CN105419532B - Waterproof is anti-corrosion traffic mark Noctilucent material and preparation method and applications - Google Patents
Waterproof is anti-corrosion traffic mark Noctilucent material and preparation method and applications Download PDFInfo
- Publication number
- CN105419532B CN105419532B CN201511033686.5A CN201511033686A CN105419532B CN 105419532 B CN105419532 B CN 105419532B CN 201511033686 A CN201511033686 A CN 201511033686A CN 105419532 B CN105419532 B CN 105419532B
- Authority
- CN
- China
- Prior art keywords
- waterproof
- traffic mark
- corrosion
- luminescent coating
- organic solvent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000005260 corrosion Methods 0.000 title claims abstract description 40
- 239000000463 material Substances 0.000 title claims abstract description 34
- 238000002360 preparation method Methods 0.000 title abstract description 10
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 47
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 40
- 239000011248 coating agent Substances 0.000 claims abstract description 35
- 238000000576 coating method Methods 0.000 claims abstract description 35
- 239000003960 organic solvent Substances 0.000 claims abstract description 33
- 230000002209 hydrophobic effect Effects 0.000 claims abstract description 28
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 19
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims abstract description 18
- 150000004645 aluminates Chemical class 0.000 claims abstract description 17
- 239000002994 raw material Substances 0.000 claims abstract description 4
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 54
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 38
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 29
- 239000004925 Acrylic resin Substances 0.000 claims description 18
- 239000005084 Strontium aluminate Substances 0.000 claims description 18
- 229920000178 Acrylic resin Polymers 0.000 claims description 17
- 239000011737 fluorine Substances 0.000 claims description 13
- 229910052731 fluorine Inorganic materials 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 13
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 10
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims description 9
- 229910001650 dmitryivanovite Inorganic materials 0.000 claims description 5
- 229910001707 krotite Inorganic materials 0.000 claims description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 4
- 239000011347 resin Substances 0.000 claims description 4
- 229920005989 resin Polymers 0.000 claims description 4
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims 2
- 241000790917 Dioxys <bee> Species 0.000 claims 1
- 229910003978 SiClx Inorganic materials 0.000 claims 1
- XYIBRDXRRQCHLP-UHFFFAOYSA-N ethyl acetoacetate Chemical compound CCOC(=O)CC(C)=O XYIBRDXRRQCHLP-UHFFFAOYSA-N 0.000 claims 1
- 239000002904 solvent Substances 0.000 claims 1
- 239000000126 substance Substances 0.000 abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 6
- 238000004078 waterproofing Methods 0.000 abstract description 4
- 230000003628 erosive effect Effects 0.000 abstract description 3
- 230000007062 hydrolysis Effects 0.000 abstract description 3
- 238000006460 hydrolysis reaction Methods 0.000 abstract description 3
- 230000007797 corrosion Effects 0.000 abstract description 2
- 231100000252 nontoxic Toxicity 0.000 abstract description 2
- 230000003000 nontoxic effect Effects 0.000 abstract description 2
- 239000007789 gas Substances 0.000 description 19
- 239000000758 substrate Substances 0.000 description 16
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 11
- 238000012360 testing method Methods 0.000 description 9
- 239000003973 paint Substances 0.000 description 8
- 239000008399 tap water Substances 0.000 description 8
- 235000020679 tap water Nutrition 0.000 description 8
- 238000009825 accumulation Methods 0.000 description 5
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- 229920001296 polysiloxane Polymers 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 4
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 4
- NLQFUUYNQFMIJW-UHFFFAOYSA-N dysprosium(III) oxide Inorganic materials O=[Dy]O[Dy]=O NLQFUUYNQFMIJW-UHFFFAOYSA-N 0.000 description 4
- 238000007654 immersion Methods 0.000 description 4
- 229940043265 methyl isobutyl ketone Drugs 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 229910000018 strontium carbonate Inorganic materials 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 235000013339 cereals Nutrition 0.000 description 3
- RSEIMSPAXMNYFJ-UHFFFAOYSA-N europium(III) oxide Inorganic materials O=[Eu]O[Eu]=O RSEIMSPAXMNYFJ-UHFFFAOYSA-N 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- 239000002253 acid Substances 0.000 description 2
- 229910000278 bentonite Inorganic materials 0.000 description 2
- 239000000440 bentonite Substances 0.000 description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 2
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 2
- 230000001680 brushing effect Effects 0.000 description 2
- 239000011247 coating layer Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000003760 hair shine Effects 0.000 description 2
- BDAGIHXWWSANSR-NJFSPNSNSA-N hydroxyformaldehyde Chemical compound O[14CH]=O BDAGIHXWWSANSR-NJFSPNSNSA-N 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- LEDMRZGFZIAGGB-UHFFFAOYSA-L strontium carbonate Chemical compound [Sr+2].[O-]C([O-])=O LEDMRZGFZIAGGB-UHFFFAOYSA-L 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 206010013786 Dry skin Diseases 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 229910017504 Nd(NO3)3 Inorganic materials 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 229910003669 SrAl2O4 Inorganic materials 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- -1 alkaline-earth metal Aluminate Chemical class 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 229910021502 aluminium hydroxide Inorganic materials 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 238000003889 chemical engineering Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000005543 nano-size silicon particle Substances 0.000 description 1
