CN105347843A - Water-proofing agent for reinforced concrete structure building - Google Patents
Water-proofing agent for reinforced concrete structure building Download PDFInfo
- Publication number
- CN105347843A CN105347843A CN201510864310.2A CN201510864310A CN105347843A CN 105347843 A CN105347843 A CN 105347843A CN 201510864310 A CN201510864310 A CN 201510864310A CN 105347843 A CN105347843 A CN 105347843A
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- Prior art keywords
- water
- parts
- ketone
- reinforced concrete
- concrete structure
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Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
- C04B41/466—Halogenated compounds, e.g. perfluor-compounds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/60—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only artificial stone
- C04B41/61—Coating or impregnation
- C04B41/62—Coating or impregnation with organic materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/27—Water resistance, i.e. waterproof or water-repellent materials
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Aftertreatments Of Artificial And Natural Stones (AREA)
Abstract
The invention relates to water-proof paint, in particular to a water-proofing agent for a reinforced concrete structure building. The water-proofing agent is prepared from 1,7,7-trimethyl bicyclic[2.2.1]heptanes-2-ketone, ethylidene diethyl ether, N-dodecyl mercaptan, cyclohexyl methyl ketone, 1,3,3-trimethyl-2-oxa bicyclic[2.2.2]octane, cyclopropyl carbinol, 1-benzyl-2-pyrrolidone and the like. The water-proofing agent for the reinforced concrete structure building has high permeability on the reinforced concrete structure building, is low in water absorption rate and has the good water preventing and protection effect on the building. Meanwhile, construction is easy, convenient and flexible, transportation is convenient, construction is safe, the manufacturing cost is low, and the water-proofing agent is suitable for being widely applied to the waterproof field of building materials.
Description
Technical field
The present invention relates to a kind of waterproof paint, be specifically related to a kind of steel reinforced concrete structure building water-resisting agent.
Background technology
Concrete steel building is the material of a kind of heterogeneous body vesicular structure and hypertonicity, is the major cause affecting concrete steel building weather resistance.It is by capillary attraction water, and its process is usually along with the absorption to objectionable impurities.With regard to water self, water can make salinity by the internal migration of material to outside, thus make building surface weathering and salt efflorescence, water can cause material generation frost and thaw, if the long-term erosion by moisture in air, will make that wall is done, wet alternate heavily stressed, cause surface cracking, water can make wall mouldy and corrosion reinforcing bar.In addition, water can also carry pollutent and dust secretly, makes buildings stained.And the material be dissolved in the water, particularly chlorion, because destroying the passivation layer on reinforcing steel bar surface, destruction is stronger, causes catastrophic corrosion.
Waterproof coating processing must be carried out to concrete steel building, its objective is:
(1) increase the resistance to CO2 penetrating power of Steel Concrete, namely increase resisting carbonization;
(2) increase the resistance to muriate penetrating power of Steel Concrete, reduce Steel Concrete to the adsorptive power of the nuisance be dissolved in the water;
(3) resistivity of Steel Concrete to frost and deicer salts is improved;
(4) improve reinforced concrete surface hydrophobic nature, reduce capillary suction, do not affect the water vapour permeability of Steel Concrete, even if Steel Concrete also can not reduce Corrosion Protection after soaking in basic solution;
(5) outward appearance of Steel Concrete is not affected.
And existing water-resisting agent all has deficiency in various degree in perviousness, water-absorbent and production cost etc. on market, the demand of users thus cannot be met.
Summary of the invention
The object of the invention is to solve the deficiency of the result of use difference that above-mentioned prior art exists, develop a kind of perviousness high, good water absorption and steel reinforced concrete structure building water-resisting agent with low cost.
A kind of steel reinforced concrete structure building water-resisting agent, special character is to be prepared from by the raw material of following weight: 1, 7, 7-trimethylammonium two ring [2.2.1] heptane-2-ketone 13-19 part, di-alcohol acetal 6-14 part, n-dodecyl mercaptan 23-27 part, cyclohexyl methyl ketone 40-46 part, 1, 3, 3-trimethylammonium-2-oxabicyclo [2.2.2] octane 35-39 part, cyclopropyl-carbinol 4-8 part, 1-benzyl-2-Pyrrolidone 17-23 part, 2, 4-butane sultone 50-58 part, diisopropylaminoethyl villaumite hydrochlorate 33-39 part, the chloro-6'-of 3'-(Cyclohexylamino) spiral shell [isobenzofuran-1 (3H), 9'-(9H) xanthenes]-3-ketone 11-17 part, undecane dicarboxylic acid 23-27 part, L-Glutimic acid alcohol 32-38 part.
