CN105348845A - Alkali-free short-cut precursor fibers for thermoplastic plastics - Google Patents

Alkali-free short-cut precursor fibers for thermoplastic plastics Download PDF

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Publication number
CN105348845A
CN105348845A CN201510941742.9A CN201510941742A CN105348845A CN 105348845 A CN105348845 A CN 105348845A CN 201510941742 A CN201510941742 A CN 201510941742A CN 105348845 A CN105348845 A CN 105348845A
Authority
CN
China
Prior art keywords
alkali
caking agent
agent
precursor fibers
lubricant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510941742.9A
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Chinese (zh)
Inventor
吴祖明
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Changshu Dongyu Insulated Compound Materials Co Ltd
Original Assignee
Changshu Dongyu Insulated Compound Materials Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Changshu Dongyu Insulated Compound Materials Co Ltd filed Critical Changshu Dongyu Insulated Compound Materials Co Ltd
Priority to CN201510941742.9A priority Critical patent/CN105348845A/en
Publication of CN105348845A publication Critical patent/CN105348845A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00Use of pretreated ingredients
    • C08K9/08Ingredients agglomerated by treatment with a binding agent
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/02Fibres or whiskers
    • C08K7/04Fibres or whiskers inorganic
    • C08K7/14Glass
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00Use of pretreated ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00Use of pretreated ingredients
    • C08K9/04Ingredients treated with organic substances
    • C08K9/06Ingredients treated with organic substances with silicon-containing compounds

Abstract

The invention discloses alkali-free short-cut precursor fibers for thermoplastic plastics. The alkali-free short-cut precursor fibers are prepared by the steps of performing surface treatment on glass fiber bundles, formed by glass monofilaments subjected to sleeve spinning, by using an impregnating compound, and then cutting off the glass fiber bundles, wherein the impregnating compound contains a caking agent, a lubricant, an antistatic agent and a coupling agent in a mass percentage ratio of (90-110):(5-15):(10-30):(5-40), and preferably in a mass percentage ratio of 100:10:20:5. Therefore, the alkali-free short-cut precursor fibers for the thermoplastic plastics, disclosed by the invention, take water-base epoxy resin as the caking agent, thereby having good protection and bundling properties, and being capable of improving the strength of a product.

Description

A kind of thermoplastics alkali-free chopped strand
Technical field
The present invention relates to a kind of chopped strand, particularly relate to a kind of thermoplastics alkali-free chopped strand.
Background technology
The characteristic of the excellences such as alkali free glass fibre has heatproof, corrosion-resistant, tensile strength is high, specific elongation rate is little, electrical insulating property is good, industrially be widely used, but the temperature tolerance of alkali free glass fibre has its limitation, more than 400 DEG C, loss of strength is very large, limits the application of alkali free glass fibre fabric in high temperature, fire prevention, the field such as fire-retardant.
Summary of the invention
The technical problem that the present invention mainly solves is to provide a kind of thermoplastics alkali-free chopped strand.
For solving the problems of the technologies described above, the technical scheme that the present invention adopts is: a kind of thermoplastics alkali-free chopped strand, comprising: use treating compound to carry out surface treatment to the glass fiber bundle that the glass monofilament spinned through sleeve is formed, cut off afterwards;
Containing caking agent, lubricant, static inhibitor and coupling agent in described treating compound, in described treating compound, the quality of caking agent, lubricant, static inhibitor and coupling agent divides per-cent to be 90 ~ 110:5 ~ 15:10 ~ 30:5 ~ 40;
In preferred described treating compound, the quality of caking agent, lubricant, static inhibitor and coupling agent divides per-cent to be 100:10:20:5.
In a preferred embodiment of the present invention, described caking agent is water-based epoxy resin.
In a preferred embodiment of the present invention, described coupling agent is silane based coupling agents.
The invention has the beneficial effects as follows: a kind of thermoplastics alkali-free of the present invention chopped strand, this alkali-free chopped strand uses water-based epoxy resin as caking agent, makes this alkali-free chopped strand have good protectiveness and convergency, can improve the intensity of goods.
Embodiment
Below preferred embodiment of the present invention is described in detail, can be easier to make advantages and features of the invention be readily appreciated by one skilled in the art, thus more explicit defining is made to protection scope of the present invention.
The embodiment of the present invention comprises: a kind of thermoplastics alkali-free chopped strand, comprising: use treating compound to carry out surface treatment to the glass fiber bundle that the glass monofilament spinned through sleeve is formed, cut off afterwards.
Containing caking agent, lubricant, static inhibitor and coupling agent in described treating compound, in described treating compound, the quality of caking agent, lubricant, static inhibitor and coupling agent divides per-cent to be 90 ~ 110:5 ~ 15:10 ~ 30:5 ~ 40, and in treating compound described in the present embodiment, the quality of caking agent, lubricant, static inhibitor and coupling agent divides per-cent to be 100:10:20:5.
Described caking agent is water-based epoxy resin; water-based epoxy resin has good protectiveness and boundling to alkali-free chopped strand, can glass fibre, coupling agent and be enhanced material tight combine, consistency is good; there is quick impregnability, contribute to the intensity improving goods.
Described coupling agent is silane based coupling agents, silane based coupling agents can improve the bond properties of glass fibre and resin, greatly improve the intensity of glass fibre reinforced composion, electrically, the performance such as water resistant, anti-weather, even if when hygrometric state, it is to the raising of matrix material machinery performance, and effect is also very remarkable.
Compared with prior art, a kind of thermoplastics alkali-free chopped strand of the present invention, this alkali-free chopped strand uses water-based epoxy resin as caking agent, makes this alkali-free chopped strand have good protectiveness and convergency, can improve the intensity of goods.
The foregoing is only embodiments of the invention; not thereby the scope of the claims of the present invention is limited; every utilize description of the present invention to do equivalent structure or equivalent flow process conversion; or be directly or indirectly used in other relevant technical fields, be all in like manner included in scope of patent protection of the present invention.

