CN105440557A - High-tenacity ABS film for packaging and preparation method thereof - Google Patents
High-tenacity ABS film for packaging and preparation method thereof Download PDFInfo
- Publication number
- CN105440557A CN105440557A CN201510880465.5A CN201510880465A CN105440557A CN 105440557 A CN105440557 A CN 105440557A CN 201510880465 A CN201510880465 A CN 201510880465A CN 105440557 A CN105440557 A CN 105440557A
- Authority
- CN
- China
- Prior art keywords
- parts
- acid ester
- high tenacity
- packaging high
- abs film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
The invention discloses a high-tenacity ABS film for packaging and a preparation method thereof. A packaging material is prepared from, by weight, 120-220 parts of ABS resin, 1-8 parts of polymethylphenyl siloxane fluid, 2-15 parts of dicyclohexyl phthalate, 1-6 parts of epoxy tetrachloro phthalic acid ester, 3-12 parts of phosphite ester, 4-9 parts of nitrile rubber, 0.5-6 parts of oxidized polyethlene wax, 0.3-2 parts of microcrystalline wax and 0.4-5 parts of a calcium-zinc stabilizer. The ABS film packaging material has the good tenacity and mechanical property, and meanwhile the method is simple in technology, easy to repeatedly implement and applicable to various packaging machines.
Description
Technical field
The invention belongs to wrapping material field, particularly a kind of packaging high tenacity ABS film and preparation method thereof.
Background technology
With the film that polyethylene, polypropylene, polyvinyl chloride, polystyrene, ABS (acryl-butadiene-vinylbenzene) and other resins are made, for packaging, and be used as coating layer.The commercially shared share of plastic wrapping and plastic packet product is increasing, particularly composite plastic soft packaging, the fields such as food, medicine, chemical industry are widely used in, wherein maximum with food product pack proportion again, such as drink pack, quickfrozen food packaging, cooking food packaging, snack food product packaging etc., these products all bring great convenience to people's life.
But plastic film material less stable, be heated and illumination effect under can decompose, simultaneously mechanical strength also can decline, as food product pack, life-time service has an impact to HUMAN HEALTH, can not reach aseptic requirement, and these all limit the scope of application of plastic film material.
Summary of the invention
For above-mentioned demand, the invention provides a kind of packaging high tenacity ABS film and preparation method thereof, the ABS film packing material obtained by the method has good toughness, good mechanical properties, meanwhile, the method technique is simple, be easy to repetition, be applicable to all kinds of wrapping machine.
Object of the present invention can be achieved through the following technical solutions:
A kind of packaging high tenacity ABS film, comprise the component of following weight part: ABS resin 120-220 part, polymethylphenyl siloxane fluid 1-8 part, dicyclohexyl phthalate 2-15 part, epoxidation tetrachlorophthalic acid ester 1-6 part, phosphorous acid ester 3-12 part, butyronitrile rubber 4-9 part, oxidized polyethlene wax 0.5-6 part, microcrystalline wax 0.3-2 part, calcium zinc stabilizer 0.4-5 part.
Preferably, described packaging high tenacity ABS film comprises the component of following weight part: ABS resin 160-200 part, polymethylphenyl siloxane fluid 3-6 part, dicyclohexyl phthalate 5-10 part, epoxidation tetrachlorophthalic acid ester 2-5 part, phosphorous acid ester 5-8 part, butyronitrile rubber 6-8 part, oxidized polyethlene wax 1.5-2 part, microcrystalline wax 0.5-1.5 part, calcium zinc stabilizer 0.6-3 part.
Preferably, described packaging high tenacity ABS film comprises the component of following weight part: ABS resin 180 parts, polymethylphenyl siloxane fluid 4 parts, dicyclohexyl phthalate 6 parts, epoxidation tetrachlorophthalic acid ester 3 parts, phosphorous acid ester 7 parts, butyronitrile rubber 7 parts, oxidized polyethlene wax 1.8 parts, microcrystalline wax 1.2 parts, calcium zinc stabilizer 0.9 part.
