CN105385061A - PVC thermal contraction printing film - Google Patents
PVC thermal contraction printing film Download PDFInfo
- Publication number
- CN105385061A CN105385061A CN201510892463.8A CN201510892463A CN105385061A CN 105385061 A CN105385061 A CN 105385061A CN 201510892463 A CN201510892463 A CN 201510892463A CN 105385061 A CN105385061 A CN 105385061A
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- CN
- China
- Prior art keywords
- weight part
- agent
- printing film
- heat shrinkable
- pvc heat
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/06—Coating with compositions not containing macromolecular substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/101—Esters; Ether-esters of monocarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
- C08K5/132—Phenols containing keto groups, e.g. benzophenones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08J2327/06—Homopolymers or copolymers of vinyl chloride
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a PVC thermal contraction printing film. The film comprises PVC resin base material of ethylene process loose resin and cooperative auxiliary agents. The film comprises the following components in parts by weight: 90 to 100 parts of PVC resin base material of ethylene process loose resin, 1.5 to 2.5 parts of UV anti-ultraviolet agent, 0.5 to 1.5 parts of water-free sodium metasilicate flameproof agent, and 0.5 to 1.8 parts of alkyl sulfonic acid, phosphoric acid or aminodithioformic acid antistatic agent. The antistatic agent is mixed with surfactant to prepare a solution and then an alkyl sulfonic acid, phosphoric acid or aminodithioformic acid solution layer is painted on the film surface. Through the technical scheme mentioned above, the PVC thermal contraction printing film has the advantages of wear resistance, static electricity resistance, flame resistance, and ultraviolet ray resistance, eliminates the disadvantages of static electricity and ultraviolet rays during the printing process, and improves the printing quality.
Description
Technical field
The present invention relates to print film, particularly relate to a kind of PVC heat shrinkable printing film.
Background technology
Print level PVC shrink film, as the term suggests be exactly for printing, can be processed into printed label.But, because PVC heat shrinkable printing film often can produce electrostatic in making processes, cause the making processes of print film to produce certain production difficulty.Meanwhile, PVC heat shrinkable printing film is after being processed into printed label, and the pattern on its label, because often leaking outside in outdoor, is easily subject to ultraviolet irradiation and variable color, causes Pattern damage or the wearing and tearing of printed label.
Summary of the invention
The technical problem that the present invention mainly solves is to provide a kind of PVC heat shrinkable printing film, there is wear-resisting, antistatic, the anti-ultraviolet advantage of fire retardant, the inconvenience preventing PVC heat-shrinkable film to bring due to electrostatic, ultraviolet when printing, improves the printing quality of PVC heat shrinkable printing film.
For solving the problems of the technologies described above, the technical scheme that the present invention adopts is: provide a kind of PVC heat shrinkable printing film, comprise ethylene process to loosen resin polyvinyl chloride resin base-material and compounding aid, the described ethylene process resin polyvinyl chloride resin base-material that loosens is 90 ~ 100 weight parts, the UV anti UV agent of 1.5 ~ 2.5 weight parts is also added with in described component, the zero water sodium metasilicate flame-proofing agent of 0.5 ~ 1.5 weight part, the alkylsulphonic acid of 0.5 ~ 1.8 weight part, phosphoric acid or dithiocarbamic acid static inhibitor, described static inhibitor is first modulated into solution with tensio-active agent, then alkylsulphonic acid is applied to film surface, phosphoric acid or dithiocarbamic acid solution layer.
In the present invention's preferred embodiments, described compounding aid comprises thermo-stabilizer 1.2 ~ 2.8 weight part, antiwear assistant 1.2 ~ 2.1 weight part, anion surfactant 2.5 ~ 3.5 weight part, anti-impact modifier 0.5 ~ 1.5 weight part, stearin 1.6 ~ 3.2 weight part, toughner 2.1 ~ 3.2 weight part.
In the present invention's preferred embodiments, described UV anti UV agent is UV-531, Octabenzone.
In the present invention's preferred embodiments, described thermo-stabilizer is calcium-zinc composite stabilizing agent, toughner is A-603 liquid toughner.
In the present invention's preferred embodiments, described print film antistatic surface agent solution is spraying.
In the present invention's preferred embodiments, described spraying antistatic solution concentration is 0.2% ~ 0.5wt%.
The invention has the beneficial effects as follows: a kind of PVC heat shrinkable printing film of the present invention, there is wear-resisting, antistatic, the anti-ultraviolet advantage of fire retardant, the inconvenience preventing PVC heat-shrinkable film to bring due to electrostatic, ultraviolet when printing, improves the printing quality of PVC heat shrinkable printing film.
Embodiment
Be clearly and completely described to the technical scheme in the embodiment of the present invention below, obviously, described embodiment is only a part of embodiment of the present invention, instead of whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art, not making other embodiments all obtained under creative work prerequisite, belong to the scope of protection of the invention.
The embodiment of the present invention comprises:
A kind of PVC heat shrinkable printing film, comprise ethylene process to loosen resin polyvinyl chloride resin base-material and compounding aid, the described ethylene process resin polyvinyl chloride resin base-material that loosens is 90 ~ 100 weight parts, the UV anti UV agent of 1.5 ~ 2.5 weight parts, the zero water sodium metasilicate flame-proofing agent of 0.5 ~ 1.5 weight part, the alkylsulphonic acid of 0.5 ~ 1.8 weight part, phosphoric acid or dithiocarbamic acid static inhibitor is also added with in described component, described static inhibitor is first modulated into solution with tensio-active agent, then applies alkylsulphonic acid, phosphoric acid or dithiocarbamic acid solution layer to film surface.
