CN105397898B - A kind of preparation method of prosthetic Form aldehyde release wood-based plate - Google Patents

A kind of preparation method of prosthetic Form aldehyde release wood-based plate Download PDF

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Publication number
CN105397898B
CN105397898B CN201510825386.4A CN201510825386A CN105397898B CN 105397898 B CN105397898 B CN 105397898B CN 201510825386 A CN201510825386 A CN 201510825386A CN 105397898 B CN105397898 B CN 105397898B
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cellulose
wood
raw material
based plate
preparation
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CN105397898A (en
Inventor
彭万喜
葛省波
王丽姝
王忠伟
邓和平
张党权
张仲凤
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Hunan Hongsen New Material Technology Co., Ltd
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Central South University of Forestry and Technology
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27NMANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
    • B27N3/00Manufacture of substantially flat articles, e.g. boards, from particles or fibres
    • B27N3/08Moulding or pressing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27NMANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
    • B27N1/00Pretreatment of moulding material
    • B27N1/02Mixing the material with binding agent
    • B27N1/0209Methods, e.g. characterised by the composition of the agent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27NMANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
    • B27N3/00Manufacture of substantially flat articles, e.g. boards, from particles or fibres
    • B27N3/002Manufacture of substantially flat articles, e.g. boards, from particles or fibres characterised by the type of binder
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J101/00Adhesives based on cellulose, modified cellulose, or cellulose derivatives
    • C09J101/02Cellulose; Modified cellulose
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/06Non-macromolecular additives organic

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Wood Science & Technology (AREA)
  • Forests & Forestry (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Dry Formation Of Fiberboard And The Like (AREA)
  • Veneer Processing And Manufacture Of Plywood (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

The invention discloses the preparation section and applying glue process of a kind of preparation method of prosthetic Form aldehyde release wood-based plate, including cellulose modified adhesive;Prepared through cellulose modified adhesive, after two procedures of applying glue, according still further to the mating formation of conventional artificial's plate, precompressed, hot pressing, display, sanding and edge cutting technology parameter, complete the manufacture of prosthetic Form aldehyde release wood-based plate.The present invention be it is a kind of be easily achieved, the preparation method for the prosthetic Form aldehyde release wood-based plate that easy to operate, production cost is low.

