CN105419661A - Anti-impact double-component acrylate structure adhesive and preparation method thereof - Google Patents
Anti-impact double-component acrylate structure adhesive and preparation method thereof Download PDFInfo
- Publication number
- CN105419661A CN105419661A CN201610006904.4A CN201610006904A CN105419661A CN 105419661 A CN105419661 A CN 105419661A CN 201610006904 A CN201610006904 A CN 201610006904A CN 105419661 A CN105419661 A CN 105419661A
- Authority
- CN
- China
- Prior art keywords
- component
- parts
- acrylate
- mixtures
- structural adhesive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
- C09J4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/07—Aldehydes; Ketones
- C08K5/08—Quinones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/11—Esters; Ether-esters of acyclic polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/12—Esters; Ether-esters of cyclic polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
- C08K5/18—Amines; Quaternary ammonium compounds with aromatically bound amino groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention relates to an anti-impact double-component acrylate structure adhesive. The structure adhesive is used after mixing according to the volume ratio of 10:1. A component A is prepared from, by weight, 40-60 parts of rigid acrylate monomer, 20-30 parts of high-breaking-elongation acrylic resin, 10-20 parts of core-shell particles, 0.1-0.5 part of fatty amine, 0.5-1 part of aromatic amine, 0.1-2 parts of phosphate ester and 0.01-1 part of stabilizer. A component B is prepared from, by weight, 10-50 parts of an initiator, 20-70 parts of a plasticizer, 1-10 parts of a thickener and 0.1-20 parts of color paste. The structure adhesive has very high impact resistance and can meet the requirement of adhesion of large-size and narrow-frame display screens and frames.
Description
Technical field
The present invention relates to polymeric material field, be specifically related to a kind of shock resistance bi-component acrylic ester structure glue.
Background technology
Handheld electric products is more and more universal, and particularly touch display screen has been widely used in the electronic products such as mobile phone, flat board, computer.The material of touch display screen is all toughened glass, and glass can only by bonding mode with the connection of electronic product framework.Current technique is bonded in the external frame of electronic product by glass display screen by Reactive hot melt adhesive.The large size of touch display screen and narrow frame are the important directions of development at present.Large size meets the visualization requirements of people, and narrow frame meets the esthetic requirement of people.And the size of display screen is larger, the bonding force of display screen and framework just requires larger; The frame of display screen is narrower, and the area that it can be bonding is less, and this just requires that the bonding strength of unit bond area will have greatly improved before comparing.The important method weighing bonding strength is exactly anti-drop experiment.Anti-drop experiment is mainly weighed by impact shear strength.The cementitious product with HI high impact shearing resistance is the developing direction in market.
Current packaging technology adopts Reactive hot melt adhesive to carry out bonding, and the feature of hot melt adhesive is that glue-line is soft, and anti-vibration resistance is better, but bonding strength is lower, needs larger bond area, could meet anti-drop requirement.But along with the application of narrow frame and large size screen, bond area reduces, and hot melt adhesive can not meet bonding demand, and the set time of hot melt adhesive is oversize, generally need more than 2 hours, the production efficiency of serious restriction client.
S-generation acrylate adhesive becomes to be grouped into stablizer etc. primarily of acrylate monomer, resin, rubber, initiator, promotor, and initiator and promotor are divided into two components, effectively can improve stability in storage.Acrylate structural adhesive can be used for the bonding of most metals and plastics, and adhesive effect is excellent, has the plurality of advantages such as curing speed is fast, bonding strength is high, easy to operate, has been widely used in the industries such as aviation, machinery, electronics, building, instrument, furniture.
Two-component acrylate structural adhesive does not generally explicitly call for resistance to impact shock in the market, acrylate adhesive cured glue layer more firmly, more crisp, absorb the ability of impact kinetic energy poor, therefore, in the bonding application of display screen, anti-drop requirement cannot be met.
