CN104312263B - A kind of 1,4-porphyrin palladium-diacetylene is as the application of micro-contact printing ink - Google Patents
A kind of 1,4-porphyrin palladium-diacetylene is as the application of micro-contact printing ink Download PDFInfo
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- CN104312263B CN104312263B CN201410619962.5A CN201410619962A CN104312263B CN 104312263 B CN104312263 B CN 104312263B CN 201410619962 A CN201410619962 A CN 201410619962A CN 104312263 B CN104312263 B CN 104312263B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M3/00—Printing processes to produce particular kinds of printed work, e.g. patterns
- B41M3/001—Printing processes to produce particular kinds of printed work, e.g. patterns using chemical colour-formers or chemical reactions, e.g. leuco dyes or acids
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/1601—Process or apparatus
- C23C18/1603—Process or apparatus coating on selected surface areas
- C23C18/1607—Process or apparatus coating on selected surface areas by direct patterning
- C23C18/1608—Process or apparatus coating on selected surface areas by direct patterning from pretreatment step, i.e. selective pre-treatment
Abstract
The invention discloses a kind of 1,4-porphyrin palladium-diacetylene is as the application of micro-contact printing ink, first substrate is carried out pretreatment, prepares Isosorbide-5-Nitrae-porphyrin palladium-diacetylene organic solution, polydimethylsiloxane seal is soaked in 1, in 4-porphyrin palladium-diacetylene organic solution, then polydimethylsiloxane seal is placed in pretreated substrate, thus substrate surface then obtains the pattern on seal, it is soaked in chemical plating fluid in substrate, metal pattern can be obtained。The inventive method letter is answered, it is easy to operation, and by the substrate surface that electron trade is conventional prepared by Isosorbide-5-Nitrae-porphyrin palladium-diacetylene organic solution metal pattern as micro-contact printing ink, provides new approaches for micro-contact printing industry。
Description
Technical field
The invention belongs to modern electronic technology field, particularly to the application as micro-contact printing ink of a kind of Isosorbide-5-Nitrae-porphyrin palladium-diacetylene。
Background technology
The micro-constructing technology in surface embodies in significant application value just gradually, particularly microcontact printing techniques, its can in small size micro-patterning, in multiple fields, particularly modern electronic technology field is significant。Current alternative micro-contact printing ink is less, has also limited to surface and can carry out the material of micro-contact printing, and substantial amounts of material cannot prepare picture on surface by the method for micro-contact printing。Thus develop new, stable ink and have a very big significance。
Disclosed in patent CN102516841B, eight (pungent alkoxyl)-Phthalocyanine Zinc carries out the application technology of micro-contact printing as ink at polyethylene terephthalate, PEN or polyimide substrate；Water miscible 5,10,15,20-tetra-4-(3 '-propoxyl group pyridine Bromide) phenyl disclosed in patent CN102964909B] zinc porphyrin carries out the application technology in micro-contact printing in polyethylene terephthalate substrate；Disclosed in patent CN102964910B, water miscible 5,10,15,20-tetrasulfonic acid sodium phenyl zinc porphyrins carry out the application technology of micro-contact printing at polyimide substrate。For promoting micro-contact printing quality further, the selectivity of abundant micro-contact printing ink and substrate, the application in micro-contact printing of applicant's development of metallic metalloporphyrin complex。
In micro-contact printing, chemical plating is to prepare the important step of fine metal pattern, and being typically in this step needs to add the catalyst such as Palladous chloride. and stannic chloride so that chemical plating becomes spontaneous reaction process, and otherwise chemical plating cannot be carried out。For Simplified flowsheet, reduce problems such as introducing ink expansions, diffusion that catalyst process is likely to bring, it is thus achieved that finer metal pattern, develop a kind of micro-contact printing ink plating process with catalytic action newly necessary。
