CN105428215A - Metal stress layer and hydrophilic agent treatment based epitaxial wafer complete stripping method - Google Patents

Metal stress layer and hydrophilic agent treatment based epitaxial wafer complete stripping method Download PDF

Info

Publication number
CN105428215A
CN105428215A CN201510799470.3A CN201510799470A CN105428215A CN 105428215 A CN105428215 A CN 105428215A CN 201510799470 A CN201510799470 A CN 201510799470A CN 105428215 A CN105428215 A CN 105428215A
Authority
CN
China
Prior art keywords
epitaxial wafer
metal stresses
layer
epitaxial
substrate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510799470.3A
Other languages
Chinese (zh)
Inventor
毛明明
张杨
杨翠柏
黄鸿
韦瑞强
马涤非
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhongshan Dehua Chip Technology Co Ltd
Original Assignee
Zhongshan Dehua Chip Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhongshan Dehua Chip Technology Co Ltd filed Critical Zhongshan Dehua Chip Technology Co Ltd
Priority to CN201510799470.3A priority Critical patent/CN105428215A/en
Publication of CN105428215A publication Critical patent/CN105428215A/en
Pending legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/02002Preparing wafers
    • H01L21/02005Preparing bulk and homogeneous wafers
    • H01L21/02032Preparing bulk and homogeneous wafers by reclaiming or re-processing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B43/00Operations specially adapted for layered products and not otherwise provided for, e.g. repairing; Apparatus therefor
    • B32B43/006Delaminating
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/02104Forming layers
    • H01L21/02365Forming inorganic semiconducting materials on a substrate
    • H01L21/02656Special treatments
    • H01L21/02664Aftertreatments
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/18Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
    • H01L31/1892Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof methods involving the use of temporary, removable substrates
    • H01L31/1896Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof methods involving the use of temporary, removable substrates for thin-film semiconductors
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Landscapes

  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Electromagnetism (AREA)
  • Recrystallisation Techniques (AREA)

Abstract

The invention discloses a metal stress layer and hydrophilic agent treatment based epitaxial wafer complete stripping method. The method is mainly characterized in that by utilizing a characteristic of high corrosive selection ratio of AlAs in HF acid, a metal stress layer with the preset thickness is introduced; under the action of the metal stress layer, an epitaxial structure on an epitaxial wafer is curled upwards, so that the epitaxial structure can be separated from a substrate of the epitaxial wafer in time and a corrosive liquid can supplement a region in which a reaction is to be performed; meanwhile, a hydrophilic agent is introduced to effectively reduce the surface tension of a contact surface, reduce a contact angle, enable air bubbles generated in the reaction to be discharged in time and promote the proceeding of the reaction; and in addition, by utilizing high uniformity and repeatability of an electronic beam evaporation device, large-batch metal stress layers can be prepared simultaneously and then substrates are removed in batch, wherein the substrates can be recycled. With the method, the completely stripped substrate and the completely stripped epitaxial structure can be obtained.

