CN105419228B - A kind of craftwork new material and preparation method thereof - Google Patents
A kind of craftwork new material and preparation method thereof Download PDFInfo
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- CN105419228B CN105419228B CN201610016525.3A CN201610016525A CN105419228B CN 105419228 B CN105419228 B CN 105419228B CN 201610016525 A CN201610016525 A CN 201610016525A CN 105419228 B CN105419228 B CN 105419228B
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C08L61/32—Modified amine-aldehyde condensates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G12/00—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C08G12/02—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes
- C08G12/40—Chemically modified polycondensates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The present invention relates to chemical material technical field more particularly to a kind of craftwork new materials, include the raw material of following mass percent：Paper pulp 45~60%, urea 15~30%, formaldehyde 5~15%, solvent 10~20%, toner 0.1~5%, auxiliary agent 0.5~5%；The craftwork new material craftwork easily processed into type, the plastic crafts quality manufactured using the craftwork new material is high-end, gloss with jade or marble etc, suitable with the craftwork quality of jade or marble etc material manufacture, consumer is difficult to discover the craftwork to be formed by plastic manufacturing, and the added value of craftwork is high, ornamental value is good, it manufactures at low cost, improves the class of craftwork, it is good in economic efficiency.
Description
Technical field
The present invention relates to chemical material technical fields more particularly to a kind of craftwork new material and preparation method thereof.
Background technology
It is existing for manufacturing the materials of plastic crafts as general-purpose plastics, the technique manufactured using the general-purpose plastics
Product quality is common, has normal plastics gloss, it is common plastics craftwork that consumer is known that at a glance, so as to cause craftwork
Added value it is low, ornamental value is poor, reduces the class of craftwork, deficiency in economic performance.
Thus, there is an urgent need for a kind of craftwork new materials that can improve plastic crafts class currently on the market.
Invention content
The present invention is overcomes drawbacks described above to provide a kind of craftwork new material and preparation method thereof, the craftwork green wood
Expect craftwork easily processed into type, the plastic crafts quality manufactured using the craftwork new material is high-end, has jade
Or the gloss of marble etc, suitable with the craftwork quality of jade or marble etc material manufacture, consumer is difficult to discover
The craftwork is formed by plastic manufacturing, and the added value of craftwork is high, and ornamental value is good, and manufacture is at low cost, improves the shelves of craftwork
It is secondary, it is good in economic efficiency；The preparation method of the craftwork new material is simple for process, and production efficiency is high, and product qualification rate is high, is suitable for
Large-scale promotion application.
To achieve the above object, the present invention adopts the following technical scheme that.
A kind of craftwork new material includes the raw material of following mass percent：
Preferably, a kind of craftwork new material includes the raw material of following mass percent：
Preferably, a kind of craftwork new material includes the raw material of following mass percent：
Wherein, the paper pulp is the one or more of wood pulp, straw pulp, jute pulp, reed pulp, sugarcane slurry, bamboo pulp, rag stock
Mixture.
Wherein, the solvent is one or more kinds of mixtures of water, ethyl alcohol, ether, acetone, glycerine.
Wherein, the toner is mixed by nanoscale toner and regular grade toner by 1~3: 2~5 mass ratio, described
The grain size of regular grade toner is 50~100 microns.Utilize the small quality and high surface energy of nanoscale toner so that nanoscale toner
Be attached to regular grade toner surface, formed core shell composite construction.During mixing, the attachment of nanoscale toner
On the surface of regular grade toner as regular grade toner moves together, the agglomeration of nanoscale toner is effectively prevented；In addition
Due to nanoscale toner have high surface can, it is combined even closer, therefore regular grade toner with the mixture of other materials
It can be combined by being attached to the nanoscale toner on its surface with the mixture of other materials, it is final to enable toner uniformly steady
Surely particulate material outer surface is adhered to；The nanoscale toner for being not adhered to regular grade toner surface is filled into other materials
The various gaps of mixture show the various advantages of nano material, overcome and nanoscale toner and regular grade color is used alone
Powder fills the shortcomings that other material gaps, keeps good physical mechanical performance.
Wherein, the auxiliary agent includes curing agent, levelling agent, brightener, antioxidant and adhesive.
