CN105353436B - A kind of eyeglass anti-blue light film - Google Patents

A kind of eyeglass anti-blue light film Download PDF

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Publication number
CN105353436B
CN105353436B CN201510932237.8A CN201510932237A CN105353436B CN 105353436 B CN105353436 B CN 105353436B CN 201510932237 A CN201510932237 A CN 201510932237A CN 105353436 B CN105353436 B CN 105353436B
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China
Prior art keywords
blue light
compound
blue
light film
ultra
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Expired - Fee Related
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CN201510932237.8A
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Chinese (zh)
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CN105353436A (en
Inventor
李先民
马亮
叶胜蓝
夏欢
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Nanchang Yidun Science & Technology Co., Ltd.
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Longnan County Productivity Promotion Center
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    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/20Filters
    • G02B5/22Absorbing filters
    • G02B5/223Absorbing filters containing organic substances, e.g. dyes, inks or pigments
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10Optical coatings produced by application to, or surface treatment of, optical elements
    • GPHYSICS
    • G02OPTICS
    • G02CSPECTACLES; SUNGLASSES OR GOGGLES INSOFAR AS THEY HAVE THE SAME FEATURES AS SPECTACLES; CONTACT LENSES
    • G02C7/00Optical parts
    • G02C7/10Filters, e.g. for facilitating adaptation of the eyes to the dark; Sunglasses
    • G02C7/104Filters, e.g. for facilitating adaptation of the eyes to the dark; Sunglasses having spectral characteristics for purposes other than sun-protection

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Health & Medical Sciences (AREA)
  • Ophthalmology & Optometry (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • General Health & Medical Sciences (AREA)
  • Eyeglasses (AREA)
  • Optical Filters (AREA)

Abstract

The present invention relates to anti-blue light technical field, a kind of eyeglass anti-blue light film being specifically disclosed, including two layers of transparent substrate and being arranged on anti-blue light glue-line between two layers of transparent substrate, the composition of raw materials of described anti-blue light glue-line includes according to mass fraction:100 parts of adhesive, 0.50 2.15 parts of blue-light absorbers, 10 20 parts of solvent;Described blue-light absorbers are compound A and compound B mixture;Shown in the chemical structural formula such as formula (I) of the compound A, shown in the chemical structural formula such as formula (II) of the compound B;Wherein compound A and compound B mol ratio are 13:2.Compound A and B has been selected in the present invention as composite blue light absorbent, big pi bond is contained in compound A and B, synergy can be played after two kinds of compounds mixing, there is more preferable blue light absorption performance.