Description

A kind of epitaxial wafer whole stripping means based on metal stresses layer and hydrophilizing agent process
Technical field
The present invention relates to field of semiconductor photoelectron technique, refer in particular to a kind of epitaxial wafer whole stripping means based on metal stresses layer and hydrophilizing agent process.
Background technology
Compound semiconductor device is GaAs such as, indium phosphide etc., affects by its material factor, price and the relative silicon-based electronic devices of cost, always higher, and the part occupying cost significant proportion then comes from the substrate needed for epitaxial growth.If substrate can be recycled, the cost then occupying the opto-electronic device of critical role based on the semiconductor laser, solar cell, hetero-junction bipolar transistor, High Electron Mobility Transistor etc. of GaAs, indium phosphide in Signal transmissions, optical communication, electronic signal process then can largely reduce, and the thin-film solar cells after removal substrate, thin film semiconductor's laser is at power-weight ratio, and the aspects such as heat dissipation characteristics all will significantly be better than traditional device.
In early days, the method that substrate major part adopts mechanical lapping is removed.In recent years, based on the substrate desquamation recovery technology of sacrifice layer process favor by more researchers.For germanium base, GaAs based, indium phosphide device, generally all adopts certain thickness AlAs sacrifice layer, utilizes its corrosion Selection radio characteristic high in HF (hydrogen fluorine) acid to realize the stripping of epitaxial layer structure.But in lateral encroaching process, if reaction product fails to drain in time, sacrifice layer can not contact by timely with fresh corrosive liquid, then largely can hinder carrying out further of reaction, even make reaction stop.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art and shortcoming, propose a kind of epitaxial wafer whole stripping means based on metal stresses layer and hydrophilizing agent process, the method can obtain the complete substrate stripped down, and the complete epitaxial structure stripped down.
For achieving the above object, technical scheme provided by the present invention is: a kind of epitaxial wafer whole stripping means based on metal stresses layer and hydrophilizing agent process, the corrosion Selection radio characteristic that the method mainly utilizes AlAs high in HF acid, introduce the metal stresses layer of preset thickness, under the effect of metal stresses layer, epitaxial structure on epitaxial wafer will upsweep, thus epitaxial structure can be separated in time with the substrate of epitaxial wafer, make corrosive liquid can supplement question response district in time, introduce hydrophilizing agent simultaneously, effectively to reduce the surface tension of contact-making surface, reduce contact angle, the steam bubble that reaction is produced can be drained in time, and then advance the carrying out of reaction, in addition, utilize high uniformity and the repeatability of electron beam evaporation equipment, metal stresses layer can be prepared in enormous quantities simultaneously, then batch carries out substrate removal, and substrate recoverable, it comprises the following steps:
1) the complete epitaxial wafer of growth is carried out organic washing and oxide on surface cleaning, to improve the bonding force of metal stresses layer on epitaxial wafer surface, wherein said epitaxial wafer comprises the substrate, AlAs sacrifice layer, the device function structure sheaf that are cascading from bottom to up;
2) the complete epitaxial wafer of cleaning is moved to electron beam evaporation equipment, the mode of electron beam evaporation is adopted to carry out repeatedly evaporation, the device function structure sheaf of epitaxial wafer prepares metal stresses layer, wherein in preparation process, control key process parameter, to control the stress of metal stresses layer, until the thickness of metal stresses layer reaches preset requirement;
3) epitaxial wafer complete for evaporation is put into jam, and carry out epitaxial structure stripping in level is immersed in containing hydrophilizing agent water-bath HF etchant solution, can obtain after soaking Preset Time peeling off complete epitaxial structure, substrate is recycled simultaneously.
In step 1) in, described AlAs sacrificial layer thickness is 5-15nm;
The organic washing of carrying out and oxide on surface cleaning comprise successively: acetone ultrasonic cleaning 5-7 minute; Isopropyl alcohol ultrasonic cleaning 5-7 minute; The hydrochloric acid solution of dilution 50 seconds to 70 seconds, dilution proportioning is HCl:H 2o=1:1; BOE solution 50 seconds to 70 seconds.
In step 2) in, metal in described metal stresses layer is chosen as goldc grains, silver granuel or shot copper, during evaporation, vacuum degree control is on 1E-7Torr, it is per second per second to 3.5 dusts that evaporation rate is set in 2.5 dusts, and evaporation adopts clearance-type stepwise heating mode, and heating-up temperature is 145 degree to 155 degree, the heating temperatures opening time melt is complete reach vacuum level requirements time, heating time continue 30 minutes; Repeat evaporation to metal stresses layer thickness and reach 25 microns to 27 microns.
In step 3) in, described hydrophilizing agent is acetone, and bath temperature controls at 40 degree of-50 degree, and during corrosion, the placement of epitaxial wafer in jam keeps metal stresses layer side upper, and the proportioning of etchant solution is acetone: HF: water=1:1:1.
Compared with prior art, tool has the following advantages and beneficial effect in the present invention:
