CN105344566B - A kind of compound high dissipated motor powdery paints of acrylic acid sial prepares spraying process - Google Patents

A kind of compound high dissipated motor powdery paints of acrylic acid sial prepares spraying process Download PDF

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Publication number
CN105344566B
CN105344566B CN201510622178.4A CN201510622178A CN105344566B CN 105344566 B CN105344566 B CN 105344566B CN 201510622178 A CN201510622178 A CN 201510622178A CN 105344566 B CN105344566 B CN 105344566B
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Prior art keywords
powdery paints
acrylic acid
agent
resin
sial
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CN201510622178.4A
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CN105344566A (en
Inventor
王佩国
王鹰
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Kuwait Scarlett powder coatings (Tianjin) Limited by Share Ltd
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Kuwait Scarlett Powder Coatings (tianjin) Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00Processes for applying liquids or other fluent materials
    • B05D1/36Successively applying liquids or other fluent materials, e.g. without intermediate treatment
    • B05D1/38Successively applying liquids or other fluent materials, e.g. without intermediate treatment with intermediate treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00Processes for applying liquids or other fluent materials
    • B05D1/02Processes for applying liquids or other fluent materials performed by spraying
    • B05D1/04Processes for applying liquids or other fluent materials performed by spraying involving the use of an electrostatic field
    • B05D1/06Applying particulate materials
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/08Metals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/09Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C08K5/092Polycarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00Use of pretreated ingredients
    • C08K9/02Ingredients treated with inorganic substances
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/03Powdery paints
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2401/00Form of the coating product, e.g. solution, water dispersion, powders or the like
    • B05D2401/30Form of the coating product, e.g. solution, water dispersion, powders or the like the coating being applied in other forms than involving eliminable solvent, diluent or dispersant
    • B05D2401/32Form of the coating product, e.g. solution, water dispersion, powders or the like the coating being applied in other forms than involving eliminable solvent, diluent or dispersant applied as powders
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/08Metals
    • C08K2003/0812Aluminium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

Spraying process is prepared the invention discloses a kind of compound high dissipated motor powdery paints of acrylic acid sial, is included the following steps:(1) bottom powdery paints is prepared;(2) surface layer powdery paints is prepared;(3) sprayed layer undercoat powdery paints;(4) surface layer powdery paints is sprayed.Compared with prior art, present invention preparation can obtain thick coating to bottom powdery paints, surface layer powder coating and their application successively, and effect is full, and wearability is high;It can reach and paint identical metal effect;Its heat dissipation effect is 20-30 DEG C lower than the temperature of ordinary powder.

