CN105385926A - Zinc alloy and preparation method and application thereof - Google Patents

Zinc alloy and preparation method and application thereof Download PDF

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Publication number
CN105385926A
CN105385926A CN201510912215.5A CN201510912215A CN105385926A CN 105385926 A CN105385926 A CN 105385926A CN 201510912215 A CN201510912215 A CN 201510912215A CN 105385926 A CN105385926 A CN 105385926A
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zinc
alloy
die casting
copper
iron
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王立鑫
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C30/00Alloys containing less than 50% by weight of each constituent
    • C22C30/06Alloys containing less than 50% by weight of each constituent containing zinc
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D17/00Pressure die casting or injection die casting, i.e. casting in which the metal is forced into a mould under high pressure
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/02Making non-ferrous alloys by melting
    • C22C1/03Making non-ferrous alloys by melting using master alloys
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/06Making non-ferrous alloys with the use of special agents for refining or deoxidising
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C18/00Alloys based on zinc
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C18/00Alloys based on zinc
    • C22C18/02Alloys based on zinc with copper as the next major constituent
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C30/00Alloys containing less than 50% by weight of each constituent
    • C22C30/02Alloys containing less than 50% by weight of each constituent containing copper
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C33/00Making ferrous alloys
    • C22C33/04Making ferrous alloys by melting
    • C22C33/06Making ferrous alloys by melting using master alloys
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/002Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/005Ferrous alloys, e.g. steel alloys containing rare earths, i.e. Sc, Y, Lanthanides
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/06Ferrous alloys, e.g. steel alloys containing aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/08Ferrous alloys, e.g. steel alloys containing nickel
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/16Ferrous alloys, e.g. steel alloys containing copper
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Manufacture And Refinement Of Metals (AREA)

Abstract

The invention discloses zinc alloy and a preparation method and application thereof. The zinc alloy is prepared from, by mass, 30%-40% of zinc, 15%-25% of copper, 6%-12% of aluminum, 0.2%-0.8% of lanthanum, 0.1%-0.8% of chromium, 0.1%-0.5% of manganese, 0.1%-0.5% of mendelevium, 1%-2.5% of nickel, 0.4%-0.8% of dysprosium, 0.2%-0.8% of lawrencium, 0.1%-1.5% of protactinium, 0.2%-0.9% of plutonium, 0.1%-0.6% of scandium, 0.2%-0.7% of curium, 0.3%-0.7% of europium, and the balance iron. The components and contents are set reasonably, so that the surface is bright, and it is ensured that the zinc alloy has the sufficient mechanical properties, especially the mechanical properties suitable for the heavy-load and high-temperature use environment; the zinc alloy has the excellent normal temperature mechanical property, and the technical parameters of pressure casting and the inert gas pressure parameters of refining are optimized.