Description

A kind of eyeglass anti-blue light film
Technical field
The invention belongs to anti-blue light technical field, and in particular to a kind of eyeglass anti-blue light film.
Background technology
It is well known that ultraviolet can injure the glasses of people, but many people do not know that the blue light in visible ray also can be to eye Mirror damages.Blue light be the wavelength of visible ray closest to ultraviolet, its wave-length coverage is between 400~500nm, in human eye In blueness in sense organ.With the fast development of society, the various electronics productions such as computer, mobile phone, TV are flooded with the life of people Product, people are also increasingly dependent on electronic product, and the substantial amounts of irregular shortwave blue light that the fluorescent screen of electronic product can be sent, It can be directed through the through retina of cornea, cause retina to produce free radical, free radical causes retinal pigment epithelium Decline, then allow photosensitive cell to lack nutrient so as to cause vision impairment, produce ARM, extruding is shunk crystalline lens, caused Myopia even results in macular disease.Long contact blue light can cause lesion to retina, it is possible that eyes are dry and astringent, eyesight Fuzzy, serious also results in the serious blinding illness in eye such as macular degeneration, glaucoma.
But not all blue light is all harmful, 400~455nm of wavelength blue light is harmful, can injure people Retina;And 465~495nm of wavelength blue light is beneficial to blue light, it is the indispensable part of visible ray, pupil can be helped Hole is shunk, and helps eyes normally to show the color of object.
Anti-blue light product in the market is also crossed while harmful blue light is absorbed to be reflected or has sponged beneficial to indigo plant Light, cause the display distortion of object color.Therefore, it is necessary to which developing one kind be able to can pass through beneficial to blue while harmful blue light is absorbed The product of light is to solve the above problems.
The content of the invention
The technical problems to be solved by the invention are to provide a kind of eyeglass anti-blue light film, and the anti-blue light film can absorb in difference Harmful blue light, and ensure the high transmittance beneficial to blue light, its preparation method is also fairly simple.
Technical scheme is as follows:
A kind of eyeglass anti-blue light film of the present invention, including two layers of transparent substrate and it is arranged on anti-blue light between two layers of transparent substrate Glue-line, the composition of raw materials of described anti-blue light glue-line include according to mass fraction:
100 parts of adhesive,
Blue-light absorbers 0.50-2.15 parts,
Solvent 10-20 parts;
Described blue-light absorbers are compound A and compound B mixture;The chemical structural formula of the compound A is such as Shown in formula (I), shown in the chemical structural formula such as formula (II) of the compound B;Wherein compound A and compound B mol ratio is 1-3:2;
Wherein R1、R2And R3It is respectively and independently selected from H, C1-C6Alkyl, C1-C6Alkoxy, phenyl;
Preferably, described compound A and compound B mol ratio is 1:2、2:2 or 3:2.
Preferably, the R in described compound A1、R2And R3Respectively H, methyl, isopropyl.
Preferably, the R in described compound A1、R2And R3Respectively methyl, methyl, isopropyl
Preferably, the R in described compound A1、R2And R3Respectively methyl, the tert-butyl group, isopropyl.
Preferably, described transparent substrate is polycarbonate, polyethylene terephtalate, polyamide One kind in PA, polystyrene, polyethylene, polymetylmethacrylate.
Preferably, described adhesive is acrylic acid adhesive, adhesive for polyurethane or epoxy resin adhesive.
Preferably, ultra-violet absorber is also contained in described anti-blue light glue-line, its dosage is 0.04-2.15 parts.
Preferably, described ultra-violet absorber is ultra-violet absorber UV-31, ultra-violet absorber UV-41, ultraviolet Absorbent UV-49, ultra-violet absorber UV-75, ultra-violet absorber UV-928, ultra-violet absorber UV-328, ultraviolet are inhaled Receive the one or more in agent UV-329.
Compound A preparation method bibliography Chem.Eur.J.2012,18,13188-13194 in the present invention.Chemical combination Thing B can react obtained in the basic conditions with direct acid blue with acrylic anhydride.
After the composition of raw materials ultrasound of above-mentioned anti-blue light glue-line, the tow sides of transparent substrate are uniformly coated on, that is, are obtained Anti-blue light glue-line.
Beneficial effect:
(1) compound A and B has been selected to contain big π in compound A and B as composite blue light absorbent in the present invention Key, synergy can be played after two kinds of compound mixing, there is more preferable blue light absorption performance.
(2) the anti-blue light film that the present invention obtains can stop more than 99% ultraviolet, and have excellent anti-blue light performance, Wavelength is gradually gradually increased to 85% in the transmitance of 400~455nm blue light from 5%, and 465~495nm wavelength is beneficial blue For the transmitance of light more than 85%, highest visible light transmissivity is up to 95%.
Embodiment
Embodiments of the invention are further illustrated below.
Embodiment 1
