CN105396699A - 一种黄铜浮选剂 - Google Patents
一种黄铜浮选剂 Download PDFInfo
- Publication number
- CN105396699A CN105396699A CN201510709753.4A CN201510709753A CN105396699A CN 105396699 A CN105396699 A CN 105396699A CN 201510709753 A CN201510709753 A CN 201510709753A CN 105396699 A CN105396699 A CN 105396699A
- Authority
- CN
- China
- Prior art keywords
- parts
- brass
- flotation agent
- flotation
- linseed oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000008396 flotation agent Substances 0.000 title claims abstract description 16
- 229910001369 Brass Inorganic materials 0.000 title claims abstract description 11
- 239000010951 brass Substances 0.000 title claims abstract description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 14
- 235000021388 linseed oil Nutrition 0.000 claims abstract description 10
- 239000000944 linseed oil Substances 0.000 claims abstract description 10
- TUZCOAQWCRRVIP-UHFFFAOYSA-N butoxymethanedithioic acid Chemical compound CCCCOC(S)=S TUZCOAQWCRRVIP-UHFFFAOYSA-N 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 7
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 claims abstract description 3
- 239000007822 coupling agent Substances 0.000 claims description 7
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 claims description 6
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 claims description 6
- 229940070765 laurate Drugs 0.000 claims description 6
- TWJNQYPJQDRXPH-UHFFFAOYSA-N 2-cyanobenzohydrazide Chemical compound NNC(=O)C1=CC=CC=C1C#N TWJNQYPJQDRXPH-UHFFFAOYSA-N 0.000 claims description 4
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 claims description 4
- 235000021360 Myristic acid Nutrition 0.000 claims description 4
- -1 neopelex Substances 0.000 claims description 2
- DVRDHUBQLOKMHZ-UHFFFAOYSA-N chalcopyrite Chemical compound [S-2].[S-2].[Fe+2].[Cu+2] DVRDHUBQLOKMHZ-UHFFFAOYSA-N 0.000 abstract description 7
- 229910052951 chalcopyrite Inorganic materials 0.000 abstract description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract description 5
- 229910052802 copper Inorganic materials 0.000 abstract description 5
- 239000010949 copper Substances 0.000 abstract description 5
- 239000006185 dispersion Substances 0.000 abstract description 3
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 abstract description 3
- 238000005188 flotation Methods 0.000 abstract description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 abstract 2
- 239000005639 Lauric acid Substances 0.000 abstract 1
- 239000003153 chemical reaction reagent Substances 0.000 abstract 1
- 230000008878 coupling Effects 0.000 abstract 1
- 238000010168 coupling process Methods 0.000 abstract 1
- 238000005859 coupling reaction Methods 0.000 abstract 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 abstract 1
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 abstract 1
- 235000019441 ethanol Nutrition 0.000 abstract 1
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 abstract 1
- 238000003756 stirring Methods 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 239000002253 acid Substances 0.000 description 1
- 238000009867 copper metallurgy Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000012719 thermal polymerization Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/012—Organic compounds containing sulfur