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/22—Luminous paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/32—Radiation-absorbing paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/66—Additives characterised by particle size
- C09D7/67—Particle size smaller than 100 nm
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Nanotechnology (AREA)
- Paints Or Removers (AREA)
- Luminescent Compositions (AREA)
Abstract
The invention discloses a kind of anti-corrosion traffic mark luminescent coating of waterproof and preparation method and applications, and waterproof is anti-corrosion, and traffic mark luminescent coating is made of the raw material of following weight percents：Hydrophobic film-forming agent is 30 45wt%, and rear-earth-doped alkali earth metal aluminate long after glow luminous material is 10 20wt%, and organic solvent is 10 15wt%, and gas phase nano silica is 5 15wt%, and surplus is organobentonite anti-settling agent.The anti-corrosion traffic mark luminescent coating of waterproof of the invention is nontoxic, "dead", stable chemical performance, after the various visible rays such as daylight, light, environment stray light are absorbed, it automatic continuous can shine, and after the erosion of contact water, the waterproof is anti-corrosion, and traffic mark luminescent coating can prevent most rear-earth-doped alkali earth metal aluminate long after glow luminous material hydrolysis, rear-earth-doped alkali earth metal aluminate long after glow luminous material is sustainable to shine, and has good water proofing property and corrosion resistance.
Description
Technical field
The invention belongs to field of light emitting materials, relate in particular to a kind of anti-corrosion traffic mark Noctilucent material of waterproof and preparation
Method and its application.
Background technology
Road traffic mark is the graphical symbol for showing traffic law and road information, it can be vivid, specific and concise
Traffic law is expressed, while can also express the content being difficult to word description, to manage traffic and instruction direction of traffic, to protect
Demonstrate,prove the coast is clear and the facility of traffic safety.The road traffic mark majority used at present is coated with reflection-type coating, generally not
There is noctilucence.But if without street lamp on road, can only be to there be photograph at this kind of passive reflection-type traffic mark night
The vehicle of bright tool plays a role, and the pedestrian and cyclist for no illuminations cannot then play its effect substantially.Therefore,
The noctilucence traffic mark coating of active illuminant is particularly significant.As traffic mark luminescent coating, it need to be exposed to rainwater for a long time, tide
Under wet environment, the water proofing property and corrosion resistance requirement to coating are very high.Noctilucence traffic mark is generally direct by luminous paint at present
Coated in being formed on road, and be added in luminous paint rear-earth-doped alkali earth metal aluminate long after glow luminous material easily with rain
Steam in water and air hydrolyzes so that noctilucence traffic mark loses guide elicitation effect.With rear-earth-doped alkaline-earth metal
Aluminate long after glow luminous material SrAl2O4：Eu2+, Dy3+For, in SrAl2O4：Eu2+, Dy3+When being contacted with water, can slowly it send out
Raw following hydrolysis:SrAl2O4+4H2O→Sr2++2OH-+2Al(OH)3↑, which can generate aluminium hydroxide, and make system
PH value raising, not only destroyed the original crystal structure of luminescent powder, but also affect the acid-base balance of system.In rainwater and moisture
Under the influence of, the luminous intensity of rear-earth-doped alkali earth metal aluminate long after glow luminous material declines at least 50% or even completely not
It shines.
Invention content
In view of the deficiencies of the prior art, it is long containing rear-earth-doped alkali earth metal aluminate the object of the present invention is to provide one kind
The anti-corrosion traffic mark Noctilucent material of waterproof and preparation method and applications of afterglow materials.
The purpose of the present invention is what is be achieved by following technical proposals.
A kind of anti-corrosion traffic mark luminescent coating of waterproof, is made of the raw material of following weight percents：Hydrophobic film-forming agent
For 30-45wt%, rear-earth-doped alkali earth metal aluminate long after glow luminous material is 10-20wt%, organic solvent 10-
15wt%, gas phase nano silica are 5-15wt%, and surplus is organobentonite anti-settling agent；Wherein, the organic solvent is
The mixture of dimethylbenzene, ethyl acetate and butanol, the hydrophobic film-forming agent are organic siliconresin, organic fluorine and acrylic acid
The mixture of resin or organic fluorinated silicone modified acrylic resin, the rear-earth-doped alkali earth metal aluminate long after glow luminous material
For SrAl2O4：Eu2+, Dy3+、CaAl2O4：Eu2+, Nd3+Or Sr4Al14O25：Eu2+, Dy3+, by mass, in the organic solvent
The ratio of middle dimethylbenzene, butanol and ethyl acetate is (4-35)：(4-35)：1, in the hydrophobic film-forming agent organic siliconresin,
The ratio of organic fluorine and acrylic resin is (0.2-0.5)：(0.2-0.5)：1.
