solution by 4-6wt% copper sulphate, 7wt% potassium sodium tartrates, 6wt% sodium hydroxides, 32wt% formaldehyde and the distilled water of surplus composition.
The present invention includes at least following advantageous effect：
1. normal in electronics industry by regarding beta-cyclodextrin and rare earth β-diketone complex complex composite solution as micro-contact printing ink PET substrate surface prepares metal pattern, and new approaches are provided for micro-contact printing industry.
2. the benzene ring structure containing alkynyl link in rare earth β-diketone complex complex molecule, containing big conjugated system, structural rigidity, together Contain beta-diketon in molecular configurational, combined with rare earth β-diketone complex coordination and obtain stable Dy complexs, is conducive to obtain stable gold Metal patterns.
3. rare earth β-diketone complex complex has very strong magnetism, magnetism of material can be assigned, obtained material is expected to be used for making Energy converter, broadband machinery resonating tube and the high precision liquid fuel injector etc. of standby a new generation's micromation.
4, the hydrophobic cavities of inside " V " font of beta-cyclodextrin are suitble to accommodate 1- biphenyl -1,3- diacetyl conjunction dysprosium molecule Into and be fixed on beta-cyclodextrin intramolecule.
5. beta-cyclodextrin and rare earth β-diketone complex complex composite solution raw material are easy to get, are at low cost, is stable, environmentally protective, in industry There are prodigious potentiality using upper.
Specific implementation mode
The present invention is described in further detail below, to enable those skilled in the art being capable of evidence with reference to specification word To implement.
Using beta-cyclodextrin and rare earth β-diketone complex complex composite solution micro-contact printing application, including：
Step 1, substrate carboxylated soak PET substrate with the isopropanol water solution of 45-55% 30-60min is steeped, then 15-20min is impregnated under the conditions of 55-65 DEG C with 2-3mol/L sulfuric acid, is then washed with water, 60-65 DEG C true Sky is dry, obtains carboxylated PET substrate.
Step 2, prepares beta-cyclodextrin and rare earth β-diketone complex complex composite solution, and beta-cyclodextrin is obtained concentration with water dissolution For the beta-cyclodextrin aqueous solution of 3-6g/L, 0.8g rare earth β-diketone complex complexs, 20kHz ultrasounds are added in every liter of beta-cyclodextrin aqueous solution 30-60min obtains evenly dispersed beta-cyclodextrin and rare earth β-diketone complex complex composite solution, wherein rare earth β-diketone complex complex joins for 1- Benzene -1,3- diacetyl closes dysprosium, and structural formula is as follows：
PDMS seals are soaked in 30- in beta-cyclodextrin and rare earth β-diketone complex complex composite solution by step 3, micro-contact printing 40s, in N after taking-up2Dry 30-60s, will be coated with the PDMS seals of beta-cyclodextrin and rare earth β-diketone complex complex composite solution in air-flow It is placed on carboxylated PET substrate, gently presses 10-20s, PDMS seal designs are transferred to poly- to benzene two Formic acid glycol ester substrate surface obtains printing figuratum PET substrate.
Step 4, chemical plating will print figuratum PET substrate and be soaked in 0.1g/L PdCl2 10-30s in solution is put in after taking-up by 4-6wt% copper sulphate, 7wt% potassium sodium tartrates, 6wt% sodium hydroxides, 32wt% first Chemical plating, time 1-10min are carried out in the chemical bronze plating liquid of aldehyde and the distilled water of surplus composition.It can be poly- to benzene after taking-up Exquisite metal copper pattern is obtained in naphthalate substrate.
Embodiment 1
Using beta-cyclodextrin and rare earth β-diketone complex complex composite solution micro-contact printing application, including：
Step 1, substrate carboxylated impregnate PET substrate with 45% isopropanol water solution 30min, then 15min is impregnated under the conditions of 55 DEG C with 2mol/L sulfuric acid, it then washes with water, 60 DEG C of vacuum drying obtain carboxyl Change PET substrate.
Step 2, prepares beta-cyclodextrin and rare earth β-diketone complex complex composite solution, and beta-cyclodextrin is obtained concentration with water dissolution For the beta-cyclodextrin aqueous solution of 3g/L, 0.8g rare earth β-diketone complex complexs, 20kHz ultrasounds are added in every liter of beta-cyclodextrin aqueous solution 30min obtains evenly dispersed beta-cyclodextrin and rare earth β-diketone complex complex composite solution.
PDMS seals are soaked in beta-cyclodextrin and rare earth β-diketone complex complex composite solution by step 3, micro-contact printing 30s, in N after taking-up2Dry 30s, will be coated with the PDMS seal lids of beta-cyclodextrin and rare earth β-diketone complex complex composite solution in air-flow In on carboxylated PET substrate, 10s is gently pressed, PDMS seal designs are transferred to poly terephthalic acid second Terephthalate substrate surface obtains printing figuratum PET substrate.
Step 4, chemical plating will print figuratum PET substrate and be soaked in 0.1g/L PdCl2 10s in solution, be put in after taking-up by 4wt% copper sulphate, 7wt% potassium sodium tartrates, 6wt% sodium hydroxides, 32wt% formaldehyde and Chemical plating, time 5min are carried out in the chemical bronze plating liquid of 51wt% distilled water composition.It can be in poly terephthalic acid after taking-up Exquisite metal copper pattern is obtained in glycol ester substrate.
Embodiment 2
Using beta-cyclodextrin and rare earth β-diketone complex complex composite solution micro-contact printing application, including：