A preparation method for packaging high tenacity ABS film, the method comprises the following steps:
(1) ABS resin 120-220 part, polymethylphenyl siloxane fluid 1-8 part, dicyclohexyl phthalate 2-15 part is taken, epoxidation tetrachlorophthalic acid ester 1-6 part, phosphorous acid ester 3-12 part, butyronitrile rubber 4-9 part, oxidized polyethlene wax 0.5-6 part, microcrystalline wax 0.3-2 part, calcium zinc stabilizer 0.4-5 part are poured in reactor, stir 30-60min, be heated to 120-140 DEG C, pressurization 0.8-2.0MPa, reaction 60-90min obtains polymer melt;
(2) add in parallel double-screw tablets press by the melt that step (1) obtains, extruding pelletization, drying, obtain polyester slice;
(3) polyester slice of step (2) is melt extruded, slab spooling, two-way stretch, cooling and shaping, obtain packaging high tenacity ABS film.
Preferably, in step (1), its speed of described stirring is 250-300 rev/min.
Preferably, in step (2), its temperature of described extruding pelletization is 240-250 DEG C.
Preferably, in step (3), described in melt extrude its temperature be 240-250 DEG C.
Preferably, in step (3), its temperature of described two-way stretch is 120-130 DEG C.
Compared with prior art, its beneficial effect is in the present invention:
(1) packaging high tenacity ABS film strength of the present invention is high, tensile property good, has good texture, is conducive to the visual appearance protecting packed article.
(2) preparation method of the present invention is simple, easy to make, and effective, and existing against sunshine, moistureproof effect, has again the function of prevent breakage.
(3) packaging high tenacity ABS film of the present invention has certain bumper and absorbing shock function, can play certain provide protection to packed article.
(4) packaging high tenacity ABS film of the present invention is due to raw materials for production environmental protection, and life-time service is harmful to human health, convenient recycling after ABS material uses, energy-conserving and environment-protective.
Embodiment
Below in conjunction with embodiment, the present invention is further illustrated.
Embodiment 1
A kind of packaging high tenacity ABS film, comprise the component of following weight part: ABS resin 180 parts, polymethylphenyl siloxane fluid 4 parts, dicyclohexyl phthalate 6 parts, epoxidation tetrachlorophthalic acid ester 3 parts, phosphorous acid ester 7 parts, butyronitrile rubber 7 parts, oxidized polyethlene wax 1.8 parts, microcrystalline wax 1.2 parts, calcium zinc stabilizer 0.9 part.
The preparation method of above-mentioned packaging high tenacity ABS film, comprises the following steps:
(1) ABS resin 180 parts, polymethylphenyl siloxane fluid 4 parts, dicyclohexyl phthalate 6 parts is taken, epoxidation tetrachlorophthalic acid ester 3 parts, phosphorous acid ester 7 parts, butyronitrile rubber 7 parts, oxidized polyethlene wax 1.8 parts, microcrystalline wax 1.2 parts, calcium zinc stabilizer 0.9 part are poured in reactor, 280 revs/min are stirred 50min, be heated to 130 DEG C, pressurization 1.0MPa, reaction 60min obtains polymer melt;
(2) add in parallel double-screw tablets press by the melt that step (1) obtains, 245 DEG C of extruding pelletizations, drying, obtain polyester slice;
(3) by the polyester slice of step (2) 245 DEG C melt extrude, slab spooling, 125 DEG C of two-way stretches, cooling and shaping, obtain packaging high tenacity ABS film.
Embodiment 2
A kind of packaging high tenacity ABS film, comprise the component of following weight part: ABS resin 120 parts, polymethylphenyl siloxane fluid 8 parts, dicyclohexyl phthalate 2 parts, epoxidation tetrachlorophthalic acid ester 6 parts, phosphorous acid ester 3 parts, butyronitrile rubber 9 parts, oxidized polyethlene wax 0.5 part, microcrystalline wax 2 parts, calcium zinc stabilizer 0.4 part.