Preferably, the steel reinforced concrete structure building water-resisting agent adopting following weight raw material to prepare has better waterproof effect: 1, 7, 7-trimethylammonium two ring [2.2.1] heptane-2-ketone 16 parts, di-alcohol acetal 6 parts, n-dodecyl mercaptan 27 parts, cyclohexyl methyl ketone 43 parts, 1, 3, 3-trimethylammonium-2-oxabicyclo [2.2.2] octane 35 parts, cyclopropyl-carbinol 8 parts, 1-benzyl-2-Pyrrolidone 20 parts, 2, 4-butane sultone 50 parts, diisopropylaminoethyl villaumite hydrochlorate 39 parts, the chloro-6'-of 3'-(Cyclohexylamino) spiral shell [isobenzofuran-1 (3H), 9'-(9H) xanthenes]-3-ketone 14 parts, undecane dicarboxylic acid 23 parts, L-Glutimic acid alcohol 38 parts.
Preparation method of the present invention, concrete steps are as follows:
By 1 under whipped state, 7, 7-trimethylammonium two ring [2.2.1] heptane-2-ketone, di-alcohol acetal, n-dodecyl mercaptan, cyclohexyl methyl ketone, 1, 3, 3-trimethylammonium-2-oxabicyclo [2.2.2] octane, cyclopropyl-carbinol, 1-benzyl-2-Pyrrolidone is dissolved in 60-90 DEG C of water, add 2 afterwards, 4-butane sultone, diisopropylaminoethyl villaumite hydrochlorate, the chloro-6'-of 3'-(Cyclohexylamino) spiral shell [isobenzofuran-1 (3H), 9'-(9H) xanthenes]-3-ketone, undecane dicarboxylic acid, L-Glutimic acid alcohol, and stirred solution makes it fully mix, after add 60-90 DEG C of water and by phosphoric acid regulator solution pH value to 3.5-4.5, leave standstill 35-50 minute.
This steel reinforced concrete structure building water-resisting agent, have higher perviousness, and water-intake rate is low to concrete steel building, has good waterproofing protection effect for buildings.Meanwhile, constructing operation is flexibly easy, convenient transportation, and construction safety is cheap, is suitable for the widespread use of material of construction in waterproof field.
Embodiment
Below provide the specific embodiment of the present invention, be used for being further described the present invention.In the present invention, if no special instructions, each raw material all in working substance content for 100%.
In following examples, raw material introduction:
1,7,7-trimethylammonium two ring [2.2.1] heptane-2-ketone, CAS accession number is: 76-22-2;
Di-alcohol acetal, CAS accession number is: 105-57-7;
N-dodecyl mercaptan, CAS accession number is: 112-55-0;
Cyclohexyl methyl ketone, CAS accession number is: 823-76-7;
1,3,3-trimethylammonium-2-oxabicyclo [2.2.2] octane, CAS accession number is: 470-82-6;
Cyclopropyl-carbinol, CAS accession number is: 2516-33-8;
1-benzyl-2-Pyrrolidone, CAS accession number is: 5291-77-0;
2,4-butane sultone, CAS accession number is: 1121-03-5;
Diisopropylaminoethyl villaumite hydrochlorate, CAS accession number is: 4261-68-1;
The chloro-6'-of 3'-(Cyclohexylamino) spiral shell [isobenzofuran-1 (3H), 9'-(9H) xanthenes]-3-ketone, CAS accession number is: 26206-78-0;
Undecane dicarboxylic acid, CAS accession number is: 505-52-2;
L-Glutimic acid alcohol, CAS accession number is: 17342-08-4.
Embodiment 1
Weigh the raw material of following weight: 1, 7, 7-trimethylammonium two ring [2.2.1] heptane-2-ketone 13kg, di-alcohol acetal 14kg, n-dodecyl mercaptan 25kg, cyclohexyl methyl ketone 40kg, 1, 3, 3-trimethylammonium-2-oxabicyclo [2.2.2] octane 39kg, cyclopropyl-carbinol 6kg, 1-benzyl-2-Pyrrolidone 17kg, 2, 4-butane sultone 58kg, diisopropylaminoethyl villaumite hydrochlorate 36kg, the chloro-6'-of 3'-(Cyclohexylamino) spiral shell [isobenzofuran-1 (3H), 9'-(9H) xanthenes]-3-ketone 11kg, undecane dicarboxylic acid 27kg, L-Glutimic acid alcohol 35kg.