Further, described compounding aid comprises thermo-stabilizer 1.2 ~ 2.8 weight part, antiwear assistant 1.2 ~ 2.1 weight part, anion surfactant 2.5 ~ 3.5 weight part, anti-impact modifier 0.5 ~ 1.5 weight part, stearin 1.6 ~ 3.2 weight part, toughner 2.1 ~ 3.2 weight part.
Further, described UV anti UV agent is UV-531, Octabenzone.
Further, described thermo-stabilizer is calcium-zinc composite stabilizing agent, toughner is A-603 liquid toughner.
Further, described print film antistatic surface agent solution is spraying.
Further, described spraying antistatic solution concentration is 0.2% ~ 0.5wt%.
The invention has the beneficial effects as follows: a kind of PVC heat shrinkable printing film of the present invention, there is wear-resisting, antistatic, the anti-ultraviolet advantage of fire retardant, the inconvenience preventing PVC heat-shrinkable film to bring due to electrostatic, ultraviolet when printing, improves the printing quality of PVC heat shrinkable printing film.
The foregoing is only embodiments of the invention; not thereby the scope of the claims of the present invention is limited; every utilize description of the present invention to do equivalent structure or equivalent flow process conversion; or be directly or indirectly used in other relevant technical field, be all in like manner included in scope of patent protection of the present invention.
Claims (6)
1. a PVC heat shrinkable printing film, it is characterized in that, comprise ethylene process to loosen resin polyvinyl chloride resin base-material and compounding aid, the described ethylene process resin polyvinyl chloride resin base-material that loosens is 90 ~ 100 weight parts, the UV anti UV agent of 1.5 ~ 2.5 weight parts is also added with in described component, the zero water sodium metasilicate flame-proofing agent of 0.5 ~ 1.5 weight part, the alkylsulphonic acid of 0.5 ~ 1.8 weight part, phosphoric acid or dithiocarbamic acid static inhibitor, described static inhibitor is first modulated into solution with tensio-active agent, then alkylsulphonic acid is applied to film surface, phosphoric acid or dithiocarbamic acid solution layer.
2. PVC heat shrinkable printing film according to claim 1, it is characterized in that, described compounding aid comprises thermo-stabilizer 1.2 ~ 2.8 weight part, antiwear assistant 1.2 ~ 2.1 weight part, anion surfactant 2.5 ~ 3.5 weight part, anti-impact modifier 0.5 ~ 1.5 weight part, stearin 1.6 ~ 3.2 weight part, toughner 2.1 ~ 3.2 weight part.
3. PVC heat shrinkable printing film according to claim 1, is characterized in that, described UV anti UV agent is UV-531, Octabenzone.
4. PVC heat shrinkable printing film according to claim 2, is characterized in that, described thermo-stabilizer is calcium-zinc composite stabilizing agent, toughner is A-603 liquid toughner.
5. PVC heat shrinkable printing film according to claim 1, is characterized in that, described print film antistatic surface agent solution is spraying.
6. PVC heat shrinkable printing film according to claim 5, is characterized in that, described spraying antistatic solution concentration is 0.2% ~ 0.5wt%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510892463.8A CN105385061A (en) | 2015-12-08 | 2015-12-08 | PVC thermal contraction printing film |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510892463.8A CN105385061A (en) | 2015-12-08 | 2015-12-08 | PVC thermal contraction printing film |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105385061A true CN105385061A (en) | 2016-03-09 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510892463.8A Pending CN105385061A (en) | 2015-12-08 | 2015-12-08 | PVC thermal contraction printing film |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105385061A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108485030A (en) * | 2018-03-28 | 2018-09-04 | 浙江达因包装材料有限公司 | A kind of processing technology of the special shrink film of bowl face |
| CN109354795A (en) * | 2018-09-14 | 2019-02-19 | 安徽明诚塑业有限公司 | A kind of uvioresistant PVC heat shrink films and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102190837A (en) * | 2011-04-09 | 2011-09-21 | 宜兴市光辉包装材料有限公司 | Polyvinyl chloride (PVC ) heat shrink label film |
| CN102304256A (en) * | 2011-06-13 | 2012-01-04 | 宜兴市光辉包装材料有限公司 | PVC (Poly Vinyl Chloride) thermal contraction printing film |
| CN104927235A (en) * | 2015-06-08 | 2015-09-23 | 安徽省金正塑业有限公司 | PVC heat shrinkable film material and preparation method thereof |
-
2015
- 2015-12-08 CN CN201510892463.8A patent/CN105385061A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102190837A (en) * | 2011-04-09 | 2011-09-21 | 宜兴市光辉包装材料有限公司 | Polyvinyl chloride (PVC ) heat shrink label film |
| CN102304256A (en) * | 2011-06-13 | 2012-01-04 | 宜兴市光辉包装材料有限公司 | PVC (Poly Vinyl Chloride) thermal contraction printing film |
| CN104927235A (en) * | 2015-06-08 | 2015-09-23 | 安徽省金正塑业有限公司 | PVC heat shrinkable film material and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108485030A (en) * | 2018-03-28 | 2018-09-04 | 浙江达因包装材料有限公司 | A kind of processing technology of the special shrink film of bowl face |
| CN109354795A (en) * | 2018-09-14 | 2019-02-19 | 安徽明诚塑业有限公司 | A kind of uvioresistant PVC heat shrink films and preparation method thereof |
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| PB01 | Publication | ||
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| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160309 |