Description

A kind of preparation method of prosthetic Form aldehyde release wood-based plate
Technical field
The present invention relates to a kind of preparation method of wood-based plate, specifically, it is related to a kind of prosthetic Form aldehyde release wood-based plate Preparation method.
Background technology
Timber industry is the pillar industry of China's economy of forestry, the development of the timber industry based on wood-based plate, for Building modern flourishing forestry industrial system, complete ecosystem and promoting Hunan Province four to change amphitypy social construction has ten Divide important meaning.With the development of economy and society, consumption figure of the wood-based plate in terms of furniture, floor, construction and decoration is Increase with surprising rapidity.
Reform and open up to the outside world over more than 30 years, China's wood-based plate yield adds nearly 30 times, China's glued board in 2015, particieboard, Fiberboard yield reaches about 3.02 hundred million m3, have become the world's strongest nation of wood-based plate, Furniture manufacturing.Wherein Hunan Province is artificial The m of plate about 5,000,0003, particularly Taojiang County timber industry (containing bamboo processing), development was swift and violent, up to 5000 enterprises, industry size Almost account for the 60~70% of Hunan Province.
However, the formaldehyde pollution problem that wood-based plate is triggered, seriously governs industry and develops in a healthy way and existence.Wood-based plate is given birth to Urea-formaldehyde resin adhesive usage amount accounts for more than 90% in production, along with the wood-based plate bonding technique of most enterprises falls behind relatively, Artificial board formaldehyde burst size is remained high, cause human settlement to deteriorate.
Air pollution turns into the significant problem of harm Living environment safety of human being.Wherein formaldehyde is to cause great people in indoor pollution The main cause that member's disease is died, the data display announced according to WHO, 80% leukaemia is as caused by formaldehyde pollution.
Formaldehyde Pollution of Indoor Air not only induces leukaemia, also directly triggers pregnant woman's miscarriage, fetal anomaly, lung cancer etc. many great Disease.Show that China there are more than 1,000 ten thousand pregnant woman to be miscarried because of formaldehyde pollution every year, is brought to up to ten million families according to planning commission's statistics is defended Grievous injury.
Therefore, formaldehyde endangers extremely serious, the first killer for being known as indoor environment.
And realize that prosthetic Form aldehyde release is the technical bottleneck of Wood-based Panel Production using urea-formaldehyde resin adhesive.Lauxite Adhesive accounts for more than the 30% of wood-based panel product cost, although being produced both at home and abroad using modified urea-formaldehyde resin with certain environmental protection The wood-based plate of property, but need to consume more adhesives and just can guarantee that properties of product, cause resource serious waste.
Thus, indoor formaldehyde content remains high, and the disease of induction takes place frequently, and seriously jeopardizes the health of people.Hunan Province youngster The latest data of virgin hospital issue is shown, between 5 years 2014 2010, accepts 12813 person-times of tumour Hospitalized Childrens for medical treatment altogether, and just with Refreshing the data of infant more than the speed of hundred/year.The ranking disease of first three is leukaemia, hemangioma, lymthoma respectively.According to Incomplete statistics, Hunan Province increases leukaemic newly at 1.5 ten thousand every year, and the whole nation increases leukaemia more than 20 ten thousand newly every year, mainly Concentrate the weak crowds of immunity such as child, old man, pregnant woman.
Based on timber industry Pollution of Formaldehyde, combine closely building Socialist New and local economic development It is required that, by the breakthrough of timber industry Formaldehyde Pollution Treatment technological package system, chance is carried out to medium-sized and small enterprises, minuscule-type-enterprise Impartial commonweal technology training, popularization artificial board formaldehyde pollution control knowledge and technology, realize that artificial board formaldehyde release reaches New step, i.e. large, medium-sized enterprises reach E0Level, medium-sized and small enterprises or minuscule-type-enterprise reach E1Or E0Level, then progressively promotes whole nation wood again Material industry, to promote public safety, construction of a comfortably-off society, developing rural economy and raising farmers' income to provide new approach.
In order to overcome this phenomenon, inventor lasts more than 20 years, costly, comprehensively analysis《Composite fiber plate》(application Number:02111211.8)、《Compacting and pressing and hardening cushions during the continuously composite wood boards such as production particieboard, fiberboard Method》(application number:03104109.4)、《The method for reducing the content of formaldehyde and burst size of methanal of particieboard》(application number: Etc. 01811365.6) on the basis of nearly 400 patents of invention, prepared by present invention applicant's original innovation adhesive, applying glue two Process, prepares prosthetic Form aldehyde release wood-based plate, and technical support is provided with added value to improve the wood-based plate feature of environmental protection.
The content of the invention
The technical problems to be solved by the invention be to provide it is a kind of be easily achieved, nobody that easy to operate, production cost is low The preparation method of work Form aldehyde release wood-based plate.
In order to solve the above-mentioned technical problem, the preparation method for the prosthetic Form aldehyde release wood-based plate that the present invention is used, including The preparation section and applying glue process of cellulose modified adhesive, it is characterized in that:The preparation work of described cellulose modified adhesive Sequence is:According to mass ratio mModified cellulose:mMelamine:mLignin=50:0~50:0~50, by modified cellulose, melamine with it is wooden Element is well mixed, is ground into the mesh of powder 10~2000, produces cellulose modified adhesive;Described applying glue process is:According to matter Amount compares mRaw material:mCellulose modified adhesive=50:1~50, raw material is well mixed with cellulose modified adhesive, or is uniformly glued to raw material Surface, obtains being glued raw material;Then according to the mating formation of conventional artificial's plate, precompressed, hot pressing, display, sanding and edge cutting technology parameter, Complete the manufacture of prosthetic Form aldehyde release wood-based plate.
Raw material refers to fiber, wood shavings, veneer or the batten that Wood-based Panel Production is used.
Described lignin purity 70~100%, pH=6.5~9.0.