Step 1, substrate carboxylated impregnate PET substrate with 50% isopropanol water solution 50min, then 20min is impregnated under the conditions of 55-65 DEG C with 2.5mol/L sulfuric acid, it then washes with water, 60 DEG C of vacuum drying obtain Carboxylated PET substrate.
Step 2, prepares beta-cyclodextrin and rare earth β-diketone complex complex composite solution, and beta-cyclodextrin is obtained concentration with water dissolution For the beta-cyclodextrin aqueous solution of 5g/L, 0.8g rare earth β-diketone complex complexs, 20kHz ultrasounds are added in every liter of beta-cyclodextrin aqueous solution 50min obtains evenly dispersed beta-cyclodextrin and rare earth β-diketone complex complex composite solution.
PDMS seals are soaked in beta-cyclodextrin and rare earth β-diketone complex complex composite solution by step 3, micro-contact printing 35s, in N after taking-up2Dry 40s, will be coated with the PDMS seal lids of beta-cyclodextrin and rare earth β-diketone complex complex composite solution in air-flow In on carboxylated PET substrate, 15s is gently pressed, PDMS seal designs are transferred to poly terephthalic acid second Terephthalate substrate surface obtains printing figuratum PET substrate.
Step 4, chemical plating will print figuratum PET substrate and be soaked in 0.1g/L PdCl2 20s in solution, be put in after taking-up by 5wt% copper sulphate, 7wt% potassium sodium tartrates, 6wt% sodium hydroxides, 32wt% formaldehyde and Chemical plating, time 10min are carried out in the chemical bronze plating liquid of 50wt% distilled water composition.It can be in poly terephthalic acid after taking-up Exquisite metal copper pattern is obtained in glycol ester substrate.
Embodiment 3
Using beta-cyclodextrin and rare earth β-diketone complex complex composite solution micro-contact printing application, including：
Step 1, substrate carboxylated impregnate PET substrate with 55% isopropanol water solution 60min, then 20min is impregnated under the conditions of 55-65 DEG C with 3mol/L sulfuric acid, it then washes with water, 65 DEG C of vacuum drying obtain carboxylic Base PET substrate.
Step 2, prepares beta-cyclodextrin and rare earth β-diketone complex complex composite solution, and beta-cyclodextrin is obtained concentration with water dissolution For the beta-cyclodextrin aqueous solution of 6g/L, 0.8g rare earth β-diketone complex complexs, 20kHz ultrasounds are added in every liter of beta-cyclodextrin aqueous solution 60min obtains evenly dispersed beta-cyclodextrin and rare earth β-diketone complex complex composite solution.
PDMS seals are soaked in beta-cyclodextrin and rare earth β-diketone complex complex composite solution by step 3, micro-contact printing 40s, in N after taking-up2Dry 60s, will be coated with the PDMS seal lids of beta-cyclodextrin and rare earth β-diketone complex complex composite solution in air-flow In on carboxylated PET substrate, 20s is gently pressed, PDMS seal designs are transferred to poly terephthalic acid second Terephthalate substrate surface obtains printing figuratum PET substrate.
Step 4, chemical plating will print figuratum PET substrate and be soaked in 0.1g/L PdCl2 30s in solution, be put in after taking-up by 6wt% copper sulphate, 7wt% potassium sodium tartrates, 6wt% sodium hydroxides, 32wt% formaldehyde and Chemical plating, time 10min are carried out in the chemical bronze plating liquid of 49wt% distilled water composition.It can be in poly terephthalic acid after taking-up Exquisite metal copper pattern is obtained in glycol ester substrate.
Embodiment 4
Human normal epidermal cell HaCaT is incubated at Dahl Burke Improved Eagle Medium (DMEM) culture solution (to contain 10% newborn bovine serum) in, set 37 DEG C, 5%CO2Under the conditions of cultivate, 1~2d changes 1 culture solution.When cell growth to logarithmic phase Untreated PET substrate is added respectively, 1,2 and 3 gained of embodiment is printed on the poly- of metal copper pattern Ethylene glycol terephthalate base treatment.Cell is placed in 37 DEG C, 5%CO with 0.25% tryptose, 96 orifice plate2Incubator is trained It supports.After 2~4h, every piece of culture plate is separately added into untreated PET substrate and embodiment 1-3 institutes The cell of PET substrate and complete culture solution culture that metal copper pattern must be printed on are as a control group And experimental group, the culture solution without cell and sample move into 37 DEG C, 5%CO as blank control, by culture plate2Incubator is trained It supports.After for 24 hours, culture solution is abandoned, 2- (2- methoxyl group -4- nitrobenzophenones) -3- (4- are added in phosphate buffer (PBS) board-washing 2 times Nitrobenzophenone) -5- (2,4- disulfonic acid benzene) -2H- tetrazolium list sodium (CCK-8) 10 μ l.Continue in 37 DEG C, 5%CO2Incubator culture Each hole optical density (D values) is surveyed at 2~4h, microplate reader 550nm.Cell survival rate (%)=[(experimental port D values-blank well D values)/ (control wells D values-blank well D values)] × 100%, experimental result is as shown in table 1.
Table 1
As it can be seen from table 1 the cell survival rate of polypropylene substrate of the present invention after electroless copper is apparently higher than not Processed polypropylene substrate illustrates beta-cyclodextrin and rare earth β-diketone complex complex composite solution as micro-contact printing ink biofacies Capacitive is good, and cytotoxicity is low, safe and non-toxic, and harm to the human body is small.
Although the embodiments of the present invention have been disclosed as above, but its is not only in the description and the implementation listed With it can be fully applied to various fields suitable for the present invention, for those skilled in the art, can be easily Realize other modification, therefore without departing from the general concept defined in the claims and the equivalent scope, the present invention is simultaneously unlimited In specific details.

