CN105424632B - A kind of micro water vapor detectable concentration method of range automatic control - Google Patents

A kind of micro water vapor detectable concentration method of range automatic control Download PDF

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CN105424632B
CN105424632B CN201511019511.9A CN201511019511A CN105424632B CN 105424632 B CN105424632 B CN 105424632B CN 201511019511 A CN201511019511 A CN 201511019511A CN 105424632 B CN105424632 B CN 105424632B
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signal
lock
harmonic
chip microcomputer
amplifier
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CN105424632A (en
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陈希
常军
魏巍
刘媛媛
王福鹏
刘永宁
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Shandong University
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    • G01N21/25Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
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Abstract

A kind of micro water vapor concentration detection method of range automatic control, belong to gas sensing system detection field, system composition includes single-chip microcomputer, laser temperature control and drive module, Distributed Feedback Laser, air chamber, photodetector, Current Voltage modular converter, lock-in amplifier, precision voltage reference generator, subtracter, gain control module, signal acquisition module.The system is transformed the measurement range selection module of the multichannel preset parameter in traditional secondary Harmonic Method micro water vapor detecting system, after lock-in amplifier obtains the also harmonic amplitude of concentration information, harmonics are controlled using gain control module, and pass through the information exchange between gain control module and signal acquisition module, range automatic control is realized, water vapor concentration under test gas is worth to finally by output harmonic wave amplitude and gain.This method breaks limitation of the concentration range to circuit measuring, expands detecting concentration scope, effectively improves signal to noise ratio, is conducive to extracting gas concentration information.

Description

A kind of micro water vapor detectable concentration method of range automatic control
Technical field
Gas sensing system detection field of the present invention is a kind of while being referred to using high-accuracy voltage, direct current is adjusted and single The new method that the control of piece machine is gathered to trace amounts of water vapor concentration information.
Background technology
Water is the important substance that we depend on for existence, and detection water vapor concentration is all significant in many fields.For example Dielectric gas SF in extra-high voltage electric transmission and transformation system equipment6In when containing moisture, toxicity and corrosivity very strong chemicals can be generated Matter, etching insulative equipment, or even explode.Water content in food-processing industry, packaging bag is exceeded, can directly affect food Quality.Water content is more in transformer oil, and oily aging itself, apparatus insulated aging and metal parts corrosion rate are faster; The presence of natural gas reclaimed water can cause pipeline water blocking, and corroded pipeline, instrument and equipment influence the degree of accuracy of gas metering, given The safety in production of natural gas and using causing high risks.And fiber gas sensor is because its stability is good, measurement accuracy is high, anti- The advantages of electromagnetic interference, on-line checking, achievable non-electric detection, obtains more and more extensive in the measurement of trace gas concentration Using.
Nowadays it is the method for quadratic harmonics for measurement micro water vapor most efficient method, belongs to fiber gas sensor A kind of effectively application, this method measurement accuracy is high, and stability is good, strong antijamming capability.In order to adapt to the vapor of wider range Measurement of concetration, while system signal noise ratio is further improved, in different concentration ranges, it is necessary to set the different circuit parameter of multichannel Selective circuit of measuring range, this causes circuit lengthy and jumbled, the wasting of resources, and can introduce more circuits noise.Therefore, in the urgent need to one kind Simple effective detection method solves the above problems.
Harbin Engineering University Zhang Keke writes paper《Spectral absorption formula fiber-optic fiber gas etection theory and technical research》In The second-harmonic detection method mentioned is that laser is modulated using first harmonic, the laser signal after gas absworption peak The signals of a large amount of frequencies of carrying, carrying out secondary frequency Harmonic Detection under secondary reference signal auxiliary using lock-in amplifier can The signal of other frequency contents is filtered to obtain the secondary singal comprising gas concentration information.The second harmonic eventually detected The amplitude of signal is relevant with water vapor concentration, as water vapor concentration increases, and linear increase is presented in harmonic amplitude.If do not taken Corresponding measure, in the moisture concentration detection of wide scope, the harmonic amplitude having under the concentration range of part exceeds acquisition range. Therefore different circuit parameter processing must be carried out to the vapor under various concentrations, can so causes circuit complicated, conversion trouble, And other circuit noises are easily introduced, therefore detection ease is restricted.