A kind of eyeglass anti-blue light film, including two layers of transparent substrate PMMA and it is arranged on anti-blue light glue between two layers of transparent substrate Layer, the composition of raw materials of described anti-blue light glue-line include according to mass fraction:
Described blue-light absorbers are compound A and compound B mixture;The chemical structural formula of the compound A is such as Shown in formula (I), shown in the chemical structural formula such as formula (II) of the compound B;Wherein compound A and compound B mol ratio is 1:2;R in compound A1、R2And R3Respectively H, methyl, isopropyl.
Embodiment 2
A kind of eyeglass anti-blue light film, including two layers of transparent substrate PA and it is arranged on anti-blue light glue between two layers of transparent substrate Layer, the composition of raw materials of described anti-blue light glue-line include according to mass fraction:
Described blue-light absorbers are compound A and compound B mixture;The chemical structural formula of the compound A is such as Shown in formula (I), shown in the chemical structural formula such as formula (II) of the compound B;Wherein compound A and compound B mol ratio is 1:1;R in compound A1、R2And R3Respectively methyl, methyl, isopropyl.
Embodiment 3
A kind of eyeglass anti-blue light film, including two layers of transparent substrate PET and it is arranged on anti-blue light glue between two layers of transparent substrate Layer, the composition of raw materials of described anti-blue light glue-line include according to mass fraction:
Described blue-light absorbers are compound A and compound B mixture;The chemical structural formula of the compound A is such as Shown in formula (I), shown in the chemical structural formula such as formula (II) of the compound B;Wherein compound A and compound B mol ratio is 3:2;R in compound A1、R2And R3Respectively methyl, the tert-butyl group, isopropyl.
Comparative example 1
A kind of eyeglass anti-blue light film, including two layers of transparent substrate PA and it is arranged on anti-blue light glue between two layers of transparent substrate Layer, the composition of raw materials of described anti-blue light glue-line include according to mass fraction:
Described blue-light absorbers are compound A, the R in compound A1、R2And R3Respectively methyl, methyl, isopropyl.
Comparative example 2
A kind of eyeglass anti-blue light film, including two layers of transparent substrate PA and it is arranged on anti-blue light glue between two layers of transparent substrate Layer, the composition of raw materials of described anti-blue light glue-line include according to mass fraction:
Described blue-light absorbers are compound B.
Comparative example 1 and 2 is respectively that the comparative example that compound A and B do blue-light absorbers is used alone.Embodiment 1-3, contrast Anti-blue light film obtained by example 1-2 is labeled as anti-blue light film 1-5 successively.
In visible blue, 400~455nm of wavelength blue light is harmful blue light, and 465~495nm of wavelength blue light is beneficial Blue light, now choose transmission of the tri- wavelength measurement anti-blue light films of 400nm, 430nm and 480nm to harmful blue light and beneficial to blue light Rate, as a result as shown in table 1.Visible anti-blue light film 1-5 is equal for the transmitance of 400nm harmful blue light as can be drawn from Table 1 It is little in below 3-5%, difference;And at the blue light of 430nm wavelength, 3 kinds of optical mirror slips obtained by 1-3 of the embodiment of the present invention Light transmission rate between 50-55%, and two kind optics of the compound A or B as the comparative example of blue-light absorbers are used alone Eyeglass, its light transmission rate are up to 75-78%;For the transmitance of the visible blue at 480nm wavelength, 5 kinds of anti-blue light films Transmitance it is substantially similar.
It can be seen that compound A and B are used in mixed way as blue-light absorbers, synergy can be produced, for wavelength 400~ 455nm harmful blue light has higher absorptivity, while does not interfere with the transmitance beneficial to blue light also.
Transmitances of the anti-blue light film 1-5 of table 1 in wavelength 400nm, 430nm and 480nm blue light
400nm 430nm 480nm
Anti-blue light film 1 4.5% 55% 88%
Anti-blue light film 2 4.2% 53% 87%
Anti-blue light film 3 3.7% 50% 85%
Anti-blue light film 4 4.0% 75% 87%
Anti-blue light film 5 4.1% 78% 87%
The anti-blue light film that the present invention obtains can stop more than 99% ultraviolet, and have excellent anti-blue light performance, ripple The transmitance grown in 400~455nm blue light is gradually gradually increased to 85% from 5%, and the beneficial blue light of 465~495nm wavelength Transmitance more than 85%, highest visible light transmissivity is up to 95%.
The specific embodiment of the present invention is described in detail above, but it is intended only as example, it is of the invention and unlimited It is formed on above description specific embodiment.To those skilled in the art, it is any to the equivalent modifications that carry out of the present invention and to replace In generation, is also all among scope of the invention.Therefore, the impartial conversion made without departing from the spirit and scope of the invention and repair Change, all cover within the scope of the present invention.