The invention provides a kind of epitaxial wafer whole lift-off technology based on metal stresses layer and hydrophilizing agent process, by complete for substrate stripping, can be recycled by this technology, thus significantly reduce the preparation cost of device.The experiment proved that, the time adopting the inventive method to peel off 4 cun of complete wafers can foreshorten to 13 hours, and utilize comparatively high uniformity and the repeatability of electron beam evaporation equipment, metal stresses layer can be prepared (in practice comparatively in enormous quantities simultaneously, our board used can carry out 52 operations simultaneously at every turn), then carry out substrate removal.And the opto-electronic device such as thin-film solar cells, thin film semiconductor's laser after removal substrate is all obviously better than traditional device in power-weight ratio, heat dissipation characteristics etc.
Accompanying drawing explanation
Fig. 1 is the structural representation after the upper metal stresses layer of the preparation of epitaxial wafer described in embodiment.
Embodiment
Below in conjunction with specific embodiment, the invention will be further described.
Epitaxial wafer whole stripping means based on metal stresses layer and hydrophilizing agent process described in the present embodiment, the corrosion Selection radio characteristic mainly utilizing AlAs high in HF acid, introduce the metal stresses layer of suitable thickness, and under the effect of metal stresses layer, epitaxial structure on epitaxial wafer will be curling slightly upward, thus epitaxial structure can be separated in time with the substrate of epitaxial wafer, make corrosive liquid can supplement question response district in time, introduce hydrophilizing agent simultaneously, effectively to reduce the surface tension of contact-making surface, reduce contact angle, the steam bubble that reaction is produced can be drained in time, and then advance the carrying out of reaction, in addition, utilize high uniformity and the repeatability of electron beam evaporation equipment, metal stresses layer can be prepared in enormous quantities simultaneously, then batch carries out substrate removal, and substrate recoverable, it comprises the following steps:
1) the complete epitaxial wafer of growth is carried out organic washing and oxide on surface cleaning, to improve the bonding force of metal stresses layer on epitaxial wafer surface; Wherein, described epitaxial wafer comprises the substrate, AlAs sacrifice layer, the device function structure sheaf that are cascading from bottom to up, as shown in Figure 1; And the organic washing of carrying out and oxide on surface cleaning comprise acetone ultrasonic cleaning 5-7 minute, 6 minutes preferred time successively; Isopropyl alcohol ultrasonic cleaning 5-7 minute, 6 minutes preferred time; The hydrochloric acid solution of dilution 50 seconds to 70 seconds, 60 seconds preferred time, dilution proportioning is HCl:H2O=1:1; BOE solution 50 seconds to 70 seconds, 60 seconds preferred time.
2) the complete epitaxial wafer of cleaning is moved to electron beam evaporation equipment, the mode of electron beam evaporation is adopted to carry out repeatedly evaporation, the device function structure sheaf of epitaxial wafer prepares metal stresses layer, in preparation process, control key process parameter, to control the stress of metal stresses layer, until the thickness of metal stresses layer reaches preset requirement; Wherein, the metal in described metal stresses layer is chosen as goldc grains, silver granuel or shot copper, preferred goldc grains (goldc grains chemical inertness is strong, and follow-up flow is unaffected); During evaporation, vacuum degree control is on 1E-7Torr, and it is per second per second to 3.5 dusts that evaporation rate is set in 2.5 dusts, and it is per second that preferred rate is set in 3 dusts; Evaporation adopts clearance-type stepwise heating mode, and heating-up temperature is 145 degree to 155 degree, and preferable temperature is 150 degree; The heating temperatures opening time melt is complete reach vacuum level requirements time, heating time continue 30 minutes; Repeat evaporation to metal stresses layer thickness and reach 25 microns to 27 microns.
3) epitaxial wafer (as shown in Figure 1 structure) complete for evaporation is put into jam, and carry out epitaxial structure stripping in level is immersed in containing hydrophilizing agent water-bath HF etchant solution, can obtain after soaking Preset Time peeling off complete epitaxial structure (epitaxial structure can be bonded to technique flow support substrates being carried out conventional solar cell), substrate is recycled simultaneously.Wherein, described hydrophilizing agent is acetone; Bath temperature controls at 40 degree of-50 degree, preferably 45 degree; During corrosion, the placement of epitaxial wafer in jam keeps metal stresses layer side upper; The proportioning of etchant solution is acetone: HF: water=1:1:1.
Remarks: semiconductor bar-type laser, vertical cavity surface emitting laser, hetero-junction bipolar transistor, High Electron Mobility Transistor, inverted structure solar cell, the opto-electronic devices such as flexible solar battery all can adopt this method to realize.
In sum, after the above scheme of employing, whole stripping process can be made to be able to acceleration by the inventive method, and by complete for substrate stripping, to recycle, thus can significantly reduce the preparation cost of device.The experiment proved that, the time adopting the inventive method to peel off 4 cun of complete wafers can foreshorten to 13 hours, and utilize comparatively high uniformity and the repeatability of electron beam evaporation equipment, metal stresses layer can be prepared (in practice comparatively in enormous quantities simultaneously, our board used can carry out 52 operations simultaneously at every turn), then carry out substrate removal.In addition, the opto-electronic device such as thin-film solar cells, thin film semiconductor's laser removed after substrate is all obviously better than traditional device in power-weight ratio, heat dissipation characteristics etc., is worthy to be popularized.
The examples of implementation of the above are only the preferred embodiment of the present invention, not limit practical range of the present invention with this, therefore the change that all shapes according to the present invention, principle are done, all should be encompassed in protection scope of the present invention.