The content of the invention
In order to overcome the defect and deficiency of prior art, the micro water vapor detection that the present invention provides a kind of range automatic control is dense Degree method, this method can more simple and convenient and the accurate detection for effectively carrying out water vapor concentration.
The technical scheme of the inventive method is as follows:
A kind of micro water vapor detectable concentration method of range automatic control, is realized, the system includes by following measuring system Chip Microcomputer A, single-chip microcomputer B, temperature control drive module, Distributed Feedback Laser, air chamber, photodetector, Current Voltage modular converter, lock phase Amplifier, precision voltage reference generator, subtracter, gain control module and signal acquisition module, temperature control drive module bag Temperature control module and drive module are included, Chip Microcomputer A connection drive module, temperature control drive module is connected with Distributed Feedback Laser, and DFB swashs Light device is located at before air chamber, photodetector is placed behind air chamber, photodetector output end is connected to Current Voltage modulus of conversion The input of block, Current Voltage modular converter output end is connected with lock-in amplifier, and Chip Microcomputer A connects the ginseng of lock-in amplifier Signal input part is examined, reference signal is provided for lock-in amplifier;Lock-in amplifier is connected with the normal phase input end of subtracter, by locking The second harmonic that the demodulation of phase amplifier is obtained can send into the normal phase input end of subtracter, precision voltage reference generator and subtraction The negative input of device is connected, and gain control module is connected between the output end of subtracter and negative input negative anti-to constitute Connected mode is presented, while gain control module and signal acquisition module are connected with single-chip microcomputer B respectively, to control harmonic amplitude to increase The backfeed loop of benefit, signal acquisition module often gathers an amplitude, and single-chip microcomputer B controls gain control module is once adjusted, The data of the harmonic amplitude collected and the yield value of adjustment are inputted computer by single-chip microcomputer B by serial ports simultaneously, and in electricity Preservation is shown in brain, this method step is as follows:
1) above-mentioned each part is connected, switched on power, debugging light path and circuit can normal works;Open air chamber Valve, under test gas is injected in air chamber, inflates 20 minutes, it is ensured that without other gas residues in air chamber;
2) scanning signal that Chip Microcomputer A produces primary modulation Signal averaging low frequency inputs drive module as drive signal, Drive module drives the luminous of Distributed Feedback Laser, while temperature control module controls laser. operating temperature, Chip Microcomputer A also produces one Frequency is twice in the reference signal input of the secondary reference signal input lock-in amplifier of primary modulation ripple, mutually amplifies for locking Device frequency-selecting, before formal measurement, oscillograph is connected on respectively drive module output end and lock-in amplifier reference signal input, Check whether drive signal and reference signal are normal;
3) the laser input air chamber that laser is sent produces absorption, and the optical signal after absorption reaches photodetection through optical fiber Device, photodetector converts optical signal into current signal, and signal is changed into carrying aqueous vapor by Current Voltage modular converter The voltage signal of information, Current Voltage modular converter output end connection lock-in amplifier input, lock-in amplifier is for the electricity Press signal and reference signal to carry out lock phase processor, obtain including the second harmonic signal of moisture concentration information;
4) for ensure second harmonic signal in the collectable scope of signal acquisition module, it is necessary to lock-in amplifier export Harmonic signal carry out DC offset voltage adjustment, lock-in amplifier output end connect subtracter normal phase input end, high accuracy The negative input of pedestal generator connection subtracter provides high-accuracy stable voltage for subtracter, by adjusting high accuracy The voltage swing that pedestal generator is produced, adjustment participates in the DC voltage size of subtracter computing, reaches adjustment harmonic wave letter The purpose of number DC offset voltage;