In the above-mentioned technical solutions, hydrophobic film-forming agent be 35-40wt%, rear-earth-doped alkali earth metal aluminate long afterglow
Luminescent material is 13-17wt%, and organic solvent 12-14wt%, gas phase nano silica is 7-13wt%, and surplus is organic
Bentonite anti-settling agent.
In the above-mentioned technical solutions, the grain size of the gas phase nano silica is 5-50 nanometers.
In the above-mentioned technical solutions, by mass, the ratio of dimethylbenzene, butanol and ethyl acetate is in the organic solvent
(20-30)：(20-30)：1.
A kind of preparation method of the anti-corrosion traffic mark luminescent coating of above-mentioned waterproof, in 20-25 DEG C of room temperature by hydrophobic film-forming
Agent, rear-earth-doped alkali earth metal aluminate long after glow luminous material, organic solvent, gas phase nano silica and organobentonite
Anti-settling agent is mixed in proportion to uniformly to get to the anti-corrosion traffic mark luminescent coating of waterproof.
In the above-mentioned technical solutions, hydrophobic film-forming agent be 35-40wt%, rear-earth-doped alkali earth metal aluminate long afterglow
Luminescent material is 13-17wt%, and organic solvent 12-14wt%, gas phase nano silica is 7-13wt%, and surplus is organic
Bentonite anti-settling agent.
In the above-mentioned technical solutions, the grain size of the gas phase nano silica is 5-50 nanometers.
In the above-mentioned technical solutions, by mass, the ratio of dimethylbenzene, butanol and ethyl acetate is in the organic solvent
(20-30)：(20-30)：1.
A kind of application of anti-corrosion traffic mark luminescent coating of above-mentioned waterproof as indication light body, uniformly sprays in road surface
The anti-corrosion traffic mark luminescent coating of waterproof described in multilayer is applied or brushes, wherein, it often sprays or one layer of waterproof of brushing is resistance to
It is after losing traffic mark luminescent coating, the anti-corrosion traffic mark luminescent coating layer of this layer of waterproof is 0.5-6 hours dry at 20-80 DEG C
To the anti-corrosion traffic mark luminescent coating layer curing of waterproof.
The anti-corrosion traffic mark luminescent coating of waterproof of the invention is nontoxic, "dead", stable chemical performance, is absorbing day
After the various visible rays such as light, light, environment stray light, without power supply, you can it is automatic continuous to shine, and in the erosion of contact water
Afterwards, the anti-corrosion traffic mark luminescent coating of the waterproof can prevent the most long-persistence luminous material of rear-earth-doped alkali earth metal aluminate
Material hydrolysis, rear-earth-doped alkali earth metal aluminate long after glow luminous material is sustainable to shine, and has good water proofing property and anti-corrosion
Property.
Specific embodiment
Dimethylbenzene, ethyl acetate, gas phase nano silica and butanol in the present embodiment are bought from Aladdin reagent
The molecular weight of (Shanghai) Co., Ltd., wherein dimethylbenzene is 106.17, product identification X112050；The molecular weight of ethyl acetate
It is 88.11, product identification E116131；Butanol is n-butanol, molecular weight 74.12, product identification B111573；Gas phase
The product identification of nano silicon dioxide is S104599, and grain size is 7-40 nanometers.Organobentonite anti-settling agent is bought from the big huge rock in Shanghai
Chemical Co., Ltd., model DP-122.Organic fluorine purchase is counted from Xuzhou Zhong Yan Science and Technology Ltd.s, model zy-1
Average molecular weight is 20000-30000.From Shanghai Wei Pu Chemical Engineering Technologies Services Co., Ltd, number is divided equally for the organic siliconresin purchase
Son amount is 500-10000.Acrylic resin is bought from Guangzhou Lian Shu commerce and trade Co., Ltd, weight average molecular weight 55000, acrylic acid
Resin includes following component, and 30-45 parts of methyl iso-butyl ketone (MIBK), 15-25 parts of acrylic acid, 7-12 parts of methacrylic acid, acrylic acid is just
1-7 parts of butyl ester, 4-15 parts of methyl iso-butyl ketone (MIBK).
Luminous paint is bought from Huang Shi chemical industry.Test equipment is CY-1000 long lad phosphors (light accumulation type fluorescent material) light
Color Performance Test System (Hangzhou Everfine Inc.).