Claims (4)

1. epitaxial wafer whole stripping means based on metal stresses layer and hydrophilizing agent process, it is characterized in that: the corrosion Selection radio characteristic that the method mainly utilizes AlAs high in HF acid, introduce the metal stresses layer of preset thickness, under the effect of metal stresses layer, epitaxial structure on epitaxial wafer will upsweep, thus epitaxial structure can be separated in time with the substrate of epitaxial wafer, make corrosive liquid can supplement question response district in time, introduce hydrophilizing agent simultaneously, effectively to reduce the surface tension of contact-making surface, reduce contact angle, the steam bubble that reaction is produced can be drained in time, and then advance the carrying out of reaction, in addition, utilize high uniformity and the repeatability of electron beam evaporation equipment, metal stresses layer can be prepared in enormous quantities simultaneously, then batch carries out substrate removal, and substrate recoverable, it comprises the following steps:
1) the complete epitaxial wafer of growth is carried out organic washing and oxide on surface cleaning, to improve the bonding force of metal stresses layer on epitaxial wafer surface, wherein said epitaxial wafer comprises the substrate, AlAs sacrifice layer, the device function structure sheaf that are cascading from bottom to up;
2) the complete epitaxial wafer of cleaning is moved to electron beam evaporation equipment, the mode of electron beam evaporation is adopted to carry out repeatedly evaporation, the device function structure sheaf of epitaxial wafer prepares metal stresses layer, wherein in preparation process, control key process parameter, to control the stress of metal stresses layer, until the thickness of metal stresses layer reaches preset requirement;
3) epitaxial wafer complete for evaporation is put into jam, and carry out epitaxial structure stripping in level is immersed in containing hydrophilizing agent water-bath HF etchant solution, can obtain after soaking Preset Time peeling off complete epitaxial structure, substrate is recycled simultaneously.
2. a kind of epitaxial wafer whole stripping means based on metal stresses layer and hydrophilizing agent process according to claim 1, is characterized in that: in step 1) in, described AlAs sacrificial layer thickness is 5-15nm;
The organic washing of carrying out and oxide on surface cleaning comprise successively: acetone ultrasonic cleaning 5-7 minute; Isopropyl alcohol ultrasonic cleaning 5-7 minute; The hydrochloric acid solution of dilution 50 seconds to 70 seconds, dilution proportioning is HCl:H 2o=1:1; BOE solution 50 seconds to 70 seconds.
3. a kind of epitaxial wafer whole stripping means based on metal stresses layer and hydrophilizing agent process according to claim 1, it is characterized in that: in step 2) in, metal in described metal stresses layer is chosen as goldc grains, silver granuel or shot copper, during evaporation, vacuum degree control is on 1E-7Torr, it is per second per second to 3.5 dusts that evaporation rate is set in 2.5 dusts, evaporation adopts clearance-type stepwise heating mode, heating-up temperature is 145 degree to 155 degree, the heating temperatures opening time melt is complete reach vacuum level requirements time, heating time continue 30 minutes; Repeat evaporation to metal stresses layer thickness and reach 25 microns to 27 microns.
4. a kind of epitaxial wafer whole stripping means based on metal stresses layer and hydrophilizing agent process according to claim 1, it is characterized in that: in step 3) in, described hydrophilizing agent is acetone, bath temperature controls at 40 degree of-50 degree, during corrosion, the placement of epitaxial wafer in jam keeps metal stresses layer side upper, and the proportioning of etchant solution is acetone: HF: water=1:1:1.
CN201510799470.3A 2015-11-19 2015-11-19 Metal stress layer and hydrophilic agent treatment based epitaxial wafer complete stripping method Pending CN105428215A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510799470.3A CN105428215A (en) 2015-11-19 2015-11-19 Metal stress layer and hydrophilic agent treatment based epitaxial wafer complete stripping method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510799470.3A CN105428215A (en) 2015-11-19 2015-11-19 Metal stress layer and hydrophilic agent treatment based epitaxial wafer complete stripping method

Publications (1)

Publication Number Publication Date
CN105428215A true CN105428215A (en) 2016-03-23

Family

ID=55506339

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201510799470.3A Pending CN105428215A (en) 2015-11-19 2015-11-19 Metal stress layer and hydrophilic agent treatment based epitaxial wafer complete stripping method

Country Status (1)