Claims (2)

1. it is a kind of using beta-cyclodextrin and rare earth β-diketone complex complex composite solution micro-contact printing application, which is characterized in that
Beta-cyclodextrin is obtained the beta-cyclodextrin aqueous solution of a concentration of 3-6g/L by step 1 with water dissolution, and in gained β-ring paste Rare earth β-diketone complex complex is added in smart aqueous solution, 20KHz ultrasonic vibration 30-60min, obtain beta-cyclodextrin and rare earth β-diketone complex complex is multiple Close solution；Wherein, the usage ratio of the beta-cyclodextrin aqueous solution and rare earth β-diketone complex complex is, in every liter of beta-cyclodextrin aqueous solution 0.8g rare earth β-diketone complex complexs are added；
PDMS seals are soaked in 30-40s in beta-cyclodextrin and rare earth β-diketone complex complex composite solution, in N after taking-up by step 22Gas The PDMS seals for being coated with beta-cyclodextrin and rare earth β-diketone complex complex composite solution are placed on poly- pair of carboxylated by dry 30-60s in stream In ethylene terephthalate substrate, 10-20s is gently pressed, PDMS seal designs are transferred to polyethylene terephthalate base Bottom surface obtains printing figuratum PET substrate；PET substrate is carried out The method of carboxylated is：Isopropanol water solution by PET substrate in 45-55% impregnates 30-60min, 15-20min is impregnated under the conditions of 55-65 DEG C with 2-3mol/L sulfuric acid again, it is poly- to benzene to obtain carboxylated for 60-65 DEG C of vacuum drying Naphthalate substrate；
Step 3 will print figuratum PET substrate and be soaked in 0.1g/L PdCl210-30s in solution, It is put into after taking-up in the solution for electroless copper and carries out chemical plating, time 1-10min, by polyethylene terephthalate After substrate is taken out, you can obtain metal copper pattern on PET substrate；
Wherein, the rare earth β-diketone complex complex is that 1- biphenyl -1,3- diacetyl closes dysprosium, and structural formula is as follows：
2. the application as described in claim 1 for utilizing beta-cyclodextrin and rare earth β-diketone complex complex composite solution in micro-contact printing, It is characterized in that, in step 3, the solution for electroless copper is by 4-6wt% copper sulphate, 7wt% potassium sodium tartrates, 6wt% hydrogen The distilled water of sodium oxide molybdena, 32wt% formaldehyde and surplus forms.
CN201510999271.7A 2015-12-28 2015-12-28 Using beta-cyclodextrin and rare earth β-diketone complex complex composite solution micro-contact printing application Active CN105462343B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510999271.7A CN105462343B (en) 2015-12-28 2015-12-28 Using beta-cyclodextrin and rare earth β-diketone complex complex composite solution micro-contact printing application