The preparation method of organic fluorinated silicone modified acrylic resin refers to following documents：
The synthesis of the super organic fluorinated silicone modified acrylic resins of of rice and performance study [D] Shandong University when [1], 2009.
[2] Chen Meiling, Xu Limin, Ding Fan, Yang Li, the synthesis of the high macro organic fluorin modified crylic acid resins of and research [J]
New Chemical Materials, 2010,10:113-115.
[3] research [D] the Dalian University Of Communications of the synthesis of the organic fluorin modified crylic acid resins of the quick of Xu Li and its coating,
2010.
[4] Huang is maintained the achievements of one's predecessors, the fluorinated silicone modified acrylic resin synthetic technologys of Liu Xiao states and application present situation [J] Chemical Industry in Guangzhou,
2012,22:19-20+36.
[5] exploitation of the fluorinated silicone modified acrylic resins of Wang Senlan, Zhang Xiaohong, Hu Shengchu and coating and application [J] Shandong
Industrial technology, 2015,24:43.
SrAl2O4:Eu2+,Dy3+Preparation method with reference to as follows：By strontium carbonate (99.2%), alundum (Al2O3)
(99.99%) analytically pure Eu is added in2O3, Dy2O3After be uniformly mixed, at 1300 DEG C in reducing atmosphere 2 hours be burnt into,
Through crushing, luminescent material sample is obtained.Wherein, by the gauge of substance, strontium carbonate (99.2%), alundum (Al2O3) (99.99%),
Eu2O3And Dy2O3Ratio be 9:10:0.1:0.4.
CaAl2O4：Eu2+, Nd3+The preparation method of fluorescent powder is with reference to as follows：
Suitable Ca (NO are stoichiometrically measured respectively3)2, Al (NO3)3, Eu (NO3)3,Nd(NO3)3In crucible, add
Enter a certain amount of urea to being uniformly mixed, be directly placed into 450 DEG C~850 DEG C of Muffle furnace, start when moisture is quickly evaporated anti-
Should, a large amount of gases are released, reactant blisters and expands, and loose white foam, entire reaction process are formed with burning
5min.3min is kept the temperature after burning in stove, then takes out sample, in air cooled to room temperature, ground
To fluorescent powder.Wherein, by the gauge of substance, Ca (NO3)2, Al (NO3)3, Eu (NO3)3With Nd (NO3)3Ratio be 984:200:15:
1。
Sr4Al14O25：Eu2+, Dy3+The preparation method of fluorescent powder is with reference to as follows：
According to stoichiometric ratio precise SrCO3,Al2O3,Eu2O3,Dy2O3, add a certain amount of H3BO3.By raw material
Fully milling is uniformly mixed it, is then charged into aluminium oxide porcelain boat, and be put into tube furnace, under hydrogen-argon-mixed protection, rises
Temperature is to scheduled temperature, after keeping the temperature a period of time, natural cooling.It by product crushing grinding and is sieved, obtains powdered bluish-green
Color long after glow luminous material Sr4Al14O25∶Eu2+,Dy3+.Wherein, by the gauge of substance, H3BO3, SrCO3,Al2O3,Eu2O3,
Dy2O3Ratio be 1:36:7:1:1.
Test method：The anti-corrosion traffic mark luminescent coating of waterproof of the present invention is brushed on a diameter of 5 centimetres of substrate
Once, cure at 50 DEG C to the anti-corrosion traffic mark luminescent coating of waterproof within dry 0.5-6 hours, be put into more than CY-1000 long after dry
Brightness fluorescent powder (light accumulation type fluorescent material) Photochromic Properties test system is tested.After test, it will be somebody's turn to do with the anti-corrosion friendship of waterproof
The substrate of logical mark luminescent coating is put into tap water to be impregnated 6 hours for 20-25 DEG C in room temperature, after immersion at 20-25 DEG C of room temperature certainly
It so dries, and is put into CY-1000 long lad phosphors (light accumulation type fluorescent material) Photochromic Properties test system and is surveyed again
Examination.
Contrast test：The luminous paint (Huang Shi chemical industry) of purchase is brushed on a diameter of 5 centimetres of substrate, in 50 DEG C of dryings
Cure to luminous paint within 0.5-6 hours, the survey of CY-1000 long lad phosphors (light accumulation type fluorescent material) Photochromic Properties is put into after dry
Test system is tested.After test, which is put into tap water and is impregnated 6 hours for 20-25 DEG C in room temperature,
After immersion at 20-25 DEG C of room temperature naturally dry, and be put into CY-1000 long lad phosphors (light accumulation type fluorescent material) photochromism
System can be tested to be tested again.
The anti-corrosion traffic mark Noctilucent material of waterproof of the present invention and its application are described in detail with reference to embodiment.
In an embodiment of the present invention, 1 mass parts are 1g.