The preparation method of the present embodiment steel reinforced concrete structure building water-resisting agent, adopt and be prepared from the following method: by 1 under whipped state, 7, 7-trimethylammonium two ring [2.2.1] heptane-2-ketone, di-alcohol acetal, n-dodecyl mercaptan, cyclohexyl methyl ketone, 1, 3, 3-trimethylammonium-2-oxabicyclo [2.2.2] octane, cyclopropyl-carbinol, 1-benzyl-2-Pyrrolidone is dissolved in 60-90 DEG C of water, add 2 afterwards, 4-butane sultone, diisopropylaminoethyl villaumite hydrochlorate, the chloro-6'-of 3'-(Cyclohexylamino) spiral shell [isobenzofuran-1 (3H), 9'-(9H) xanthenes]-3-ketone, undecane dicarboxylic acid, L-Glutimic acid alcohol, and stirred solution makes it fully mix, after add 60-90 DEG C of water and by phosphoric acid regulator solution pH value to 3.5-4.5, leave standstill 35-50 minute.
Embodiment 2
Weigh the raw material of following weight: 1, 7, 7-trimethylammonium two ring [2.2.1] heptane-2-ketone 16kg, di-alcohol acetal 6kg, n-dodecyl mercaptan 27kg, cyclohexyl methyl ketone 43kg, 1, 3, 3-trimethylammonium-2-oxabicyclo [2.2.2] octane 35kg, cyclopropyl-carbinol 8kg, 1-benzyl-2-Pyrrolidone 20kg, 2, 4-butane sultone 50kg, diisopropylaminoethyl villaumite hydrochlorate 39kg, the chloro-6'-of 3'-(Cyclohexylamino) spiral shell [isobenzofuran-1 (3H), 9'-(9H) xanthenes]-3-ketone 14kg, undecane dicarboxylic acid 23kg, L-Glutimic acid alcohol 38kg.
The preparation method of the present embodiment steel reinforced concrete structure building water-resisting agent is with embodiment 1.
Embodiment 3
Weigh the raw material of following weight: 1, 7, 7-trimethylammonium two ring [2.2.1] heptane-2-ketone 19kg, di-alcohol acetal 10kg, n-dodecyl mercaptan 23kg, cyclohexyl methyl ketone 46kg, 1, 3, 3-trimethylammonium-2-oxabicyclo [2.2.2] octane 37kg, cyclopropyl-carbinol 4kg, 1-benzyl-2-Pyrrolidone 23kg, 2, 4-butane sultone 54kg, diisopropylaminoethyl villaumite hydrochlorate 33kg, the chloro-6'-of 3'-(Cyclohexylamino) spiral shell [isobenzofuran-1 (3H), 9'-(9H) xanthenes]-3-ketone 17kg, undecane dicarboxylic acid 25kg, L-Glutimic acid alcohol 32kg.
The preparation method of the present embodiment steel reinforced concrete structure building water-resisting agent is with embodiment 1.
The water resistance test of building water-proof agent.
The present invention adopts following reinforced concrete soil sample: the concrete steel die trial of 10cm × 10cm × 10cm is shaping, and die trial internal surface does not use oil-based release agent.
Embodiment 1-3 steel reinforced concrete structure building water-resisting agent carries out water resistance test to this reinforced concrete soil sample.
1, penetrating quality test, in table 1.
Table 1 gives embodiment 1-3 water-resisting agent depth of penetration test data in the sample.Specific as follows.
Table 1: the depth of penetration test result of water-resisting agent
Water-resisting agent kind | Depth of penetration/mm |
Embodiment 1 | 4.7 |
Embodiment 2 | 4.9 |
Embodiment 3 | 4.8 |
As can be seen from Table 1: embodiment 1-3 steel reinforced concrete structure building water-resisting agent depth of penetration in the sample, all more than 4mm, should reach the acceptance requirement of 3-4mm more than impregnating depth in JTJ275-2000.Wherein, the penetrating quality of embodiment 2 steel reinforced concrete structure building water-resisting agent is more excellent, and depth of penetration reaches 4.9mm, has better osmotic effect to steel reinforced concrete structure building.
