CN105440962A - Semi-cured OCA (optical clear adhesive) induction film laminating method - Google Patents

Semi-cured OCA (optical clear adhesive) induction film laminating method Download PDF

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Publication number
CN105440962A
CN105440962A CN201510981143.XA CN201510981143A CN105440962A CN 105440962 A CN105440962 A CN 105440962A CN 201510981143 A CN201510981143 A CN 201510981143A CN 105440962 A CN105440962 A CN 105440962A
Authority
CN
China
Prior art keywords
oca
laminating
semi
cured
adhesive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510981143.XA
Other languages
Chinese (zh)
Inventor
弋天宝
余崇圣
谷峰
蔡茂林
盖川
潘洪亮
向双扬
何代军
段小伟
张亮
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chongqing Graphene Technology Co Ltd
Original Assignee
Chongqing Graphene Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chongqing Graphene Technology Co Ltd filed Critical Chongqing Graphene Technology Co Ltd
Priority to CN201510981143.XA priority Critical patent/CN105440962A/en
Publication of CN105440962A publication Critical patent/CN105440962A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J4/00Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J171/00Adhesives based on polyethers obtained by reactions forming an ether link in the main chain; Adhesives based on derivatives of such polymers
    • C09J171/02Polyalkylene oxides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J5/00Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J5/00Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers
    • C09J5/02Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers involving pretreatment of the surfaces to be joined

Abstract

The invention discloses a semi-cured OCA (optical clear adhesive) induction film laminating method which comprises the following steps: treating to-be-glued laminated material layers; filling the space between the laminated material layers with an adhesive; laminating and removing bubbles; and performing photocuring of the adhesive using ultraviolet (UV). According to the method disclosed by the invention, semi-cured OCA replaces traditional OCA. The semi-cured OCA combines the advantages of OCA and LOCA (liquid optical clear adhesive); in a form of solid adhesive, the semi-cured OCA is suitable for laminating soft materials; and after the laminating and bubble removal, since the composition comprises an ultraviolet initiator and a monomer which is not completely cured or cross-linked, further curing can be performed through ultraviolet irradiation. After ultraviolet irradiation, the initiator initiates further crosslinking reaction of the monomer, the peeling strength between two layers is enhanced, and the problems of creases and cracking of the layers of a touch module and a display module are avoided when the flexible equipment is repeatedly bent for use.