Country Link
CN (1) CN105428215A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107275186A (en) * 2017-06-16 2017-10-20 中山德华芯片技术有限公司 A kind of preparation method of flexible structure support substrate
CN107649785A (en) * 2017-09-22 2018-02-02 北京世纪金光半导体有限公司 A kind of wafer thining method and device
CN116252188A (en) * 2023-05-15 2023-06-13 苏州焜原光电有限公司 Method for removing epitaxial layer from gallium antimonide epitaxial wafer

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102804408A (en) * 2009-09-10 2012-11-28 密歇根大学董事会 Methods of preparing flexible photovoltaic devices using epitaxial liftoff, and preserving the integrity of growth substrates used in epitaxial growth
CN103811626A (en) * 2012-11-12 2014-05-21 天津中环新光科技有限公司 Red light emitting diode with high-reflectivity metal reflecting layer and preparation method thereof
CN104362196A (en) * 2014-11-25 2015-02-18 苏州矩阵光电有限公司 InGaAs infrared detector and preparing method thereof
CN105070412A (en) * 2015-08-27 2015-11-18 西安交通大学 Method for transferring silver nano wire transparent electrode by use of dry method

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102804408A (en) * 2009-09-10 2012-11-28 密歇根大学董事会 Methods of preparing flexible photovoltaic devices using epitaxial liftoff, and preserving the integrity of growth substrates used in epitaxial growth
CN103811626A (en) * 2012-11-12 2014-05-21 天津中环新光科技有限公司 Red light emitting diode with high-reflectivity metal reflecting layer and preparation method thereof
CN104362196A (en) * 2014-11-25 2015-02-18 苏州矩阵光电有限公司 InGaAs infrared detector and preparing method thereof
CN105070412A (en) * 2015-08-27 2015-11-18 西安交通大学 Method for transferring silver nano wire transparent electrode by use of dry method

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107275186A (en) * 2017-06-16 2017-10-20 中山德华芯片技术有限公司 A kind of preparation method of flexible structure support substrate
CN107649785A (en) * 2017-09-22 2018-02-02 北京世纪金光半导体有限公司 A kind of wafer thining method and device
CN116252188A (en) * 2023-05-15 2023-06-13 苏州焜原光电有限公司 Method for removing epitaxial layer from gallium antimonide epitaxial wafer
CN116252188B (en) * 2023-05-15 2023-08-11 苏州焜原光电有限公司 Method for removing epitaxial layer from gallium antimonide epitaxial wafer

Similar Documents

Publication Publication Date Title
US6448155B1 (en) Production method of semiconductor base material and production method of solar cell
EP2620409B1 (en) Method for producing thin, free-standing layers of solid state materials with structured surfaces
US6649485B2 (en) Method for the formation and lift-off of porous silicon layers
CN1188898C (en) Method for producing semiconductor unit, method for producing solar cell and anodizing process equipment
US7022585B2 (en) Method for making thin film devices intended for solar cells or silicon-on-insulator (SOI) applications
CN1127122C (en) Substrate processing method and apparatus and SOI substrate
CN110534474B (en) Method for preparing film on substrate
KR101113849B1 (en) Method for isolating flexible substrate from support substrate
WO2017177499A1 (en) Method for stripping flexible substrate
CN105428215A (en) Metal stress layer and hydrophilic agent treatment based epitaxial wafer complete stripping method
JPH0897389A (en) Preparation of structure that has semiconductor thin film onsubstrate
CN103545239B (en) Epitaxial wafer stripping process based on films
CN104078407A (en) Thin film and method for manufacturing thin film
CN1541406A (en) Detachable substrate with controlled mechanical hold and method for prodn. thereof
JP2001284622A (en) Method for manufacturing semiconductor member and method for manufacturing solar cell
WO2003092041B1 (en) Method for fabricating a soi substrate a high resistivity support substrate
CN105190835A (en) Method for producing hybrid substrate, and hybrid substrate
CN110120438B (en) Preparation method of solar cell based on metal flexible substrate
RU2515420C2 (en) Method of making photoconverter with integrated diode
ES2946702T3 (en) Recycling procedure for the silver present in a photovoltaic cell
CN107275186A (en) A kind of preparation method of flexible structure support substrate
CN111446164A (en) Manufacturing method of edge-gentle-slope/step-shaped wafer
KR20110028265A (en) Method of forming an electronic device including removing a differential etch layer
JP2002100791A (en) Manufacturing method for solar battery
CN105280541A (en) Temporary bonding method and bonding-removing method for ultrathin semiconductor wafer

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20160323

WD01 Invention patent application deemed withdrawn after publication