CN105315793A - Novel printing jet ink for science education - Google Patents

Novel printing jet ink for science education Download PDF

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Publication number
CN105315793A
CN105315793A CN201510803705.1A CN201510803705A CN105315793A CN 105315793 A CN105315793 A CN 105315793A CN 201510803705 A CN201510803705 A CN 201510803705A CN 105315793 A CN105315793 A CN 105315793A
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CN
China
Prior art keywords
parts
jet
printing ink
weight percentage
acid
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Pending
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CN201510803705.1A
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Chinese (zh)
Inventor
周小东
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Sichuan Huaying No 1 Middle School
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Sichuan Huaying No 1 Middle School
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Priority to CN201510803705.1A priority Critical patent/CN105315793A/en
Publication of CN105315793A publication Critical patent/CN105315793A/en
Pending legal-status Critical Current

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  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Ink Jet Recording Methods And Recording Media Thereof (AREA)

Abstract

The invention relates to the field of office supplies for science education, and discloses novel printing jet ink for the science education. The novel printing jet ink for the science education is prepared from, by mass, 5-20 parts of methyl alcohol, 7-10 parts of ethyl alcohol, 6-12 parts of acetonitrile, 9-15 parts of acetic acid, 8-12 parts of dimethyl sulfoxide, 6-10 parts of N,N-dimethyl formamide, 11-20 parts of isopropyl alcohol, 7-21 parts of cyclohexane, 9-22 parts of concentrated nitric acid, 2-11 parts of hydrogen peroxide, 13-22 parts of ethylene glycol monomethyl ether, 2-19 parts of phenolphthalein, 1-5 parts of a thickening agent, 2-6 parts of white oil, 3-9 parts of glycerol, 11-40 parts of water, 2-8 parts of silicon dioxide, 5-26 parts of edible alcohol, 3-12 parts of sodium hydroxide, 1-20 parts of a color-fixing agent, 2-25 parts of stabilizer, 7-22 parts of corrosion inhibitor, 5-19 parts of a wetting agent, 3-20 parts of an anti-corrosion agent and 2-5 parts of glue. When the novel printing jet ink for the science education is used in printing coating, the novel printing jet ink is lasting, sanitary, clean, environmentally friendly and free of pollution to the environment, all the used materials are low in price, and the production cost is reduced; the printing jet ink can be made into multiple colors such as red, blue and purple through different proportions of all the components such as the phenolphthalein and the edible alcohol; meanwhile, the used components such as the phenolphthalein and the edible alcohol are harmless to a human body, healthy and environmentally friendly, and physical and psychological health of a reader is guaranteed.