Summary of the invention
For solving the problems of the technologies described above, the invention provides a kind of two-component acrylate structural adhesive can with higher resistance to impact shock, the effectively bonding and fast setting to display screen and framework can be realized.
Concrete technical scheme of the present invention is:
A kind of bi-component acrylic structure glue, is made up of component A and B component, after A, B component carry out proportioning mixing according to volume ratio 10:1, both described acrylate structural adhesive.
Described component A comprises following raw material composition (by mass fraction): rigid acrylates's monomer 40 parts-60 parts, high elongation at tear acrylic resin 20-30 part, core-shell particles 10-20 part, aliphatic amide 0.1 part-0.5 part, aromatic amine 0.5 part-1 part, phosphoesterase 30 .1-2 part, stablizer 0.01 part-1 part.
Described B component comprises following raw material composition (by mass fraction): initiator 10 parts-50 parts, 20 parts-70 parts, softening agent, thickening material 1 part-10 parts, mill base 0.1 part-2.0 parts.
Described rigid acrylates's monomer is methyl methacrylate, methacrylic acid, (methyl) isobornyl acrylate, acryloyl morpholine, trimethyl-cyclohexane acrylate, one or more mixtures in cyclohexane dimethanol diacrylate.
Described high elongation at tear acrylic resin is one or more mixtures in polyester type acrylic resin, polyether-type acrylic resin, and the acrylic resin of high elongation at tear is the resin that elongation at break is greater than 300%.
Described aliphatic amide is one or more mixtures in quadrol, propylene diamine, hexanediamine, diethylamine, triethylamine, trolamine, dipropyl amine, tripropyl amine.
Described aromatic amine is N, N-dimethyl-p-toluidine, N, N-diethyl-p-tlouidine, benzyldimethylamine, one or more mixtures of N, N-dihydroxyethyl p-toluidine.
Described rigid acrylates's monomer and the rational proportion of high elongation at tear acrylate are between 1.5-3.0, and the ratio of compound resin and core-shell particles is between 4.0-7.0.
Described aliphatic amide and the rational proportion of aromatic amine are between 0.1-0.5.
Described phosphoric acid ester is one or more mixtures in PM-2, PM1500, PM1520, PM3030, PM3060, CD9050, CD9051.
Described core-shell particles is ABS, MBS, styrene-butadiene rubber(SBR) core-shell particles, one or more mixtures in divinyl rubber core-shell particles.
Described initiator is benzoyl peroxide.
Described stablizer is Resorcinol, para benzoquinone, 1,4-naphthoquinone, 2,6 di tert butyl 4 methyl phenol, one or more mixtures in Na4EDTA.
Described softening agent is dioctyl phthalate (DOP), dibutyl phthalate, dimethyl phthalate, Octyl adipate, dioctyl sebacate, bisphenol A epoxide resin, one or more mixtures in bisphenol F epoxy resin.
Described thickening material is organobentonite, aerosil, hydrogenated castor oil, one or more mixtures in polyethylene wax.
Described pigment is one or more mixtures in phthalocyanine blue, barba hispanica, solvent blue.
The preparation method of structure glue of the present invention is:
Prepared by component A: by acrylate rigid unitary, high elongation at tear vinylformic acid tree, the mixing of stablizer fat, then core-shell particles is added and stir, add phosphoric acid ester successively, aliphatic amide stirs, finally add aromatic series promotor and stir evenly, froth in vacuum, discharging obtains component A.
Prepared by B component: mixed with initiator by softening agent, add pigment and mix, finally add thickening material and stir evenly, froth in vacuum discharging obtains B component.
After component A and B component carry out proportioning mixing according to volume ratio 10:1, both described acrylate structural adhesive.
Beneficial effect of the present invention is:
(1) select rigid acrylates's monomer and high elongation at tear acrylic resin composite, coordinate core-shell particles, improve the ability of glue-line bulk absorption impact energy.
