CN105017718A - Jade vein simulated high-intensity low-shrinkage amino moulding plastic particle material and production method - Google Patents

Jade vein simulated high-intensity low-shrinkage amino moulding plastic particle material and production method Download PDF

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Publication number
CN105017718A
CN105017718A CN201410170697.7A CN201410170697A CN105017718A CN 105017718 A CN105017718 A CN 105017718A CN 201410170697 A CN201410170697 A CN 201410170697A CN 105017718 A CN105017718 A CN 105017718A
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production method
intensity low
jade
packing material
amino
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CN201410170697.7A
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陈天云
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Abstract

The invention discloses a jade vein simulated high-intensity low-shrinkage amino moulding plastic particle material and a production method. The high-intensity low-shrinkage amino moulding plastic particle material is characterized by being prepared from formaldehyde water solution, urea, melamine, auxiliary agents, sodium hudroxide, filling materials and the like, wherein the filling materials are mixed bodies of wood powder, inorganic and organic medium short fiber, paper pulp plates, waste paper wood pulp, grain and fruit hulls, bone meal, starch and inorganic oxides; the auxiliary agents are urotropine, oxalic acid, water, ammonium sulfamate, magnesium oxide, zinc oxide, ammonium chloride, ethanol, trolamine, ammonia water, PPG, T-8, sodium-naphthalenesulfonate, glycerin, magnesium carbonate, hydroxyphenol, pigment, zinc stearate and the like. The production method of the jade vein simulated high-intensity low-shrinkage amino moulding plastic particle material comprises the following steps that in a resin synthesis stage, a general alkali-acid-alkali method is selected for synthesizing the resin; in an evaporation polycondensation stage, the resin and the filling materials are input into a vacuum granulation reaction kettle, and the sealed production is completed in one step.