Wherein, the dosage of the curing agent is the 0.1~1% of total raw material quality, and the dosage of the levelling agent is total raw material
The 0.1~1% of quality, the dosage of the brightener are the 0.1~1% of total raw material quality, and the dosage of the antioxidant is total former
Expect the 0.1~1% of quality, the dosage of described adhesive is the 0.1~1% of total raw material quality.
Wherein, the curing agent is vinyl triamine, diaminocyclohexane, trimethylhexane diamine, m-phenylene diamine (MPD), diamino
One or more kinds of mixtures of diphenyl methane, benzidine；
Wherein, the levelling agent is silicone oil, dimethyl silicone polymer, polyether polyester azo polyether polyeste, acrylic acid tree
Fat, Lauxite, melamine resin one or more kinds of mixtures；
Wherein, the brightener is the one or more of benzylideneacetone, nonylphenol polyoxyethylene ether, sodium benzoate
Mixture；
Wherein, the antioxidant is one kind of diphenylamines, 2,6- three-level butyl -4- methylphenols, thio-2 acid dibasic acid esters
Or more than one mixture；
Wherein, described adhesive for starch, waterglass, polyurethane, butyl rubber, acrylic resin, epoxy resin one
Kind or more than one mixture.
A kind of preparation method of craftwork new material, including following procedure of processing：
Step A, the material of formula ratio is accurately weighed according to formula, is placed individually into different containers；
Step B, solvent being added in into reaction kettle, paper pulp and urea are then added in reaction kettle by heated solvent to 70~80 DEG C,
It is stirring while adding so that paper pulp and urea are dissolved into solvent；
Step C, the temperature in reaction kettle is increased to 190~210 DEG C, adds formaldehyde into reaction kettle, it is stirring while adding,
After adding formaldehyde, state is kept stirring, the reaction was continued 3~5 minutes, obtains mixed serum；
Step D, mixed serum is added in comminutor to be granulated, obtains particulate material；
Step E, temperature is 40~50 DEG C in the hopper of setting batch mixer, and toner and auxiliary agent are added to hopper stirring together
2~4 minutes, toner agent mixture is formed, then particulate material is added in hopper and continues stirring 3~5 minutes so that toner helps
Agent composition is evenly distributed to particulate material outer surface, and then particulate material is dried, and drying temperature is 60~70 DEG C, when dry
Between for 2~3 minutes to get finished product.
Beneficial effects of the present invention are：
A kind of craftwork new material of the present invention includes the raw material of following mass percent：Paper pulp 45~60%, urea 15
~30%, formaldehyde 5~15%, solvent 10~20%, toner 0.1~5%, auxiliary agent 0.5~5%；The craftwork new material is easy to
Processing and forming technology product, the plastic crafts quality manufactured using the craftwork new material is high-end, has jade or Dali
The gloss of stone etc, suitable with the craftwork quality of jade or marble etc material manufacture, consumer is difficult to discover the technique
Product are formed by plastic manufacturing, and the added value of craftwork is high, and ornamental value is good, and manufacture is at low cost, improves the class of craftwork, economical
It is profitable；The characteristic why craftwork molded using the new material forms similar to jade or marble material be because
Internal in itself for new material is pure white particulate material, and particulate material outer surface uniform fold has toner, during molding, particle
Material is crushed, and internal white particle material is exposed, it is final so that the craftwork to form out occur certain colored (such as green) with
The alternate special decorative pattern of white, it is high with jade or marble similarity, so that the craftwork to form out seems by jade
Stone or marble are fabricated.In addition, also as using above-mentioned formula for raw stock so that the craftwork has similar to stone
Gloss, it is final so that there is jade or marble appearance using the craftwork that the new material forms out.
A kind of preparation method of craftwork new material, including following procedure of processing：Step A, it accurately weighs and matches according to formula
The material just measured is placed individually into different containers；Step B, solvent is added in into reaction kettle, heated solvent to 70~80 DEG C,
Then paper pulp and urea are added in into reaction kettle, it is stirring while adding so that paper pulp and urea are dissolved into solvent；It step C, will reaction
Temperature in kettle is increased to 190~210 DEG C, adds formaldehyde into reaction kettle, stirring while adding, after adding formaldehyde, is kept stirring
State, the reaction was continued 3~5 minutes, obtains mixed serum；Step D, mixed serum is added in comminutor to be granulated, obtains particulate material；
Step E, temperature is 40~50 DEG C in the hopper of setting batch mixer, and toner and auxiliary agent are added to hopper together stirs 2~4 points
Clock forms toner agent mixture, then particulate material is added in hopper and continues stirring 3~5 minutes so that toner auxiliary agent mixes
Object is evenly distributed to particulate material outer surface, and then particulate material is dried, and drying temperature is 60~70 DEG C, drying time 2
~3 minutes to get finished product；The preparation method of the craftwork new material is simple for process, and production efficiency is high, and product qualification rate is high, fits
Together in large-scale promotion application.