Claims (3)

1. a thermoplastics alkali-free chopped strand, is characterized in that, comprising: use treating compound to carry out surface treatment to the glass fiber bundle that the glass monofilament spinned through sleeve is formed, cut off afterwards;
Containing caking agent, lubricant, static inhibitor and coupling agent in described treating compound, in described treating compound, the quality of caking agent, lubricant, static inhibitor and coupling agent divides per-cent to be 90 ~ 110:5 ~ 15:10 ~ 30:5 ~ 40;
In preferred described treating compound, the quality of caking agent, lubricant, static inhibitor and coupling agent divides per-cent to be 100:10:20:5.
2. a kind of thermoplastics alkali-free chopped strand according to claim 1, is characterized in that: described caking agent is water-based epoxy resin.
3. a kind of thermoplastics alkali-free chopped strand according to claim 1, is characterized in that: described coupling agent is silane based coupling agents.
CN201510941742.9A 2015-12-16 2015-12-16 Alkali-free short-cut precursor fibers for thermoplastic plastics Pending CN105348845A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510941742.9A CN105348845A (en) 2015-12-16 2015-12-16 Alkali-free short-cut precursor fibers for thermoplastic plastics

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510941742.9A CN105348845A (en) 2015-12-16 2015-12-16 Alkali-free short-cut precursor fibers for thermoplastic plastics

Publications (1)

Publication Number Publication Date
CN105348845A true CN105348845A (en) 2016-02-24

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201510941742.9A Pending CN105348845A (en) 2015-12-16 2015-12-16 Alkali-free short-cut precursor fibers for thermoplastic plastics

Country Status (1)

Country Link
CN (1) CN105348845A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114164558A (en) * 2021-11-29 2022-03-11 通城县同力玻纤有限公司 Alkali-free glass fiber non-woven fabric and manufacturing method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07277778A (en) * 1994-04-04 1995-10-24 Nippon Electric Glass Co Ltd Glass fiber
CN101343396A (en) * 2008-08-18 2009-01-14 巨石集团有限公司 Glass fiber reinforced acetal resin composite material

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07277778A (en) * 1994-04-04 1995-10-24 Nippon Electric Glass Co Ltd Glass fiber
CN101343396A (en) * 2008-08-18 2009-01-14 巨石集团有限公司 Glass fiber reinforced acetal resin composite material

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114164558A (en) * 2021-11-29 2022-03-11 通城县同力玻纤有限公司 Alkali-free glass fiber non-woven fabric and manufacturing method thereof

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Application publication date: 20160224