(2) adopt aliphatic amide and the two promotor initiator system of aromatic amine, realize the unhomogeneity of cured article internal structure, improve impact resistance.In aliphatic amide and phosphoric acid ester and after, form solubility strong acid weak base salt, acrylate local PhastGel can be impelled, but cannot deeply-curing, generate low-molecular weight polymer, absorb stress as elastic particle; Aromatic amine promotor causes crosslinking curing again to the unreacted acrylate of residue, forms framework and the main structure of colloid.
(3) this structure glue can realize impact shear strength and is greater than 30KJ/m
2, elongation reaches more than 250%, and have the operating time long, viscosity is low simultaneously, and applying glue is convenient, the features such as storage at room temperature good stability.
Embodiment
Below in conjunction with specific embodiment, the present invention is further described, but the present invention is not limited thereto.
Embodiment 1
A kind of esters of acrylic acid structure glue, comprise component A and B component, by mass fraction, each composition component is as follows:
| B component raw material | ％ |
| Peroxidation is to benzoyl | 30 |
| Bisphenol A epoxide resin | 40 |
| Dioctyl sebacate | 27 |
| Aerosil | 2 |
| Phthalocyanine blue | 1 |
Preparation technology:
Prepared by component A: accurately take methyl methacrylate, isobornyl methacrylate, polyester acrylate, 2,6 di tert butyl 4 methyl phenol mix; Then ABS powder is added, make it disperse completely; Add PM-2, diethylamine mixes; Add N again, N-dimethyl-p-toluidine also stirs; Last froth in vacuum, namely discharging obtains component A.
Prepared by B component: accurately take benzoyl peroxide, bisphenol A epoxide resin and dioctyl sebacate, mix, add phthalocyanine blue and aerosil, stir, last froth in vacuum, obtain bicomponent structural adhesive B component.
Finally by component A and B component according to volume ratio 10:1 mix both described acrylate structural adhesive.
Embodiment 2
A kind of esters of acrylic acid structure glue, comprise component A and B component, by mass fraction, each composition component is as follows:
| Component A raw material | ％ |
| Methyl methacrylate | 47.6 |
| Acryloyl morpholine | 10 |
| Polyester acrylate | 30 |
| MBS | 10 |
| Trolamine | 0.3 |
| N, N-dihydroxyethyl p-toluidine | 1 |
| Para benzoquinone | 0.1 |
| Phosphoric acid ester PM1500 | 1 |
| B component raw material | ％ |
| Benzoyl peroxide | 30 |
| Bisphenol F epoxy resin | 30 |
| Octyl adipate | 36 |
| Aerosil | 3 |
| Barba hispanica | 1 |
Preparation technology:
Prepared by component A: accurately take methyl methacrylate, acryloyl morpholine, polyester acrylate, para benzoquinone mix; Then MBS powder is added, make it disperse completely; Add PM1500, trolamine mixes; Add N again, N-dihydroxyethyl p-toluidine, and stir; Last froth in vacuum, namely discharging obtains component A.
Prepared by B component: accurately take benzoyl peroxide, bisphenol F epoxy resin and Octyl adipate, mix, add barba hispanica, meteorological silicon-dioxide, stir, after removing bubble, namely discharging obtains B component.
Finally by component A and B component according to volume ratio 10:1 mix both described acrylate structural adhesive.
Embodiment 3
A kind of esters of acrylic acid structure glue, comprise component A and B component, by mass fraction, each composition component is as follows:
| Component A raw material | ％ |
| Methyl methacrylate | 47.6 |
| Trimethyl-cyclohexane acrylate | 15 |
| Polyether acrylates | 20 |
| Phosphoric acid ester CD9051 | 1 |
| MBS | 15 |
| Triethylamine | 0.3 |
| N, N-dimethyl-p-toluidine | 1 |
| Para benzoquinone | 0.1 |
Prepared by component A: accurately take methyl methacrylate, trimethyl-cyclohexane acrylate, polyether acrylates, para benzoquinone mix; Then MBS is added, make it disperse completely; Add phosphoric acid ester CD9051, triethylamine mixes; Add N again, N-dimethyl-p-toluidine mixes; Last froth in vacuum, namely discharging obtains component A.