Description

A kind of preparation spraying of the compound high dissipated motor powdery paints of acrylic acid sial Technique
Technical field
The present invention relates to powder coating technology fields, are used more particularly to a kind of compound high dissipated motor of acrylic acid sial Powdery paints prepares spraying process.
Background technology
Environmental requirement is to push a big power of powdery paints development, since reduction product VOC is all finding in manufacturer Approach, therefore in certain field powdery paints naturally instead of liquid coating.
Powdery paints is made of polymer, pigment and additive.In past 10 years, powdery paints in the world Development speed quickly, annual average rate of increase 8%-15%.The method for the control Volatile organic emissions amount that U.S. government formulates Rule are conducive to the application of powdery paints.
But the application of powdery paints is also restricted because of the intrinsic disadvantage of some, as finish is low and is painting Cupboard is difficult to change color etc..Powder spray using primary spraying, in effect and performance cannot replacing paint effect completely, needle To problem universal existing for above powdery paints industry, my company is dedicated to the powder painting that research is equal to paint effect Layer is designed into production and the improvement of spraying process from formula, and is correspondingly better than paint spraying in actual use performance, reaches Domestic and international higher advanced level
At present oil paint coating production there are the problem of:Solution paint largely discharges to atmospheric environment toxic in use Harmful organic solvent, the cost that environment is paid for it is too big, paints the use shadow caused by construction personnel's physical impairment in the process Sound is long-term lifelong, solves the paint injury to construction personnel's body in the construction process, and paint belongs to combustible and explosive articles, All there is certain difficulty and danger during transport and storage, oil paint coating not only low production efficiency, and also painting cannot Recycling uses.
In the prior art, the combination effect of powder coating and metal is clear not as good as painting;And the thermal diffusivity of powdery paints It is poor.The radiating of engine has following several situations 1, Water in Water Tanks in engine cylinder body surrounding loop, passes through water tank wind The air-flow that fan rotation generates takes away hot temperature.2, the lubricating oil in engine block also plays cooling effect, it is removed in machine body-internal-circulation Lubrication friction surface, cleaning be miscellaneous cut it is outer hot temperate zone can also be walked, pass through oil radiator and complete heat dissipation.
Invention content
In view of the technical drawbacks of the prior art, it is an object of the present invention to provide a kind of raising engine radiatings The preparation method of the compound high dissipated motor powdery paints of acrylic acid sial of energy.
The technical solution adopted to achieve the purpose of the present invention is:
A kind of compound high dissipated motor powdery paints of acrylic acid sial prepares spraying process, it is characterised in that including Following steps:
(1) bottom powdery paints is prepared
By weatherable polyether resin, hypocrystalline modified resin, epoxy resin, high heat conduction agent, levelling agent, barium sulfate filler and face After mixing, after extruded machine melting extrusion, broken tabletting is ground into powder obtained material;
(2) surface layer powdery paints is prepared
After Weathering-resisting acrylic-resin and dodecanedicarboxylic acid curing agent are sufficiently mixed, by extruder melting extrusion, Broken tabletting and grind into powder;Sial coating aluminium powder, bonding auxiliary agent and dispersing aid will be added in the powder again, by high speed Mixer is made after being sufficiently mixed;
(3) sprayed layer undercoat powdery paints
Bottom powdery paints is sprayed using high-pressure electrostatic spray gun, is cured by thermostatic drying chamber after spraying, is cured Coating thickness afterwards reaches 60-80 μm;Bottom powdery paints is sprayed using high-pressure electrostatic spray gun, passes through constant temperature after spraying Drying box cures at 180 DEG C, and the coating thickness after solidification reaches 60-80 μm;
(4) surface layer powdery paints is sprayed
Surface layer powdery paints is sprayed using high-pressure electrostatic spray gun, after spraying by thermostatic drying chamber at 180 DEG C Solidification, the coating thickness after solidification reach 120-160 μm.
Bottom powdery paints is according to mass percent meter, including following component described in step (1):60% weatherable polyether Resin, 3% hypocrystalline modified resin, 7% epoxy resin, 4% high heat conduction agent, 5% levelling agent, 16% barium sulfate Filler and 5% pigment.
Preferably, the hypocrystalline modified resin is acroleic acid resin.
Preferably, the high heat conduction agent is high thermal conductive silicon glue caking agent.
Preferably, the levelling agent is polyacrylate.
Surface layer powdery paints is according to mass percent meter, including following component described in step (2):75% weatherability third Olefin(e) acid resin, 5% dodecanedicarboxylic acid curing agent, 3% sial coating aluminium powder, 1% bonding auxiliary agent and 1% dispersion Auxiliary agent.
The running parameter of super mixer described in step (2) is:50 DEG C of mixing temperature, motor speed per minute 1500 Turn, electric moter voltage 380V, current of electric 36A, power of motor 18.5KW.
The operating voltage 60-80V of high-pressure electrostatic spray gun described in step (3), (4).
Compared with prior art, the beneficial effects of the invention are as follows:
(1) the compound high dissipated motor powdery paints of acrylic acid sial prepared by the present invention can be solid matter, without molten Agent is volatilized.Coating construction process is simple, and production efficiency is high, environmentally protective;Bottom powdery paints, surface layer powdery paints are applied successively Dress can obtain thick coating, and effect is full, and wearability is high;Since its coating is thicker, density is higher, in loading transportational process significantly Improve service life, good mechanical performance can be good at solving pull-away caused by colliding in transportational process Problem;
(2) surface layer powdery paints is added to sial coating aluminium powder, bonding auxiliary agent and dispersing aid, can be reached after being sufficiently mixed To and paint identical metal effect;
(3) present invention is coated in the outside of engine, heat dissipation effect is 20-30 DEG C lower than the temperature of ordinary powder.
Description of the drawings
Fig. 1 show heat dissipation performance comparison diagram.
Specific implementation mode
Below in conjunction with specific embodiment, invention is further described in detail.It should be appreciated that described herein specific Embodiment is only used to explain the present invention, is not intended to limit the present invention.
Embodiment:
A kind of compound high dissipated motor powdery paints of acrylic acid sial, including bottom powdery paints and surface layer powder apply Material;
The bottom powdery paints is according to mass percent meter, including following component:60% weatherable polyether resin, 3% Hypocrystalline modified resin, 7% epoxy resin, 4% high heat conduction agent, 5% levelling agent, 16% barium sulfate filler and 5% pigment;
The surface layer powdery paints is according to mass percent meter, including following component:75% Weathering-resisting acrylic-resin, 5% dodecanedicarboxylic acid curing agent, 3% sial coating aluminium powder, 1% bonding auxiliary agent and 1% dispersing aid.
The preparation method of the above-mentioned compound high dissipated motor powdery paints of acrylic acid sial, it is characterised in that including following Step:
(1) bottom powdery paints is prepared
According to mass percent meter, following component is weighed:60% weatherable polyether resin, 3% hypocrystalline modified resin, 7% epoxy resin, 4% high heat conduction agent, 5% levelling agent, 16% barium sulfate filler and 5% pigment;By what is weighed After mixing, after extruded machine melting extrusion, broken tabletting is ground into powder obtained each component;
(2) surface layer powdery paints is prepared
According to mass percent meter, following component is weighed:75% Weathering-resisting acrylic-resin, 5% 12 charcoal binary acid Curing agent, 3% sial coating aluminium powder, 1% bonding auxiliary agent and 1% dispersing aid;The Weathering-resisting acrylic tree that will be weighed After fat and dodecanedicarboxylic acid curing agent are sufficiently mixed, by extruder melting extrusion, it is crushed tabletting and grind into powder;Again Sial coating aluminium powder, bonding auxiliary agent and the dispersing aid weighed will be added in the powder, carried out by super mixer fully mixed It is made after conjunction;The running parameter of the super mixer is:50 DEG C of mixing temperature, motor speed are 1500 turns per minute, motor is electric Press 380V, current of electric 36A, power of motor 18.5KW.
(3) sprayed layer undercoat powdery paints
Bottom powdery paints is sprayed using high-pressure electrostatic spray gun, is cured by thermostatic drying chamber after spraying, is cured Coating thickness afterwards reaches 60-80 μm;Bottom powdery paints is sprayed using high-pressure electrostatic spray gun, passes through constant temperature after spraying Drying box cures at 180 DEG C, and the coating thickness after solidification reaches 60-80 μm;
(4) surface layer powdery paints is sprayed
Surface layer powdery paints is sprayed using high-pressure electrostatic spray gun, after spraying by thermostatic drying chamber at 180 DEG C Solidification, the coating thickness after solidification reach 120-160 μm.
The operating voltage 60-80V of high-pressure electrostatic spray gun described in step (3), (4).
Prepare selection and the source of bottom powdery paints component:
Weatherable polyether resin is purchased from Holland DSM;
Hypocrystalline modified resin selects acroleic acid resin, purchases from Zhejiang Tian Song Co., Ltds;
Epoxy resin buying is permanent remote from Anhui;
High heat conduction agent selects high thermal conductive silicon glue caking agent, purchases from Tianjin Song Wei trade Co., Ltds;
Levelling agent selects polyacrylate, purchases from the good scientific and technological trade Co., Ltd of Tianjin ancestor;
Barium sulfate filler is purchased from Qingdao east wind Co., Ltd;
Pigment is purchased from Taiwan Lian Hong pigment Co., Ltd.
Prepare selection and the source of surface layer powdery paints component:
Acrylic resin buying is purchased from Degussa, dodecanedicarboxylic acid curing agent from Japan DIC, sial coating aluminium powder Buying likes card, bonding auxiliary agent and dispersing aid buying from Tianjin Song Wei trading companies from Germany.
Detection:The compound high dissipated motor powdery paints of acrylic acid sial prepared by the above method, sampling are examined It surveys, testing result is as follows:
By the compound high dissipated motor powder coating material of acrylic acid sial for preparing of the present invention in the outside of engine, Its heat dissipation effect curve graph is as shown in Figure 1, show the heat dissipation effect of powdery paints prepared by the present invention than commercially available ordinary powder The temperature of coating is 20-30 DEG C low.
The above is only a preferred embodiment of the present invention, it is noted that for the common skill of the art For art personnel, various improvements and modifications may be made without departing from the principle of the present invention, these improvements and modifications Also it should be regarded as protection scope of the present invention.

