CN105462289A - A coloring agent not liable to fade and used for scientific education - Google Patents
A coloring agent not liable to fade and used for scientific education Download PDFInfo
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- CN105462289A CN105462289A CN201510803668.4A CN201510803668A CN105462289A CN 105462289 A CN105462289 A CN 105462289A CN 201510803668 A CN201510803668 A CN 201510803668A CN 105462289 A CN105462289 A CN 105462289A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
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- Organic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Paints Or Removers (AREA)
Abstract
The invention relates to the field of scientific education office supplies and discloses a coloring agent not liable to fade and used for scientific education. The coloring agent is characterized by comprising 5-20 parts by mass of methanol, 7-10 parts by mass of ethanol, 6-12 parts by mass of acetonitrile, 9-15 parts by mass of acetic acid, 8-12 parts by mass of dimethylsulfoxide, 6-10 parts by mass of N,N-dimethylformamide, 11-20 parts by mass of isopropanol, 7-21 parts by mass of cyclohexane, 9-22 parts by mass of concentrated nitric acid, 2-11 parts by mass of hydrogen peroxide, 13-22 parts by mass of ethylene glycol monomethyl ether, 2-19 parts by mass of phenolphthalein, 1-5 parts by mass of a thickening agent, 2-6 parts by mass of white oil, 3-9 parts by mass of glycerol, 11-40 parts by mass of water, 2-8 parts by mass of silicon dioxide, 5-26 parts by mass of edible alcohol, 3-12 parts by mass of sodium hydroxide, 1-20 parts by mass of a coloring stabilizer, 2-25 parts by mass of a stabilizer, 7-22 parts by mass of a corrosion inhibitor, 5-19 parts by mass of a wetting agent, 3-20 parts by mass of an antiseptic, 2-6 parts by mass of fast green, 2-5 parts by mass of glue, 2-6 parts by mass of fast green and 3-9 parts by mass of methylene blue. The coloring agent is durable, clean, sanitary, environmental friendly, free of pollution to air, cheap in raw materials, and capable of saving the cost when being used for printing and coating. By different proportions of the phenolphthalein, the edible alcohol, and other components, the coloring agent can be prepared into red, blue, purple, and the like. In addition, the phenolphthalein, the edible alcohol, and other components are free of harm to human bodies, healthy and environmental friendly, thus ensuring physical and psychological health of readers.
Description
Technical field
The present invention relates to education of science office appliance field, particularly a kind of staining agent of not fugitive color education of science.
Background technology
Staining agent is the correction with writing tools of writing books, and from the chemical property of its raw material, can be divided into blue-black staining agent and colors staining agent.Blue-black staining agent, also known as Tannic acids, iron salts staining agent, does not take off composition, pigment composition, stablizer, resist, wetting agent and sanitas etc. lastingly by blackening and forms.The composition mainly composition chemical combination each other such as tannic acid, gallic acid and ferrous sulfate is not taken off in blackening lastingly, generate tannic acid ferrous iron and gallic acid ferrous iron, insoluble high price iron is all become after oxidation, i.e. Tannic acids, iron salts and gallic acid iron, the former strengthens water tolerance, the latter strengthens blackening, makes that staining agent is water-fast, blackening like this, and look does not take off lastingly.And pigment composition conventional be at present the blue and direct acid blue dyestuff of acid stain, staining agent indigo plant is the mass-tone of staining agent, and the acid of its aqueous solution chance is never degenerated, but chance alkali then becomes brown.Direct acid blue plays and helps look effect in staining agent, due to wherein impure more, unsuitable multiplex, at the easy mildew of wet environment.In staining agent, add the object of stablizer, mainly eliminate the precipitation of staining agent, in order to avoid phenomenon of cutting off the water supply when writing.Conventional stablizer has sulfuric acid, oxalic acid, formaldehyde solution.These stablizers all have certain acidity, have buried potential harm to paper acidifying, unsuitable multiplex.Because the stablizer added in staining agent has comparatively strongly-acid, for preventing corrosion, often adding resist, making it and irony form film, reducing the corrosive nature 90% of sulfuric acid.Iron-holder in staining agent can not be increased because of corrosion nib, thus add the stability of staining agent.As can be seen here, staining agent of the prior art, one of its primary efficacy is that will to reach the person's handwriting sprayed out colour-fast lastingly, thus adds blackening and does not take off composition lastingly; The pigment composition added in addition, its main component is staining agent indigo plant or direct acid blue dyestuff, and color is comparatively single, sometimes in order to express needs, needing polychrome and using.Need a kind of novel staining agent of exploitation to meet the demand of numerous clients.