Prepared by B component: accurately take benzoyl peroxide, bisphenol F epoxy resin and dibutyl phthalate, mix, add barba hispanica, polyoxyethylene wax, stir, after removing bubble, namely discharging obtains B component.
Finally by component A and B component according to volume ratio 10:1 mix both described acrylate structural adhesive.
According to GB/T7124-2008 tackiness agent tensile shear strength testing standard, test the shearing resistance of ink coating and aluminium alloy; According to ASTMD950-1998 tackiness agent impact shear strength testing standard, test the impact shear strength of ink coating and aluminium alloy, according to GB/T1040.1-2006 sizing agent body tensile strength testing standard, test the elongation at break of glue-line body, in table 1.
Table 1
As can be seen from the above table, compared with commercially available acrylic ester structure adhesive, it is effectively bonding that two-component acrylate structural adhesive stick of the present invention achieves ink coating, shock resistance shearing resistance improves 2 times, and the operating time is long, meet the Complex Assembly technique of electronic product to the demand of longer operating time.
Claims (9)
1. an acrylate structural adhesive, is characterized in that, counts by weight, component A comprises: rigidity Acrylic Acid Monomer 40 parts-60 parts, high elongation at tear acrylic resin 20-30 part, core-shell particles 10-20 part, aliphatic amide 0.1 part-0.5 part, aromatic amine 0.5 part-1 part, phosphoesterase 30 .1-2 part;
B component comprises: initiator 10 parts-50 parts, 20 parts-70 parts, softening agent, thickening material 1 part-10 parts.
2. acrylate structural adhesive according to claim 1, is characterized in that, described aliphatic amide is one or more mixtures in quadrol, propylene diamine, hexanediamine, diethylamine, triethylamine, trolamine, dipropyl amine, tripropyl amine.
3. acrylate structural adhesive according to claim 1, it is characterized in that, described rigid acrylates's monomer is methyl methacrylate, methacrylic acid, (methyl) isobornyl acrylate, acryloyl morpholine, trimethyl-cyclohexane acrylate, one or more mixtures in cyclohexane dimethanol diacrylate;
Described high elongation at tear acrylic resin is one or more mixtures in polyester type acrylic resin, polyether-type acrylic resin.
4. acrylate structural adhesive according to claim 1, is characterized in that, described aromatic amine is N, N-dimethyl-p-toluidine, N, N-diethyl-p-tlouidine, benzyldimethylamine, one or more mixtures in N, N-dihydroxyethyl p-toluidine.
5. acrylate structural adhesive according to claim 1, is characterized in that, described core-shell particles is ABS, MBS, styrene-butadiene rubber(SBR) core-shell particles, one or more mixtures in divinyl rubber core-shell particles.
6. acrylate structural adhesive according to claim 1, is characterized in that described phosphoric acid ester is one or more mixtures in PM-2, PM1500, PM1520, PM3030, PM3060, CD9050, CD9051;
Described initiator is benzoyl peroxide;
Described softening agent is dioctyl phthalate (DOP), dibutyl phthalate, dimethyl phthalate, Octyl adipate, dioctyl sebacate, bisphenol A epoxide resin, one or more mixtures in bisphenol F epoxy resin;
Described thickening material is organobentonite, aerosil, hydrogenated castor oil, one or more mixtures in polyethylene wax.
7. acrylate structural adhesive according to claim 1, it is characterized in that the proportioning (by weight mark meter) of described rigid acrylates's monomer and high elongation at tear acrylate is between 1.5-3.0, the proportioning (by weight mark meter) of compound resin and core-shell particles is between 4.0-7.0.