Description

A kind of semicure OCA sensor film applying method
Technical field
The present invention relates to electronic display field, particularly a kind of semicure OCA sensor film applying method.
Background technology
The wearable device development such as current bracelet, intelligent watch rapidly, touch module wherein between layers and still have employed the laminating type of the curling purposes of inflexibility in the past between touch module and display module, OCA, LOCA of adopting as smart mobile phone panel computer etc. or the laminating of two-sided gum.Although the stripping strength after LOCA laminating is fine and bending tolerance is very excellent, but and be not suitable between flexible curling touch module and display module for soft to soft laminating, OCA or two-sided gum are fitted, film type touch-screen normally uses OCA (Optical transparent adhesive) to fit between layers, and is fitted by OCA, LOCA (Liquid optical clear adhesive) or two-sided gum between film type touch-screen and display screen.This laminating material is applicable for the touch control display apparatus of the curling purposes of inflexibility, but when be applied to needs repeatedly curling touch control display device be just there will be following problem: for soft to soft laminating between touch module and display module, can not fit with LOCA, although the stripping strength after LOCA laminating is fine and bending tolerance is very excellent.Can only fit with OCA or two-sided gum between layers, and under OCA or two-sided gum be fitted in repeatedly curling service condition, easily occur, the problems such as cracking, folding line.
Therefore, need to study a kind of semicure OCA sensor film applying method.
Summary of the invention
In view of this, technical problem to be solved by this invention is to provide a kind of semicure OCA sensor film applying method.This method solve flexible volume district touch control display device in repeatedly curling process, occur that glue-line stripping strength is inadequate, and easily occur the problems such as cracking and folding line.
The object of the present invention is achieved like this:
A kind of semicure OCA sensor film applying method provided by the invention, comprises the following steps:
Process to be glued by subsides material layer;
Cementing agent is being filled between layers by subsides material;
After laminating de-bubble;
With UV-light UV, photocuring is carried out to cementing agent;
Further; described cementing agent is 2-hydroxy-2-methyl-1-phenyl-acetone, 1-hydroxycyclohexyl phenyl ketone, 2-methyl-2-(4-morpholinyl)-1-[4-(methylthio group) phenyl]-1-acetone, T2; the mixture of one or more in 4,6-trimethylbenzoy-dipheny phosphine oxide free radical light trigger.
Further, the mixture of one or more in isobornyl acrylate, isobornyl methacrylate, tripropylene glycol diacrylate, polyoxyethylene glycol (400) dimethacrylate photo-curing monomer is also included in described cementing agent.
Beneficial effect of the present invention is: the present invention adopts semicure OCA to substitute traditional OCA.Semicure OCA, combines the advantage of both OCA and LOCA, due to the form of solid gums own, be applicable to soft to soft laminating, laminating, after finishing, owing to there being the monomer of ultraviolet initiator and incomplete curing cross-linked in composition, so can be solidified further by ultraviolet lighting.The further crosslinking reaction of initiator trigger monomer after illumination, enhance two-layer between peeling force, under the state that flexible apparatus is used in alternating bending, touch module also there will not be the problem of folding line, cracking with display module layer and layer.
Accompanying drawing explanation
In order to make the object, technical solutions and advantages of the present invention clearly, below in conjunction with accompanying drawing, the present invention is described in further detail, wherein:
The semicure OCA sensor film applying method schema that Fig. 1 provides for the embodiment of the present invention.
Embodiment
Hereinafter with reference to accompanying drawing, the preferred embodiments of the present invention are described in detail.Should be appreciated that preferred embodiment only in order to the present invention is described, instead of in order to limit the scope of the invention.
Embodiment 1
As shown in the figure, a kind of semicure OCA sensor film applying method provided by the invention, comprises the following steps:
Process to be glued by subsides material layer;
Cementing agent is being filled between layers by subsides material;
After laminating de-bubble;
With UV-light UV, photocuring is carried out to cementing agent;
Described cementing agent is 2-hydroxy-2-methyl-1-phenyl-acetone, 1-hydroxycyclohexyl phenyl ketone, 2-methyl-2-(4-morpholinyl)-1-[4-(methylthio group) phenyl]-1-acetone, T2; the mixture of one or more in 4,6-trimethylbenzoy-dipheny phosphine oxide free radical light trigger.
The mixture of one or more in isobornyl acrylate, isobornyl methacrylate, tripropylene glycol diacrylate, polyoxyethylene glycol (400) dimethacrylate photo-curing monomer is also included in described cementing agent.
Embodiment 2
The semicure OCA sensor film applying method concrete steps that the present embodiment provides are as follows:
Sensor film and semicure OCA fit;
High pressure de-bubble;
Touch module is fitted with display module semicure OCA;
High pressure de-bubble;
UV illumination curing;
LOCA is glue laminating, then uses UV (UV-light) photocuring, is filled what bonding between layers by subsides material by glue molecular level, and the fine and bending tolerance of stripping strength is better than the OCA laminating of pressure sensitive adhesive principle far away.But glue laminating cannot be applied to soft to soft laminating, and under OCA or two-sided gum be fitted in repeatedly curling service condition, easily occurs, the problems such as cracking, folding line.
The present invention adopts semicure OCA to substitute traditional OCA.Semicure OCA, combines the advantage of both OCA and LOCA, due to the form of solid gums own, be applicable to soft to soft laminating, laminating, after finishing, owing to there being the monomer of ultraviolet initiator and incomplete curing cross-linked in composition, so can be solidified further by ultraviolet lighting.The further crosslinking reaction of initiator trigger monomer after illumination, enhance two-layer between peeling force, under the state that flexible apparatus is used in alternating bending, touch module also there will not be the problem of folding line, cracking with display module layer and layer.
The method that the present embodiment provides adopts semicure OCA to substitute the two-sided gum of traditional OCA, for the laminating between sensor film and the laminating between inductive module and display module.
The operation that half OCA is different from traditional OCA re-uses UV illumination and glue-line is thoroughly solidified after being laminating de-bubble.
Containing 2-hydroxy-2-methyl-1-phenyl-acetone, 1-hydroxycyclohexyl phenyl ketone, 2-methyl-2-(4-morpholinyl)-1-[4-(methylthio group) phenyl]-1-acetone, T2 in the composition of semicure OCA; the mixture of one or more in the free radical photo-initiations such as 4,6-trimethylbenzoy-dipheny phosphine oxide.
Simultaneously containing the mixture of one or more in the photo-curing monomers such as isobornyl acrylate, isobornyl methacrylate, tripropylene glycol diacrylate, polyoxyethylene glycol (400) dimethacrylate.
What finally illustrate is, above embodiment is only in order to illustrate technical scheme of the present invention and unrestricted, although by referring to the preferred embodiments of the present invention, invention has been described, but those of ordinary skill in the art is to be understood that, various change can be made to it in the form and details, and not depart from the spirit and scope that the present invention limits.