The preparation method of above-mentioned packaging high tenacity ABS film, comprises the following steps:
(1) ABS resin 120 parts, polymethylphenyl siloxane fluid 8 parts, dicyclohexyl phthalate 2 parts is taken, epoxidation tetrachlorophthalic acid ester 6 parts, phosphorous acid ester 3 parts, butyronitrile rubber 9 parts, oxidized polyethlene wax 0.5 part, microcrystalline wax 2 parts, calcium zinc stabilizer 0.4 part are poured in reactor, 250 revs/min are stirred 60min, be heated to 120 DEG C, pressurization 2.0MPa, reaction 60-90min obtains polymer melt;
(2) add in parallel double-screw tablets press by the melt that step (1) obtains, 240 DEG C of extruding pelletizations, drying, obtain polyester slice;
(3) by the polyester slice of step (2) 240 DEG C melt extrude, slab spooling, 130 DEG C of two-way stretches, cooling and shaping, obtain packaging high tenacity ABS film.
Embodiment 3
A kind of packaging high tenacity ABS film, comprise the component of following weight part: ABS resin 220 parts, polymethylphenyl siloxane fluid 1 part, dicyclohexyl phthalate 15 parts, epoxidation tetrachlorophthalic acid ester 1 part, phosphorous acid ester 12 parts, butyronitrile rubber 4 parts, oxidized polyethlene wax 6 parts, microcrystalline wax 0.3 part, calcium zinc stabilizer 5 parts.
The preparation method of above-mentioned packaging high tenacity ABS film, comprises the following steps:
(1) ABS resin 220 parts, polymethylphenyl siloxane fluid 1 part, dicyclohexyl phthalate 15 parts is taken, epoxidation tetrachlorophthalic acid ester 1 part, phosphorous acid ester 12 parts, butyronitrile rubber 4 parts, oxidized polyethlene wax 6 parts, microcrystalline wax 0.3 part, calcium zinc stabilizer 5 parts are poured in reactor, 300 revs/min are stirred 30min, be heated to 140 DEG C, pressurization 0.8MPa, reaction 90min obtains polymer melt;
(2) add in parallel double-screw tablets press by the melt that step (1) obtains, 250 DEG C of extruding pelletizations, drying, obtain polyester slice;
(3) by the polyester slice of step (2) 250 DEG C melt extrude, slab spooling, 120 DEG C of two-way stretches, cooling and shaping, obtain packaging high tenacity ABS film.
Embodiment 4
A kind of packaging high tenacity ABS film, comprise the component of following weight part: ABS resin 200 parts, polymethylphenyl siloxane fluid 3 parts, dicyclohexyl phthalate 12 parts, epoxidation tetrachlorophthalic acid ester 5 parts, phosphorous acid ester 6 parts, butyronitrile rubber 5 parts, oxidized polyethlene wax 4 parts, microcrystalline wax 1 part, calcium zinc stabilizer 3 parts.
The preparation method of above-mentioned packaging high tenacity ABS film, comprises the following steps:
(1) ABS resin 200 parts, polymethylphenyl siloxane fluid 3 parts, dicyclohexyl phthalate 12 parts is taken, epoxidation tetrachlorophthalic acid ester 5 parts, phosphorous acid ester 6 parts, butyronitrile rubber 5 parts, oxidized polyethlene wax 4 parts, microcrystalline wax 1 part, calcium zinc stabilizer 3 parts are poured in reactor, 260 revs/min are stirred 45min, be heated to 130 DEG C, pressurization 1.5MPa, reaction 80min obtains polymer melt;
(2) add in parallel double-screw tablets press by the melt that step (1) obtains, 250 DEG C of extruding pelletizations, drying, obtain polyester slice;
(3) by the polyester slice of step (2) 250 DEG C melt extrude, slab spooling, 125 DEG C of two-way stretches, cooling and shaping, obtain packaging high tenacity ABS film.
Packaging high tenacity ABS film performance test result prepared by embodiment 1-4 is as following table:
Table 1 high tenacity ABS film performance test result
| Test event | Testing standard | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 |
| Tensile strength (MPa) | ASTM D638 | 98 | 92 | 95 | 93 |
| Flexural strength (MPa) | ASTM D790 | 112 | 108 | 105 | 110 |
| Modulus in flexure (MPa) | ASTM D790 | 2332 | 2241 | 2228 | 2305 |
The invention is not restricted to embodiment here, those skilled in the art, according to announcement of the present invention, do not depart from improvement that scope makes and amendment all should within protection scope of the present invention.