Using the preparation method of the prosthetic Form aldehyde release wood-based plate of above-mentioned technical proposal, the manufacturing process of conventional artificial's plate Parameter, only changes the preparation section and applying glue process of cellulose modified adhesive with regard to that can produce prosthetic Form aldehyde release people simultaneously Make plate, it is easy to accomplish, easy to operate, production cost is low, to improve artificial forest wood added value and offer skill of increasing farmers' income Art is supported, and can increase orchard worker's income, significant to building a harmonious society.The invention can produce significant economy and society Meeting benefit, with good promotional value.
In summary, the present invention be it is a kind of be easily achieved, prosthetic Form aldehyde release that easy to operate, production cost is low it is artificial The preparation method of plate.
Embodiment
The present invention, but following implementations can be further expressly understood by the specific embodiment of invention now given below Example is not limitation of the invention.
Embodiment 1:
The preparation method of prosthetic Form aldehyde release wood-based plate, includes the preparation section and applying glue work of cellulose modified adhesive Sequence, the preparation section of cellulose modified adhesive is:Modified cellulose is ground into the mesh of powder 10, cellulose modified gluing is produced Agent;Being glued process is:According to mass ratio mRaw material:mCellulose modified adhesive=50:1, fiber is well mixed with cellulose modified adhesive, Obtain being glued raw material;Then according to the mating formation of conventional artificial's plate, precompressed, hot pressing, display, sanding and edge cutting technology parameter, complete Prosthetic Form aldehyde release wood-based plate is manufactured.
Embodiment 2:
The preparation method of prosthetic Form aldehyde release wood-based plate, includes the preparation section and applying glue work of cellulose modified adhesive Sequence, the preparation section of cellulose modified adhesive is:According to mass ratio mModified cellulose:mLignin=50:10, by modified cellulose and wood Quality is well mixed, and is ground into the mesh of powder 200, is produced cellulose modified adhesive;Being glued process is:According to mass ratio mRaw material: mCellulose modified adhesive=50:10, wood shavings are well mixed with cellulose modified adhesive, obtain being glued raw material;Wherein lignin purity 70%, pH=6.5;Then according to the mating formation of conventional artificial's plate, precompressed, hot pressing, display, sanding and edge cutting technology parameter, complete Prosthetic Form aldehyde release wood-based plate is manufactured.
Embodiment 3:
The preparation method of prosthetic Form aldehyde release wood-based plate, includes the preparation section and applying glue work of cellulose modified adhesive Sequence, the preparation section of cellulose modified adhesive is:According to mass ratio mModified cellulose:mMelamine=50:10, by modified cellulose with Melamine is well mixed, and is ground into the mesh of powder 500, is produced cellulose modified adhesive;Being glued process is:According to mass ratio mRaw material:mCellulose modified adhesive=50:20, uniformly it is glued to veneer surface, obtains being glued raw material;Then according to the paving of conventional artificial's plate Dress, precompressed, hot pressing, display, sanding and edge cutting technology parameter, complete the manufacture of prosthetic Form aldehyde release wood-based plate.
Embodiment 4:
The preparation method of prosthetic Form aldehyde release wood-based plate, includes the preparation section and applying glue work of cellulose modified adhesive Sequence, the preparation section of cellulose modified adhesive is:According to mass ratio mModified cellulose:mMelamine:mLignin=50:10:10, by modification Cellulose, melamine are well mixed with lignin, are ground into the mesh of powder 800, are produced cellulose modified adhesive;It is glued process It is:According to mass ratio mRaw material:mCellulose modified adhesive=50:30, uniformly it is glued to batten surface, obtains being glued raw material;Wherein lignin Purity 100%, pH=9.0;Then according to the mating formation of conventional artificial's plate, precompressed, hot pressing, display, sanding and edge cutting technology parameter, Complete the manufacture of prosthetic Form aldehyde release wood-based plate.
Embodiment 5:
The preparation method of prosthetic Form aldehyde release wood-based plate, includes the preparation section and applying glue work of cellulose modified adhesive Sequence, the preparation section of cellulose modified adhesive is:According to mass ratio mModified cellulose:mMelamine:mLignin=50:40:40, by modification Cellulose, melamine are well mixed with lignin, are ground into the mesh of powder 1200, are produced cellulose modified adhesive;It is glued work Sequence is:According to mass ratio mRaw material:mCellulose modified adhesive=50:25, uniformly it is glued to veneer surface, obtains being glued raw material;It is wherein wooden Plain purity 80%, pH=7.0;Then according to the mating formation of conventional artificial's plate, precompressed, hot pressing, display, sanding and edge cutting technology are joined Number, completes the manufacture of prosthetic Form aldehyde release wood-based plate.
Embodiment 6:
The preparation method of prosthetic Form aldehyde release wood-based plate, includes the preparation section and applying glue work of cellulose modified adhesive Sequence, the preparation section of cellulose modified adhesive is:According to mass ratio mModified cellulose:mMelamine:mLignin=50:20:30, by modification Cellulose, melamine are well mixed with lignin, are ground into the mesh of powder 1500, are produced cellulose modified adhesive;It is glued work Sequence is:According to mass ratio mRaw material:mCellulose modified adhesive=50:40, wood shavings are well mixed with cellulose modified adhesive, are glued Raw material;Wherein lignin purity 90%, pH=8.5;Then according to the mating formation of conventional artificial's plate, precompressed, hot pressing, display, sanding With edge cutting technology parameter, the manufacture of prosthetic Form aldehyde release wood-based plate is completed.
Embodiment 7:
The preparation method of prosthetic Form aldehyde release wood-based plate, includes the preparation section and applying glue work of cellulose modified adhesive Sequence, the preparation section of cellulose modified adhesive is:According to mass ratio mModified cellulose:mMelamine:mLignin=50:50:50, by modification Cellulose, melamine are well mixed with lignin, are ground into the mesh of powder 2000, are produced cellulose modified adhesive;It is glued work Sequence is:According to mass ratio mRaw material:mCellulose modified adhesive=50:50, uniformly it is glued to batten surface, obtains being glued raw material;It is wherein wooden Plain purity 85%, pH=6.8;Then according to the mating formation of conventional artificial's plate, precompressed, hot pressing, display, sanding and edge cutting technology are joined Number, completes the manufacture of prosthetic Form aldehyde release wood-based plate.

