CN105399281B - 一种去除废水中卡马西平的处理方法 - Google Patents
一种去除废水中卡马西平的处理方法 Download PDFInfo
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- CN105399281B CN105399281B CN201510966249.2A CN201510966249A CN105399281B CN 105399281 B CN105399281 B CN 105399281B CN 201510966249 A CN201510966249 A CN 201510966249A CN 105399281 B CN105399281 B CN 105399281B
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- waste water
- carbamazepine
- electrion
- rhodium
- biopolymerization
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- 239000002351 wastewater Substances 0.000 title claims abstract description 40
- FFGPTBGBLSHEPO-UHFFFAOYSA-N carbamazepine Chemical compound C1=CC2=CC=CC=C2N(C(=O)N)C2=CC=CC=C21 FFGPTBGBLSHEPO-UHFFFAOYSA-N 0.000 title claims abstract description 27
- 229960000623 carbamazepine Drugs 0.000 title claims abstract description 27
- 238000003672 processing method Methods 0.000 title claims abstract description 9
- 229920001220 nitrocellulos Polymers 0.000 claims abstract description 38
- 229910052703 rhodium Inorganic materials 0.000 claims abstract description 31
- 239000010948 rhodium Substances 0.000 claims abstract description 31
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims abstract description 31
- 238000006555 catalytic reaction Methods 0.000 claims abstract description 23
- 230000014621 translational initiation Effects 0.000 claims abstract description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 21
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims abstract description 18
- 239000008187 granular material Substances 0.000 claims abstract description 15
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 15
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 12
- 125000003963 dichloro group Chemical group Cl* 0.000 claims abstract description 12
- 230000000694 effects Effects 0.000 claims abstract description 11
- 239000000020 Nitrocellulose Substances 0.000 claims abstract description 10
- FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2s,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6s)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2r,3r,4s,5r,6s)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 claims abstract description 10
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 10
- 235000013877 carbamide Nutrition 0.000 claims abstract description 9
- 150000003672 ureas Chemical class 0.000 claims abstract description 9
- 230000001105 regulatory effect Effects 0.000 claims abstract description 8
- 150000001412 amines Chemical class 0.000 claims abstract description 5
- 230000005284 excitation Effects 0.000 claims abstract description 5
- 238000004064 recycling Methods 0.000 claims abstract description 3
- 239000002699 waste material Substances 0.000 claims description 17
- 238000001035 drying Methods 0.000 claims description 14
- 238000006243 chemical reaction Methods 0.000 claims description 11
- 210000005056 cell body Anatomy 0.000 claims description 10
- 238000007599 discharging Methods 0.000 claims description 10
- 230000015572 biosynthetic process Effects 0.000 claims description 9
- 241000221523 Rhodotorula toruloides Species 0.000 claims description 7
- 241000194017 Streptococcus Species 0.000 claims description 7
- 241000588621 Moraxella Species 0.000 claims description 6
- 239000010410 layer Substances 0.000 claims description 6
- 239000003054 catalyst Substances 0.000 claims description 5
- 125000004122 cyclic group Chemical group 0.000 claims description 4
- 239000011241 protective layer Substances 0.000 claims description 4
- 238000000746 purification Methods 0.000 claims description 4
- 230000004071 biological effect Effects 0.000 claims description 3
- 239000000919 ceramic Substances 0.000 claims description 3
- 238000001125 extrusion Methods 0.000 claims description 3
- 239000000945 filler Substances 0.000 claims description 3
- 238000012856 packing Methods 0.000 claims description 3
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical group [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 3
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 3
- 229920000642 polymer Polymers 0.000 claims description 2
- 238000010891 electric arc Methods 0.000 claims 1
- 229920000620 organic polymer Polymers 0.000 claims 1
- 238000007493 shaping process Methods 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 11
- 239000000126 substance Substances 0.000 abstract description 7
- 238000005516 engineering process Methods 0.000 abstract description 3
- 230000002906 microbiologic effect Effects 0.000 abstract description 2
- 229920000742 Cotton Polymers 0.000 description 3
- 101000911390 Homo sapiens Coagulation factor VIII Proteins 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 102000057593 human F8 Human genes 0.000 description 2
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 2
- 229940047431 recombinate Drugs 0.000 description 2
- 239000010865 sewage Substances 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 229920002160 Celluloid Polymers 0.000 description 1