Description

A kind of printing ink-jet of novel education of science
Technical field
The present invention relates to education of science office appliance field, particularly a kind of printing ink-jet of novel education of science.
Background technology
Ink-jet is the correction with writing tools of writing books, and from the chemical property of its raw material, can be divided into blue-black ink-jet and color ink jet.Blue-black ink-jet, also known as Tannic acids, iron salts ink-jet, is not taken off composition, pigment composition, stablizer, resist, wetting agent and sanitas etc. lastingly by blackening and is formed.The composition mainly composition chemical combination each other such as tannic acid, gallic acid and ferrous sulfate is not taken off in blackening lastingly, generate tannic acid ferrous iron and gallic acid ferrous iron, insoluble high price iron is all become after oxidation, i.e. Tannic acids, iron salts and gallic acid iron, the former strengthens water tolerance, the latter strengthens blackening, makes that ink-jet is water-fast, blackening like this, and look does not take off lastingly.And pigment composition conventional be at present the blue and direct acid blue dyestuff of acid ink-jet, ink-jet indigo plant is the mass-tone of ink-jet, and the acid of its aqueous solution chance is never degenerated, but chance alkali then becomes brown.Direct acid blue plays and helps look effect in ink-jet, due to wherein impure more, unsuitable multiplex, at the easy mildew of wet environment.In ink-jet, add the object of stablizer, mainly eliminate the precipitation of ink-jet, in order to avoid phenomenon of cutting off the water supply when writing.Conventional stablizer has sulfuric acid, oxalic acid, formaldehyde solution.These stablizers all have certain acidity, have buried potential harm to paper acidifying, unsuitable multiplex.Because the stablizer added in ink-jet has comparatively strongly-acid, for preventing corrosion, often adding resist, making it and irony form film, reducing the corrosive nature 90% of sulfuric acid.Iron-holder in ink-jet can not be increased because of corrosion nib, thus add the stability of ink-jet.As can be seen here, ink-jet of the prior art, one of its primary efficacy is that will to reach the person's handwriting sprayed out colour-fast lastingly, thus adds blackening and does not take off composition lastingly; The pigment composition added in addition, its main component is ink-jet indigo plant or direct acid blue dyestuff, and color is comparatively single, sometimes in order to express needs, needing polychrome and using.Need a kind of novel ink-jet of exploitation to meet the demand of numerous clients.
Summary of the invention
The object of the invention is to overcome above-mentioned deficiency existing in prior art, a kind of printing ink-jet of novel education of science is provided.
In order to realize foregoing invention object, the invention provides following technical scheme:
A kind of printing ink-jet of novel education of science, by mass parts, comprise: 5-20 part methyl alcohol, 7-10 part ethanol, 6-12 part acetonitrile, 9-15 part acetic acid, 8-12 part methyl-sulphoxide, 6-10 part N, dinethylformamide, 11-20 part Virahol, 7-21 part hexanaphthene, 9-22 part concentrated nitric acid, 2-11 part hydrogen peroxide, 13-22 part ethylene glycol monoemethyl ether, 2-19 part phenolphthalein, 1-5 part thickening material, 2-6 part white oil, 3-9 part glycerine, 11-40 part water, 2-8 part silicon-dioxide, 5-26 part edible ethanol, 3-12 part sodium hydroxide, 1-20 part laking agent, 2-25 part stablizer, 7-22 part corrosion inhibitor, 5-19 part wetting agent, 3-20 part sanitas, 2-5 part glue, 2-6 part is fast green, described laking agent is 10-20 part tannic acid, 15-30 part gallic acid, one or more of 20-39 part ferrous sulfate.Writing after glue allows printing spray is more clear more firm, the time that laking agent manifests after spray coating by ink-jet is more permanent, the color that stablizer shows by ink-jet is more stable, not fugitive color, wetting agent is by ink-jet prevented from caking in storage process, erosion resistance makes ink-jet not perishable, and the shelf time is more of a specified duration, and sanitas not easily rots by the material in ink-jet.
As preferably, by weight percentage, described stablizer be 12-39 part sulfuric acid, 11-41 part oxalic acid, 10-30 part formaldehyde solution one or more.
As preferably, by weight percentage, described wetting agent is 6-30 part glycerol.
As preferably, by weight percentage, comprise: 10 parts of methyl alcohol, 12 parts of ethanol, 11 parts of acetonitriles, 14 parts of acetic acid, 13 parts of methyl-sulphoxides, 9 parts of DMFs, 16 parts of Virahols, 12 parts of hexanaphthenes, 14 parts of concentrated nitric acids, 7 parts of hydrogen peroxide, 18 parts of ethylene glycol monoemethyl ethers, 7 parts of phenolphthalein, 4 parts of thickening materials, 5 parts of white oils, 8 parts of glycerine, 16 parts of water, 7 parts of silicon-dioxide, 10 portions of edible ethanols, 8 parts of sodium hydroxide, 6 parts of laking agent, 17 parts of stablizers, 12 portions of corrosion inhibitors, 11 parts of wetting agents, 15 portions of sanitass, 3 parts of glue, 5 parts fast green.
As preferably, by weight percentage, comprise: 11 parts of methyl alcohol, 13 parts of ethanol, 12 parts of acetonitriles, 15 parts of acetic acid, 14 parts of methyl-sulphoxides, 12 parts of DMFs, 17 parts of Virahols, 13 parts of hexanaphthenes, 15 parts of concentrated nitric acids, 6 parts of hydrogen peroxide, 19 parts of ethylene glycol monoemethyl ethers, 8 parts of phenolphthalein, 5 parts of thickening materials, 6 parts of white oils, 9 parts of glycerine, 30 parts of water, 8 parts of silicon-dioxide, 16 portions of edible ethanols, 12 parts of sodium hydroxide, 13 parts of laking agent, 15 parts of stablizers, 16 portions of corrosion inhibitors, 15 parts of wetting agents, 17 portions of sanitass, 3 parts of glue, 5 parts fast green.