Summary of the invention
The object of the invention is to overcome above-mentioned deficiency existing in prior art, provide a kind of.(for problem existing in prior art, indicating order of the present invention successively)
In order to realize foregoing invention object, the invention provides following technical scheme:
A kind of staining agent of not fugitive color education of science, by mass parts, comprise: 5-20 part methyl alcohol, 7-10 part ethanol, 6-12 part acetonitrile, 9-15 part acetic acid, 8-12 part methyl-sulphoxide, 6-10 part N, dinethylformamide, 11-20 part Virahol, 7-21 part hexanaphthene, 9-22 part concentrated nitric acid, 2-11 part hydrogen peroxide, 13-22 part ethylene glycol monoemethyl ether, 2-19 part phenolphthalein, 1-5 part thickening material, 2-6 part white oil, 3-9 part glycerine, 11-40 part water, 2-8 part silicon-dioxide, 5-26 part edible ethanol, 3-12 part sodium hydroxide, 1-20 part laking agent, 2-25 part stablizer, 7-22 part corrosion inhibitor, 5-19 part wetting agent, 3-20 part sanitas, 2-6 part is fast green, 2-5 part glue, 2-6 part is fast green, 3-9 part methylenum coeruleum, described laking agent is 10-20 part tannic acid, 15-30 part gallic acid, one or more of 20-39 part ferrous sulfate, by weight percentage, described stablizer is 12-39 part sulfuric acid, 11-41 part oxalic acid, one or more of 10-30 part formaldehyde solution.Writing after glue allows printing spray is more clear more firm, the time that laking agent manifests after spray coating by staining agent is more permanent, the color that stablizer shows by staining agent is more stable, not fugitive color, wetting agent is by staining agent prevented from caking in storage process, erosion resistance makes staining agent not perishable, and the shelf time is more of a specified duration, and sanitas not easily rots by the material in staining agent.
As preferably, by weight percentage, described wetting agent is 6-30 part glycerol.
As preferably, by weight percentage, comprise: 10 parts of methyl alcohol, 12 parts of ethanol, 11 parts of acetonitriles, 14 parts of acetic acid, 13 parts of methyl-sulphoxides, 9 parts of DMFs, 16 parts of Virahols, 12 parts of hexanaphthenes, 14 parts of concentrated nitric acids, 7 parts of hydrogen peroxide, 18 parts of ethylene glycol monoemethyl ethers, 7 parts of phenolphthalein, 4 parts of thickening materials, 5 parts of white oils, 8 parts of glycerine, 16 parts of water, 7 parts of silicon-dioxide, 10 portions of edible ethanols, 8 parts of sodium hydroxide, 6 parts of laking agent, 17 parts of stablizers, 12 portions of corrosion inhibitors, 11 parts of wetting agents, 15 portions of sanitass, 5 parts of glue, 6 parts of fast green, 9 parts of methylenum coeruleum.
As preferably, by weight percentage, comprise: 11 parts of methyl alcohol, 13 parts of ethanol, 12 parts of acetonitriles, 15 parts of acetic acid, 14 parts of methyl-sulphoxides, 12 parts of N, dinethylformamide, 17 parts of Virahols, 13 parts of hexanaphthenes, 15 parts of concentrated nitric acids, 6 parts of hydrogen peroxide, 19 parts of ethylene glycol monoemethyl ethers, 8 parts of phenolphthalein, 5 parts of thickening materials, 6 parts of white oils, 9 parts of glycerine, 30 parts of water, 8 parts of silicon-dioxide, 16 portions of edible ethanols, 12 parts of sodium hydroxide, 13 parts of laking agent, 15 parts of stablizers, 16 portions of corrosion inhibitors, 15 parts of wetting agents, 17 portions of sanitass, 3 parts of glue, 4 parts fast green, 7 parts of methylenum coeruleum.