Description

A kind of zinc alloy and its production and use
Technical field
The present invention relates to metal material field, specifically a kind of zinc alloy and its production and use.
Background technology
Die casting is widely used in the industry-by-industries such as automobile making, oil engine production, motorcycle manufacture, electric motor manufacture, oil pump manufacture, gearing manufacture, precision instrument, landscaping, power construction, building decoration.
Existing die casting zinc alloy material generally includes the compositions such as aluminium, iron, copper, zinc, because the content of element each in alloy is different, therefore spatial distribution differences is comparatively large in the alloy for each element, causes each alloy over-all properties different, particularly mechanical property differs greatly.The defects such as loosening easily appears in castingprocesses, segregation, and its use temperature is also lower, and a large amount of heat releases usually produced due to frictional wear under fully loaded transportation condition make component temperature overheating and are difficult to use.
Summary of the invention
The object of the present invention is to provide and be a kind ofly applicable to zinc alloy of the die casting of high temperature heavy load work and its production and use, to solve the problem proposed in above-mentioned background technology.
For achieving the above object, the invention provides following technical scheme:
A kind of zinc alloy, be grouped into by the following one-tenth according to mass percent: zinc 30-40%, copper 15-25%, aluminium 6-12%, lanthanum 0.2-0.8%, chromium 0.1-0.8%, manganese 0.1-0.5%, mendelevium 0.1-0.5%, nickel 1-2.5%, dysprosium 0.4-0.8%, lawrencium 0.2-0.8%, protactinium 0.1-1.5%, plutonium 0.2-0.9%, scandium 0.1-0.6%, curium 0.2-0.7%, europium 0.3-0.7%, surplus is iron.
As preferred version of the present invention, of the present inventionly to be grouped into by the following one-tenth according to mass percent: zinc 32-38%, copper 18-22%, aluminium 8-10%, lanthanum 0.3-0.7%, chromium 0.3-0.6%, manganese 0.2-0.4%, mendelevium 0.2-0.4%, nickel 1.5-2%, dysprosium 0.5-0.7%, lawrencium 0.4-0.6%, protactinium 0.5-1%, plutonium 0.4-0.7%, scandium 0.2-0.4%, curium 0.4-0.6%, europium 0.4-0.6%, surplus is iron.
As preferred version of the present invention, the present invention is grouped into by the following one-tenth according to mass percent: zinc 35%, copper 20%, aluminium 9%, lanthanum 0.5%, chromium 0.4%, manganese 0.3%, mendelevium 0.3%, nickel 1.9%, dysprosium 0.6%, lawrencium 0.5%, protactinium 0.8%, plutonium 0.6%, scandium 0.3%, curium 0.5%, europium 0.5%, surplus is iron.
The present invention also provides a kind of preparation method of zinc alloy, comprises the following steps:
1) zinc, copper, iron, aluminium are put into vacuum melting furnace crucible, be evacuated to 8.8 × more than 10-2Pa, start to heat up, after temperature rises to 920-935 DEG C, stop vacuumizing and be filled with rare gas element to 4.8 × 104Pa in vacuum melting furnace; Then continue to be warming up to 1300-1350 DEG C, after zinc, dibenzenesulfonyl imines, iron, copper dissolve completely, start in zinc, copper, iron, aluminum alloy melt, be filled with rare gas element and stir 40-45 minute, aluminium alloy is cooled, obtains master alloy;
2) master alloy and other remaining ingredients are joined in vacuum melting furnace crucible, be evacuated to 8.9 × more than 10-2Pa, start to heat up, after temperature rises to 920-940 DEG C, stop vacuumizing and be filled with rare gas element to 4 × 104Pa in vacuum melting furnace; Then continue to be warming up to 1400-1450 DEG C, treat that alloy dissolves completely, after refining leaves standstill 42-45 minute, after inspection bath composition is qualified, namely obtain refining liquid;
3) after refining liquid being cooled to 720-730 DEG C, die casting is preheated in the mold cavity of 250-300 DEG C to passing through, the refining liquid melt flow of wherein filling when type starts is 0.4m/s, casting pressure is 75MPa, fill type rate more than 65% after, the melt flow improving refining liquid is 105MPa to 2.5m/s, casting pressure, terminates until fill type die casting;
4) thermal treatment: by die casting foundry goods under 450 DEG C of conditions after homogenizing 35-40h after shrend to room temperature, then be warming up to the ageing treatment that 170-175 DEG C is carried out 13-15h, obtain the zinc alloy of die casting.
As preferred version of the present invention, the purposes in die casting prepared by described zinc alloy of the present invention.
Compared with prior art, the invention has the beneficial effects as follows:
The reasonable disposition of each composition and content in the present invention, surface-brightening, ensure that zinc alloy has enough mechanical properties, particularly be applicable to the mechanical property under heavy duty, applied at elevated temperature environment, not only there is excellent ambient temperature mechanical properties, and inert gas pressure parameter when optimizing processing parameter and the refining of die casting.
Embodiment
Below in conjunction with the embodiment of the present invention, be clearly and completely described the technical scheme in the embodiment of the present invention, obviously, described embodiment is only the present invention's part embodiment, instead of whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art, not making the every other embodiment obtained under creative work prerequisite, belong to the scope of protection of the invention.
A kind of zinc alloy, be grouped into by the following one-tenth according to mass percent: zinc 30-40%, copper 15-25%, aluminium 6-12%, lanthanum 0.2-0.8%, chromium 0.1-0.8%, manganese 0.1-0.5%, mendelevium 0.1-0.5%, nickel 1-2.5%, dysprosium 0.4-0.8%, lawrencium 0.2-0.8%, protactinium 0.1-1.5%, plutonium 0.2-0.9%, scandium 0.1-0.6%, curium 0.2-0.7%, europium 0.3-0.7%, surplus is iron.
