CN105348651A - Environment-friendly plastic with high mechanical properties - Google Patents
Environment-friendly plastic with high mechanical properties Download PDFInfo
- Publication number
- CN105348651A CN105348651A CN201510879294.4A CN201510879294A CN105348651A CN 105348651 A CN105348651 A CN 105348651A CN 201510879294 A CN201510879294 A CN 201510879294A CN 105348651 A CN105348651 A CN 105348651A
- Authority
- CN
- China
- Prior art keywords
- parts
- boron nitride
- environment
- polypropylene
- high mechanical
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/14—Copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses environment-friendly plastic with high mechanical properties. The plastic comprises the following raw materials in parts by weight: 100 parts of polypropylene, 3-15 parts of maleic anhydride grafted polypropylene, 10-20 parts of an ethylene-propylene-diene monomer, 3-10 parts of polyvinyl butyral, 2-10 parts of a styrene-butadiene-styrene segmented copolymer, 5-15 parts of polybutyleneterephthalate, 3-15 parts of epoxy resin, 10-30 parts of boron nitride, 5-15 parts of a carbon nano-fiber, 2-12 parts of nanometer titanium dioxide, 3-10 parts of nano calcium carbonate, 3-10 parts of silicon carbide, 2-14 parts of hexagonal boron nitride, 2-5 parts of cerium hydroxide, 2-5 parts of magnesium stearate, 1-2 parts of vinyltrimethoxysilane, 1-3 parts of one or more lubricants and 1-2.5 parts of an anti-oxidant. The plastic provided by the invention is high in strength, impact resistance and corrosion resistance, excellent in environment-friendly property, and long in service life.
Description
Technical field
The present invention relates to plastics arts, particularly relate to a kind of Environment-friendlyplastic plastic with high mechanical property.
Background technology
Along with the development of science and technology, resource, energy day are becoming tight, and environmental problem will be more outstanding.Although the performance of current plastic material obtains develop rapidly, still Shortcomings in some aspects, limits the Application Areas of plastics.Polypropylene is the polymkeric substance of nontoxic, odorless, tasteless oyster white height crystallization, its good moldability, be widely used in the various field such as daily life, suitability for industrialized production at present, but polyacrylic fragility is comparatively large, its intensity of existing polypropylene material and shock resistance are not very desirable.
Summary of the invention
The object of the invention is to solve the shortcoming existed in prior art, and a kind of Environment-friendlyplastic plastic with high mechanical property proposed, its intensity is high, shock resistance and good corrosion resistance, and environmental-protecting performance is excellent, long service life.
To achieve these goals, present invention employs following technical scheme:
A kind of Environment-friendlyplastic plastic with high mechanical property, its raw material comprises by weight: polypropylene 100 parts, maleic anhydride inoculated polypropylene 3-15 part, terpolymer EP rubber 10-20 part, polyvinyl butyral acetal 3-10 part, styrene-butadiene-styrene block copolymer 2-10 part, polybutylene terephthalate 5-15 part, epoxy resin 3-15 part, boron nitride 10-30 part, carbon nano fiber 5-15 part, nano titanium oxide 2-12 part, nano-calcium carbonate 3-10 part, silicon carbide 3-10 part, hexagonal boron nitride 2-14 part, cerous hydroxide 2-5 part, Magnesium Stearate 2-5 part, vinyltrimethoxy silane 1-2 part, lubricant 1-3 part, oxidation inhibitor 1-2.5 part.
Preferably, in its raw material, the weight ratio of boron nitride, carbon nano fiber, nano titanium oxide, nano-calcium carbonate, silicon carbide, hexagonal boron nitride, cerous hydroxide is 15-22:8-13:6-10:5-9:8-10:6-12:3-4.
Preferably, its raw material comprises by weight: polypropylene 100 parts, maleic anhydride inoculated polypropylene 9-12 part, terpolymer EP rubber 13-17 part, polyvinyl butyral acetal 6-8 part, styrene-butadiene-styrene block copolymer 5-7 part, polybutylene terephthalate 9-12 part, epoxy resin 8-12 part, boron nitride 18-21 part, carbon nano fiber 10-12 part, nano titanium oxide 8-9 part, nano-calcium carbonate 7-8 part, silicon carbide 8-9 part, hexagonal boron nitride 7-9 part, cerous hydroxide 3.2-3.8 part, Magnesium Stearate 3.2-4 part, vinyltrimethoxy silane 1.3-1.7 part, lubricant 2-2.6 part, oxidation inhibitor 1.5-2.1 part.