Claims (8)
1. a packaging high tenacity ABS film, it is characterized in that, comprise the component of following weight part: ABS resin 120-220 part, polymethylphenyl siloxane fluid 1-8 part, dicyclohexyl phthalate 2-15 part, epoxidation tetrachlorophthalic acid ester 1-6 part, phosphorous acid ester 3-12 part, butyronitrile rubber 4-9 part, oxidized polyethlene wax 0.5-6 part, microcrystalline wax 0.3-2 part, calcium zinc stabilizer 0.4-5 part.
2. packaging high tenacity ABS film according to claim 1, it is characterized in that, comprise the component of following weight part: ABS resin 160-200 part, polymethylphenyl siloxane fluid 3-6 part, dicyclohexyl phthalate 5-10 part, epoxidation tetrachlorophthalic acid ester 2-5 part, phosphorous acid ester 5-8 part, butyronitrile rubber 6-8 part, oxidized polyethlene wax 1.5-2 part, microcrystalline wax 0.5-1.5 part, calcium zinc stabilizer 0.6-3 part.
3. packaging high tenacity ABS film according to claim 2, it is characterized in that, comprise the component of following weight part: ABS resin 180 parts, polymethylphenyl siloxane fluid 4 parts, dicyclohexyl phthalate 6 parts, epoxidation tetrachlorophthalic acid ester 3 parts, phosphorous acid ester 7 parts, butyronitrile rubber 7 parts, oxidized polyethlene wax 1.8 parts, microcrystalline wax 1.2 parts, calcium zinc stabilizer 0.9 part.
4. a preparation method for packaging high tenacity ABS film, is characterized in that, the method comprises the following steps:
(1) ABS resin 120-220 part, polymethylphenyl siloxane fluid 1-8 part, dicyclohexyl phthalate 2-15 part is taken, epoxidation tetrachlorophthalic acid ester 1-6 part, phosphorous acid ester 3-12 part, butyronitrile rubber 4-9 part, oxidized polyethlene wax 0.5-6 part, microcrystalline wax 0.3-2 part, calcium zinc stabilizer 0.4-5 part are poured in reactor, stir 30-60min, be heated to 120-140 DEG C, pressurization 0.8-2.0MPa, reaction 60-90min obtains polymer melt;
(2) add in parallel double-screw tablets press by the melt that step (1) obtains, extruding pelletization, drying, obtain polyester slice;
(3) polyester slice of step (2) is melt extruded, slab spooling, two-way stretch, cooling and shaping, obtain packaging high tenacity ABS film.
5. the preparation method of packaging high tenacity ABS film according to claim 4, is characterized in that, in step (1), its speed of described stirring is 250-300 rev/min.
6. the preparation method of packaging high tenacity ABS film according to claim 4, is characterized in that, in step (2), its temperature of described extruding pelletization is 240-250 DEG C.
7. the preparation method of packaging high tenacity ABS film according to claim 4, is characterized in that, in step (3), described in melt extrude its temperature be 240-250 DEG C.
8. the preparation method of packaging high tenacity ABS film according to claim 4, is characterized in that, in step (3), its temperature of described two-way stretch is 120-130 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510880465.5A CN105440557A (en) | 2015-12-03 | 2015-12-03 | High-tenacity ABS film for packaging and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510880465.5A CN105440557A (en) | 2015-12-03 | 2015-12-03 | High-tenacity ABS film for packaging and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105440557A true CN105440557A (en) | 2016-03-30 |
Family
ID=55551225
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510880465.5A Pending CN105440557A (en) | 2015-12-03 | 2015-12-03 | High-tenacity ABS film for packaging and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105440557A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106398092A (en) * | 2016-08-24 | 2017-02-15 | 宁波鸿雁包装材料有限公司 | Packaging winding film |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1185797A (en) * | 1996-03-26 | 1998-06-24 | 大赛璐化学工业株式会社 | Styrene resin composition and molding thereof |
| DE10030636A1 (en) * | 2000-06-29 | 2002-01-10 | Basf Ag | Thermoplastic styrene homo- or copolymer molding composition, useful for production of molded articles, film, fiber and foam contains polyethyleneimine homo or copolymer |