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510999271.7A CN105462343B (en) 2015-12-28 2015-12-28 Using beta-cyclodextrin and rare earth β-diketone complex complex composite solution micro-contact printing application

Publications (2)

Publication Number Publication Date
CN105462343A CN105462343A (en) 2016-04-06
CN105462343B true CN105462343B (en) 2018-09-21

Family

ID=55600523

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201510999271.7A Active CN105462343B (en) 2015-12-28 2015-12-28 Using beta-cyclodextrin and rare earth β-diketone complex complex composite solution micro-contact printing application

Country Status (1)

Country Link
CN (1) CN105462343B (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20050034776A (en) * 2003-10-07 2005-04-15 도레이새한 주식회사 Highly antistatic polyester shaped film
CN102477167A (en) * 2010-11-22 2012-05-30 大连创达技术交易市场有限公司 Application of organic polymer material complex used as light stabilizer
CN104387835A (en) * 2014-11-05 2015-03-04 广西师范学院 Water-soluble double-sandwich-type La metalloporphyrin complex and application thereof in micro-contact printing technique
CN104447820A (en) * 2014-11-05 2015-03-25 广西师范学院 Water-soluble double-layer sandwich-type Ce metalloporphyrin complex and application of complex in microcontact printing technique

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20050034776A (en) * 2003-10-07 2005-04-15 도레이새한 주식회사 Highly antistatic polyester shaped film
CN102477167A (en) * 2010-11-22 2012-05-30 大连创达技术交易市场有限公司 Application of organic polymer material complex used as light stabilizer
CN104387835A (en) * 2014-11-05 2015-03-04 广西师范学院 Water-soluble double-sandwich-type La metalloporphyrin complex and application thereof in micro-contact printing technique
CN104447820A (en) * 2014-11-05 2015-03-25 广西师范学院 Water-soluble double-layer sandwich-type Ce metalloporphyrin complex and application of complex in microcontact printing technique