Preferably, its raw material comprises by weight: polypropylene 100 parts, maleic anhydride inoculated polypropylene 11 parts, terpolymer EP rubber 16 parts, polyvinyl butyral acetal 7 parts, styrene-butadiene-styrene block copolymer 6.5 parts, polybutylene terephthalate 10 parts, epoxy resin 9 parts, boron nitride 20 parts, carbon nano fiber 11 parts, nano titanium oxide 8.7 parts, nano-calcium carbonate 7.7 parts, 8.5 parts, silicon carbide, hexagonal boron nitride 8 parts, cerous hydroxide 3.5 parts, Magnesium Stearate 3.6 parts, vinyltrimethoxy silane 1.5 parts, lubricant 2.2 parts, 2 parts, oxidation inhibitor.
Preferably, described polypropylene is that homo-polypropylene, Atactic Polypropelene are by weight the mixture for 2-5:3-6.
Preferably, described epoxy resin is the mixture of a kind of in bisphenol A type epoxy resin, novolac epoxy or two kinds.
Preferably, the particle diameter of described nano titanium oxide is 10-30nm; The particle diameter of described nano-calcium carbonate is 20-40nm.
Preferably, described lubricant is the mixture of a kind of in calcium stearate, ethylenebisstearamide or two kinds.
Environmentally-friendly plastic of the present invention, take polypropylene as major ingredient, and with the addition of terpolymer EP rubber, polyvinyl butyral acetal, styrene-butadiene-styrene block copolymer, polybutylene terephthalate and epoxy resin to its modification, under the effect of maleic anhydride inoculated polypropylene and vinyltrimethoxy silane, the consistency of system is good, the environmentally-friendly plastic environmental-protecting performance obtained and processing characteristics are excellent, and thermotolerance and shock strength high, excellent anti-corrosion performance; Boron nitride, carbon nano fiber, nano titanium oxide, nano-calcium carbonate, silicon carbide, hexagonal boron nitride, cerous hydroxide are uniformly dispersed in system, improve the crystal property of plastics, give the mechanical property of plastics excellence.
Embodiment
In order to make object of the present invention, technical scheme and advantage clearly understand, below in conjunction with specific embodiment, the present invention is further elaborated.Should be appreciated that specific embodiment described herein only in order to explain the present invention, be not intended to limit the present invention.
Embodiment 1
A kind of Environment-friendlyplastic plastic with high mechanical property, its raw material comprises by weight: polypropylene 100 parts, maleic anhydride inoculated polypropylene 3 parts, terpolymer EP rubber 20 parts, polyvinyl butyral acetal 3 parts, styrene-butadiene-styrene block copolymer 10 parts, polybutylene terephthalate 5 parts, epoxy resin 15 parts, boron nitride 10 parts, carbon nano fiber 15 parts, nano titanium oxide 2 parts, nano-calcium carbonate 10 parts, 3 parts, silicon carbide, hexagonal boron nitride 14 parts, cerous hydroxide 2 parts, Magnesium Stearate 5 parts, vinyltrimethoxy silane 1 part, lubricant 3 parts, 1 part, oxidation inhibitor.
Embodiment 2
A kind of Environment-friendlyplastic plastic with high mechanical property, its raw material comprises by weight: polypropylene 100 parts, maleic anhydride inoculated polypropylene 15 parts, terpolymer EP rubber 10 parts, polyvinyl butyral acetal 10 parts, styrene-butadiene-styrene block copolymer 2 parts, polybutylene terephthalate 15 parts, epoxy resin 3 parts, boron nitride 30 parts, carbon nano fiber 5 parts, nano titanium oxide 12 parts, nano-calcium carbonate 3 parts, 10 parts, silicon carbide, hexagonal boron nitride 2 parts, cerous hydroxide 5 parts, Magnesium Stearate 2 parts, vinyltrimethoxy silane 2 parts, lubricant 1 part, 2.5 parts, oxidation inhibitor.