2, water-intake rate performance test, in table 2.
The water-intake rate effect of the Steel Concrete after the process of embodiment 1-3 water-resisting agent is in table 2.
Table 2: the water-intake rate effect of embodiment 1-3 water-resisting agent process Steel Concrete
Data as can be seen from table 2: after using the process of embodiment 1-3 water-resisting agent, the water-intake rate of Steel Concrete reduces by more than 90% than when not using water-resisting agent to protect, and exceeds in JTJ275-2000 and is not more than 0.01mm/min
0.5acceptance requirement.Wherein, embodiment 2 steel reinforced concrete structure building water-resisting agent reduces more obvious for the water-intake rate of buildings.
Claims (2)
1. a steel reinforced concrete structure building water-resisting agent, it is characterized in that being prepared from by the raw material of following weight: 1, 7, 7-trimethylammonium two ring [2.2.1] heptane-2-ketone 13-19 part, di-alcohol acetal 6-14 part, n-dodecyl mercaptan 23-27 part, cyclohexyl methyl ketone 40-46 part, 1, 3, 3-trimethylammonium-2-oxabicyclo [2.2.2] octane 35-39 part, cyclopropyl-carbinol 4-8 part, 1-benzyl-2-Pyrrolidone 17-23 part, 2, 4-butane sultone 50-58 part, diisopropylaminoethyl villaumite hydrochlorate 33-39 part, the chloro-6'-of 3'-(Cyclohexylamino) spiral shell [isobenzofuran-1 (3H), 9'-(9H) xanthenes]-3-ketone 11-17 part, undecane dicarboxylic acid 23-27 part, L-Glutimic acid alcohol 32-38 part.
2. steel reinforced concrete structure building water-resisting agent as claimed in claim 1, it is characterized in that being prepared from by the raw material of following weight: 1, 7, 7-trimethylammonium two ring [2.2.1] heptane-2-ketone 16 parts, di-alcohol acetal 6 parts, n-dodecyl mercaptan 27 parts, cyclohexyl methyl ketone 43 parts, 1, 3, 3-trimethylammonium-2-oxabicyclo [2.2.2] octane 35 parts, cyclopropyl-carbinol 8 parts, 1-benzyl-2-Pyrrolidone 20 parts, 2, 4-butane sultone 50 parts, diisopropylaminoethyl villaumite hydrochlorate 39 parts, the chloro-6'-of 3'-(Cyclohexylamino) spiral shell [isobenzofuran-1 (3H), 9'-(9H) xanthenes]-3-ketone 14 parts, undecane dicarboxylic acid 23 parts, L-Glutimic acid alcohol 38 parts.
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CN201510864310.2A CN105347843A (en) | 2015-11-29 | 2015-11-29 | Water-proofing agent for reinforced concrete structure building |
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Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1261094A (en) * | 2000-02-15 | 2000-07-26 | 长春市吉工科教开发技术研究所 | Novel waterproof agent |
CN101386780A (en) * | 2007-09-11 | 2009-03-18 | 嘉兴联合化学有限公司 | Water proof anti-seepage agent for maritime building and structure |
CN102134443A (en) * | 2010-01-26 | 2011-07-27 | 北京建筑材料科学研究总院有限公司 | Method for preparing clear water concrete protectant |
US20130331476A1 (en) * | 2012-06-12 | 2013-12-12 | Korea Advanced Institute Of Science And Technology | Siloxane hard coating resin |
-
2015
- 2015-11-29 CN CN201510864310.2A patent/CN105347843A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1261094A (en) * | 2000-02-15 | 2000-07-26 | 长春市吉工科教开发技术研究所 | Novel waterproof agent |
CN101386780A (en) * | 2007-09-11 | 2009-03-18 | 嘉兴联合化学有限公司 | Water proof anti-seepage agent for maritime building and structure |
CN102134443A (en) * | 2010-01-26 | 2011-07-27 | 北京建筑材料科学研究总院有限公司 | Method for preparing clear water concrete protectant |
US20130331476A1 (en) * | 2012-06-12 | 2013-12-12 | Korea Advanced Institute Of Science And Technology | Siloxane hard coating resin |
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Application publication date: 20160224 |