As preferably, by weight percentage, described laking agent be 13 parts of tannic acids, 18 parts of gallic acids, 38 parts of ferrous sulfate one or more.
As preferably, by weight percentage, described stablizer be 22 parts of sulfuric acid, 32 parts of oxalic acid, 26 parts of formaldehyde solutions one or more.
As preferably, by weight percentage, described wetting agent is 19 parts of glycerol.
As preferably, described thickening material is 5 parts of inorganic thickening agents and/or 6 parts of ether of cellulose.
compared with prior art, beneficial effect of the present invention: according to composition of the present invention, those skilled in the art are known, add the effect of other compositions, the writing sprayed out is clear, and do not take off lastingly containing blackening and wait composition, during for printing in spraying, lasting, health totally, environmental protection, not polluted air, related chemical species in ink-jet in the raw material hinge structure that it uses is more cheap, thus saves production cost; Different by the proportioning of each composition such as phenolphthalein, edible ethanol, can be made into the polychromes such as redness, blueness and purple; Meanwhile, the compositions such as the phenolphthalein used, edible ethanol are all harmless starting material, health environment-friendly more, ensure the physical and mental health of reader.
Embodiment
Below in conjunction with test example and embodiment, the present invention is described in further detail.But this should be interpreted as that the scope of the above-mentioned theme of the present invention is only limitted to following embodiment, all technology realized based on content of the present invention all belong to scope of the present invention.
Embodiment 1
A kind of printing ink-jet of novel education of science, by weight percentage, comprise: 10 parts of methyl alcohol, 12 parts of ethanol, 11 parts of acetonitriles, 14 parts of acetic acid, 13 parts of methyl-sulphoxides, 9 parts of N, dinethylformamide, 16 parts of Virahols, 12 parts of hexanaphthenes, 14 parts of concentrated nitric acids, 7 parts of hydrogen peroxide, 18 parts of ethylene glycol monoemethyl ethers, 7 parts of phenolphthalein, 4 parts of thickening materials, 5 parts of white oils, 8 parts of glycerine, 16 parts of water, 7 parts of silicon-dioxide, 10 portions of edible ethanols, 8 parts of sodium hydroxide, 6 parts of laking agent, 17 parts of stablizers, 12 portions of corrosion inhibitors, 11 parts of wetting agents, 15 portions of sanitass, 3 parts of glue, 4 parts fast green, described laking agent is 15 parts of tannic acids, 17 parts of gallic acids, 32 parts of ferrous sulfate.
By weight percentage, described stablizer is 21 parts of sulfuric acid, 32 parts of oxalic acid, 17 parts of formaldehyde solutions.
By weight percentage, described wetting agent is 14 parts of glycerol.
Described thickening material is 4 parts of inorganic thickening agents and 5 parts of ether of cellulose.
Embodiment 2
A kind of printing ink-jet of novel education of science, by weight percentage, comprise: 10 parts of methyl alcohol, 12 parts of ethanol, 11 parts of acetonitriles, 14 parts of acetic acid, 13 parts of methyl-sulphoxides, 9 parts of N, dinethylformamide, 16 parts of Virahols, 12 parts of hexanaphthenes, 14 parts of concentrated nitric acids, 7 parts of hydrogen peroxide, 18 parts of ethylene glycol monoemethyl ethers, 7 parts of phenolphthalein, 4 parts of thickening materials, 5 parts of white oils, 8 parts of glycerine, 16 parts of water, 7 parts of silicon-dioxide, 10 portions of edible ethanols, 8 parts of sodium hydroxide, 6 parts of laking agent, 17 parts of stablizers, 12 portions of corrosion inhibitors, 11 parts of wetting agents, 15 portions of sanitass, 3 parts of glue, 5 parts fast green, described laking agent is 15 parts of tannic acids, 17 parts of gallic acids, 32 parts of ferrous sulfate.
By weight percentage, described stablizer is 20 parts of sulfuric acid, 31 parts of oxalic acid, 18 parts of formaldehyde solutions.
By weight percentage, described wetting agent is 15 parts of glycerol.
Described thickening material is 5 parts of inorganic thickening agents and 6 parts of ether of cellulose.
Embodiment 3
A kind of printing ink-jet of novel education of science, by weight percentage, comprise: 11 parts of methyl alcohol, 13 parts of ethanol, 12 parts of acetonitriles, 15 parts of acetic acid, 14 parts of methyl-sulphoxides, 12 parts of N, dinethylformamide, 17 parts of Virahols, 13 parts of hexanaphthenes, 15 parts of concentrated nitric acids, 6 parts of hydrogen peroxide, 19 parts of ethylene glycol monoemethyl ethers, 8 parts of phenolphthalein, 5 parts of thickening materials, 6 parts of white oils, 9 parts of glycerine, 30 parts of water, 8 parts of silicon-dioxide, 16 portions of edible ethanols, 12 parts of sodium hydroxide, 13 parts of laking agent, 15 parts of stablizers, 16 portions of corrosion inhibitors, 15 parts of wetting agents, 17 portions of sanitass, 3 parts of glue, 5 parts fast green, described laking agent is 15 parts of tannic acids, 17 parts of gallic acids, 32 parts of ferrous sulfate.
By weight percentage, described stablizer is 20 parts of sulfuric acid, 31 parts of oxalic acid, 18 parts of formaldehyde solutions.
By weight percentage, described wetting agent is 15 parts of glycerol.
Described thickening material is 5 parts of inorganic thickening agents and 6 parts of ether of cellulose.