Summary of the invention
It is an object of the invention to provide a kind of 1,4-porphyrin palladium-diacetylene is as the application of micro-contact printing ink, 1,4-porphyrin palladium-diacetylene carries out micro-contact printing as a kind of new ink in substrate, obtain exquisite pattern, simplify technique, avoid the introducing of catalyst simultaneously and cause printing ink to expand, the problem of diffusion, substantially increase micro-contact printing quality, the selection of abundant micro-contact printing ink and substrate。
Present invention provide the technical scheme that
Isosorbide-5-Nitrae-porphyrin palladium-diacetylene organic solution, as the application of micro-contact printing ink, is coated on the figuratum seal of tool, is developed after being then needed on substrate by a kind of Isosorbide-5-Nitrae-porphyrin palladium-diacetylene, has both obtained transferred pattern。
Preferably, in described Isosorbide-5-Nitrae-porphyrin palladium-diacetylene application as micro-contact printing ink, described substrate one in politef, polyethylene terephthalate substrate or polyimides。
Preferably, in described Isosorbide-5-Nitrae-porphyrin palladium-diacetylene application as micro-contact printing ink, the following structural features of described Isosorbide-5-Nitrae-porphyrin palladium-diacetylene:
Preferably, in described Isosorbide-5-Nitrae-porphyrin palladium-diacetylene application as micro-contact printing ink, further comprising the steps of:
Step one, 80-150g is immersed in 1-3% silane coupler 20-30 hour, takes out, with 60-75% alcoholic solution, substrate is carried out, dry；Substrate is put into addition solution one in container, reacts 1-3 hour at 80-100 DEG C, obtain the substrate of pretreatment；
Step 2, the Isosorbide-5-Nitrae-porphyrin palladium-diacetylene taking 1-10g are dissolved in 50-100ml organic solvent, obtain Isosorbide-5-Nitrae-porphyrin palladium-diacetylene organic solution that concentration is 1-10g/L；
Step 3, polydimethylsiloxane seal is soaked in 1,30-40s in 4-porphyrin palladium-diacetylene organic solution, dry, obtain scribbling 1, the polydimethylsiloxane seal of 4-porphyrin palladium-diacetylene two organic solution, and described seal is placed in pretreated substrate, gently press 10-20s, polydimethylsiloxane seal designs is transferred to substrate surface, obtains printing figuratum substrate；
Figuratum for print substrate, for metal pattern, is put in chemical plating fluid by step 4, chemically plating, takes out after 1-10min, can obtain the metal pattern of transfer in substrate。
Preferably, in described Isosorbide-5-Nitrae-porphyrin palladium-diacetylene application as micro-contact printing ink, described in, the following structural features of 4-porphyrin palladium-diacetylene:
Preferably, in described Isosorbide-5-Nitrae-porphyrin palladium-diacetylene application as micro-contact printing ink, before step one soaks substrate, first the EtOH Sonicate of substrate 60-75% is cleaned 0.5-1.5 hour, take out, 80-100 DEG C of vacuum drying。
Preferably, in described Isosorbide-5-Nitrae-porphyrin palladium-diacetylene application as micro-contact printing ink, silane coupler described in step one is vinyl three ('beta '-methoxy ethyoxyl) solution of silane or butadienyl triethoxysilane solution。
Preferably, in described Isosorbide-5-Nitrae-porphyrin palladium-diacetylene application as micro-contact printing ink, the preparation of solution one described in step one is for be dissolved in 1-3g methacrylic acid and 0.05-0.2g azodiisobutyronitrile in 500-600ml distilled water。
Preferably, in described Isosorbide-5-Nitrae-porphyrin palladium-diacetylene application as micro-contact printing ink, organic solvent described in step 2 is dichloromethane solution or dimethyl sulphoxide solution。
Preferably, in described Isosorbide-5-Nitrae-porphyrin palladium-diacetylene application as micro-contact printing ink, dry described in step 3 for by be soaked in Isosorbide-5-Nitrae-porphyrin palladium-diacetylene dichloromethane solution polydimethylsiloxane seal take out after in N2Dry 30-60s in air-flow。