- 229910004679 ONO2 Inorganic materials 0.000 description 1
- NWPJLRSCSQHPJV-UHFFFAOYSA-N carpipramine Chemical compound C1CN(CCCN2C3=CC=CC=C3CCC3=CC=CC=C32)CCC1(C(=O)N)N1CCCCC1 NWPJLRSCSQHPJV-UHFFFAOYSA-N 0.000 description 1
- 229960000700 carpipramine Drugs 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000001037 epileptic effect Effects 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 210000003608 fece Anatomy 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000002207 metabolite Substances 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- -1 nitrogenous aromatic compounds Chemical class 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- DPJRMOMPQZCRJU-UHFFFAOYSA-M thiamine hydrochloride Chemical compound Cl.[Cl-].CC1=C(CCO)SC=[N+]1CC1=CN=C(C)N=C1N DPJRMOMPQZCRJU-UHFFFAOYSA-M 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 206010044652 trigeminal neuralgia Diseases 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/001—Processes for the treatment of water whereby the filtration technique is of importance
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/66—Treatment of water, waste water, or sewage by neutralisation; pH adjustment
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F2001/007—Processes including a sedimentation step
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/38—Organic compounds containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2301/00—General aspects of water treatment
- C02F2301/08—Multistage treatments, e.g. repetition of the same process step under different conditions
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/34—Biological treatment of water, waste water, or sewage characterised by the microorganisms used
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
- Catalysts (AREA)
Abstract
Description
Claims (4)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201510966249.2A CN105399281B (zh) | 2015-12-22 | 2015-12-22 | 一种去除废水中卡马西平的处理方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CN201510966249.2A CN105399281B (zh) | 2015-12-22 | 2015-12-22 | 一种去除废水中卡马西平的处理方法 |
Publications (2)
Publication Number | Publication Date |
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CN105399281A CN105399281A (zh) | 2016-03-16 |
CN105399281B true CN105399281B (zh) | 2017-09-22 |
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CN201510966249.2A Active CN105399281B (zh) | 2015-12-22 | 2015-12-22 | 一种去除废水中卡马西平的处理方法 |
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Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
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KR101150159B1 (ko) * | 2009-12-01 | 2012-05-25 | 휴켐스주식회사 | 니트로 화합물의 제조 과정에서 발생하는 폐수의 처리방법 |
JP2014131785A (ja) * | 2013-01-07 | 2014-07-17 | Mitsui Zosen Plant Engineering Inc | 窒素含有有機化合物のアルカリ洗浄法 |
CN104229972A (zh) * | 2013-10-17 | 2014-12-24 | 同济大学 | 一种利用芬顿技术强氧化去除污水中卡马西平的方法 |
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2015
- 2015-12-22 CN CN201510966249.2A patent/CN105399281B/zh active Active
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Publication number | Publication date |
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CN105399281A (zh) | 2016-03-16 |
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Legal Events
Date | Code | Title | Description |
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C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
CB03 | Change of inventor or designer information |
Inventor after: Ye Hairong Inventor after: Tao Lianyou Inventor after: Zhang Yingxian Inventor before: Pan Haojie |
|
CB03 | Change of inventor or designer information | ||
TA01 | Transfer of patent application right | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20170714 Address after: 325055 Wenzhou, Longwan District, Haicheng Street prosperous road, No. 55, No. Applicant after: Zhang Jun Address before: 315000, room 9, No. 110, Lane 403, Feng Sheng Road, Haishu District, Zhejiang, Ningbo Applicant before: Pan Haojie |
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GR01 | Patent grant | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right |
Effective date of registration: 20180206 Address after: 321002 Zhejiang province Jinhua City Jindong Kangji No. 878 North Street No. 2 workshop Patentee after: Zhejiang Hoodi Environmental Science & Technology Co., Ltd. Address before: 325055 Wenzhou, Longwan District, Haicheng Street prosperous road, No. 55, No. Patentee before: Zhang Jun |
|
TR01 | Transfer of patent right | ||
CP03 | Change of name, title or address |
Address after: 321000 No. 2, No. 878, North Kang Jie street, Jindong District, Jinhua, Zhejiang. Patentee after: Zhejiang Hongdian Environmental Protection Co., Ltd. Address before: 321002 No. 878 Kangji North Street, Jindong District, Jinhua City, Zhejiang Province Patentee before: Zhejiang Hoodi Environmental Science & Technology Co., Ltd. |
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CP03 | Change of name, title or address |