Description

A kind of amino granular molding compound of high intensity low shrinkage of jade bag and production method
Technical field
The present invention relates to plastic applications, relate in particular to the amino granular molding material manufacturing technique of environment-friendly type.
Background technology
Along with the propelling of human civilization, the environmental consciousness of people is more and more stronger, requirement that is green to clothing, food, lodging and transportion--basic necessities of life, environmental protection is also more and more higher, and the plastics pressing close to the life of people enjoy the concern of human consumer especially, research staff has released one after another many nontoxic, harmless, pollution-free, degredation plastic new variety, because its machine-shaping is convenient, bright in luster, cost is low, extensively should in fields such as furniture building materials and ornaments, daily necessities, artwork, tablewares.Utilizing wood powder saw powder shaving, vegetable fibre, paddy shell, carapace powder, starch and inorganic oxide etc. to improve thermosetting resin, is exactly the class in nontoxic, harmless plastics.
The amino Moulding powder processing method of current domestic production is for raw material with formaldehyde, urea, trimeric cyanamide etc., by integrating slurrying with filler, dry with mesh bag drying baker, formation plate mould material, then carry out pulverizing, ball milling, make melamine moulding powder, whole production process about 8 hours.This mode labour intensity is large, big energy-consuming, and have pollution to environment, have infringement to human body, the dust of finished product is many, density is low, appearance poor, Quality and yield is all difficult to effective raising.
Summary of the invention
Raw material in the amino granular molding compound of the high intensity low shrinkage of a kind of jade bag of the present invention and production method is: a kind of amino granular molding compound of high intensity low shrinkage of jade bag and production method, the amino granular molding compound raw material of high intensity low shrinkage that it is characterized in that preparing this kind of jade bag is: formalin, urea, trimeric cyanamide, auxiliary agent, caustic soda, the material compositions such as packing material, for the resins synthesis stage: the alkali-acid-alkali method synthetic resins of gating, evaporation polycondensation phase: by resin and packing material input vacuum granulation reactor all-in-one, there is polymerization, mediate, dispersion, closed production one step of the functions such as drying completes.
The parts by weight of each component are respectively: formalin 2400, urea 1380, trimeric cyanamide 115, auxiliary agent 180, packing material 1000-2000, described packing material is wood powder, has the mixture of inorganic middle short fiber, pulp board, waste paper wood pulp, paddy shell, bone meal, starch and inorganic oxide, and packing material is wood powder, has the weight ratio of inorganic middle short fiber, pulp board, waste paper wood pulp, paddy shell, bone meal, starch and inorganic oxide to be 50-90:4-10, described inorganic oxide is selected from calcium oxide, aluminum oxide and kaolin etc.Auxiliary agent parts by weight are respectively: urotropine 88, oxalic acid 6, the 40-80 such as water, Ammonium sulfamate, magnesium oxide, zinc oxide, ammonium chloride, ethanol, trolamine, ammoniacal liquor, PPG, T8, sodium naphthalene sulfonate, glycerine, magnesiumcarbonate, Resorcinol, colorant and Zinic stearas etc. 40.
Deliver in vacuum granulation reactor by adding packing material in resin liquid, fully be uniformly mixed, high-speed stirring is after 2 ~ 5 minutes, turn low speed, material reaction temperature is incubated 60 minutes under 50-60 degree, open vacuum valve to draw water vapour, stirring at low speed 10 ~ 15 minutes, transfer interval high-speed stirring to, temperature of charge 60-85 DEG C, measure moisture after 60 minutes, meet decompress(ion) cooling blowing after moisture content requirement, this material once shaped jade bag is luicd and elegant, be widely used in decorative building material, ornaments furniture, omnidistance tasteless without bisque quality better, cost-saving raising effect.
beneficial effect:
1, the present invention is in thermosetting resin synthesis, and with the addition of multiple material composition auxiliary curing agent, improve resin property namely in moulding process, operation facilitates quick solidifying without powder, and the shelf-time is long, cost-saving raising effect.
2, packing material is: wood powder, have the mixture of inorganic middle short fiber, pulp board, waste paper wood pulp, paddy shell, bone meal, starch and inorganic oxide, and cost is low, and performance is good, improves Performance Strength, expands the use range of such material.
3, this material once shaped jade bag is luicd and elegant, is widely used in decorative building material, ornaments furniture, omnidistance tasteless without bisque quality better, cost-saving raising effect.
embodiment:
Embodiment 1: get formalin 240 kilograms, 138 kilograms, urea, trimeric cyanamide 6 kilograms, auxiliary agent (urotropine 8.8 kilograms, oxalic acid 0.6 kg of water, Ammonium sulfamate, magnesium oxide, zinc oxide, ammonium chloride, ethanol, trolamine, ammoniacal liquor, PPG, T8, sodium naphthalene sulfonate, glycerine, magnesiumcarbonate, Resorcinol etc. 5.7 kilograms, colorant and Zinic stearas etc. 4 kilograms) 18 kilograms etc. add in vacuum granulation reactor all-in-one, the alkali-acid-alkali method synthetic resins of gating.
Be wood powder by adding packing material in resin liquid, have inorganic middle short fiber etc. 165 kilograms, vacuum granulation reactor all-in-one, is fully uniformly mixed, high-speed stirring, after 2 ~ 5 minutes, turns low speed, and material reaction temperature is incubated 60 minutes under 50-60 degree, open vacuum valve to draw water vapour, intensification stirring at low speed 10 ~ 15 minutes, temperature of charge 60-85 DEG C, measured moisture after 60 minutes, after meeting moisture requirement, transfer to interval high-speed stirring, decompress(ion) cooling blowing, amino granular molding compound.
Embodiment 2: get formalin 300 kilograms, 150 kilograms, urea, trimeric cyanamide 10 kilograms, auxiliary agent (urotropine 8.8 kilograms, oxalic acid 0.6 kg of water, Ammonium sulfamate, magnesium oxide, zinc oxide, ammonium chloride, ethanol, trolamine, ammoniacal liquor, PPG, T8, sodium naphthalene sulfonate, glycerine, magnesiumcarbonate, Resorcinol etc. 6.4 kilograms, colorant and Zinic stearas etc. 5 kilograms) 20 kilograms etc. add in vacuum granulation reactor all-in-one, the alkali-acid-alkali method synthetic resins of gating.
By material wood powder 350 kilograms, 150 kilograms, shell powder, 20 kilograms, the calcium oxide based on bone meal, puts into all-in-one, closed productions such as being polymerized with example 1, mediating, disperse, be dry.Not only environmental protection, but also the amino granular molding compound of economy and durability.
Embodiment 3: get formalin 180 kilograms, 110 kilograms, urea, trimeric cyanamide 1 kilogram, auxiliary agent (urotropine 6 kilograms, oxalic acid 0.3 kg of water, Ammonium sulfamate, magnesium oxide, zinc oxide, ammonium chloride, ethanol, trolamine, ammoniacal liquor, PPG, T8, sodium naphthalene sulfonate, glycerine, magnesiumcarbonate, Resorcinol etc. 5.7 kilograms, colorant and Zinic stearas etc. 3 kilograms) 15 kilograms etc. add in vacuum granulation reactor all-in-one, the alkali-acid-alkali method synthetic resins of gating.
Vacuum granulation reactor all-in-one, under whipped state, adds fiber 28 kilograms, waste paper starch 46 kilograms, the kaolin 33 kilograms such as waste cotton fiber crops chemical fibre glass successively, following operating process as implemented with example 1, polymerization, mediate, dispersion, the closed production such as dry.Can high strength be manufactured, shock resistance, stretching resistance labour safety product with this material, attractive in appearance, generous, fall not bad, also can make Dining tool, available mahjong chess and card, flowerpot, tableware, artwork, Top Grade Decorative Plank, the environment-friendly materials such as imitative solid wood household, economical, material benefit.
Can also use farm crop tangerine bar, add starch and make packing material, mix inorganic oxide in right amount, produce environment-friendly type plastic, use this craft articles, household utensils, decorative building material etc. not only have above-mentioned advantage, and raw material sources are extensive, with low cost.