Preferably, in described Isosorbide-5-Nitrae-porphyrin palladium-diacetylene application as micro-contact printing ink, the one in chemical bronze plating liquid, chemical plating liquid or chemical nickel-plating liquid of the chemical plating fluid described in step 4。
The invention has the beneficial effects as follows: Isosorbide-5-Nitrae-porphyrin palladium-diacetylene organic solution as micro-contact printing ink, substrate surface conventional in electron trade is prepared metal pattern, is provided new approaches for micro-contact printing industry by the present invention；Introducing polyacrylic acid by silane coupler in the present invention, this method of modifying is to carry out at substrate surface, does not affect the chemical constitution of substrate, is therefore more conducive to the performance of protection substrate compared with the method that hydrolysis obtains carboxyl；The method of the present invention is simple simultaneously, and easy and simple to handle, Isosorbide-5-Nitrae-porphyrin palladium-diacetylene organic solution raw material is easy to get, cost is low and effect stability, has very big potentiality in commercial Application。
Detailed description of the invention
The present invention is described in further detail below, to make those skilled in the art can implement according to this with reference to description word。
Isosorbide-5-Nitrae-porphyrin palladium-diacetylene organic solution, as the application of micro-contact printing ink, is coated on the figuratum seal of tool, is developed after being then needed on substrate by a kind of Isosorbide-5-Nitrae-porphyrin palladium-diacetylene, has both obtained transferred pattern。
Preferably, in described Isosorbide-5-Nitrae-porphyrin palladium-diacetylene application as micro-contact printing ink, described substrate one in politef, polyethylene terephthalate substrate or polyimides。
Preferably, in described Isosorbide-5-Nitrae-porphyrin palladium-diacetylene application as micro-contact printing ink, the following structural features of described Isosorbide-5-Nitrae-porphyrin palladium-diacetylene:
Preferably, in described Isosorbide-5-Nitrae-porphyrin palladium-diacetylene application as micro-contact printing ink, further comprising the steps of:
Step one, first the EtOH Sonicate of 80-150g substrate 60-75% is cleaned 0.5-1.5 hour, take out, dry when 80-100 DEG C of vacuum is 0.2-0.5MPa, substrate is immersed in 1-3% silane coupler 20-30 hour, take out, clean with 60-75% alcoholic solution, dry when 80-100 DEG C of 0.1MPa；Then putting in container by substrate, add solution one, described solution one is for be dissolved in 500-600ml distilled water, by 1-3g methacrylic acid and 0.05-0.2g azodiisobutyronitrile, the solution obtained, and at 80-100 DEG C, reaction 1-3 hour, obtains the substrate of pretreatment；Act on politef substrate surface by the chemical bonding of silane coupler and introduce acrylate copolymer, compared with the carboxylated surface obtained by hydrolysis, its a large amount of carboxyls having can adsorb in conjunction with more 1,4-porphyrin palladium-diacetylene, there is provided higher catalytic action for next step chemical plating, obtain combining more close metallic circuit；And by changing the parameter of polyreaction, it is possible to adjust the acrylic acid units quantity introduced, therefore can according to product requirements, parameter be adjusted easily。
Step 2, the Isosorbide-5-Nitrae-porphyrin palladium-diacetylene taking 1-10g are dissolved in 50-100ml organic solvent, obtain Isosorbide-5-Nitrae-porphyrin palladium-diacetylene two organic solution that concentration is 1-10g/L；Relative to single metalloporphyrin complex, Isosorbide-5-Nitrae-porphyrin palladium-diacetylene has some special natures, the diacetylene of two metalloporphyrin complexes in its structure and a bridge linking effect is all at grade, forming bigger conjugated system, its pi-pi bond effect is higher, so have very strong stability when film forming；The site simultaneously can reacted is more, it is possible to introduces new group as required and regulates its physical and chemical performance。