Claims (6)

1. a kind of compound high dissipated motor powdery paints of acrylic acid sial prepares spraying process, it is characterised in that including with Lower step:
(1) bottom powdery paints is prepared
Weatherable polyether resin, hypocrystalline modified resin, epoxy resin, high heat conduction agent, levelling agent, barium sulfate filler and pigment are mixed After closing uniformly, after extruded machine melting extrusion, broken tabletting is ground into powder obtained;The bottom powdery paints is according to quality Percentages, including following component:60% weatherable polyether resin, 3% hypocrystalline modified resin, 7% epoxy resin, 4% high heat conduction agent, 5% levelling agent, 16% barium sulfate filler and 5% pigment;
(2) surface layer powdery paints is prepared
After Weathering-resisting acrylic-resin and dodecanedicarboxylic acid curing agent are sufficiently mixed, by extruder melting extrusion, it is crushed Tabletting and grind into powder;Sial coating aluminium powder, bonding auxiliary agent and dispersing aid will be added in the powder again, by mixed at high speed Device is made after being sufficiently mixed;The surface layer powdery paints is according to mass percent meter, including following component:75% it is weather-proof Property acrylic resin, 5% dodecanedicarboxylic acid curing agent, 3% sial coating aluminium powder, 1% bonding auxiliary agent and 1% Dispersing aid;
(3) sprayed layer undercoat powdery paints
Bottom powdery paints is sprayed using high-pressure electrostatic spray gun, is cured by thermostatic drying chamber after spraying, after solidification Coating thickness reaches 60-80 μm;Bottom powdery paints is sprayed using high-pressure electrostatic spray gun, passes through freeze-day with constant temperature after spraying Case cures at 180 DEG C, and the coating thickness after solidification reaches 60-80 μm;
(4) surface layer powdery paints is sprayed
Surface layer powdery paints is sprayed using high-pressure electrostatic spray gun, is cured at 180 DEG C by thermostatic drying chamber after spraying, Coating thickness after solidification reaches 120-160 μm.
2. a kind of preparation of the compound high dissipated motor powdery paints of acrylic acid sial according to claim 1 sprays work Skill, it is characterised in that the hypocrystalline modified resin is acroleic acid resin.
3. a kind of preparation of the compound high dissipated motor powdery paints of acrylic acid sial according to claim 1 sprays work Skill, it is characterised in that the high heat conduction agent is high thermal conductive silicon glue caking agent.
4. a kind of preparation of the compound high dissipated motor powdery paints of acrylic acid sial according to claim 1 sprays work Skill, it is characterised in that the levelling agent is polyacrylate.
5. a kind of preparation of the compound high dissipated motor powdery paints of acrylic acid sial according to claim 1 sprays work Skill, it is characterised in that the running parameter of super mixer described in step (2) is:50 DEG C of mixing temperature, motor speed are per minute 1500 turns, electric moter voltage 380V, current of electric 36A, power of motor 18.5KW.
6. a kind of preparation of the compound high dissipated motor powdery paints of acrylic acid sial according to claim 1 sprays work Skill, it is characterised in that the operating voltage 60-80V of high-pressure electrostatic spray gun described in step (3), (4).
CN201510622178.4A 2015-09-25 2015-09-25 A kind of compound high dissipated motor powdery paints of acrylic acid sial prepares spraying process Active CN105344566B (en)

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CN109913088A (en) * 2019-02-23 2019-06-21 廊坊艾格玛新立材料科技有限公司 The compound high heat-dissipation powder paint of acrylic acid sial and its preparation process
CN112940572A (en) * 2021-02-01 2021-06-11 廊坊艾格玛新立材料科技有限公司 Acrylic silicon-aluminum composite high-heat-dissipation powder coating and preparation process thereof

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CN102775887B (en) * 2012-08-23 2014-10-29 广东华江粉末科技有限公司 Weather-resistant metal type powder coating for aluminum profiles and preparation method thereof
CN104693933A (en) * 2013-12-10 2015-06-10 科威嘉粉末涂料(天津)有限公司 Powdery coating and preparation technology thereof

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Address after: 300000 Fuda Road 69, Beijing-Tianjin Science and Technology Valley, Wuqing District, Tianjin

Patentee after: Kuwait Scarlett powder coatings (Tianjin) Limited by Share Ltd

Address before: 300 000 South Side of Ruiyuan Road, Bicycle Kingdom Industrial Park, Wuqing District, Tianjin

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