Claims (4)

1. the amino granular molding compound of the high intensity low shrinkage of a jade bag and production method, the amino granular molding compound of high intensity low shrinkage and the production method raw material that it is characterized in that preparing this kind of jade bag are: formalin, urea, trimeric cyanamide, auxiliary agent, caustic soda, the material compositions such as packing material, for the resins synthesis stage: the alkali-acid-alkali method synthetic resins of gating, evaporation polycondensation phase: vacuum granulation reactor all-in-one resin and packing material being inputted designed, designed, closed production one step with functions such as polymerization, kneading, dispersion, dryings completes.
2. prepare the amino granular molding compound of high intensity low shrinkage of a kind of jade bag described in claim 1 and the production method of production method for one kind, the parts by weight of each component of its feature are respectively: formalin 2400, urea 1380, trimeric cyanamide 115, auxiliary agent 180, packing material 1000-2000, described packing material is wood powder, there is inorganic middle short fiber, pulp board, waste paper wood pulp, paddy shell, bone meal, the mixture of starch and inorganic oxide, and packing material is wood powder, there is inorganic middle short fiber, pulp board, waste paper wood pulp, paddy shell, bone meal, the weight ratio of the mixture of starch and inorganic oxide is 50-90:4-10, described inorganic oxide is selected from calcium oxide, aluminum oxide and kaolin etc.
3. auxiliary agent parts by weight described in the amino granular molding compound of the high intensity low shrinkage preparing a kind of jade bag described in claim 1 and production method are respectively: urotropine 88, oxalic acid 6, the 40-80 such as water, Ammonium sulfamate, magnesium oxide, zinc oxide, ammonium chloride, ethanol, trolamine, ammoniacal liquor, PPG, T8, sodium naphthalene sulfonate, glycerine, magnesiumcarbonate, Resorcinol, colorant and Zinic stearas etc. 40.
4. prepare the amino granular molding compound of high intensity low shrinkage and the production method of a kind of jade bag described in claim 1 for one kind, it is characterized in that general alkali-acid-alkali method synthetic resins, deliver in vacuum granulation reactor by adding packing material in resin liquid, fully be uniformly mixed, high-speed stirring is after 2 ~ 5 minutes, turn low speed, material reaction temperature is incubated 60 minutes under 50-60 degree, unlatching vacuum valve draws water, stirring at low speed 10 ~ 15 minutes, transfer interval high-speed stirring to, temperature of charge 60-85 DEG C, moisture is measured after 60 minutes, meet decompress(ion) cooling blowing after moisture content requirement, the short storage of this material solidification is long, omnidistance tasteless without bisque quality better, cost-saving raising effect.
CN201410170697.7A 2014-04-26 2014-04-26 Jade vein simulated high-intensity low-shrinkage amino moulding plastic particle material and production method Pending CN105017718A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105419228A (en) * 2016-01-08 2016-03-23 东莞市唯轩家居用品有限公司 New artware material and preparation method thereof
CN105904608A (en) * 2016-04-12 2016-08-31 温州乔建塑料有限公司 Wet granulation technology of urea-formaldehyde resin
CN107053517A (en) * 2017-03-14 2017-08-18 山东高兴新材料股份有限公司 A kind of compound amino film plastics grain granulation Processes and apparatus
CN107936466A (en) * 2017-11-30 2018-04-20 东莞菌怕怕科技实业有限公司 A kind of manufacture method of the beautiful material of colorful electricity and its electric beautiful product

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105419228A (en) * 2016-01-08 2016-03-23 东莞市唯轩家居用品有限公司 New artware material and preparation method thereof
CN105904608A (en) * 2016-04-12 2016-08-31 温州乔建塑料有限公司 Wet granulation technology of urea-formaldehyde resin
CN107053517A (en) * 2017-03-14 2017-08-18 山东高兴新材料股份有限公司 A kind of compound amino film plastics grain granulation Processes and apparatus
CN107936466A (en) * 2017-11-30 2018-04-20 东莞菌怕怕科技实业有限公司 A kind of manufacture method of the beautiful material of colorful electricity and its electric beautiful product

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Application publication date: 20151104