As preferred version of the present invention, of the present inventionly to be grouped into by the following one-tenth according to mass percent: zinc 32-38%, copper 18-22%, aluminium 8-10%, lanthanum 0.3-0.7%, chromium 0.3-0.6%, manganese 0.2-0.4%, mendelevium 0.2-0.4%, nickel 1.5-2%, dysprosium 0.5-0.7%, lawrencium 0.4-0.6%, protactinium 0.5-1%, plutonium 0.4-0.7%, scandium 0.2-0.4%, curium 0.4-0.6%, europium 0.4-0.6%, surplus is iron.
As preferred version of the present invention, the present invention is grouped into by the following one-tenth according to mass percent: zinc 35%, copper 20%, aluminium 9%, lanthanum 0.5%, chromium 0.4%, manganese 0.3%, mendelevium 0.3%, nickel 1.9%, dysprosium 0.6%, lawrencium 0.5%, protactinium 0.8%, plutonium 0.6%, scandium 0.3%, curium 0.5%, europium 0.5%, surplus is iron.
The present invention also provides a kind of preparation method of zinc alloy, comprises the following steps:
1) zinc, copper, iron, aluminium are put into vacuum melting furnace crucible, be evacuated to 8.8 × more than 10-2Pa, start to heat up, after temperature rises to 920-935 DEG C, stop vacuumizing and be filled with rare gas element to 4.8 × 104Pa in vacuum melting furnace; Then continue to be warming up to 1300-1350 DEG C, after zinc, dibenzenesulfonyl imines, iron, copper dissolve completely, start in zinc, copper, iron, aluminum alloy melt, be filled with rare gas element and stir 40-45 minute, aluminium alloy is cooled, obtains master alloy;
2) master alloy and other remaining ingredients are joined in vacuum melting furnace crucible, be evacuated to 8.9 × more than 10-2Pa, start to heat up, after temperature rises to 920-940 DEG C, stop vacuumizing and be filled with rare gas element to 4 × 104Pa in vacuum melting furnace; Then continue to be warming up to 1400-1450 DEG C, treat that alloy dissolves completely, after refining leaves standstill 42-45 minute, after inspection bath composition is qualified, namely obtain refining liquid;
3) after refining liquid being cooled to 720-730 DEG C, die casting is preheated in the mold cavity of 250-300 DEG C to passing through, the refining liquid melt flow of wherein filling when type starts is 0.4m/s, casting pressure is 75MPa, fill type rate more than 65% after, the melt flow improving refining liquid is 105MPa to 2.5m/s, casting pressure, terminates until fill type die casting;
4) thermal treatment: by die casting foundry goods under 450 DEG C of conditions after homogenizing 35-40h after shrend to room temperature, then be warming up to the ageing treatment that 170-175 DEG C is carried out 13-15h, obtain the zinc alloy of die casting.
As preferred version of the present invention, the purposes in die casting prepared by described zinc alloy of the present invention.
Embodiment 1
A kind of zinc alloy, be grouped into by the following one-tenth according to mass percent: zinc 35%, copper 20%, aluminium 9%, lanthanum 0.5%, chromium 0.4%, manganese 0.3%, mendelevium 0.3%, nickel 1.9%, dysprosium 0.6%, lawrencium 0.5%, protactinium 0.8%, plutonium 0.6%, scandium 0.3%, curium 0.5%, europium 0.5%, surplus is iron.
The present invention also provides a kind of preparation method of zinc alloy, comprises the following steps:
1) zinc, copper, iron, aluminium are put into vacuum melting furnace crucible, be evacuated to 8.8 × more than 10-2Pa, start to heat up, after temperature rises to 920-935 DEG C, stop vacuumizing and be filled with rare gas element to 4.8 × 104Pa in vacuum melting furnace; Then continue to be warming up to 1300-1350 DEG C, after zinc, dibenzenesulfonyl imines, iron, copper dissolve completely, start in zinc, copper, iron, aluminum alloy melt, be filled with rare gas element and stir 40-45 minute, aluminium alloy is cooled, obtains master alloy;
2) master alloy and other remaining ingredients are joined in vacuum melting furnace crucible, be evacuated to 8.9 × more than 10-2Pa, start to heat up, after temperature rises to 920-940 DEG C, stop vacuumizing and be filled with rare gas element to 4 × 104Pa in vacuum melting furnace; Then continue to be warming up to 1400-1450 DEG C, treat that alloy dissolves completely, after refining leaves standstill 42-45 minute, after inspection bath composition is qualified, namely obtain refining liquid;
3) after refining liquid being cooled to 720-730 DEG C, die casting is preheated in the mold cavity of 250-300 DEG C to passing through, the refining liquid melt flow of wherein filling when type starts is 0.4m/s, casting pressure is 75MPa, fill type rate more than 65% after, the melt flow improving refining liquid is 105MPa to 2.5m/s, casting pressure, terminates until fill type die casting;
4) thermal treatment: by die casting foundry goods under 450 DEG C of conditions after homogenizing 35-40h after shrend to room temperature, then be warming up to the ageing treatment that 170-175 DEG C is carried out 13-15h, obtain the zinc alloy of die casting.
As preferred version of the present invention, the purposes in die casting prepared by described zinc alloy of the present invention.
To those skilled in the art, obviously the invention is not restricted to the details of above-mentioned one exemplary embodiment, and when not deviating from spirit of the present invention or essential characteristic, the present invention can be realized in other specific forms.Therefore, no matter from which point, all should embodiment be regarded as exemplary, and be nonrestrictive, scope of the present invention is limited by claims instead of above-mentioned explanation, and all changes be therefore intended in the implication of the equivalency by dropping on claim and scope are included in the present invention.
In addition, be to be understood that, although this specification sheets is described according to embodiment, but not each embodiment only comprises an independently technical scheme, this narrating mode of specification sheets is only for clarity sake, those skilled in the art should by specification sheets integrally, and the technical scheme in each embodiment also through appropriately combined, can form other embodiments that it will be appreciated by those skilled in the art that.