Embodiment 3
A kind of Environment-friendlyplastic plastic with high mechanical property, its raw material comprises by weight: polypropylene 100 parts, maleic anhydride inoculated polypropylene 9 parts, terpolymer EP rubber 17 parts, polyvinyl butyral acetal 6 parts, styrene-butadiene-styrene block copolymer 7 parts, polybutylene terephthalate 9 parts, epoxy resin 12 parts, boron nitride 18 parts, carbon nano fiber 12 parts, nano titanium oxide 8 parts, nano-calcium carbonate 7 parts, 8 parts, silicon carbide, hexagonal boron nitride 9 parts, cerous hydroxide 3.2 parts, Magnesium Stearate 4 parts, vinyltrimethoxy silane 1.3 parts, lubricant 2.6 parts, 1.5 parts, oxidation inhibitor,
Wherein, described polypropylene is that homo-polypropylene, Atactic Polypropelene are by weight the mixture for 2:3;
Described lubricant is that calcium stearate, ethylenebisstearamide are by weight the mixture for 3:2.
Embodiment 4
A kind of Environment-friendlyplastic plastic with high mechanical property, its raw material comprises by weight: polypropylene 100 parts, maleic anhydride inoculated polypropylene 12 parts, terpolymer EP rubber 13 parts, polyvinyl butyral acetal 8 parts, styrene-butadiene-styrene block copolymer 5 parts, polybutylene terephthalate 12 parts, epoxy resin 8 parts, boron nitride 21 parts, carbon nano fiber 10 parts, nano titanium oxide 9 parts, nano-calcium carbonate 8 parts, 9 parts, silicon carbide, hexagonal boron nitride 7 parts, cerous hydroxide 3.8 parts, Magnesium Stearate 3.2 parts, vinyltrimethoxy silane 1.7 parts, lubricant 2 parts, 2.1 parts, oxidation inhibitor,
Wherein, described polypropylene is that homo-polypropylene, Atactic Polypropelene are by weight the mixture for 5:6;
Described epoxy resin is that bisphenol A type epoxy resin, novolac epoxy are by weight the mixture for 1:3;
Described lubricant is ethylenebisstearamide.
Embodiment 5
A kind of Environment-friendlyplastic plastic with high mechanical property, its raw material comprises by weight: polypropylene 100 parts, maleic anhydride inoculated polypropylene 11 parts, terpolymer EP rubber 16 parts, polyvinyl butyral acetal 7 parts, styrene-butadiene-styrene block copolymer 6.5 parts, polybutylene terephthalate 10 parts, epoxy resin 9 parts, boron nitride 20 parts, carbon nano fiber 11 parts, nano titanium oxide 8.7 parts, nano-calcium carbonate 7.7 parts, 8.5 parts, silicon carbide, hexagonal boron nitride 8 parts, cerous hydroxide 3.5 parts, Magnesium Stearate 3.6 parts, vinyltrimethoxy silane 1.5 parts, lubricant 2.2 parts, 2 parts, oxidation inhibitor,
Wherein, described polypropylene is that homo-polypropylene, Atactic Polypropelene are by weight the mixture for 4:5;
Described epoxy resin is bisphenol A type epoxy resin;
The particle diameter of described nano titanium oxide is 10-30nm; The particle diameter of described nano-calcium carbonate is 20-40nm;
Described lubricant is calcium stearate.
The above; be only the present invention's preferably embodiment; but protection scope of the present invention is not limited thereto; anyly be familiar with those skilled in the art in the technical scope that the present invention discloses; be equal to according to technical scheme of the present invention and inventive concept thereof and replace or change, all should be encompassed within protection scope of the present invention.
Claims (8)
1. an Environment-friendlyplastic plastic with high mechanical property, it is characterized in that, its raw material comprises by weight: polypropylene 100 parts, maleic anhydride inoculated polypropylene 3-15 part, terpolymer EP rubber 10-20 part, polyvinyl butyral acetal 3-10 part, styrene-butadiene-styrene block copolymer 2-10 part, polybutylene terephthalate 5-15 part, epoxy resin 3-15 part, boron nitride 10-30 part, carbon nano fiber 5-15 part, nano titanium oxide 2-12 part, nano-calcium carbonate 3-10 part, silicon carbide 3-10 part, hexagonal boron nitride 2-14 part, cerous hydroxide 2-5 part, Magnesium Stearate 2-5 part, vinyltrimethoxy silane 1-2 part, lubricant 1-3 part, oxidation inhibitor 1-2.5 part.