8. acrylate structural adhesive according to claim 1, is characterized in that the proportioning (by weight mark meter) of described aliphatic amide and aromatic amine is between 0.1-0.5.
9. the method for the acrylate structural adhesive of preparation as described in any one of claim 1-8, it is characterized in that, prepared by component A: by acrylate rigid unitary, high elongation at tear vinylformic acid tree, stablizer mixing, then core-shell particles is added and stir, add phosphoric acid ester successively, aliphatic amide stirs, finally add aromatic series promotor to stir evenly, froth in vacuum, discharging obtains component A;
Prepared by B component: mixed with initiator by softening agent, add pigment and mix, finally add thickening material and stir evenly, froth in vacuum discharging obtains B component;
Component A and B component mix according to volume ratio 10:1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610006904.4A CN105419661B (en) | 2016-01-05 | 2016-01-05 | A kind of shock resistance bi-component acrylic ester structure glue and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610006904.4A CN105419661B (en) | 2016-01-05 | 2016-01-05 | A kind of shock resistance bi-component acrylic ester structure glue and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105419661A true CN105419661A (en) | 2016-03-23 |
| CN105419661B CN105419661B (en) | 2018-07-06 |
Family
ID=55498216
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610006904.4A Active CN105419661B (en) | 2016-01-05 | 2016-01-05 | A kind of shock resistance bi-component acrylic ester structure glue and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105419661B (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106590447A (en) * | 2016-12-14 | 2017-04-26 | 湖北回天新材料股份有限公司 | Acrylate adhesive for bonding bullet train roof reinforcing ribs |
| WO2019012088A1 (en) * | 2017-07-12 | 2019-01-17 | Arkema France | (meth) acrylic adhesive composition, its method of preparation and its use |
| CN112778942A (en) * | 2021-01-29 | 2021-05-11 | 厦门韦尔通科技有限公司 | Bi-component acrylate structural adhesive capable of being rapidly cured by hot pressing and long in operable time after being mixed at normal temperature and preparation method thereof |
| JP2021531389A (en) * | 2018-07-25 | 2021-11-18 | ヘンケル アイピー アンド ホールディング ゲゼルシャフト ミット ベシュレンクテル ハフツング | Fast Curing Epoxy Acrylic Liquid Sim |
| CN116564577A (en) * | 2023-05-09 | 2023-08-08 | 上海席亚高分子材料有限公司 | High-elasticity conductive silver paste for flexible circuit and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102115641A (en) * | 2010-12-03 | 2011-07-06 | 烟台德邦科技有限公司 | High-toughness acrylate structural adhesive and preparation method thereof |
| CN104178075A (en) * | 2014-08-27 | 2014-12-03 | 北京海斯迪克新材料有限公司 | Double-component acrylate structure adhesive for bonding electrophoretic coating materials |
-
2016
- 2016-01-05 CN CN201610006904.4A patent/CN105419661B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102115641A (en) * | 2010-12-03 | 2011-07-06 | 烟台德邦科技有限公司 | High-toughness acrylate structural adhesive and preparation method thereof |
| CN104178075A (en) * | 2014-08-27 | 2014-12-03 | 北京海斯迪克新材料有限公司 | Double-component acrylate structure adhesive for bonding electrophoretic coating materials |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106590447A (en) * | 2016-12-14 | 2017-04-26 | 湖北回天新材料股份有限公司 | Acrylate adhesive for bonding bullet train roof reinforcing ribs |
| WO2019012088A1 (en) * | 2017-07-12 | 2019-01-17 | Arkema France | (meth) acrylic adhesive composition, its method of preparation and its use |
| FR3068979A1 (en) * | 2017-07-12 | 2019-01-18 | Arkema France | (METH) ACRYLIC ADHESIVE COMPOSITION, PROCESS FOR PREPARING THE SAME, AND USE THEREOF |