Embodiment 1
By hydrophobic film-forming agent, SrAl2O4：Eu2+, organic solvent, gas phase nano silica and organobentonite it is anti-settling
Agent is mixed in 20-25 DEG C of room temperature to uniformly to get to the anti-corrosion traffic mark luminescent coating of waterproof, wherein, hydrophobic film-forming agent is
30 mass parts, SrAl2O4：Eu2+For 12 mass parts, organic solvent is 11 mass parts, and gas phase nano silica is 6 mass parts,
Organobentonite anti-settling agent is 41 mass parts；Wherein, the organic solvent is the mixture of dimethylbenzene, ethyl acetate and butanol,
By mass, the ratio of dimethylbenzene, butanol and ethyl acetate is in the organic solvent：20：30：1；The hydrophobic film-forming agent
For the mixture of organic siliconresin, organic fluorine and acrylic resin, wherein, by mass, in the hydrophobic film-forming agent
The ratio of organic siliconresin, organic fluorine and acrylic resin is 0.2：0.2：1.
Embodiment 2
By hydrophobic film-forming agent, SrAl2O4：Eu2+, organic solvent, gas phase nano silica and organobentonite it is anti-settling
Agent is mixed in 20-25 DEG C of room temperature to uniformly to get to the anti-corrosion traffic mark luminescent coating of waterproof, wherein, hydrophobic film-forming agent is
35 mass parts, SrAl2O4：Eu2+For 15 mass parts, organic solvent is 12 mass parts, and gas phase nano silica is 9 mass parts,
Organobentonite anti-settling agent is 29 mass parts；Wherein, the organic solvent is the mixture of dimethylbenzene, ethyl acetate and butanol,
By mass, the ratio of dimethylbenzene, butanol and ethyl acetate is in the organic solvent：30：20：1；The hydrophobic film-forming agent
For the mixture of organic siliconresin, organic fluorine and acrylic resin, wherein, by mass, in the hydrophobic film-forming agent
The ratio of organic siliconresin, organic fluorine and acrylic resin is 0.3：0.3：1.
Embodiment 3
By hydrophobic film-forming agent, SrAl2O4：Eu2+, organic solvent, gas phase nano silica and organobentonite it is anti-settling
Agent is mixed in 20-25 DEG C of room temperature to uniformly to get to the anti-corrosion traffic mark luminescent coating of waterproof, wherein, hydrophobic film-forming agent is
40 mass parts, SrAl2O4：Eu2+For 17 mass parts, organic solvent is 13 mass parts, and gas phase nano silica is 12 mass parts,
Organobentonite anti-settling agent is 18 mass parts；Wherein, the organic solvent is the mixture of dimethylbenzene, ethyl acetate and butanol,
By mass, the ratio of dimethylbenzene, butanol and ethyl acetate is 20 in the organic solvent：20：1；The hydrophobic film-forming agent
For the mixture of organic siliconresin, organic fluorine and acrylic resin, wherein, organosilicon tree in the hydrophobic film-forming agent
The ratio of fat, organic fluorine and acrylic resin is 0.4：0.3：1.
Embodiment 4
By hydrophobic film-forming agent, CaAl2O4：Eu2+, Nd3+, organic solvent, gas phase nano silica and organobentonite
Anti-settling agent is mixed in 20-25 DEG C of room temperature to uniformly to get to the anti-corrosion traffic mark luminescent coating of waterproof, wherein, hydrophobic film-forming
Agent be 45 mass parts, CaAl2O4：Eu2+, Nd3+For 19 mass parts, organic solvent is 15 mass parts, and gas phase nano silica is
14 mass parts, organobentonite anti-settling agent are 7 mass parts；Wherein, the organic solvent is dimethylbenzene, ethyl acetate and butanol
Mixture, by mass, the ratio of dimethylbenzene, butanol and ethyl acetate is in the organic solvent：10：15：1；It is described hydrophobic
Property film forming agent be organic siliconresin, organic fluorine and acrylic resin mixture, wherein, by mass, the hydrophobicity
The ratio of organic siliconresin, organic fluorine and acrylic resin is 0.2 in film forming agent：0.5：1.
Embodiment 5
By hydrophobic film-forming agent, Sr4Al14O25：Eu2+, Dy3+, organic solvent, gas phase nano silica and organic swelling
Native anti-settling agent is mixed in 20-25 DEG C of room temperature to uniformly to get to the anti-corrosion traffic mark luminescent coating of waterproof, wherein, hydrophobicity into
Film be 30 mass parts, Sr4Al14O25：Eu2+, Dy3+For 12 mass parts, organic solvent is 11 mass parts, gas phase nano titanium dioxide
Silicon is 6 mass parts, and organobentonite anti-settling agent is 41 mass parts；Wherein, the organic solvent is dimethylbenzene, ethyl acetate and fourth
The mixture of alcohol, by mass, the ratio of dimethylbenzene, butanol and ethyl acetate is in the organic solvent：(4-35)：(4-
35)：1；The hydrophobic film-forming agent is Organic fluoride/fluorine-silicon modified acrylic resin.