2. Environment-friendlyplastic plastic with high mechanical property according to claim 1, it is characterized in that, in its raw material, the weight ratio of boron nitride, carbon nano fiber, nano titanium oxide, nano-calcium carbonate, silicon carbide, hexagonal boron nitride, cerous hydroxide is 15-22:8-13:6-10:5-9:8-10:6-12:3-4.
3. Environment-friendlyplastic plastic with high mechanical property according to claim 1, it is characterized in that, its raw material comprises by weight: polypropylene 100 parts, maleic anhydride inoculated polypropylene 9-12 part, terpolymer EP rubber 13-17 part, polyvinyl butyral acetal 6-8 part, styrene-butadiene-styrene block copolymer 5-7 part, polybutylene terephthalate 9-12 part, epoxy resin 8-12 part, boron nitride 18-21 part, carbon nano fiber 10-12 part, nano titanium oxide 8-9 part, nano-calcium carbonate 7-8 part, silicon carbide 8-9 part, hexagonal boron nitride 7-9 part, cerous hydroxide 3.2-3.8 part, Magnesium Stearate 3.2-4 part, vinyltrimethoxy silane 1.3-1.7 part, lubricant 2-2.6 part, oxidation inhibitor 1.5-2.1 part.
4. Environment-friendlyplastic plastic with high mechanical property according to claim 1, it is characterized in that, its raw material comprises by weight: polypropylene 100 parts, maleic anhydride inoculated polypropylene 11 parts, terpolymer EP rubber 16 parts, polyvinyl butyral acetal 7 parts, styrene-butadiene-styrene block copolymer 6.5 parts, polybutylene terephthalate 10 parts, epoxy resin 9 parts, boron nitride 20 parts, carbon nano fiber 11 parts, nano titanium oxide 8.7 parts, nano-calcium carbonate 7.7 parts, 8.5 parts, silicon carbide, hexagonal boron nitride 8 parts, cerous hydroxide 3.5 parts, Magnesium Stearate 3.6 parts, vinyltrimethoxy silane 1.5 parts, lubricant 2.2 parts, 2 parts, oxidation inhibitor.
5. Environment-friendlyplastic plastic with high mechanical property according to claim 1, is characterized in that, described polypropylene is that homo-polypropylene, Atactic Polypropelene are by weight the mixture for 2-5:3-6.
6. Environment-friendlyplastic plastic with high mechanical property according to claim 1, is characterized in that, described epoxy resin is the mixture of a kind of in bisphenol A type epoxy resin, novolac epoxy or two kinds.
7. Environment-friendlyplastic plastic with high mechanical property according to claim 1, it is characterized in that, the particle diameter of described nano titanium oxide is 10-30nm; The particle diameter of described nano-calcium carbonate is 20-40nm.