| CN101885895A (en) * | 2010-07-28 | 2010-11-17 | 太仓市华鼎塑料有限公司 | Modification method of ABS resin and modified ABS resin |
| CN104419130A (en) * | 2013-09-04 | 2015-03-18 | 青岛欣展塑胶有限公司 | Core-shell particle toughened PET/ABS (polyethylene terephthalate/acrylonitrile butadiene styrene) composite material |
-
2015
- 2015-12-03 CN CN201510880465.5A patent/CN105440557A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1185797A (en) * | 1996-03-26 | 1998-06-24 | 大赛璐化学工业株式会社 | Styrene resin composition and molding thereof |
| DE10030636A1 (en) * | 2000-06-29 | 2002-01-10 | Basf Ag | Thermoplastic styrene homo- or copolymer molding composition, useful for production of molded articles, film, fiber and foam contains polyethyleneimine homo or copolymer |
| CN101885895A (en) * | 2010-07-28 | 2010-11-17 | 太仓市华鼎塑料有限公司 | Modification method of ABS resin and modified ABS resin |
| CN104419130A (en) * | 2013-09-04 | 2015-03-18 | 青岛欣展塑胶有限公司 | Core-shell particle toughened PET/ABS (polyethylene terephthalate/acrylonitrile butadiene styrene) composite material |
Non-Patent Citations (2)
| Title |
|---|
| 刘西文 等: "《塑料挤出工 中、高级 培训教程》", 31 January 2013, 印刷工业出版社 * |
| 罗河胜 等: "《实用ABS树脂》", 31 July 1991, 广东科技出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106398092A (en) * | 2016-08-24 | 2017-02-15 | 宁波鸿雁包装材料有限公司 | Packaging winding film |
| CN106398092B (en) * | 2016-08-24 | 2018-10-26 | 宁波鸿雁包装材料有限公司 | A kind of packaging winding film |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105440400A (en) | Anti-aging PE film for packaging and preparation method thereof | |
| CN104449469B (en) | A kind of preparation method of multi-layer co-extruded barrier package polyethylene adhering resin | |
| CN103073787B (en) | Special material for injection molding of low temperature resistant food barrel, and its preparation method | |
| CN103554632B (en) | A kind of High-strength linear low density polyethylene film resin and preparation method thereof | |
| CN104371597B (en) | A kind of preparation method of multi-layer co-extruded barrier package polypropylene adhering resin | |
| CN105440401A (en) | High-tenacity PE film for packaging and preparation method thereof | |
| CN102746575A (en) | Polypropylene and kieselguhr composite material and method for preparing same | |
| CN105440436A (en) | Anti-aging PP film for packaging and preparation method thereof | |
| CN105482291A (en) | Ageing-proof PVC film for packaging, and making method thereof | |
| CN106700272A (en) | Low-density low-shrinkage polypropylene composite material and preparation method thereof | |
| CN106009184A (en) | PE (Poly Ethylene) heat shrink film and preparation method thereof | |
| CN105440469A (en) | High-tenacity PS film for packaging and preparation method thereof | |
| CN105440556A (en) | Anti-aging ABS film for packaging and preparation method thereof | |
| CN104448739A (en) | Composite medical chitosan/ polycaprolactone film and preparation method thereof | |
| CN104119594A (en) | Scratch-resistant PE (polyethylene) film packaging material and preparation method thereof | |
| CN105440557A (en) | High-tenacity ABS film for packaging and preparation method thereof | |
| CN105440435A (en) | High-tenacity PP film for packaging and preparation method thereof | |
| CN105440478A (en) | High-tenacity PVC film for packaging and preparation method thereof | |
| CN105440470A (en) | Anti-aging PS film for packaging and preparation method thereof | |
| CN104558989A (en) | Heat-insulating antibacterial composite plastic film | |
| CN103965546A (en) | Polypropylene nanocomposite and preparation method thereof | |
| CN107573597A (en) | It is adapted to blow molding process to prepare the acrylic resin of clear hollow product | |
| CN102504501A (en) | High-barrier polyester composite material and preparation method thereof | |
| CN104292641A (en) | High-transparency filling material as well as preparation method and application of high-transparency filling material | |
| CN103601970B (en) | A kind of High-strength transparent plastic barrel |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20160330 |
|
| WD01 | Invention patent application deemed withdrawn after publication |