Step 3, polydimethylsiloxane seal is soaked in 30-40s in Isosorbide-5-Nitrae-porphyrin palladium-diacetylene organic solution, in N after taking-up2In air-flow, dry 30-60s, obtains scribbling the polydimethylsiloxane seal of Isosorbide-5-Nitrae-porphyrin palladium-diacetylene organic solution, and described seal is placed in pretreated substrate, gently press 10-20s, polydimethylsiloxane seal designs is transferred to substrate surface, obtain printing figuratum substrate；
Figuratum for print substrate, for metal pattern, is put in chemical plating fluid by step 4, chemically plating, takes out after 1-10min, can obtain the metal pattern of transfer in substrate。
In described Isosorbide-5-Nitrae-porphyrin palladium-diacetylene application as micro-contact printing ink, silane coupler described in step one is vinyl three ('beta '-methoxy ethyoxyl) solution of silane or butadienyl triethoxysilane solution。
Preferably, in described Isosorbide-5-Nitrae-porphyrin palladium-diacetylene application as micro-contact printing ink, organic solvent described in step 2 is dichloromethane solution or dimethyl sulphoxide solution。
In described Isosorbide-5-Nitrae-porphyrin palladium-diacetylene application as micro-contact printing ink, the one in chemical bronze plating liquid, chemical plating liquid or chemical nickel-plating liquid of the chemical plating fluid described in step 4。Wherein, described chemical bronze plating liquid is prepared by 4-6wt% copper sulfate, 6-8wt% sodium potassium tartrate tetrahydrate, 5-7wt% sodium hydroxide, 30-33wt% formaldehyde and 46-55wt% distilled water；Described chemical plating liquid is prepared by 5-7wt% Silver monobromide, 20-28wt% Ammonium hyposulfite., 3-4wt% ammonium acetate, 7-9wt% sodium sulfite and 52-65wt% distilled water；Chemical nickel-plating liquid is prepared by 4-8wt% nickel sulfate, 4-8wt% sodium hypophosphite, 30-35wt% citric acid and 49-51wt% distilled water。
Embodiment 1
A kind of Isosorbide-5-Nitrae-porphyrin palladium-diacetylene, as the application of micro-contact printing ink, comprises the following steps:
Step one, first by 80g politef substrate with 75% EtOH Sonicate clean 1 hour, take out, dry when 80 DEG C of vacuums are 0.2MPa, politef substrate is immersed in 1% vinyl three ('beta '-methoxy ethyoxyl) solution of silane 30 hours, take out, clean with 75% alcoholic solution, dry when 80 DEG C of 0.1MPa；Then putting in container by politef substrate, add solution one, described solution one is for be dissolved in 500m1 distilled water, by 1g methacrylic acid and 0.1g azodiisobutyronitrile, the solution obtained, and at 80 DEG C, reaction 3 hours, obtain the politef substrate of pretreatment；
Step 2, the Isosorbide-5-Nitrae-porphyrin palladium-diacetylene taking 1-10g are dissolved in 50-100ml dichloromethane solution, obtain Isosorbide-5-Nitrae-porphyrin palladium-diacetylene dichloromethane solution that concentration is 1-10g/L；
Step 3, polydimethylsiloxane seal is soaked in 40s in Isosorbide-5-Nitrae-porphyrin palladium-diacetylene dichloromethane solution, in N after taking-up2Dry 40s in air-flow, obtain scribbling 1, the polydimethylsiloxane seal of 4-porphyrin palladium-diacetylene dichloromethane solution, and described seal is placed in pretreated politef substrate, gently press 20s, polydimethylsiloxane seal designs is transferred to politef substrate surface, obtains printing figuratum politef substrate；
Step 4, chemically plating are for metallic copper pattern, being put in chemical bronze plating liquid by figuratum for print politef substrate, described chemical bronze plating liquid is prepared by the distilled water of 6wt% copper-bath, 7wt% potassium sodium tartrate solution, 6wt% sodium hydroxide solution, 31wt% formalin and surplus；Take out politef substrate after 5min, metallic copper pattern can be obtained in politef substrate。
Embodiment 2
A kind of Isosorbide-5-Nitrae-porphyrin palladium-diacetylene, as the application of micro-contact printing ink, comprises the following steps:
Step one, first by 100g polyethylene terephthalate substrate with 75% EtOH Sonicate clean 1 hour, take out, dry when 80 DEG C of vacuums are 0.1MPa, polyethylene terephthalate substrate is immersed in 1% vinyl three ('beta '-methoxy ethyoxyl) solution of silane 24 hours, take out, clean with 75% alcoholic solution, dry when 80 DEG C of vacuums are 0.1MPa；Then polyethylene terephthalate substrate is put in container, add solution one, described solution one is that 1.5g methacrylic acid and 0.1g azodiisobutyronitrile are dissolved in 500ml distilled water the solution prepared, react 1 hour at 80 DEG C, obtain the polyethylene terephthalate substrate of pretreatment；