Specific embodiment
With reference to embodiment, the present invention is further illustrated, this is presently preferred embodiments of the present invention.
Embodiment 1.
A kind of craftwork new material of the present invention includes the raw material of following mass percent：
The paper pulp of the present embodiment is wood pulp.
The solvent of the present embodiment is ethyl alcohol.
The toner of the present embodiment is mixed by nanoscale toner and regular grade toner by 1: 2 mass ratio, described common
The grain size of grade toner is 100 microns.
The auxiliary agent of the present embodiment includes curing agent, levelling agent, brightener, antioxidant and adhesive.
The dosage of the curing agent of the present embodiment is the 1% of total raw material quality, and the dosage of the levelling agent is total raw material quality
1%, the dosage of the brightener is the 1% of total raw material quality, and the dosage of the antioxidant is the 1% of total raw material quality, institute
The dosage for stating adhesive is the 1% of total raw material quality.
The curing agent of the present embodiment is vinyl triamine；
The levelling agent of the present embodiment is silicone oil；
The brightener of the present embodiment is benzylideneacetone；
The antioxidant of the present embodiment is diphenylamines；
The adhesive of the present embodiment is acrylic resin.
A kind of preparation method of craftwork new material, including following procedure of processing：
Step A, the material of formula ratio is accurately weighed according to formula, is placed individually into different containers；
Step B, solvent is added in into reaction kettle, paper pulp and urea are then added in reaction kettle, Bian Jia by heated solvent to 75 DEG C
It stirs on side so that paper pulp and urea are dissolved into solvent；
Step C, the temperature in reaction kettle is increased to 200 DEG C, adds formaldehyde into reaction kettle, it is stirring while adding, it adds
After formaldehyde, state is kept stirring, the reaction was continued 4 minutes, obtains mixed serum；
Step D, mixed serum is added in comminutor to be granulated, obtains particulate material；
Step E, temperature is 45 DEG C in the hopper of setting batch mixer, and toner and auxiliary agent are added to hopper together stirs 3 points
Clock forms toner agent mixture, then particulate material is added in hopper and continues stirring 4 minutes so that toner agent mixture
Particulate material outer surface is evenly distributed to, then particulate material is dried, drying temperature is 65 DEG C, and drying time is 3 minutes, i.e.,
Obtain finished product.
Embodiment 2.
A kind of craftwork new material of the present invention includes the raw material of following mass percent：
The paper pulp of the present embodiment is wood pulp, the mixture of straw pulp, bamboo pulp.
The solvent of the present embodiment is ethyl alcohol, the mixture of glycerine.
The toner of the present embodiment is mixed by nanoscale toner and regular grade toner by 3: 2 mass ratio, described common
The grain size of grade toner is 50 microns.
The auxiliary agent of the present embodiment includes curing agent, levelling agent, brightener, antioxidant and adhesive.
The dosage of the curing agent of the present embodiment is the 0.5% of total raw material quality, and the dosage of the levelling agent is total raw material matter
The 0.5% of amount, the dosage of the brightener are the 0.5% of total raw material quality, and the dosage of the antioxidant is total raw material quality
0.5%, the dosage of described adhesive is the 0.5% of total raw material quality.
The curing agent of the present embodiment is diaminocyclohexane, the mixture of m-phenylene diamine (MPD)；
The levelling agent of the present embodiment is dimethyl silicone polymer, the mixture of acrylic resin；
The brightener of the present embodiment is benzylideneacetone, the mixture of nonylphenol polyoxyethylene ether, sodium benzoate；
The antioxidant of the present embodiment is diphenylamines, the mixture of thio-2 acid dibasic acid esters；
The adhesive of the present embodiment is starch, the mixture of waterglass.