The anti-corrosion traffic mark luminescent coating of the waterproof of embodiment 1-5 is carried out on substrate successively according to above-mentioned test method
It brushes, the luminous intensity of the substrate (i.e. unsoaked substrate) before immersion is set as 100%, after being impregnated 6 hours in tap water
Substrate luminous intensity be impregnate before substrate luminous intensity relative value.Unsoaked substrate shines with immersion meron
Intensity and fluorescent lifetime are as follows：
As seen from the above table, the substrate prepared by the anti-corrosion traffic mark luminescent coating of the waterproof of embodiment 1-5 is immersed in originally
In water after 6 hours, luminous intensity at most has dropped 27%.The anti-corrosion traffic mark luminescent coating of waterproof of embodiment 1-5 is made
The fluorescent lifetime of standby substrate is done reduces 25% more.
Luminous paint is brushed on substrate according to the method for above-mentioned contrast test, the luminous intensity before which is not impregnated
100% is set as, the luminous intensity of the substrate after being impregnated 6 hours in tap water is the opposite of the luminous intensity of substrate before impregnating
Value.The luminous intensity of substrate and time such as following table after not impregnating and being impregnated 6 hours in tap water：
As seen from the above table, its luminous intensity after being impregnated 6 hours in tap water of the substrate after luminous paint brushing has dropped
70%, fluorescent lifetime shortens 78%.
It can be obtained by above-mentioned test result, the hair of the anti-corrosion traffic mark luminescent coating of waterproof after being impregnated 6 hours in tap water
Luminous intensity at most has dropped 27%, and its luminous intensity has dropped 70% after luminous paint impregnates 6 hours in tap water, thus may be used
Know, waterproof of the invention is anti-corrosion traffic mark luminescent coating is after the erosion of contact water, and the waterproof is anti-corrosion, and traffic mark noctilucence applies
Rear-earth-doped alkali earth metal aluminate long after glow luminous material in material is sustainable to shine, and has good water proofing property and anti-corrosion
Property.
Illustrative description has been done to the present invention above, it should explanation, in the situation for the core for not departing from the present invention
Under, any simple deformation, modification or other skilled in the art can not spend the equivalent replacement of creative work equal
Fall into protection scope of the present invention.
Claims (4)
1. a kind of anti-corrosion traffic mark luminescent coating of waterproof, which is characterized in that be prepared by the raw material of following weight percents：
Hydrophobic film-forming agent is 30-45 wt%, and rear-earth-doped alkali earth metal aluminate long after glow luminous material is 10-20 wt%, organic
Solvent is 10-15 wt%, and gas phase nano silica is 5-15 wt%, and surplus is organobentonite anti-settling agent；Wherein, it is described to have
Solvent is the mixture of dimethylbenzene, ethyl acetate and butanol, and the hydrophobic film-forming agent is organic siliconresin, organic fluorine
With the mixture of acrylic resin, the rear-earth-doped alkali earth metal aluminate long after glow luminous material is SrAl2O4：Eu2+, Dy3 +、CaAl2O4：Eu2+, Nd3+Or Sr4Al14O25：Eu2+, Dy3+, by mass, dimethylbenzene, butanol and second in the organic solvent
The ratio of acetoacetic ester is（4-35）：（4-35）：1, organic siliconresin, organic fluorine and acrylic acid in the hydrophobic film-forming agent
The ratio of resin is（0.2-0.5）：（0.2-0.5）：1.
2. the anti-corrosion traffic mark luminescent coating of waterproof according to claim 1, which is characterized in that the hydrophobic film-forming agent
For 35-40 wt%, rear-earth-doped alkali earth metal aluminate long after glow luminous material is 13-17 wt %, organic solvent 12-14
Wt %, gas phase nano silica are 7-13 wt %, and surplus is organobentonite anti-settling agent.
3. the anti-corrosion traffic mark luminescent coating of waterproof according to claim 1, which is characterized in that the gas phase nano dioxy
The grain size of SiClx is 5-50 nanometers.