5) input of the second harmonic signal entering signal acquisition module exported by subtracter, signal acquisition module is to two Subharmonic carries out amplitude collection, just can obtain carrying the harmonic amplitude of moisture concentration information, signal acquisition module and single-chip microcomputer B phases Even, harmonic amplitude by signal acquisition module export after input single-chip microcomputer B, the program of pre-set control gain in single-chip microcomputer B, And harmonic amplitude scope is specified, single-chip microcomputer B makes comparisons the harmonic amplitude of collection with setting range, if harmonic amplitude is in setting Within the scope of, then it is not required to adjustment;Harmonic amplitude is if greater than setting range maximum, and gain control module can control to reduce gain Value, harmonics reduce, and amplitude declines;If harmonic amplitude is less than setting range minimum value, gain control module can control to increase Large gain values, harmonics increase, amplitude becomes big;The harmonic wave being adjusted will be again introduced into signal acquisition module, repeat above-mentioned Process, often through once adjusting, single-chip microcomputer B is defeated by serial ports by the data of the harmonic amplitude collected and the yield value of adjustment Enter computer, and preservation is shown in computer, by the data of display, script harmonic amplitude is reduced, and then it is dense to obtain vapor Degree;
6) the moisture concentration detection of under test gas is finished, and closes power supply.
The Cleaning Principle that the present invention is used such as Harbin Engineering University Zhang Keke writes paper《Spectral absorption fiber-optic fiber gas is examined Survey theoretical and technical research》Described, at one atm, the absorption of vapor can linearly be represented by lorentzian curve, red Wave section, the absorption coefficient of vapor is smaller, and the output intensity of normal atmosphere pressure is represented by:
I (v)=I0(v)[1-α(v)CL] (1)
α (υ) is gas in the absorption coefficient that light frequency is at υ in formula, and L is light path of the light by under test gas, and C is to be measured The volumetric concentration of gas.The temperature and direct driving current of laser are adjusted, it is to be scheduled on a certain suction of vapor to make optical maser wavelength Receive at peak.Then, the sinusoidal signal of appropriate frequency and amplitude is superimposed in the driving current signal of laser, to the ripple of laser Length is modulated, and it is changed at absworption peak by sinusoidal rule, laser instantaneous output is:
(t)=vc+Δνcosωt (2)
Δ ν is modulation amplitude in formula, and ω is modulation angular frequency, νcFor filters center frequency.Laser wavelength is stable At absorbent core, that is, there is νc0, normalized frequency skew x can be represented using line half-width γ and instantaneous frequency ν
In formula:x0=(νc0)/γ;M=Δs ν/γ is the wavelength index of modulation.After being absorbed by gas, what is detected is defeated Going out signal is
S (x)=I (x)=I (x0+mcosωt) (4)
Fourier expansion is carried out to (4), direct current and 1, the expression formula of 2,3 subharmonic, for warbled Lip river is can obtain Human relations hereby for line style, contain the concentration letter of under test gas in the even harmonics signal amplitude at the centre frequency of Absorption Line Breath, available for measurement gas concentration.Water vapor concentration is bigger, and harmonic amplitude can be higher.But the maximum of each even harmonics signal Amplitude reduces with the increase of overtone order, only even-order harmonic and second harmonic signal be it is most strong in each harmonic, two Subharmonic expression formula is as follows
In formula:X=1-x2+m2
The signal of other frequencies of the target signal filter of second harmonic frequency is locked using Phase Lock Technique, second harmonic is detected, if Now secondary harmonic amplitude is A.Because the second harmonic signal demodulated is without direct current biasing, DC reference voltage is added, will Second harmonic is adjusted in the collectable scope of signal acquisition module, and DC reference voltage does not change second harmonic width Value, it is assumed that direct current adjustment reference voltage is M, and output voltage now is
S′2(x)=S2(x)+M (6)
Now second harmonic S '2(x) amplitude is still in A, the concentration range of different ranges, to make secondary harmonic amplitude same One scope is, it is necessary to be amplified multiple adjustment, it is assumed that p times of signal intensity, then now output signal is
S″2(x)=p [S2(x)+M] (7)
The secondary harmonic amplitude collected is pA, in the signal processing, will be secondary humorous by permanent circuit parameters relationship Wave amplitude is reduced, you can obtain water vapor concentration information.
Second harmonic measurement range selection part is the fortune by different amplification in traditional micro water vapor detecting system Circuit realiration is put, measurement range selection scope is small, parameter setting is complicated, troublesome poeration, and circuit is lengthy and jumbled, and noise is big.The present invention Gain control module is added, the part adjusted as harmonic signal gain factor, by single-chip microcomputer control, passes through signal acquisition mould The backfeed loop of block-single-chip microcomputer-gain control module formation control harmonics, monitors secondary harmonic amplitude, while fast in real time The whole yield value of velocity modulation so that harmonic amplitude is in the acquisition range of setting, and final water vapor concentration information is by adopting to obtain second harmonic Amplitude is together decided on yield value.This method breaks traditions the limitation of circuit measurement range selection, no matter moisture concentration size, gain adjusts Mould preparation block in acquisition range, expands moisture concentration measurement range by harmonic amplitude adjustment.The circuit system is more succinctly stablized, Signal-to-Noise is effectively improved, and the performance boost for micro water vapor Concentration Testing has very great help.
Brief description of the drawings
Fig. 1 be the present invention realize system construction drawing.
Wherein:1st, Chip Microcomputer A, 2, temperature control drive module, 3, Distributed Feedback Laser, 4, air chamber, 5, photodetector, 6, electric current Voltage transformation module, 7, lock-in amplifier, 8, subtracter, 9, gain control module, 10, precision voltage reference generator, 11, Signal acquisition module, 12, single-chip microcomputer B, 13, the reference signal of lock-in amplifier, 14, drive signal.
Fig. 2 is that the drive signal that single-chip microcomputer is sent is transferred to drive module to drive laser to light, and the waveform is by height What frequency sine-wave Signal averaging was obtained in low frequency trapezoidal wave scanning signal.
The harmonic signal that Fig. 3 obtains for detection, the amplitude of harmonic signal also has the information of moisture concentration, therefore collection harmonic wave Amplitude just can obtain moisture concentration.
Embodiment
The invention will be further described with reference to the accompanying drawings and examples, but not limited to this.
Embodiment:
As shown in figure 1, a kind of micro water vapor detectable concentration method of range automatic control, is realized by following measuring system, The system includes Chip Microcomputer A, B, temperature control drive module 2, Distributed Feedback Laser 3, air chamber 4, photodetector 5, Current Voltage modulus of conversion Block 6, lock-in amplifier 7, subtracter 8, gain control module 9, precision voltage reference generator 10 and signal acquisition module 11, Temperature control drive module 2 includes temperature control module and drive module, Chip Microcomputer A connection drive module, temperature control drive module and DFB laser Device 3 is connected, and Distributed Feedback Laser 3 is located at before air chamber 4, and air chamber 4 places photodetector 5, the output end of photodetector 5 below The input of Current Voltage modular converter 6 is connected to, the output end of Current Voltage modular converter 6 is connected with lock-in amplifier 7, it is single The reference signal input of piece machine A connections lock-in amplifier 7, is that lock-in amplifier 7 provides reference signal;Lock-in amplifier 7 with The normal phase input end of subtracter 8 is connected, and the positive that the second harmonic obtained by the demodulation of lock-in amplifier 7 can send into subtracter 8 is defeated Enter end, precision voltage reference generator 10 is connected with the negative input of subtracter 8, and gain control module 9 is connected to subtraction To constitute negative-feedback connected mode between the output end and negative input of device 8, while gain control module 9 and signal acquisition mould Block 11 is connected with single-chip microcomputer B respectively, and to control the backfeed loop of harmonic amplitude gain, signal acquisition module often gathers once width Value, single-chip microcomputer B controls gain control module is once adjusted, while single-chip microcomputer B is by the harmonic amplitude collected and tune The data of whole yield value input computer by serial ports, and show in computer preservation, and this method step is as follows:
1) above-mentioned each part is connected, switched on power, debugging light path and circuit can normal works;Open air chamber Valve, under test gas is injected in air chamber, inflates 20 minutes, it is ensured that without other gas residues in air chamber;
2) scanning signal that Chip Microcomputer A produces primary modulation Signal averaging low frequency inputs drive module as drive signal, Drive module drives the luminous of Distributed Feedback Laser, while temperature control module controls laser. operating temperature, Chip Microcomputer A also produces one Frequency is twice in the reference signal input of the secondary reference signal input lock-in amplifier of primary modulation ripple, mutually amplifies for locking Device frequency-selecting.Before formal measurement, oscillograph is connected on to drive module output end and lock-in amplifier reference signal input respectively, Check whether drive signal and reference signal are normal;
3) the laser input air chamber that laser is sent produces absorption, and the optical signal after absorption reaches photodetection through optical fiber Device, converts optical signal into current signal, and signal is changed into the voltage for carrying aqueous vapor information by Current Voltage modular converter Signal, Current Voltage modular converter output end connection lock-in amplifier input, lock-in amplifier is for the voltage signal and ginseng Examine signal and carry out lock phase processor, obtain including the second harmonic signal of moisture concentration information;
4) for ensure second harmonic signal in the collectable scope of signal acquisition module, it is necessary to lock-in amplifier export Harmonic signal carry out DC offset voltage adjustment, lock-in amplifier output end connect subtracter normal phase input end, high accuracy The negative input of pedestal generator connection subtracter provides high-accuracy stable voltage for subtracter, by adjusting high accuracy The voltage swing that pedestal generator is produced, adjustment participates in the DC voltage size of subtracter computing, reaches adjustment harmonic wave letter The purpose of number DC offset voltage;
5) input of the second harmonic signal entering signal acquisition module exported by subtracter, signal acquisition module is to two Subharmonic carries out amplitude collection, just can obtain carrying the harmonic amplitude of moisture concentration information, signal acquisition module and single-chip microcomputer B phases Even, harmonic amplitude by signal acquisition module export after input single-chip microcomputer B, the program of pre-set control gain in single-chip microcomputer B, And harmonic amplitude scope is specified, single-chip microcomputer B makes comparisons the harmonic amplitude of collection with setting range, if harmonic amplitude is in setting Within the scope of, then it is not required to adjustment;Harmonic amplitude is if greater than setting range maximum, and gain control module can control to reduce gain Value, harmonics reduce, and amplitude declines;If harmonic amplitude is less than setting range minimum value, gain control module can control to increase Large gain values, harmonics increase, amplitude becomes big;The harmonic wave being adjusted will be again introduced into signal acquisition module, repeat above-mentioned Process, often through once adjusting, single-chip microcomputer B is defeated by serial ports by the data of the harmonic amplitude collected and the yield value of adjustment Enter computer, and preservation is shown in computer, by the data of display, script harmonic amplitude is reduced, and then it is dense to obtain vapor Degree;
6) the moisture concentration detection of under test gas is finished, and closes power supply.