A kind of preparation method of craftwork new material, including following procedure of processing：
Step A, the material of formula ratio is accurately weighed according to formula, is placed individually into different containers；
Step B, solvent is added in into reaction kettle, paper pulp and urea are then added in reaction kettle, Bian Jia by heated solvent to 70 DEG C
It stirs on side so that paper pulp and urea are dissolved into solvent；
Step C, the temperature in reaction kettle is increased to 190 DEG C, adds formaldehyde into reaction kettle, it is stirring while adding, it adds
After formaldehyde, state is kept stirring, the reaction was continued 5 minutes, obtains mixed serum；
Step D, mixed serum is added in comminutor to be granulated, obtains particulate material；
Step E, temperature is 40 DEG C in the hopper of setting batch mixer, and toner and auxiliary agent are added to hopper together stirs 4 points
Clock forms toner agent mixture, then particulate material is added in hopper and continues stirring 5 minutes so that toner agent mixture
Particulate material outer surface is evenly distributed to, then particulate material is dried, drying temperature is 60 DEG C, and drying time is 3 minutes, i.e.,
Obtain finished product.
Embodiment 3.
A kind of craftwork new material of the present invention includes the raw material of following mass percent：
The paper pulp of the present embodiment is jute pulp, the mixture of sugarcane slurry, rag stock.
The solvent of the present embodiment is water, the mixture of ether, glycerine.
The toner of the present embodiment is mixed by nanoscale toner and regular grade toner by 1: 1 mass ratio, described common
The grain size of grade toner is 50 microns.
The auxiliary agent of the present embodiment includes curing agent, levelling agent, brightener, antioxidant and adhesive.
The dosage of the curing agent of the present embodiment is the 1% of total raw material quality, and the dosage of the levelling agent is total raw material quality
0.5%, the dosage of the brightener is the 1% of total raw material quality, and the dosage of the antioxidant is total raw material quality
0.5%, the dosage of described adhesive is the 1% of total raw material quality.
The curing agent of the present embodiment is m-phenylene diamine (MPD), the mixture of diaminodiphenyl-methane, benzidine；
The levelling agent of the present embodiment is silicone oil, the mixture of dimethyl silicone polymer, acrylic resin；
The brightener of the present embodiment is nonylphenol polyoxyethylene ether, the mixture of sodium benzoate；
The antioxidant of the present embodiment is the mixing of diphenylamines, 2,6- three-level butyl -4- methylphenol, thio-2 acid dibasic acid esters
Object；
The adhesive of the present embodiment is polyurethane, the mixture of butyl rubber, epoxy resin.
A kind of preparation method of craftwork new material, including following procedure of processing：
Step A, the material of formula ratio is accurately weighed according to formula, is placed individually into different containers；
Step B, solvent is added in into reaction kettle, paper pulp and urea are then added in reaction kettle, Bian Jia by heated solvent to 80 DEG C
It stirs on side so that paper pulp and urea are dissolved into solvent；
Step C, the temperature in reaction kettle is increased to 210 DEG C, adds formaldehyde into reaction kettle, it is stirring while adding, it adds
After formaldehyde, state is kept stirring, the reaction was continued 3 minutes, obtains mixed serum；
Step D, mixed serum is added in comminutor to be granulated, obtains particulate material；
Step E, temperature is 50 DEG C in the hopper of setting batch mixer, and toner and auxiliary agent are added to hopper together stirs 2 points
Clock forms toner agent mixture, then particulate material is added in hopper and continues stirring 3 minutes so that toner agent mixture
Particulate material outer surface is evenly distributed to, then particulate material is dried, drying temperature is 70 DEG C, and drying time is 2 minutes, i.e.,
Obtain finished product.
Finally it should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention rather than the present invention is protected
The limitation of range is protected, although being explained in detail with reference to preferred embodiment to the present invention, those of ordinary skill in the art should
Work as understanding, technical scheme of the present invention can be modified or replaced equivalently, without departing from the reality of technical solution of the present invention
Matter and range.