As preferably, by weight percentage, described laking agent be 13 parts of tannic acids, 18 parts of gallic acids, 38 parts of ferrous sulfate one or more.
As preferably, by weight percentage, described stablizer be 22 parts of sulfuric acid, 32 parts of oxalic acid, 26 parts of formaldehyde solutions one or more.
As preferably, by weight percentage, described wetting agent is 19 parts of glycerol.
As preferably, described thickening material is 5 parts of inorganic thickening agents and/or 6 parts of ether of cellulose.
Compared with prior art, beneficial effect of the present invention: according to composition of the present invention, those skilled in the art are known, add the effect of other compositions, the writing sprayed out is clear, and the composition such as not to take off lastingly containing blackening, during for printing in spraying, lastingly, health clean, environmental protection, not polluted air, the related chemical species in the staining agent in the raw material hinge structure that it uses is more cheap, thus saves production cost; Different by the proportioning of each composition such as phenolphthalein, edible ethanol, can be made into the polychromes such as redness, blueness and purple; Meanwhile, the compositions such as the phenolphthalein used, edible ethanol are all harmless starting material, health environment-friendly more, ensure the physical and mental health of reader.
Embodiment
Below in conjunction with test example and embodiment, the present invention is described in further detail.But this should be interpreted as that the scope of the above-mentioned theme of the present invention is only limitted to following embodiment, all technology realized based on content of the present invention all belong to scope of the present invention.
Embodiment 1
A kind of staining agent of not fugitive color education of science, by mass parts, comprise: 12 parts of methyl alcohol, 15 parts of ethanol, 17 parts of acetonitriles, 12 parts of acetic acid, 11 parts of methyl-sulphoxides, 10 parts of N, dinethylformamide, 15 parts of Virahols, 13 parts of hexanaphthenes, 12 parts of concentrated nitric acids, 6 parts of hydrogen peroxide, 16 parts of ethylene glycol monoemethyl ethers, 7 parts of phenolphthalein, 4 parts of thickening materials, 5 parts of white oils, 8 parts of glycerine, 16 parts of water, 7 parts of silicon-dioxide, 10 portions of edible ethanols, 8 parts of sodium hydroxide, 6 parts of laking agent, 15 parts of stablizers, 12 portions of corrosion inhibitors, 11 parts of wetting agents, 15 portions of sanitass, 4 parts of glue, 5 parts fast green, 8 parts of methylenum coeruleum.
By weight percentage, described laking agent is 12 parts of tannic acids, 17 parts of gallic acids, 39 parts of ferrous sulfate.
By weight percentage, described stablizer is 25 parts of sulfuric acid, 33 parts of oxalic acid, 27 parts of formaldehyde solutions.
By weight percentage, described wetting agent is 19 parts of glycerol.
Described thickening material is 5 parts of inorganic thickening agents and 6 parts of ether of cellulose.
Embodiment 2
A kind of staining agent of not fugitive color education of science, by mass parts, comprise: 10 parts of methyl alcohol, 12 parts of ethanol, 11 parts of acetonitriles, 14 parts of acetic acid, 13 parts of methyl-sulphoxides, 9 parts of N, dinethylformamide, 16 parts of Virahols, 12 parts of hexanaphthenes, 14 parts of concentrated nitric acids, 7 parts of hydrogen peroxide, 18 parts of ethylene glycol monoemethyl ethers, 7 parts of phenolphthalein, 4 parts of thickening materials, 5 parts of white oils, 8 parts of glycerine, 16 parts of water, 7 parts of silicon-dioxide, 10 portions of edible ethanols, 8 parts of sodium hydroxide, 6 parts of laking agent, 17 parts of stablizers, 12 portions of corrosion inhibitors, 11 parts of wetting agents, 15 portions of sanitass, 5 parts of glue, 6 parts fast green, 9 parts of methylenum coeruleum.
By weight percentage, described laking agent is 12 parts of tannic acids, 17 parts of gallic acids, 39 parts of ferrous sulfate.
By weight percentage, described stablizer is 25 parts of sulfuric acid, 33 parts of oxalic acid, 27 parts of formaldehyde solutions.
By weight percentage, described wetting agent is 19 parts of glycerol.
Described thickening material is 5 parts of inorganic thickening agents.