Claims (9)

1. the printing ink-jet of a novel education of science, it is characterized in that, by mass parts, comprise: 5-20 part methyl alcohol, 7-10 part ethanol, 6-12 part acetonitrile, 9-15 part acetic acid, 8-12 part methyl-sulphoxide, 6-10 part N, dinethylformamide, 11-20 part Virahol, 7-21 part hexanaphthene, 9-22 part concentrated nitric acid, 2-11 part hydrogen peroxide, 13-22 part ethylene glycol monoemethyl ether, 2-19 part phenolphthalein, 1-5 part thickening material, 2-6 part white oil, 3-9 part glycerine, 11-40 part water, 2-8 part silicon-dioxide, 5-26 part edible ethanol, 3-12 part sodium hydroxide, 1-20 part laking agent, 2-25 part stablizer, 7-22 part corrosion inhibitor, 5-19 part wetting agent, 3-20 part sanitas, 2-5 part glue, 2-6 part is fast green, described laking agent is 10-20 part tannic acid, 15-30 part gallic acid, one or more of 20-39 part ferrous sulfate.
2. the printing ink-jet of a kind of novel education of science according to claim 1, is characterized in that, by weight percentage, described stablizer be 12-39 part sulfuric acid, 11-41 part oxalic acid, 10-30 part formaldehyde solution one or more.
3. the printing ink-jet of a kind of novel education of science according to claim 1, is characterized in that, by weight percentage, described wetting agent is 6-30 part glycerol.
4. the printing ink-jet of a kind of novel education of science according to claim 1, it is characterized in that, by weight percentage, comprise: 10 parts of methyl alcohol, 12 parts of ethanol, 11 parts of acetonitriles, 14 parts of acetic acid, 13 parts of methyl-sulphoxides, 9 parts of N, dinethylformamide, 16 parts of Virahols, 12 parts of hexanaphthenes, 14 parts of concentrated nitric acids, 7 parts of hydrogen peroxide, 18 parts of ethylene glycol monoemethyl ethers, 7 parts of phenolphthalein, 4 parts of thickening materials, 5 parts of white oils, 8 parts of glycerine, 16 parts of water, 7 parts of silicon-dioxide, 10 portions of edible ethanols, 8 parts of sodium hydroxide, 6 parts of laking agent, 17 parts of stablizers, 12 portions of corrosion inhibitors, 11 parts of wetting agents, 15 portions of sanitass, 3 parts of glue, 5 parts fast green.
5. the printing ink-jet of a kind of novel education of science according to claim 1, it is characterized in that, by weight percentage, comprise: 11 parts of methyl alcohol, 13 parts of ethanol, 12 parts of acetonitriles, 15 parts of acetic acid, 14 parts of methyl-sulphoxides, 12 parts of N, dinethylformamide, 17 parts of Virahols, 13 parts of hexanaphthenes, 15 parts of concentrated nitric acids, 6 parts of hydrogen peroxide, 19 parts of ethylene glycol monoemethyl ethers, 8 parts of phenolphthalein, 5 parts of thickening materials, 6 parts of white oils, 9 parts of glycerine, 30 parts of water, 8 parts of silicon-dioxide, 16 portions of edible ethanols, 12 parts of sodium hydroxide, 13 parts of laking agent, 15 parts of stablizers, 16 portions of corrosion inhibitors, 15 parts of wetting agents, 17 portions of sanitass, 3 parts of glue, 5 parts fast green.
6. the printing ink-jet of a kind of novel education of science according to claim 1, is characterized in that, by weight percentage, described laking agent be 13 parts of tannic acids, 18 parts of gallic acids, 38 parts of ferrous sulfate one or more.
7. the printing ink-jet of a kind of novel education of science according to claim 2, is characterized in that, by weight percentage, described stablizer be 22 parts of sulfuric acid, 32 parts of oxalic acid, 26 parts of formaldehyde solutions one or more.
8. the printing ink-jet of a kind of novel education of science according to claim 3, is characterized in that, by weight percentage, described wetting agent is 19 parts of glycerol.
9. the printing ink-jet of a kind of novel education of science according to any one of claim 1-8, is characterized in that, described thickening material is 5 parts of inorganic thickening agents and/or 6 parts of ether of cellulose.
CN201510803705.1A 2015-11-20 2015-11-20 Novel printing jet ink for science education Pending CN105315793A (en)

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101831217A (en) * 2010-05-11 2010-09-15 山西大学 Children colour pen ink
CN102925006A (en) * 2012-11-23 2013-02-13 重庆市秀峰教学设备有限公司 Ink and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101831217A (en) * 2010-05-11 2010-09-15 山西大学 Children colour pen ink
CN102925006A (en) * 2012-11-23 2013-02-13 重庆市秀峰教学设备有限公司 Ink and preparation method thereof

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