Claims (9)

1. a kind of eyeglass anti-blue light film, including two layers of transparent substrate and it is arranged on anti-blue light glue-line between two layers of transparent substrate, institute The composition of raw materials for the anti-blue light glue-line stated includes according to mass fraction:
100 parts of adhesive,
Blue-light absorbers 0.50-2.15 parts,
Solvent 10-20 parts;
Described blue-light absorbers are compound A and compound B mixture;The chemical structural formula such as formula (I) of the compound A It is shown, shown in the chemical structural formula such as formula (II) of the compound B;Wherein compound A and compound B mol ratio are 1-3:2;
Wherein R1、R2And R3It is respectively and independently selected from H, C1-C6Alkyl;
2. eyeglass anti-blue light film according to claim 1, it is characterised in that described compound A and compound B mole Than for 1:2、2:2 or 3:2.
3. eyeglass anti-blue light film according to claim 1, it is characterised in that the R in described compound A1、R2And R3Point Wei not H, methyl, isopropyl.
4. eyeglass anti-blue light film according to claim 1, it is characterised in that the R in described compound A1、R2And R3Point Wei not methyl, methyl, isopropyl.
5. eyeglass anti-blue light film according to claim 1, it is characterised in that the R in described compound A1、R2And R3Point Wei not methyl, the tert-butyl group, isopropyl.
6. eyeglass anti-blue light film according to claim 1, it is characterised in that described transparent substrate be polycarbonate, In polyethylene terephtalate, polyamide PA, polystyrene, polyethylene, polymetylmethacrylate It is a kind of.
7. eyeglass anti-blue light film according to claim 1, it is characterised in that described adhesive be acrylic acid adhesive, Adhesive for polyurethane or epoxy resin adhesive.
8. eyeglass anti-blue light film according to claim 1, it is characterised in that also containing ultraviolet in described anti-blue light glue-line Light absorbers, its dosage are 0.04-2.15 parts.
9. eyeglass anti-blue light film according to claim 8, it is characterised in that described ultra-violet absorber is inhaled for ultraviolet Receive agent UV-31, ultra-violet absorber UV-41, ultra-violet absorber UV-49, ultra-violet absorber UV-75, ultra-violet absorber One or more in UV-928, ultra-violet absorber UV-328, ultra-violet absorber UV-329.
CN201510932237.8A 2015-12-15 2015-12-15 A kind of eyeglass anti-blue light film Expired - Fee Related CN105353436B (en)

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CN112539922B (en) * 2020-12-08 2023-12-05 Oppo广东移动通信有限公司 Head-mounted display device, blue light testing system and blue light testing method

Citations (2)

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CN104449422A (en) * 2014-12-26 2015-03-25 南京汇鑫光电材料有限公司 Anti-blue-light ultraviolet curable acrylate optical adhesive film and preparation method as well as application thereof
CN104557959A (en) * 2015-01-24 2015-04-29 福州大学 Benzoperylene imide derivatives, and preparation method and application thereof

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DE19848555A1 (en) * 1998-10-21 2000-04-27 Heinz Langhals New perylene-3,4,9,10-tetracarboxylic acid bis-imide derivatives and analogs, used as dyes, especially fluorescent dyes, e.g. for bulk dyeing plastics, vat dyeing natural fibers or staining DNA

Patent Citations (2)

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Publication number Priority date Publication date Assignee Title
CN104449422A (en) * 2014-12-26 2015-03-25 南京汇鑫光电材料有限公司 Anti-blue-light ultraviolet curable acrylate optical adhesive film and preparation method as well as application thereof
CN104557959A (en) * 2015-01-24 2015-04-29 福州大学 Benzoperylene imide derivatives, and preparation method and application thereof

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
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Perylene derivatives as photoinitiators in blue light sensitive cationic or radical curable films and panchromatic chiol-ene polymerizable films;Pu Xiao等;《European Polymer Journal》;20140130;第53卷;第215-222页 *

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Inventor after: Li Xianmin

Inventor after: Ma Liang

Inventor after: Ye Shenglan

Inventor after: Xia Huan

Inventor before: Fan Rongsheng

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Address after: 341700 Jiangxi province Ganzhou city dragon road Longnan County e-commerce Industrial Park Room 8207

Applicant after: Longnan County Productivity Promotion Center

Address before: 330000 Jiangxi Province, Nanchang Honggutan Regency Road No. 388 Seattle Huilong Ming International Club 3 building 917 room (ninth floor)

Applicant before: Nanchang Yidun Science & Technology Co., Ltd.

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Address after: 330000 Xihu District, Nanchang, Jiangxi, No. 1199, No. 5 Jiangnan Road, Wanjiang 1199, along the Jiangnan Avenue.

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Address before: 341700 room 8207, Longnan County, Longnan County, Ganzhou, Jiangxi.

Patentee before: Longnan County Productivity Promotion Center

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