Claims (5)

1. a zinc alloy, it is characterized in that, be grouped into by the following one-tenth according to mass percent: zinc 30-40%, copper 15-25%, aluminium 6-12%, lanthanum 0.2-0.8%, chromium 0.1-0.8%, manganese 0.1-0.5%, mendelevium 0.1-0.5%, nickel 1-2.5%, dysprosium 0.4-0.8%, lawrencium 0.2-0.8%, protactinium 0.1-1.5%, plutonium 0.2-0.9%, scandium 0.1-0.6%, curium 0.2-0.7%, europium 0.3-0.7%, surplus is iron.
2. the highlighted zinc alloy of die casting according to claim 1, it is characterized in that, be grouped into by the following one-tenth according to mass percent: zinc 32-38%, copper 18-22%, aluminium 8-10%, lanthanum 0.3-0.7%, chromium 0.3-0.6%, manganese 0.2-0.4%, mendelevium 0.2-0.4%, nickel 1.5-2%, dysprosium 0.5-0.7%, lawrencium 0.4-0.6%, protactinium 0.5-1%, plutonium 0.4-0.7%, scandium 0.2-0.4%, curium 0.4-0.6%, europium 0.4-0.6%, surplus is iron.
3. the zinc alloy of die casting according to claim 2, it is characterized in that, be grouped into by the following one-tenth according to mass percent: zinc 35%, copper 20%, aluminium 9%, lanthanum 0.5%, chromium 0.4%, manganese 0.3%, mendelevium 0.3%, nickel 1.9%, dysprosium 0.6%, lawrencium 0.5%, protactinium 0.8%, plutonium 0.6%, scandium 0.3%, curium 0.5%, europium 0.5%, surplus is iron.
4. the die casting preparation method for highlighted zinc alloy as described in as arbitrary in claim 1-3, is characterized in that, comprise the following steps:
1) zinc, copper, iron, aluminium are put into vacuum melting furnace crucible, be evacuated to 8.8 × 10 -2more than Pa, starts to heat up, and after temperature rises to 920-935 DEG C, stops vacuumizing and be filled with rare gas element to 4.8 × 10 in vacuum melting furnace 4pa; Then continue to be warming up to 1300-1350 DEG C, after zinc, dibenzenesulfonyl imines, iron, copper dissolve completely, start in zinc, copper, iron, aluminum alloy melt, be filled with rare gas element and stir 40-45 minute, aluminium alloy is cooled, obtains master alloy;
2) master alloy and other remaining ingredients are joined in vacuum melting furnace crucible, be evacuated to 8.9 × 10 -2more than Pa, starts to heat up, and after temperature rises to 920-940 DEG C, stops vacuumizing and be filled with rare gas element to 4 × 10 in vacuum melting furnace 4pa; Then continue to be warming up to 1400-1450 DEG C, treat that alloy dissolves completely, after refining leaves standstill 42-45 minute, after inspection bath composition is qualified, namely obtain refining liquid;
3) after refining liquid being cooled to 720-730 DEG C, die casting is preheated in the mold cavity of 250-300 DEG C to passing through, the refining liquid melt flow of wherein filling when type starts is 0.4m/s, casting pressure is 75MPa, fill type rate more than 65% after, the melt flow improving refining liquid is 105MPa to 2.5m/s, casting pressure, terminates until fill type die casting;
4) thermal treatment: by die casting foundry goods under 450 DEG C of conditions after homogenizing 35-40h after shrend to room temperature, then be warming up to the ageing treatment that 170-175 DEG C is carried out 13-15h, obtain the zinc alloy of die casting.
5. the purposes in die casting prepared by the zinc alloy as described in as arbitrary in claim 1-3.
CN201510912215.5A 2015-12-11 2015-12-11 Zinc alloy and preparation method and application thereof Pending CN105385926A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115233036A (en) * 2022-06-17 2022-10-25 广州湘龙高新材料科技股份有限公司 3D printing method for zinc alloy false tooth