4. the anti-corrosion traffic mark luminescent coating of waterproof according to claim 1, which is characterized in that by mass, described
The ratio of dimethylbenzene, butanol and ethyl acetate is in organic solvent（20-30）：（20-30）：1.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711405098.9A CN107987643B (en) | 2015-12-30 | 2015-12-30 | Application of waterproof corrosion-resistant traffic sign luminous material |
| CN201511033686.5A CN105419532B (en) | 2015-12-30 | 2015-12-30 | Waterproof is anti-corrosion traffic mark Noctilucent material and preparation method and applications |
| CN201711405055.0A CN107841217B (en) | 2015-12-30 | 2015-12-30 | Preparation method of waterproof corrosion-resistant traffic sign noctilucent material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201511033686.5A CN105419532B (en) | 2015-12-30 | 2015-12-30 | Waterproof is anti-corrosion traffic mark Noctilucent material and preparation method and applications |
Related Child Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711405098.9A Division CN107987643B (en) | 2015-12-30 | 2015-12-30 | Application of waterproof corrosion-resistant traffic sign luminous material |
| CN201711405055.0A Division CN107841217B (en) | 2015-12-30 | 2015-12-30 | Preparation method of waterproof corrosion-resistant traffic sign noctilucent material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105419532A CN105419532A (en) | 2016-03-23 |
| CN105419532B true CN105419532B (en) | 2018-06-08 |
Family
ID=55498087
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711405055.0A Active CN107841217B (en) | 2015-12-30 | 2015-12-30 | Preparation method of waterproof corrosion-resistant traffic sign noctilucent material |
| CN201511033686.5A Active CN105419532B (en) | 2015-12-30 | 2015-12-30 | Waterproof is anti-corrosion traffic mark Noctilucent material and preparation method and applications |
| CN201711405098.9A Active CN107987643B (en) | 2015-12-30 | 2015-12-30 | Application of waterproof corrosion-resistant traffic sign luminous material |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711405055.0A Active CN107841217B (en) | 2015-12-30 | 2015-12-30 | Preparation method of waterproof corrosion-resistant traffic sign noctilucent material |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711405098.9A Active CN107987643B (en) | 2015-12-30 | 2015-12-30 | Application of waterproof corrosion-resistant traffic sign luminous material |
Country Status (1)
| Country | Link |
|---|---|
| CN (3) | CN107841217B (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106010225B (en) * | 2016-06-27 | 2018-04-20 | 国网河南省电力公司南阳供电公司 | The ground coloured colour code identification device and its laying method of a kind of cable |
| CN108949165A (en) * | 2017-12-29 | 2018-12-07 | 张世远 | The method of inexpensive high-grade large-scale production succession ancient architecture structure |
| CN109370410A (en) * | 2018-09-28 | 2019-02-22 | 合众（佛山）化工有限公司 | A kind of high performance nanometer energy storage aqueous luminous paint |
| CN109627890B (en) * | 2018-11-27 | 2020-08-25 | 浙江欧路德交通科技有限公司 | Fluorine-silicon modified water-based marking paint |
| CN113845804A (en) * | 2021-11-18 | 2021-12-28 | 广东电网有限责任公司 | Energy storage type luminous paint and preparation method thereof |
| CN114671707B (en) * | 2022-04-22 | 2023-01-03 | 江苏路强智慧交通科技有限公司 | Weather-resistant luminous protective paint for concrete traffic guardrail and preparation method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5202368A (en) * | 1989-01-31 | 1993-04-13 | Ici Australia Operations Proprietary Limited | Silicone coating compositions |
| JP2006077095A (en) * | 2004-09-08 | 2006-03-23 | Chugoku Marine Paints Ltd | Antifouling coating composition, its coated film, ship or underwater construction coated with the same and method of antifouling |
| CN101386719A (en) * | 2008-08-28 | 2009-03-18 | 冯守中 | Multifunctional coatings and preparation method thereof |
| CN101864228A (en) * | 2010-06-04 | 2010-10-20 | 王大鹏 | Thick-slurry type self-luminous traffic marking paint and preparation method thereof |
| CN101914334A (en) * | 2010-08-26 | 2010-12-15 | 宋光华 | Light cumulating water-based paint |
| CN101928498A (en) * | 2010-08-24 | 2010-12-29 | 中国电力科学研究院 | Fluorosilicone-modified acrylic resin hydrophobic anti-corrosion paint |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3046227B2 (en) * | 1995-09-13 | 2000-05-29 | リズム時計工業株式会社 | Display panel |
| CN101333357B (en) * | 2008-07-02 | 2010-06-23 | 大连海事大学 | Luminous paint and method for preparing same |
| CN101333349B (en) * | 2008-07-02 | 2010-11-17 | 大连海事大学 | Water-soluble luminous paint with long afterglow phosphorescent material coated by nanometer titanium dioxide and method for preparing same |
| CN101555376A (en) * | 2009-05-07 | 2009-10-14 | 广东工业大学 | Method for preparing multi-color long afterglow water borne luminescent coatings |
| CN104592871A (en) * | 2013-10-30 | 2015-05-06 | 烟台纳克环保科技有限公司 | Colorful luminous paint |