Step 2, the Isosorbide-5-Nitrae-porphyrin palladium-diacetylene taking 10g are dissolved in 100ml dichloromethane solution, obtain Isosorbide-5-Nitrae-porphyrin palladium-diacetylene dichloromethane solution that concentration is 10g/L；
Step 3, polydimethylsiloxane seal is soaked in 40s in Isosorbide-5-Nitrae-porphyrin palladium-diacetylene dichloromethane solution, in N after taking-up2Dry 60s in air-flow, obtain scribbling 1, the polydimethylsiloxane seal of 4-porphyrin palladium-diacetylene dichloromethane solution, and described seal is placed in pretreated polyethylene terephthalate substrate, gently press 20s, polydimethylsiloxane seal designs is transferred to polyethylene terephthalate substrate surface, obtains printing figuratum polyethylene terephthalate substrate；
Step 4, chemically plating are for argent pattern, being put in chemical nickel-plating liquid by figuratum for print polyethylene terephthalate substrate, described chemical plating liquid is prepared by 6wt% Silver monobromide, 25wt% Ammonium hyposulfite., 3wt% ammonium acetate, 8wt% sodium sulfite and 60wt% distilled water；Take out polyethylene terephthalate substrate after 8min, argent pattern can be obtained in polyethylene terephthalate substrate。
Embodiment 3
A kind of Isosorbide-5-Nitrae-porphyrin palladium-diacetylene, as the application of micro-contact printing ink, comprises the following steps:
Step one, first by 150g polyimide substrate with 65% EtOH Sonicate clean 1.5 hours, take out, dry when 100 DEG C of vacuums are 0.4MPa, polyimide substrate is immersed in 2% butadienyl triethoxysilane solution 30 hours, take out, clean with 65% alcoholic solution, dry when 90 DEG C of vacuums are 0.1MPa；Then putting in container by polyimide substrate, add solution one, described solution one is for be dissolved in 600ml distilled water, by 2g methacrylic acid and 0.2g azodiisobutyronitrile, the solution obtained, and at 90 DEG C, reaction 2 hours, obtain the polyimide substrate of pretreatment；
Step 2, the Isosorbide-5-Nitrae-porphyrin palladium-diacetylene taking 5g are dissolved in 80ml dimethyl sulphoxide solution, obtain Isosorbide-5-Nitrae-porphyrin palladium-diacetylene dimethyl sulphoxide solution that concentration is 5g/L；
Step 3, polydimethylsiloxane seal is soaked in 35s in Isosorbide-5-Nitrae-porphyrin palladium-diacetylene dimethyl sulphoxide solution, in N after taking-up2Dry 50s in air-flow, obtain scribbling 1, the polydimethylsiloxane seal of 4-porphyrin palladium-diacetylene dimethyl sulphoxide solution, and described seal is placed on pretreated polyimide substrate, gently press 15s, polydimethylsiloxane seal designs is transferred to poly-polyimide-based basal surface, obtains printing figuratum polyimide substrate；
Figuratum for print politef substrate, for metallic nickel pattern, is put in chemical bronze plating liquid by step 4, chemically plating, and chemical nickel-plating liquid is prepared by 7wt% nickel sulfate, 8wt% sodium hypophosphite, 35wt% citric acid and 50wt% distilled water；Take out politef substrate after 10min, metallic nickel pattern can be obtained on polyimide substrate。
Preparation method of the present invention is simple, easy and simple to handle, reduces cost, provides a kind of novel ink for microcontact printing techniques, expands the use scope of microcontact printing techniques, have very big potentiality in commercial Application。
Although embodiment of the present invention are disclosed as above, but listed utilization that it is not restricted in description and embodiment, it can be applied to various applicable the field of the invention completely, for those skilled in the art, it is easily achieved other amendment, therefore, under the general concept limited without departing substantially from claim and equivalency range, the present invention is not limited to specific details。
Claims (9)
1. 4-porphyrin palladium-diacetylene is as the application of micro-contact printing ink, it is characterised in that Isosorbide-5-Nitrae-porphyrin palladium-diacetylene organic solution is coated on the figuratum seal of tool, develops after being then needed on substrate, both transferred pattern。