Embodiment 3
A kind of staining agent of not fugitive color education of science, by mass parts, comprise: 11 parts of methyl alcohol, 13 parts of ethanol, 12 parts of acetonitriles, 15 parts of acetic acid, 14 parts of methyl-sulphoxides, 12 parts of N, dinethylformamide, 17 parts of Virahols, 13 parts of hexanaphthenes, 15 parts of concentrated nitric acids, 6 parts of hydrogen peroxide, 19 parts of ethylene glycol monoemethyl ethers, 8 parts of phenolphthalein, 5 parts of thickening materials, 6 parts of white oils, 9 parts of glycerine, 30 parts of water, 8 parts of silicon-dioxide, 16 portions of edible ethanols, 12 parts of sodium hydroxide, 13 parts of laking agent, 15 parts of stablizers, 16 portions of corrosion inhibitors, 15 parts of wetting agents, 17 portions of sanitass, 3 parts of glue, 4 parts fast green, 7 parts of methylenum coeruleum.
By weight percentage, described laking agent is 12 parts of tannic acids, 17 parts of gallic acids, 39 parts of ferrous sulfate.
By weight percentage, described stablizer is 25 parts of sulfuric acid, 33 parts of oxalic acid, 27 parts of formaldehyde solutions.
By weight percentage, described wetting agent is 19 parts of glycerol.
Described thickening material is 6 parts of ether of cellulose.
Claims (8)
1. a staining agent for not fugitive color education of science, is characterized in that, by mass parts, comprising: 5-20 part methyl alcohol, 7-10 part ethanol, 6-12 part acetonitrile, 9-15 part acetic acid, 8-12 part methyl-sulphoxide, 6-10 part DMF, 11-20 part Virahol, 7-21 part hexanaphthene, 9-22 part concentrated nitric acid, 2-11 part hydrogen peroxide, 13-22 part ethylene glycol monoemethyl ether, 2-19 part phenolphthalein, 1-5 part thickening material, 2-6 part white oil, 3-9 part glycerine, 11-40 part water, 2-8 part silicon-dioxide, 5-26 part edible ethanol, 3-12 part sodium hydroxide, 1-20 part laking agent, 2-25 part stablizer, 7-22 part corrosion inhibitor, 5-19 part wetting agent, 3-20 part sanitas, 2-6 part is fast green, 2-5 part glue, 2-6 part is fast green, 3-9 part methylenum coeruleum, described laking agent is 10-20 part tannic acid, 15-30 part gallic acid, one or more of 20-39 part ferrous sulfate, by weight percentage, described stablizer is 12-39 part sulfuric acid, 11-41 part oxalic acid, one or more of 10-30 part formaldehyde solution.
2. the staining agent of a kind of not fugitive color education of science according to claim 1, is characterized in that, by weight percentage, described wetting agent is 6-30 part glycerol.
3. the staining agent of a kind of not fugitive color education of science according to claim 1, it is characterized in that, by weight percentage, comprise: 10 parts of methyl alcohol, 12 parts of ethanol, 11 parts of acetonitriles, 14 parts of acetic acid, 13 parts of methyl-sulphoxides, 9 parts of N, dinethylformamide, 16 parts of Virahols, 12 parts of hexanaphthenes, 14 parts of concentrated nitric acids, 7 parts of hydrogen peroxide, 18 parts of ethylene glycol monoemethyl ethers, 7 parts of phenolphthalein, 4 parts of thickening materials, 5 parts of white oils, 8 parts of glycerine, 16 parts of water, 7 parts of silicon-dioxide, 10 portions of edible ethanols, 8 parts of sodium hydroxide, 6 parts of laking agent, 17 parts of stablizers, 12 portions of corrosion inhibitors, 11 parts of wetting agents, 15 portions of sanitass, 5 parts of glue, 6 parts fast green, 9 parts of methylenum coeruleum.