Citations (6)

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Publication number Priority date Publication date Assignee Title
CN102011029A (en) * 2010-12-08 2011-04-13 宁波博威合金材料股份有限公司 Zinc alloy for zipper tooth belt and preparation method of zipper tooth belt
CN102286677A (en) * 2011-08-29 2011-12-21 镇江汇通金属成型有限公司 Wearable zinc alloy vehicle steering knuckle shaft sleeve and manufacturing method thereof
CN102418006A (en) * 2011-12-08 2012-04-18 广东金亿合金制品有限公司 High-aluminum and high-copper zinc alloy special for lock industry
CN102453817A (en) * 2010-10-28 2012-05-16 广东金亿合金制品有限公司 Zinc alloy special for stamping and manufacturing method thereof
CN102994805A (en) * 2012-12-17 2013-03-27 宁波香豪莱宝金属工业有限公司 Extruded zinc alloy and preparation method thereof
CN103014415A (en) * 2012-12-17 2013-04-03 宁波香豪莱宝金属工业有限公司 Zinc alloy material

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102453817A (en) * 2010-10-28 2012-05-16 广东金亿合金制品有限公司 Zinc alloy special for stamping and manufacturing method thereof
CN102011029A (en) * 2010-12-08 2011-04-13 宁波博威合金材料股份有限公司 Zinc alloy for zipper tooth belt and preparation method of zipper tooth belt
CN102286677A (en) * 2011-08-29 2011-12-21 镇江汇通金属成型有限公司 Wearable zinc alloy vehicle steering knuckle shaft sleeve and manufacturing method thereof
CN102418006A (en) * 2011-12-08 2012-04-18 广东金亿合金制品有限公司 High-aluminum and high-copper zinc alloy special for lock industry
CN102994805A (en) * 2012-12-17 2013-03-27 宁波香豪莱宝金属工业有限公司 Extruded zinc alloy and preparation method thereof
CN103014415A (en) * 2012-12-17 2013-04-03 宁波香豪莱宝金属工业有限公司 Zinc alloy material

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115233036A (en) * 2022-06-17 2022-10-25 广州湘龙高新材料科技股份有限公司 3D printing method for zinc alloy false tooth

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Application publication date: 20160309