Claims (6)
1. a kind of artwork, it is characterised in that：Include the raw material of following mass percent：
The toner is mixed by nanoscale toner and regular grade toner by 1~3: 2~5 mass ratio, the regular grade color
The grain size of powder is 50~100 microns,
The auxiliary agent includes curing agent, levelling agent, brightener, antioxidant and adhesive；
The curing agent for vinyl triamine, diaminocyclohexane, m-phenylene diamine (MPD), diaminodiphenyl-methane, benzidine one
Kind or more than one mixture；
The levelling agent is dimethyl silicone polymer, polyether polyester azo polyether polyeste, acrylic resin, Lauxite, three
One or more kinds of mixtures of melamine-formaldehyde resin；
The brightener is benzylideneacetone, one or more kinds of mixtures of nonylphenol polyoxyethylene ether, sodium benzoate；
The antioxidant is diphenylamines, the one or more of 2,6- three-level butyl -4- methylphenols, thio-2 acid dibasic acid esters
Mixture；
Described adhesive is starch, one kind of waterglass, polyurethane, butyl rubber, acrylic resin, epoxy resin or it is a kind of with
On mixture；
The preparation method of the artwork includes following procedure of processing：
Step A, the material of formula ratio is accurately weighed according to formula, is placed individually into different containers；
Step B, solvent is added in into reaction kettle, paper pulp and urea are then added in reaction kettle, Bian Jia by heated solvent to 70~80 DEG C
It stirs on side so that paper pulp and urea are dissolved into solvent；
Step C, the temperature in reaction kettle is increased to 190~210 DEG C, adds formaldehyde into reaction kettle, it is stirring while adding, it adds
After formaldehyde, state is kept stirring, the reaction was continued 3~5 minutes, obtains mixed serum；
Step D, mixed serum is added in comminutor to be granulated, obtains particulate material；
Step E, temperature is 40~50 DEG C in the hopper of setting batch mixer, and toner and auxiliary agent are added to hopper stirring 2~4 together
Minute, toner agent mixture is formed, then particulate material is added in hopper and continues stirring 3~5 minutes so that toner auxiliary agent mixes
It closes object and is evenly distributed to particulate material outer surface, then particulate material is dried, drying temperature is 60~70 DEG C, and drying time is
2~3 minutes to get finished product.
2. a kind of artwork according to claim 1, it is characterised in that：Include the raw material of following mass percent：
3. a kind of artwork according to claim 1, it is characterised in that：Include the raw material of following mass percent：
4. a kind of artwork according to claim 1, it is characterised in that：The paper pulp for wood pulp, straw pulp, jute pulp,
Reed pulp, sugarcane slurry, bamboo pulp, rag stock one or more kinds of mixtures.
5. a kind of artwork according to claim 1, it is characterised in that：The solvent is water, ethyl alcohol, ether, third
One or more kinds of mixtures of ketone, glycerine.
6. a kind of artwork according to claim 1, it is characterised in that：The dosage of the curing agent is total raw material matter
The 0.1~1% of amount, the dosage of the levelling agent are the 0.1~1% of total raw material quality, and the dosage of the brightener is total raw material
The 0.1~1% of quality, the dosage of the antioxidant are the 0.1~1% of total raw material quality, and the dosage of described adhesive is total former
Expect the 0.1~1% of quality.
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| CN201610016525.3A CN105419228B (en) | 2016-01-08 | 2016-01-08 | A kind of craftwork new material and preparation method thereof |
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| CN201610016525.3A CN105419228B (en) | 2016-01-08 | 2016-01-08 | A kind of craftwork new material and preparation method thereof |
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| CN110482906A (en) * | 2019-07-16 | 2019-11-22 | 书香门地（上海）美学家居股份有限公司 | A kind of craftwork wood raw material with high-intensitive plasticity |
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| CN1647948A (en) * | 2005-01-01 | 2005-08-03 | 王志深 | Pulp handicraft and its producing method |
| CN100486821C (en) * | 2005-06-03 | 2009-05-13 | 潮州市三泰陶瓷有限公司 | Manufacturing method of pottary imitation paper bandicraft article |
| CN104419116A (en) * | 2013-09-02 | 2015-03-18 | 陈天云 | Environment-friendly amino molding granule and production method thereof |
| CN104761866A (en) * | 2014-01-04 | 2015-07-08 | 陈天云 | Method for rapidly producing amino molded material |
| CN105017718A (en) * | 2014-04-26 | 2015-11-04 | 陈天云 | Jade vein simulated high-intensity low-shrinkage amino moulding plastic particle material and production method |
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