Also Published As

Publication number Publication date
CN105462343A (en) 2016-04-06

Similar Documents

Publication Publication Date Title
Liu et al. Cellulose nanopaper: fabrication, functionalization, and applications
CN102582146B (en) Composite material with magnesium alloy as base body and manufacturing method thereof
CN104387835A (en) Water-soluble double-sandwich-type La metalloporphyrin complex and application thereof in micro-contact printing technique
CN106847589A (en) A kind of production technology of the plastic press key with stealthy character effect
CN104119723B (en) The application of double-deck sandwich type Eu metal phthalocyanine complex in micro-contact printing
CN105462343B (en) Using beta-cyclodextrin and rare earth β-diketone complex complex composite solution micro-contact printing application
CN104191803A (en) Preparation method of graphene/substrate composite conducting material
CN105504958B (en) Using gamma-cyclodextrin and rare earth β-diketone complex complex composite solution micro-contact printing application
CN105462339B (en) Using beta-cyclodextrin and rare earth Tb complexs composite solution micro-contact printing application
CN105647279B (en) Using beta-cyclodextrin and nitro ferrocene composite solution micro-contact printing application
CN105504983B (en) Utilize gamma-cyclodextrin and anilinomethyl two（Ferrocene）Application of the composite solution in micro-contact printing
CN105462342B (en) Gamma-cyclodextrin and rare earth Tb complexs and its application in microcontact printing techniques
CN103588883A (en) Manufacturing method for modified cellulose membrane material based on ionic liquid
CN105504957B (en) Application using alpha-cyclodextrin and ferrocene as compound ink in micro-contact printing
CN104312263B (en) A kind of 1,4-porphyrin palladium-diacetylene is as the application of micro-contact printing ink
CN105504982B (en) Beta-cyclodextrin and tertiary fourth oxygen acetyl group ruthenium compound and its application in microcontact printing techniques
CN105542563B (en) Gamma-cyclodextrin and binuclear organometallic ruthenium compound and its application in microcontact printing techniques
CN105504959B (en) Beta-cyclodextrin and carboxymethyl ruthenium compound and its application in microcontact printing techniques
CN112723855B (en) Laser engraving preparation method and application of graphene-ceramic composite electrode array
CN105504960B (en) Beta-cyclodextrin and ruthenium complex and its application in microcontact printing techniques
CN109096946B (en) Graphene oxide aqueous adhesive and preparation method thereof
CN110935333A (en) Bacterial cellulose-polyoxyethylene-polyoxypropylene-polyoxyethylene block copolymer composite membrane and preparation method thereof
CN105462340B (en) Gamma-cyclodextrin and ruthenium complex and its application in microcontact printing techniques
CN105462338B (en) Alpha-cyclodextrin and gold complex and its application in microcontact printing techniques
CN110917881A (en) Preparation method of bipolar membrane

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
CP01 Change in the name or title of a patent holder

Address after: Mingxiu Road East of Nanning city the Guangxi Zhuang Autonomous Region 530001 Guangxi Teachers Education University No. 175

Patentee after: NANNING NORMAL University

Address before: Mingxiu Road East of Nanning city the Guangxi Zhuang Autonomous Region 530001 Guangxi Teachers Education University No. 175

Patentee before: Guangxi Normal University

CP01 Change in the name or title of a patent holder
TR01 Transfer of patent right

Effective date of registration: 20191011

Address after: 314500 Building 1, Chongfu Industrial Zone, Tongxiang City, Jiaxing City, Zhejiang Province

Patentee after: ZHEJIANG DONGHE PRINTING PACKAGING Co.,Ltd.

Address before: Mingxiu Road East of Nanning city the Guangxi Zhuang Autonomous Region 530001 Guangxi Teachers Education University No. 175

Patentee before: Nanning Normal University

TR01 Transfer of patent right