2. Isosorbide-5-Nitrae-porphyrin palladium-diacetylene as claimed in claim 1 is as the application of micro-contact printing ink, it is characterised in that described substrate one in politef, polyethylene terephthalate substrate or polyimides。
3. Isosorbide-5-Nitrae-porphyrin palladium-diacetylene as claimed in claim 1 is as the application of micro-contact printing ink, it is characterised in that the following structural features of described Isosorbide-5-Nitrae-porphyrin palladium-diacetylene:
4. Isosorbide-5-Nitrae-porphyrin palladium-diacetylene as claimed in claim 3 is as the application of micro-contact printing ink, it is characterised in that further comprising the steps of:
Step one, the substrate of 80-150g is immersed in 1-3% silane coupler 20-30 hour, takes out, with 60-75% alcoholic solution, substrate is carried out, dry；Substrate is put into addition solution one in container, and the preparation of described solution one, for be dissolved in 500-600ml distilled water by 1-3g methacrylic acid and 0.05-0.2g azodiisobutyronitrile, is reacted 1-3 hour at 80-100 DEG C, is obtained the substrate of pretreatment；
Step 2, the Isosorbide-5-Nitrae-porphyrin palladium-diacetylene taking 1-10g are dissolved in 50-100ml organic solvent, obtain Isosorbide-5-Nitrae-porphyrin palladium-diacetylene organic solution that concentration is 1-10g/L；
Step 3, polydimethylsiloxane seal is soaked in 1,30-40s in 4-porphyrin palladium-diacetylene organic solution, dry, obtain scribbling 1, the polydimethylsiloxane seal of 4-porphyrin palladium-diacetylene organic solution, and described seal is placed in pretreated substrate, gently press 10-20s, polydimethylsiloxane seal designs is transferred to substrate surface, obtains printing figuratum substrate；
Figuratum for print substrate, for metal pattern, is put in chemical plating fluid by step 4, chemically plating, takes out after 1-10min, can obtain the metal pattern of transfer in substrate。
5. Isosorbide-5-Nitrae-porphyrin palladium-diacetylene as claimed in claim 4 is as the application of micro-contact printing ink, it is characterised in that before soaking substrate in step one, first by clear for the EtOH Sonicate of substrate 60-75% 0.5-1.5 hour, takes out, 80-100 DEG C of vacuum drying。
6. as claimed in claim 41,4-porphyrin palladium-diacetylene is as the application of micro-contact printing ink, it is characterized in that, silane coupler described in step one is vinyl three ('beta '-methoxy ethyoxyl) solution of silane or butadienyl triethoxysilane solution。
7. Isosorbide-5-Nitrae-porphyrin palladium-diacetylene as claimed in claim 4 is as the application of micro-contact printing ink, it is characterised in that organic solvent described in step 2 is dichloromethane solution or dimethyl sulphoxide solution。
8. Isosorbide-5-Nitrae-porphyrin palladium-diacetylene as claimed in claim 4 is as the application of micro-contact printing ink, it is characterised in that dry described in step 3 for after the polydimethylsiloxane seal being soaked in Isosorbide-5-Nitrae-porphyrin palladium-diacetylene organic solution is taken out in N2Dry 30-60s in air-flow。
9. Isosorbide-5-Nitrae-porphyrin palladium-diacetylene as claimed in claim 4 is as the application of micro-contact printing ink, it is characterised in that the one in chemical bronze plating liquid, chemical plating liquid or chemical nickel-plating liquid of the chemical plating fluid described in step 4。
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| CN105440044B (en) * | 2015-12-22 | 2018-07-17 | 南京邮电大学 | The preparation method and application of different structure frame metal porphyrin metal complex |
| CN110964179B (en) * | 2019-12-19 | 2022-06-21 | 湘潭大学 | Porphyrin polymer, preparation method thereof and application thereof in positive electrode material |
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| CN102516841A (en) * | 2011-11-21 | 2012-06-27 | 广西师范学院 | Application of zinc phthalocyanine complex as ink in micro-contact printing |
| CN102964909A (en) * | 2012-11-30 | 2013-03-13 | 广西师范学院 | Method for applying water-soluble zinc porphyrin complex to microcontact printing |
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