| CN103602094A (en) * | 2013-11-21 | 2014-02-26 | 董绍品 | Self-cleaning self-flame-retardant self-luminous material and preparation method thereof |
-
2015
- 2015-12-30 CN CN201711405055.0A patent/CN107841217B/en active Active
- 2015-12-30 CN CN201511033686.5A patent/CN105419532B/en active Active
- 2015-12-30 CN CN201711405098.9A patent/CN107987643B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5202368A (en) * | 1989-01-31 | 1993-04-13 | Ici Australia Operations Proprietary Limited | Silicone coating compositions |
| JP2006077095A (en) * | 2004-09-08 | 2006-03-23 | Chugoku Marine Paints Ltd | Antifouling coating composition, its coated film, ship or underwater construction coated with the same and method of antifouling |
| CN101386719A (en) * | 2008-08-28 | 2009-03-18 | 冯守中 | Multifunctional coatings and preparation method thereof |
| CN101864228A (en) * | 2010-06-04 | 2010-10-20 | 王大鹏 | Thick-slurry type self-luminous traffic marking paint and preparation method thereof |
| CN101928498A (en) * | 2010-08-24 | 2010-12-29 | 中国电力科学研究院 | Fluorosilicone-modified acrylic resin hydrophobic anti-corrosion paint |
| CN101914334A (en) * | 2010-08-26 | 2010-12-15 | 宋光华 | Light cumulating water-based paint |
Also Published As
| Publication number | Publication date |
|---|---|
| CN107841217A (en) | 2018-03-27 |
| CN107987643A (en) | 2018-05-04 |
| CN107841217B (en) | 2020-04-21 |
| CN105419532A (en) | 2016-03-23 |
| CN107987643B (en) | 2019-12-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105419532B (en) | Waterproof is anti-corrosion traffic mark Noctilucent material and preparation method and applications | |
| Forti | Genetic processes of cave minerals in volcanic environments: an overview | |
| CN105400338B (en) | Waterproof accumulation of energy noctilucence traffic mark coating and its application | |
| CN104277645A (en) | Noctilucent paint | |
| HRP20191113T1 (en) | Mineral wool product and its use | |
| CN111875337A (en) | Inorganic cooling coating and preparation method thereof | |
| CN101210153A (en) | Luminous water paint and preparing method thereof | |
| CN104293104B (en) | Noctilucent epoxy coiled material and preparation method thereof | |
| UA123306C2 (en) | Element for mineral synthetic surface covering | |
| CN101407652A (en) | Preparation of UV curing luminous paint | |
| CN109401749A (en) | A kind of inorganic ability of reverse photochromism material and preparation method thereof | |
| CN110819192A (en) | Noctilucent anti-sticking urban landscape sticking cloth with coating for preventing sticking | |
| CN101428974A (en) | High-brightness extinction, light-storing, luminescent glass and method of producing the same | |
| CN103377599B (en) | A kind of long-persistence luminous fire symbol and preparation method thereof | |
| CN108610924A (en) | A kind of aqueous high-performance luminous paint and preparation method thereof | |
| CN104175669B (en) | Luminescent film and preparation method thereof | |
| CN104327628A (en) | Fluorescent paint for glass doors, and its preparation method | |
| CN204492052U (en) | Fluoresent coating structure | |
| TWI743662B (en) | Long afterglow material and preparation method thereof | |
| CN104531145A (en) | Method for preparing bamboo strip/strontium aluminate fluorescent powder composite material | |
| CN102174784A (en) | Light storage and emission counterfeiting paper and manufacturing method and application thereof | |
| CN103194141B (en) | A kind of protective coating, preparation method and its usage | |
| TWI712672B (en) | Long afterglow material and preparation method thereof | |
| CN203282763U (en) | Fluorescent color steel plate | |
| Liu et al. | Novel functional coating: luminescent coating |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB03 | Change of inventor or designer information | ||
| CB03 | Change of inventor or designer information |
Inventor after: Zhou Zeqian Inventor after: Hu Zhongyuan Inventor after: Zheng Qi Inventor after: Tang Erjun Inventor after: Li Muying Inventor before: Li Rui Inventor before: Mao Zhiyong Inventor before: Wang Yanze Inventor before: Song Weiwei Inventor before: Wang Zhongkai |
|
| TA01 | Transfer of patent application right |
Effective date of registration: 20180420 Address after: 072550 Hebei city of Baoding province Xushui Chenyang Street No. 1 Applicant after: Hebei Chenyang IndustrialL&trade Group Co., Ltd. Address before: 300384 Tianjin Binhai New Area of Tianjin Huayuan Industrial Zone Ziyuan Road No. 6 Building 7 room 531 Applicant before: Quantum opto electronic technology (Tianjin) Co., Ltd. |
|
| TA01 | Transfer of patent application right | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| PP01 | Preservation of patent right | ||
| PP01 | Preservation of patent right |
Effective date of registration: 20200929 Granted publication date: 20180608 |
|
| PD01 | Discharge of preservation of patent | ||
| PD01 | Discharge of preservation of patent |
Date of cancellation: 20210902 Granted publication date: 20180608 |