Claims (3)

1. a semicure OCA sensor film applying method, is characterized in that: comprise the following steps:
Process to be glued by subsides material layer;
Cementing agent is being filled between layers by subsides material;
Laminating de-bubble;
With UV-light UV, photocuring is carried out to cementing agent.
2. semicure OCA sensor film applying method according to claim 1; it is characterized in that: described cementing agent is 2-hydroxy-2-methyl-1-phenyl-acetone, 1-hydroxycyclohexyl phenyl ketone, 2-methyl-2-4-morpholinyl-1-4-methylthio group phenyl-1-acetone, T2; the mixture of one or more in 4,6-trimethylbenzoy-dipheny phosphine oxide free radical light trigger.
3. semicure OCA sensor film applying method according to claim 1, is characterized in that: also include the mixture of one or more in isobornyl acrylate, isobornyl methacrylate, tripropylene glycol diacrylate, polyoxyethylene glycol (400) dimethacrylate photo-curing monomer in described cementing agent.
CN201510981143.XA 2015-12-23 2015-12-23 Semi-cured OCA (optical clear adhesive) induction film laminating method Pending CN105440962A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510981143.XA CN105440962A (en) 2015-12-23 2015-12-23 Semi-cured OCA (optical clear adhesive) induction film laminating method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510981143.XA CN105440962A (en) 2015-12-23 2015-12-23 Semi-cured OCA (optical clear adhesive) induction film laminating method

Publications (1)

Publication Number Publication Date
CN105440962A true CN105440962A (en) 2016-03-30

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Family Applications (1)

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Country Status (1)

Country Link
CN (1) CN105440962A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109096929A (en) * 2018-06-29 2018-12-28 新纶科技(常州)有限公司 Type OCA optical cement and preparation method thereof is not fully cured for a kind of multi-ply construction

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103777812A (en) * 2012-09-07 2014-05-07 苹果公司 Liquid optically clear adhesive lamination process control
CN103820043A (en) * 2014-02-27 2014-05-28 深圳市友联亨达光电有限公司 UV curing-type thermal-melt optical clear adhesive (TOCA) and bonding method
US20140262002A1 (en) * 2011-10-24 2014-09-18 3M Innovative Properties Company Micro-structured optically clear adhesives

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20140262002A1 (en) * 2011-10-24 2014-09-18 3M Innovative Properties Company Micro-structured optically clear adhesives
CN103777812A (en) * 2012-09-07 2014-05-07 苹果公司 Liquid optically clear adhesive lamination process control
CN103820043A (en) * 2014-02-27 2014-05-28 深圳市友联亨达光电有限公司 UV curing-type thermal-melt optical clear adhesive (TOCA) and bonding method

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109096929A (en) * 2018-06-29 2018-12-28 新纶科技(常州)有限公司 Type OCA optical cement and preparation method thereof is not fully cured for a kind of multi-ply construction

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Application publication date: 20160330

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