4. the staining agent of a kind of not fugitive color education of science according to claim 1, it is characterized in that, by weight percentage, comprise: 11 parts of methyl alcohol, 13 parts of ethanol, 12 parts of acetonitriles, 15 parts of acetic acid, 14 parts of methyl-sulphoxides, 12 parts of N, dinethylformamide, 17 parts of Virahols, 13 parts of hexanaphthenes, 15 parts of concentrated nitric acids, 6 parts of hydrogen peroxide, 19 parts of ethylene glycol monoemethyl ethers, 8 parts of phenolphthalein, 5 parts of thickening materials, 6 parts of white oils, 9 parts of glycerine, 30 parts of water, 8 parts of silicon-dioxide, 16 portions of edible ethanols, 12 parts of sodium hydroxide, 13 parts of laking agent, 15 parts of stablizers, 16 portions of corrosion inhibitors, 15 parts of wetting agents, 17 portions of sanitass, 3 parts of glue, 4 parts fast green, 7 parts of methylenum coeruleum.
5. the staining agent of a kind of not fugitive color education of science according to claim 1, is characterized in that, by weight percentage, described laking agent be 13 parts of tannic acids, 18 parts of gallic acids, 38 parts of ferrous sulfate one or more.
6. the staining agent of a kind of not fugitive color education of science according to claim 1, is characterized in that, by weight percentage, described stablizer be 22 parts of sulfuric acid, 32 parts of oxalic acid, 26 parts of formaldehyde solutions one or more.
7. the staining agent of a kind of not fugitive color education of science according to claim 2, is characterized in that, by weight percentage, described wetting agent is 19 parts of glycerol.
8. the staining agent of a kind of not fugitive color education of science according to any one of claim 1-7, is characterized in that, described thickening material is 5 parts of inorganic thickening agents and/or 6 parts of ether of cellulose.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510803668.4A CN105462289A (en) | 2015-11-20 | 2015-11-20 | A coloring agent not liable to fade and used for scientific education |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510803668.4A CN105462289A (en) | 2015-11-20 | 2015-11-20 | A coloring agent not liable to fade and used for scientific education |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105462289A true CN105462289A (en) | 2016-04-06 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510803668.4A Pending CN105462289A (en) | 2015-11-20 | 2015-11-20 | A coloring agent not liable to fade and used for scientific education |
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| CN (1) | CN105462289A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108314906A (en) * | 2017-12-28 | 2018-07-24 | 北京纽维逊建筑工程技术有限公司 | Theme facade road surface coloring agent and colouring method |
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| CN1908088A (en) * | 2006-08-09 | 2007-02-07 | 山西大学 | Dustless board writing liquid and liniment for the same |
| CN101358051A (en) * | 2008-07-30 | 2009-02-04 | 曾观涛 | Jet ink for digital print and preparation method thereof |
| CN102399476A (en) * | 2010-09-13 | 2012-04-04 | 吴晨 | Blue ink |
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| CN102702863A (en) * | 2012-06-18 | 2012-10-03 | 南通顺阳化工有限公司 | Blue-black ink |
| CN103525192A (en) * | 2013-10-25 | 2014-01-22 | 卢逸凡 | Ink |
| CN104650650A (en) * | 2013-11-20 | 2015-05-27 | 青岛古宇石墨有限公司 | Preparation formula of smooth blooming-free carbon ink |
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2015
- 2015-11-20 CN CN201510803668.4A patent/CN105462289A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1908088A (en) * | 2006-08-09 | 2007-02-07 | 山西大学 | Dustless board writing liquid and liniment for the same |
| CN101358051A (en) * | 2008-07-30 | 2009-02-04 | 曾观涛 | Jet ink for digital print and preparation method thereof |
| CN102399476A (en) * | 2010-09-13 | 2012-04-04 | 吴晨 | Blue ink |
| CN102558952A (en) * | 2012-01-06 | 2012-07-11 | 浙江大学 | Irreversible thermally induced decoloring printing ink and preparation method thereof |
| CN102702863A (en) * | 2012-06-18 | 2012-10-03 | 南通顺阳化工有限公司 | Blue-black ink |
| CN103525192A (en) * | 2013-10-25 | 2014-01-22 | 卢逸凡 | Ink |
| CN104650650A (en) * | 2013-11-20 | 2015-05-27 | 青岛古宇石墨有限公司 | Preparation formula of smooth blooming-free carbon ink |
Non-Patent Citations (1)
| Title |
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| 辛秀兰: "《水性油墨》", 31 January 2005 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108314906A (en) * | 2017-12-28 | 2018-07-24 | 北京纽维逊建筑工程技术有限公司 | Theme facade road surface coloring agent and colouring method |
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Application publication date: 20160406 |
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