Claims (2)

1. a kind of preparation method of prosthetic Form aldehyde release wood-based plate, includes preparation section and the applying glue of cellulose modified adhesive Process, it is characterized in that:The preparation section of described cellulose modified adhesive is:According to mass ratio mModified cellulose:mMelamine:mLignin =50:50:50, modified cellulose, melamine are well mixed with lignin, the mesh of powder 10~2000 is ground into, produces fibre The modified adhesive of dimension element;Described applying glue process is:According to mass ratio mRaw material:mCellulose modified adhesive=50:1~50, by raw material and fibre The modified adhesive of dimension element is well mixed, or is uniformly glued to raw material surface, obtains being glued raw material;Then according to conventional artificial's plate Mat formation, precompressed, hot pressing, display, sanding and edge cutting technology parameter, complete the manufacture of prosthetic Form aldehyde release wood-based plate;It is wherein described Raw material refer to fiber, wood shavings, veneer or batten that Wood-based Panel Production is used;Described lignin purity 70~100%, pH =6.5~9.0.
2. the preparation method of prosthetic Form aldehyde release wood-based plate according to claim 1, it is characterized in that:Described cellulose Being modified the preparation section of adhesive is:According to mass ratio mModified cellulose:mMelamine:mLignin=50:50:50, by modified cellulose, three Poly cyanamid is well mixed with lignin, is ground into the mesh of powder 2000, is produced cellulose modified adhesive;Described applying glue process It is:According to mass ratio mRaw material:mCellulose modified adhesive=50:50, uniformly it is glued to batten surface, obtains being glued raw material;Wherein lignin Purity 85%, pH=6.8;Then according to the mating formation of conventional artificial's plate, precompressed, hot pressing, display, sanding and edge cutting technology parameter, Complete the manufacture of prosthetic Form aldehyde release wood-based plate.
CN201510825386.4A 2015-11-24 2015-11-24 A kind of preparation method of prosthetic Form aldehyde release wood-based plate Active CN105397898B (en)

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CN109109109A (en) * 2018-08-01 2019-01-01 福州市晋安区绿奇鑫环保科技有限公司 A kind of method that wood-based plate removes formaldehyde
CN111098383B (en) * 2019-12-16 2021-03-19 中国科学院化学研究所 Method for manufacturing environment-friendly artificial board by cotton stalks
SE546098C2 (en) * 2020-07-03 2024-05-21 Stora Enso Oyj Method for preparing a bonding resin comprising lignin, a bonding resin comprising lignin, products comprising said bonding resin, and use of said bonding resin

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FI970158A (en) * 1997-01-14 1998-07-15 Neste Oy New fiberboard adhesive
PT1419038E (en) * 2001-05-03 2007-03-30 Kronospan Tech Co Ltd Method for reducing formaldehyde content and formaldehyde emission from particleboard
CN104411492A (en) * 2012-09-24 2015-03-11 塞拉尼斯醋酸纤维有限公司 Fibrous substrates adhered with substituted cellulose ester adhesives and methods relating thereto
CN102863907B (en) * 2012-10-17 2013-10-23 中南林业科技大学 Flexible water-resistant silicate wood adhesive and preparation method thereof
CN103612295A (en) * 2013-12-05 2014-03-05 南京林业大学 Method of manufacturing aldehyde-free plywood through cellulose modified soybean gum
CN104449411B (en) * 2014-12-10 2017-01-25 中南林业科技大学 Adhesive and preparation method thereof as well as application of adhesive in vegetable fiberboard or artificial board
CN104629662B9 (en) * 2015-02-03 2016-11-16 北华大学 The urea-formaldehyde resin adhesive of a kind of ultra-low formaldehyde release and preparation technology thereof

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Effective date of registration: 20180626

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