Claims (1)

1. a kind of micro water vapor detectable concentration method of range automatic control, is realized by following measuring system, the system includes single Piece machine A, single-chip microcomputer B, temperature control drive module, Distributed Feedback Laser, air chamber, photodetector, Current Voltage modular converter, lock are mutually put Big device, precision voltage reference generator, subtracter, gain control module and signal acquisition module, temperature control drive module include Temperature control module and drive module, Chip Microcomputer A connection drive module, temperature control drive module are connected with Distributed Feedback Laser, DFB laser Device is located at before air chamber, photodetector is placed behind air chamber, photodetector output end is connected to Current Voltage modular converter Input, Current Voltage modular converter output end is connected with lock-in amplifier, and Chip Microcomputer A connects the reference of lock-in amplifier Signal input part, reference signal is provided for lock-in amplifier;Lock-in amplifier is connected with the normal phase input end of subtracter, by lock phase The second harmonic that amplifier demodulation is obtained can send into the normal phase input end of subtracter, precision voltage reference generator and subtracter Negative input be connected, gain control module is connected between the output end of subtracter and negative input to constitute negative-feedback Connected mode, while gain control module and signal acquisition module are connected with single-chip microcomputer B respectively, to control harmonic amplitude gain Backfeed loop, signal acquisition module often gathers an amplitude, and single-chip microcomputer B controls gain control module is once adjusted, together When single-chip microcomputer B the data of the harmonic amplitude collected and the yield value of adjustment are inputted into computer by serial ports, and in computer Middle display is preserved, and this method step is as follows:
1) above-mentioned each part is connected, switched on power, debugging light path and circuit can normal works;Open air-chamber valve Door, under test gas is injected in air chamber, inflates 20 minutes, it is ensured that without other gas residues in air chamber;
2) scanning signal that Chip Microcomputer A produces primary modulation Signal averaging low frequency inputs drive module, driving as drive signal Module drive Distributed Feedback Laser it is luminous, while temperature control module controls laser. operating temperature, Chip Microcomputer A also produces a frequency The secondary reference signal for being twice in primary modulation ripple inputs the reference signal input of lock-in amplifier, for lock-in amplifier choosing Frequently, before formal measurement, oscillograph is connected on to drive module output end and lock-in amplifier reference signal input respectively, checked Whether drive signal and reference signal are normal;
3) the laser input air chamber that laser is sent produces absorption, and the optical signal after absorption reaches photodetector, light through optical fiber Electric explorer converts optical signal into current signal, is changed into signal by Current Voltage modular converter and carries aqueous vapor information Voltage signal, Current Voltage modular converter output end connection lock-in amplifier input, lock-in amplifier is for the voltage signal Lock phase processor is carried out with reference signal, obtains including the second harmonic signal of moisture concentration information;
4) for ensure second harmonic signal in the collectable scope of signal acquisition module, it is necessary to lock-in amplifier export it is humorous Ripple signal carries out DC offset voltage adjustment, and lock-in amplifier output end connects the normal phase input end of subtracter, high precision reference The negative input of voltage generator connection subtracter provides high-accuracy stable voltage for subtracter, by adjusting high precision reference The voltage swing that voltage generator is produced, adjustment participates in the DC voltage size of subtracter computing, reaches that adjustment harmonic signal is straight Flow the purpose of bias voltage;
5) input of the second harmonic signal entering signal acquisition module exported by subtracter, signal acquisition module is to secondary humorous Ripple carries out amplitude collection, just can obtain carrying the harmonic amplitude of moisture concentration information, and signal acquisition module is connected with single-chip microcomputer B, Harmonic amplitude by signal acquisition module export after input single-chip microcomputer B, the program of pre-set control gain in single-chip microcomputer B, and Harmonic amplitude scope is specified, single-chip microcomputer B makes comparisons the harmonic amplitude of collection with setting range, if harmonic amplitude is in setting model Within enclosing, then adjustment is not required to;Harmonic amplitude is if greater than setting range maximum, and gain control module can control to reduce gain Value, harmonics reduce, and amplitude declines;If harmonic amplitude is less than setting range minimum value, gain control module can control to increase Large gain values, harmonics increase, amplitude becomes big;The harmonic wave being adjusted will be again introduced into signal acquisition module, repeat above-mentioned Process, often through once adjusting, single-chip microcomputer B is defeated by serial ports by the data of the harmonic amplitude collected and the yield value of adjustment Enter computer, and preservation is shown in computer, by the data of display, script harmonic amplitude is reduced, and then it is dense to obtain vapor Degree;
6) the moisture concentration detection of under test gas is finished, and closes power supply.
CN201511019511.9A 2015-12-29 2015-12-29 A kind of micro water vapor detectable concentration method of range automatic control Expired - Fee Related CN105424632B (en)

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