8. Environment-friendlyplastic plastic with high mechanical property according to any one of claim 1-7, is characterized in that, described lubricant is the mixture of a kind of in calcium stearate, ethylenebisstearamide or two kinds.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510879294.4A CN105348651A (en) | 2015-12-05 | 2015-12-05 | Environment-friendly plastic with high mechanical properties |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510879294.4A CN105348651A (en) | 2015-12-05 | 2015-12-05 | Environment-friendly plastic with high mechanical properties |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105348651A true CN105348651A (en) | 2016-02-24 |
Family
ID=55324721
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510879294.4A Pending CN105348651A (en) | 2015-12-05 | 2015-12-05 | Environment-friendly plastic with high mechanical properties |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105348651A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105741912A (en) * | 2016-03-31 | 2016-07-06 | 安徽富悦达电子有限公司 | Flame-retardant and anti-impact cable |
| CN107236255A (en) * | 2017-06-27 | 2017-10-10 | 苏州亚得宝消防设备有限公司 | Environment-friendlyplastic plastic with high mechanical property |
| CN110615962A (en) * | 2019-11-08 | 2019-12-27 | 徐州运杰机械设备制造有限公司 | High-performance polymer material for mechanical equipment |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103113662A (en) * | 2011-11-17 | 2013-05-22 | 上海金发科技发展有限公司 | Low-odor ultrahigh-toughness polypropylene compound and preparation method thereof |
| CN103571036A (en) * | 2013-11-13 | 2014-02-12 | 上海交通大学 | Recovered carbon fiber reinforced polypropylene composite material and preparation method thereof |
| CN103788489A (en) * | 2014-01-28 | 2014-05-14 | 江苏圣通环境工程有限公司 | Functional composite filler modified polypropylene and preparation method thereof |
| CN103951874A (en) * | 2014-03-31 | 2014-07-30 | 芜湖同达新材料科技有限公司 | Super-strength and super-toughness polypropylene modified resin and its preparation technology |
-
2015
- 2015-12-05 CN CN201510879294.4A patent/CN105348651A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103113662A (en) * | 2011-11-17 | 2013-05-22 | 上海金发科技发展有限公司 | Low-odor ultrahigh-toughness polypropylene compound and preparation method thereof |
| CN103571036A (en) * | 2013-11-13 | 2014-02-12 | 上海交通大学 | Recovered carbon fiber reinforced polypropylene composite material and preparation method thereof |
| CN103788489A (en) * | 2014-01-28 | 2014-05-14 | 江苏圣通环境工程有限公司 | Functional composite filler modified polypropylene and preparation method thereof |
| CN103951874A (en) * | 2014-03-31 | 2014-07-30 | 芜湖同达新材料科技有限公司 | Super-strength and super-toughness polypropylene modified resin and its preparation technology |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105741912A (en) * | 2016-03-31 | 2016-07-06 | 安徽富悦达电子有限公司 | Flame-retardant and anti-impact cable |
| CN105741912B (en) * | 2016-03-31 | 2018-08-31 | 安徽富悦达电子有限公司 | A kind of flame-proof impact resistant cable |
| CN107236255A (en) * | 2017-06-27 | 2017-10-10 | 苏州亚得宝消防设备有限公司 | Environment-friendlyplastic plastic with high mechanical property |
| CN110615962A (en) * | 2019-11-08 | 2019-12-27 | 徐州运杰机械设备制造有限公司 | High-performance polymer material for mechanical equipment |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105348651A (en) | Environment-friendly plastic with high mechanical properties | |
| CN102731916B (en) | Reclaimed EPDM rubber mixed rubber sealing ring | |
| TW200728388A (en) | Highly processible compounds of high MW conventional block copolymers and controlled distribution block copolymers | |
| MX2016013504A (en) | High performance water-based adhesion compositions and applications. | |
| TW200708557A (en) | Nanocomposite and thermoplastic nanocomposite resin composition using the same | |
| CN102504391A (en) | Novel crossing pipeline outer layer material and preparation method | |
| CN104112785A (en) | Film used for synergistic type solar cell back plate and preparation method thereof | |
| CN108329573A (en) | A kind of Environment-friendlyplastic plastic with high mechanical property | |
| CN106336574A (en) | BOPP film | |
| CN104212052A (en) | Environment-friendly plastic | |
| CN104650571A (en) | Modified polycarbonate plastic for packaging | |
| CN104292700A (en) | High-strength high-toughness modified polyvinyl chloride insulating cable material | |
| Baek et al. | Effect of grain size and replacement ratio on the plastic properties of precipitated calcium carbonate using limestone as raw material | |
| CN103571049A (en) | Impact-resistant PP (Polypropylene) composite material | |
| CN104893124A (en) | O-shaped sealing ring | |
| CN105330973A (en) | Environment-friendly plastic emitting nerve-soothing smell | |
| CN106084487A (en) | A kind of weather resistance environmental protection type automobile bumper material | |
| CN105153623A (en) | High-strength toughened filling modified polypropylene resin | |
| CN104513475A (en) | High-performance nanometer PA6 nano-composite material | |
| CN107189210A (en) | A kind of polymer composite | |
| CN107189219A (en) | Shopping bag | |
| CN106633494A (en) | Hard self-cleaning type plastic plate and preparation method thereof | |
| JP2002030196A5 (en) | ||
| CN102634197B (en) | Modified nylon alloy material | |
| CN108219292A (en) | A kind of packaging material expanded material |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20160224 |