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2201/00—Specified effects produced by the flotation agents
- B03D2201/005—Dispersants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2201/00—Specified effects produced by the flotation agents
- B03D2201/02—Collectors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2203/00—Specified materials treated by the flotation agents; Specified applications
- B03D2203/02—Ores
Landscapes
- Lubricants (AREA)
Abstract
本发明提出了一种黄铜浮选剂，所述黄铜浮选剂由丁黄药，月桂酸，肉豆蔻酸，马来酸酐化亚麻籽油，乙二醇乙醚，乙醇，十二烷基苯磺酸钠，偶联剂KH550与水组成，所述黄铜浮选剂的分散与捕收效果良好，选择性良好，能够高效地浮选出低品位黄铜矿中的铜。
Description
技术领域
本发明涉及浮选剂领域，特别涉及黄铜浮选剂领域。
背景技术
黄铜矿主要为铜铁硫化物，其中还含有微量金、银等物质，是分布最广的铜矿类型，也是炼铜最主要的原料，在川滇地区有集中的分布，对一般黄铜矿中铜的提取已有较成熟、稳定、高效的技术，但现有技术关于低品位的黄铜矿中铜的充分提取仍存在较大的改进空间。
发明内容
本发明的目的在于提出一种分散与捕收效果良好，选择性良好，特别针对低品位黄铜矿浮选的浮选剂。
本发明的技术方案如下：
一种黄铜浮选剂，由以下组分组成：丁黄药，月桂酸，肉豆蔻酸，马来酸酐化亚麻籽油，乙二醇乙醚，乙醇，十二烷基苯磺酸钠，偶联剂KH550与水。
优选的是：按质量份，所述浮选剂包括丁黄药10~20份，月桂酸1~5份，肉豆蔻酸1~5份，马来酸酐化亚麻籽油5~7份，乙二醇乙醚10~15份，乙醇5~10份，十二烷基苯磺酸钠1~5份，偶联剂KH5501~3份，水30~50份。
上述成分主要包括用于产生疏水效果的部分、表面活性剂、稀释剂、偶联剂等，其中马来酸酐化亚麻籽油为马来酸酐与亚麻籽油反应的产物，可以为完全反应的产物，也可以为不完全反应的产物，反应可以为热聚合、自由基引发聚合、酸/碱催化聚合等各种能够使马来酸酐与亚麻籽油反应的形式。
本发明的分散与捕收效果良好，选择性良好，能够高效地浮选出低品位黄铜矿中的铜。
具体实施方式
实施例1
将丁黄药10份，月桂酸1份，肉豆蔻酸1份，马来酸酐化亚麻籽油5份，乙二醇乙醚10份，乙醇5份混合后搅拌均匀，再将十二烷基苯磺酸钠1份，偶联剂KH5501份与水30份加入其中,搅拌均匀后即得到所述的黄铜浮选剂。
实施例2
将丁黄药20份，月桂酸5份，肉豆蔻酸5份，马来酸酐化亚麻籽油7份，乙二醇乙醚15份，乙醇10份混合后搅拌均匀，再将十二烷基苯磺酸钠5份，偶联剂KH5503份与水50份加入其中,搅拌均匀后即得到所述的黄铜浮选剂。
Claims (2)
1.一种黄铜浮选剂，其特征在于：所述浮选剂由以下组分组成：丁黄药，月桂酸，肉豆蔻酸，马来酸酐化亚麻籽油，乙二醇乙醚，乙醇，十二烷基苯磺酸钠，偶联剂KH550与水。
2.根据权利要求1所述的黄铜浮选剂，其特征在于：按质量份，所述浮选剂包括丁黄药10~20份，月桂酸1~5份，肉豆蔻酸1~5份，马来酸酐化亚麻籽油5~7份，乙二醇乙醚10~15份，乙醇5~10份，十二烷基苯磺酸钠1~5份，偶联剂KH5501~3份，水30~50份。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510709753.4A CN105396699A (zh) | 2015-10-28 | 2015-10-28 | 一种黄铜浮选剂 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510709753.4A CN105396699A (zh) | 2015-10-28 | 2015-10-28 | 一种黄铜浮选剂 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105396699A true CN105396699A (zh) | 2016-03-16 |
Family
ID=55462646
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510709753.4A Pending CN105396699A (zh) | 2015-10-28 | 2015-10-28 | 一种黄铜浮选剂 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105396699A (zh) |
-
2015
- 2015-10-28 CN CN201510709753.4A patent/CN105396699A/zh active Pending
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104107762B (zh) | 一种耐低温型胶磷矿反浮选捕收剂及其制备方法 | |
| CN105537003B (zh) | 一种地沟油类胶磷矿反浮选捕收剂及其制备方法 | |
| CN103909021A (zh) | 一种选煤用微乳化复合浮选剂和制备方法 | |
| CN105344490A (zh) | 一种胶磷矿反浮选捕收剂及其制备方法 | |
| CN103341412A (zh) | 萤石矿浮选捕收剂 | |
| CN108480055A (zh) | 一种白钨矿浮选捕收剂及其制备方法 | |
| CN105396699A (zh) | 一种黄铜浮选剂 | |
| CN105233999A (zh) | 一种黄铜矿浮选剂 | |
| CN104259008B (zh) | 一种复合捕收剂及应用 | |
| CN105195333A (zh) | 一种矿物浮选剂 | |
| CN106238221A (zh) | 一种改进型铜矿浮选剂 | |
| CN105233997A (zh) | 一种低品位矿物浮选剂 | |
| CN105195332A (zh) | 一种铜矿精选浮选剂 | |
| CN105344486A (zh) | 一种低品位黄铜浮选剂 | |
| CN106111348A (zh) | 一种改进型浮选剂 | |
| CN105385069A (zh) | 一种发泡复合材料 | |
| CN105234002A (zh) | 一种低品位黄铜矿浮选剂 | |
| CN106140487A (zh) | 一种改进型矿物浮选剂 | |
| CN105234004A (zh) | 一种铜钴精选浮选剂 | |
| CN105234003A (zh) | 一种铜矿精选用浮选剂 | |
| CN106140484A (zh) | 一种改进型低品位黄铜矿浮选剂 | |
| CN105344489A (zh) | 一种浮选剂的制备方法 | |
| CN105195329A (zh) | 一种矿物浮选剂的制备方法 | |
| CN105233995A (zh) | 一种黄铜矿浮选剂的制备方法 | |
| CN105234001A (zh) | 一种铜钼浮选剂 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20160316 |