| CN110832044A (en) * | 2017-07-12 | 2020-02-21 | 阿科玛法国公司 | (meth) acrylic adhesive composition, method for producing same, and use thereof |
| JP2020527621A (en) * | 2017-07-12 | 2020-09-10 | アルケマ フランス | (Meta) Acrylic Adhesive Composition, Its Preparation Method and Its Use |
| JP7463269B2 (en) | 2017-07-12 | 2024-04-08 | アルケマ フランス | (Meth)acrylic adhesive composition, method for preparing same and use thereof |
| JP2021531389A (en) * | 2018-07-25 | 2021-11-18 | ヘンケル アイピー アンド ホールディング ゲゼルシャフト ミット ベシュレンクテル ハフツング | Fast Curing Epoxy Acrylic Liquid Sim |
| JP7259006B2 (en) | 2018-07-25 | 2023-04-17 | ヘンケル・アクチェンゲゼルシャフト・ウント・コムパニー・コマンディットゲゼルシャフト・アウフ・アクチェン | Fast curing epoxy acrylic liquid shim |
| CN112778942A (en) * | 2021-01-29 | 2021-05-11 | 厦门韦尔通科技有限公司 | Bi-component acrylate structural adhesive capable of being rapidly cured by hot pressing and long in operable time after being mixed at normal temperature and preparation method thereof |
| CN116564577A (en) * | 2023-05-09 | 2023-08-08 | 上海席亚高分子材料有限公司 | High-elasticity conductive silver paste for flexible circuit and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105419661B (en) | 2018-07-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105419661A (en) | Anti-impact double-component acrylate structure adhesive and preparation method thereof | |
| EP0647251B1 (en) | Surface mount conductive adhesives | |
| DE68913867T2 (en) | Adhesive for low temperature applications. | |
| CN104327752B (en) | A kind of weathering resistance and the acrylic acid structure glue had good stability | |
| US9216434B2 (en) | Light-heat dual curing anisotropic conductive adhesive, anisotropic conductive film and preparation methods thereof | |
| CN103160212A (en) | Ultraviolet light curing optical adhesive | |
| CN102604561B (en) | Aqueous adhesive and preparation method thereof | |
| CN103305132A (en) | Fast-curing structural adhesive and preparation method thereof | |
| CN103409095A (en) | Flexible one-component epoxy adhesive and preparation method thereof | |
| CN109355048A (en) | Epoxy adhesive capable of being rapidly cured at ultralow temperature and preparation method thereof | |
| CN111073526A (en) | Fast-positioning two-component acrylate structural adhesive and preparation and use methods thereof | |
| CN104277724A (en) | Special adhesive for thermoplastic PVC table tennis | |
| CN104178038A (en) | Instant-drying solvent-free adhesive for PVC (polyvinyl chloride) pipeline bonding | |
| CN102876270A (en) | Epoxy resin conducting adhesive with high bonding strength | |
| CN101338173A (en) | Single-component anaerobic structure glue and method for preparing same | |
| CN102827565A (en) | One-component epoxy adhesive for automobiles and preparation method thereof | |
| CN101935510A (en) | Epoxy resin conductive silver colloid with high adhesive strength | |
| CN110343502A (en) | A kind of rubber-plastic composite floor board solvent-free polyurethane adhesive and preparation method thereof | |
| CN108949064A (en) | A kind of high foaming rate automobile PVC foam primary coat glue and preparation method thereof | |
| CN101463235A (en) | High elongation rate acrylic ester adhesive | |
| CN102153979A (en) | Intermediate-temperate rapidly-cured surface mount adhesive for lead-free welding | |
| CN109957077A (en) | A kind of two-component room-temperature self crosslinking binder and preparation method | |
| CN108410392B (en) | Glue for water-based spray glue, water-based spray glue and preparation method thereof | |
| CN102373029A (en) | Preparation method of rapid curing of flexible conductive adhesive under room temperature | |
| CN107141658B (en) | A kind of modified polyvinyl chloride paste resin and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |