CN105330195A - Additive for mineral solidification aqueous mortar composition - Google Patents
Additive for mineral solidification aqueous mortar composition Download PDFInfo
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- CN105330195A CN105330195A CN201410352609.5A CN201410352609A CN105330195A CN 105330195 A CN105330195 A CN 105330195A CN 201410352609 A CN201410352609 A CN 201410352609A CN 105330195 A CN105330195 A CN 105330195A
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- Prior art keywords
- additive
- vinyl
- multipolymer
- water
- cellulose
- Prior art date
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- 239000000654 additive Substances 0.000 title claims abstract description 54
- 230000000996 additive effect Effects 0.000 title claims abstract description 50
- 239000000203 mixture Substances 0.000 title claims abstract description 42
- 229910052500 inorganic mineral Inorganic materials 0.000 title claims abstract description 26
- 239000011707 mineral Substances 0.000 title claims abstract description 26
- 239000004570 mortar (masonry) Substances 0.000 title abstract description 29
- 238000007711 solidification Methods 0.000 title abstract 4
- 230000008023 solidification Effects 0.000 title abstract 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 40
- 239000000843 powder Substances 0.000 claims abstract description 28
- 229920000642 polymer Polymers 0.000 claims abstract description 17
- 229920003086 cellulose ether Polymers 0.000 claims abstract description 8
- 238000002360 preparation method Methods 0.000 claims abstract description 3
- 239000004568 cement Substances 0.000 claims description 26
- 239000000178 monomer Substances 0.000 claims description 19
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 16
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 16
- XEKOWRVHYACXOJ-UHFFFAOYSA-N ethyl acetate Substances CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 16
- -1 vinyl aromatic compounds Chemical class 0.000 claims description 16
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 15
- 239000004576 sand Substances 0.000 claims description 14
- 125000004432 carbon atom Chemical group C* 0.000 claims description 13
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 claims description 12
- 239000011230 binding agent Substances 0.000 claims description 9
- 229920001479 Hydroxyethyl methyl cellulose Polymers 0.000 claims description 8
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 8
- 239000000945 filler Substances 0.000 claims description 8
- 239000000126 substance Substances 0.000 claims description 8
- 229920002554 vinyl polymer Polymers 0.000 claims description 8
- 229910052799 carbon Inorganic materials 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 6
- 125000000217 alkyl group Chemical group 0.000 claims description 5
- 239000001856 Ethyl cellulose Substances 0.000 claims description 4
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 claims description 4
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 claims description 4
- 125000004181 carboxyalkyl group Chemical group 0.000 claims description 4
- 238000007334 copolymerization reaction Methods 0.000 claims description 4
- 229920001249 ethyl cellulose Polymers 0.000 claims description 4
- 235000019325 ethyl cellulose Nutrition 0.000 claims description 4
- 239000001863 hydroxypropyl cellulose Substances 0.000 claims description 4
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 claims description 4
- 125000001424 substituent group Chemical group 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 3
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims description 3
- 150000001336 alkenes Chemical class 0.000 claims description 3
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims description 3
- LLVWLCAZSOLOTF-UHFFFAOYSA-N 1-methyl-4-[1,4,4-tris(4-methylphenyl)buta-1,3-dienyl]benzene Chemical compound C1=CC(C)=CC=C1C(C=1C=CC(C)=CC=1)=CC=C(C=1C=CC(C)=CC=1)C1=CC=C(C)C=C1 LLVWLCAZSOLOTF-UHFFFAOYSA-N 0.000 claims description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 2
- 229920000896 Ethulose Polymers 0.000 claims description 2
- 239000001859 Ethyl hydroxyethyl cellulose Substances 0.000 claims description 2
- 229920013820 alkyl cellulose Polymers 0.000 claims description 2
- 235000019326 ethyl hydroxyethyl cellulose Nutrition 0.000 claims description 2
- 229920013821 hydroxy alkyl cellulose Polymers 0.000 claims description 2
- 229920000609 methyl cellulose Polymers 0.000 claims description 2
- 239000001923 methylcellulose Substances 0.000 claims description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 19
- 239000000463 material Substances 0.000 description 12
- 239000006185 dispersion Substances 0.000 description 8
- 238000010276 construction Methods 0.000 description 7
- 239000003292 glue Substances 0.000 description 7
- 238000002156 mixing Methods 0.000 description 7
- 229920002678 cellulose Polymers 0.000 description 6
- 239000001913 cellulose Substances 0.000 description 6
- 230000000295 complement effect Effects 0.000 description 6
- 238000001035 drying Methods 0.000 description 6
- 239000004372 Polyvinyl alcohol Substances 0.000 description 5
- 239000000853 adhesive Substances 0.000 description 5
- 230000001070 adhesive effect Effects 0.000 description 5
- 230000007062 hydrolysis Effects 0.000 description 5
- 238000006460 hydrolysis reaction Methods 0.000 description 5
- 229920002451 polyvinyl alcohol Polymers 0.000 description 5
- 239000006004 Quartz sand Substances 0.000 description 4
- 150000001735 carboxylic acids Chemical class 0.000 description 4
- GLVVKKSPKXTQRB-UHFFFAOYSA-N ethenyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OC=C GLVVKKSPKXTQRB-UHFFFAOYSA-N 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
- 229920001519 homopolymer Polymers 0.000 description 3
- 238000012856 packing Methods 0.000 description 3
- CCJAYIGMMRQRAO-UHFFFAOYSA-N 2-[4-[(2-hydroxyphenyl)methylideneamino]butyliminomethyl]phenol Chemical group OC1=CC=CC=C1C=NCCCCN=CC1=CC=CC=C1O CCJAYIGMMRQRAO-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
- 235000011941 Tilia x europaea Nutrition 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- BLCTWBJQROOONQ-UHFFFAOYSA-N ethenyl prop-2-enoate Chemical compound C=COC(=O)C=C BLCTWBJQROOONQ-UHFFFAOYSA-N 0.000 description 2
- 230000009477 glass transition Effects 0.000 description 2
- 239000010440 gypsum Substances 0.000 description 2
- 229910052602 gypsum Inorganic materials 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 239000004571 lime Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 239000002893 slag Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 230000008719 thickening Effects 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- JHPBZFOKBAGZBL-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylprop-2-enoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)=C JHPBZFOKBAGZBL-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 229920003091 Methocel™ Polymers 0.000 description 1
- 239000011398 Portland cement Substances 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- VRDIULHPQTYCLN-UHFFFAOYSA-N Prothionamide Chemical compound CCCC1=CC(C(N)=S)=CC=N1 VRDIULHPQTYCLN-UHFFFAOYSA-N 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 244000309464 bull Species 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000004815 dispersion polymer Substances 0.000 description 1
- 238000007580 dry-mixing Methods 0.000 description 1
- 238000010981 drying operation Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 1
- 239000011440 grout Substances 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- YLGXILFCIXHCMC-JHGZEJCSSA-N methyl cellulose Chemical compound COC1C(OC)C(OC)C(COC)O[C@H]1O[C@H]1C(OC)C(OC)C(OC)OC1COC YLGXILFCIXHCMC-JHGZEJCSSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 description 1
- DNTMQTKDNSEIFO-UHFFFAOYSA-N n-(hydroxymethyl)-2-methylprop-2-enamide Chemical compound CC(=C)C(=O)NCO DNTMQTKDNSEIFO-UHFFFAOYSA-N 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 150000002924 oxiranes Chemical class 0.000 description 1
- 239000011505 plaster Substances 0.000 description 1
- 229920005646 polycarboxylate Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 239000003340 retarding agent Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
- C04B40/0028—Aspects relating to the mixing step of the mortar preparation
- C04B40/0039—Premixtures of ingredients
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00663—Uses not provided for elsewhere in C04B2111/00 as filling material for cavities or the like
- C04B2111/00672—Pointing or jointing materials
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Sealing Material Composition (AREA)
Abstract
The invention relates to an additive for a mineral solidification aqueous mortar composition. The additive basically consists of a water redispersible polymer powder and b) a cellulose-ether powder. The invention also relates to the application of the additive in the preparation of mineral solidification aqueous mortar composition, and a mineral solidification mortar composition obtained by the additive.
Description
Technical field
The present invention relates to and solidify the additive of water-based cement composition, described additive for mineral and solidify purposes in water-based cement composition preparing mineral, and the mineral utilizing described additive to obtain solidify cement composition.
Background technology
Within whole front 1/3 time in 20th century, it is all mix for use with some starting material immediately at the construction field (site) that the mineral of any kind solidify water-based cement composition.In steel tank or motorize mixing drum, first such as, by mummification compound (such as mineral binder, cement; And filler, such as sand; Such as, with other additive, thickening material) mix and then reach desirable consistency by adding water.
Since then, the specification of quality for material of construction improves significantly, uses industrial dry mortar to prepare material of construction at present.Dry mortar is the term of the mortar dry component mixed in the factory of material of construction manufacturers according to fixing explanation.
The basal component of this prefabricated dry mortar is mineral binder, as cement, gypsum or lime; And filler, as sand; For regulating the thickening material of rheological, for regulating the promotor of processibility and retarding agent and the water polymer powders redispersible for improvement of hardened sand pulp layer mechanical properties.
In order to improve described dry mortar composition, other additive can be incorporated in dry mortar composition: WO03/106369A1 describes for improvement of rheological flow and comprises the additive of water-soluble cellulose ether and polycarboxylate.EP2297060B1 discloses the additive affecting rheological of the combination containing dispersion agent and stablizer.WO2011/073224A1 describes and uses the additive containing softening agent to improve the bonding of mortar to construction substrate.WO2011/098412A1 discloses and utilizes rosin additive to carry out hydrophobization to mortar.
This dry mortar is in bag or loosely (in the silo) is delivered to working-yard.Before processing, dry mortar is not being had only to mix with the water of limitation under other composition.The advantage of dry mortar is quality product and the high storage stability of factory's support, because do not comprise the liquid ingredient that can freeze.
Obtaining the precondition using all above-mentioned advantage of dry mortar is highly developed Infrastructure, which ensure that the safe transportation of dry mortar from factory to construction site, and ensure that and to be distributed the regionality of described product by hard ware store and professional retailer.In the more underdeveloped region of Infrastructure, cement, sand and water (basal component of mortar) can obtain immediately in local shop, but are not dry mortars.Therefore, the material of construction meeting quality standard that dry mortar composition can be utilized to obtain cannot be obtained.
Consider this background, the object of this invention is to provide make it possible to generally can basic material such as cement, sand and water to start and the means of high quality buildings material prepared by the mortar of the workability and physical strength that realize demonstrating hardened mortar, its be similar to the dry mortar institute utilizing factory obtained obtainable those.
Summary of the invention
Find surprisingly, described object can obtain by means of the additive solidifying water-based cement composition for mineral, and wherein said additive consists of the following composition substantially:
A) water polymer powders redispersible, and
B) Mierocrystalline cellulose-ether powder.
Corresponding aqueous polymer dispersion drying normally by under drying aids (being generally protecting glue) and antiblocking agent existence, obtains by water polymer powders redispersible.Due to the content of protecting glue, first prevent the irreversible adhesion of polymer particle in drying operation process, because described water-soluble protecting glue particle has encased polymer particle.Secondly; this protecting glue matrix can be dissolved when polymer powder dispersion is in water again, and has following effect: polymer particle is present in (TIZ-Fachberichte, 1985 in moisture redispersion body with the granularity of initial dispersion again; 109th (9) volume, 698).
Water polymer powders redispersible is normally based on the polymkeric substance of one or more ethylenically unsaturated monomers.Preferred ethylenically unsaturated monomers be selected from contain vinyl acetate, (methyl) acrylate, vinyl aromatic compounds, alkene, 1,3-diene and vinyl halide and optional exist can with the group of other monomer of its copolymerization.
Suitable vinyl acetate is those of the carboxylic acid such as with 1-15 C atom.Proper monomer from acrylate or methacrylic ester such as has the non-branched of 1-15 C atom or the ester of branched-chain alcoho.Preferred vinyl aromatic compounds is vinylbenzene, vinyl toluene and Vinyl toluene.Preferred vinyl halide is vinylchlorid.Preferred alkene is ethene and propylene, and preferred diene is 1,3-butadiene and isoprene.
Optionally, the complementary monomer copolymerization of the gross weight 0.1-10 % by weight based on monomer mixture can also be made.The complementary monomer of preferred use 0.1-5 % by weight.The example of complementary monomer is ethylenic unsaturated monocarboxylic and dicarboxylic acid, the unsaturated carboxylic acid amides of ethylenic and nitrile, and maleic anhydride, ethylenic unsaturated sulfonic acid and its salt.Other example of complementary monomer is the comonomer of precrosslink, such as multi-ethylenical unsaturated comonomer; Or rear cross-linking comonomer, example is N hydroxymethyl acrylamide (NMA), N-methylol methacrylamide.Also it is suitable that epoxide functional's comonomer, such as glycidyl methacrylate; With silicon functionalized comonomer, such as methacryloxypropyl trialkoxy silane, vinyl trialkyl oxysilane.
Suitable homopolymer and the example of co-polymer are leifas, the multipolymer of vinyl-acetic ester and ethene, the multipolymer of vinyl-acetic ester and ethene and one or more other vinyl acetate, the multipolymer of vinyl-acetic ester and one or more other vinyl acetate, the multipolymer of vinyl-acetic ester and ethene and acrylate, the multipolymer of vinyl-acetic ester and ethene and vinylchlorid, the multipolymer of vinylchlorid and ethene and optional one or more other vinyl acetate existed, copolymer in cinnamic acrylic ester, vinylbenzene-1, 3-butadienecopolymer, wherein said polymkeric substance separately can also be mentioned amount containing the complementary monomer mentioned, and the numeral represented with % by weight in each case adds up to 100 % by weight.
Be preferably leifa; The multipolymer of other comonomer in vinyl-acetic ester and 1-50 % by weight one or more following group: the vinyl acetate in carboxyl with 1-12 carbon atom, such as vinyl acrylate, vinyl laurate, there is the vinyl acetate of the alpha-branched chain carboxylic acids of 5 to 12 carbon atoms, such as VeoVa9
r, VeoVa10
r; The multipolymer of the ethene of vinyl-acetic ester and 1-40 % by weight; The multipolymer of other comonomer in the ethene of vinyl-acetic ester and 1-40 % by weight and one or more following group of 1-50 % by weight: the vinyl acetate in carboxyl with 1-12 carbon atom, such as vinyl acrylate, vinyl laurate, there is the vinyl acetate of the alpha-branched chain carboxylic acids of 5 to 12 carbon atoms, such as VeoVa9
r, VeoVa10
r; The ethene of vinyl-acetic ester, 1-40 % by weight and the multipolymer of the preferred non-branched with 1-15 carbon atom of 1-60 % by weight or (methyl) acrylate (especially methyl methacrylate, methyl acrylate, n-butyl acrylate or 2-EHA) of branched-chain alcoho; The vinyl-acetic ester of 30-75 % by weight, the vinyl laurate of 1-30 % by weight or there is the multipolymer of the vinyl acetate of alpha-branched chain carboxylic acids of 5 to 12 carbon atoms and (methyl) acrylate (especially methyl methacrylate, methyl acrylate, n-butyl acrylate or 2-EHA) of the non-branched with 1-15 carbon atom of 1-30 % by weight or branched-chain alcoho, it also can ethene containing 1-40 % by weight; One or more have the vinyl acetate (such as vinyl-acetic ester, propionate, vinyl laurate) of 1-12 carbon atom, have vinyl acetate (the such as VeoVa9 of the alpha-branched chain carboxylic acids of 5 to 12 carbon atoms in carboxyl
r, VeoVa10
r), the multipolymer of the ethene of 1-40 % by weight and the vinylchlorid of 1-60 % by weight; Wherein said polymkeric substance mentioned amount can also contain mentioned complementary monomer separately, and the numeral represented with % by weight in each case adds up to 100 % by weight.
Preferably here make monomer select and the selection of weight fraction of comonomer to obtain-50 DEG C to+50 DEG C, the glass transition temp Tg of more preferably-40 DEG C to+40 DEG C, most preferably-20 DEG C to+30 DEG C.The glass transition temp Tg of polymkeric substance can measure by dsc (DSC) in known manner.Tg also can use Fox equation to calculate approx in advance.According to FoxT.G., Bull.Am.PhysicsSoc.1,3,123rd page (1956), be calculated as follows: 1/Tg=x1/Tg1+x2/Tg2+...+xn/Tgn, wherein xn represents the massfraction (wt%/100) of monomer n, and Tgn is the gamma transition Kelvin's temperature of the homopolymer of monomer n.PolymerHandbook the 2nd edition, in J.Wiley & Sons, NewYork (1975), list the Tg value of homopolymer.
Described polymkeric substance, normally in water-bearing media, is prepared preferably by the emulsion such as described in WO2010/057888A1 or suspension polymerization technique.In this case polymkeric substance obtains with aqueous dispersion form.In polymerization, the common protecting glue described in WO2010/057888A1 and/or emulsifying agent can be used.As protecting glue, preferably there is the partial hydrolysis of the degree of hydrolysis of 80mol-% to 100mol-% or the polyvinyl alcohol of complete hydrolysis, more specifically for have the degree of hydrolysis of 80mol-% to 94mol-% and 1-30mPas in the aqueous solution of 4% concentration
viscosity (
method, 20 DEG C, DIN53015) the polyvinyl alcohol of partial hydrolysis.Described protecting glue obtains by method known to those skilled in the art, and usually makes an addition in described polymerization with the amount of the 1-20 % by weight altogether of the gross weight based on monomer.
By spraying dry, the polymer conversion in aqueous dispersion form is become redispersible corresponding powder in water, as such as described in WO2010/057888A1.In said case, usually drying aids is added with the total amount of the polymeric constituent 3-30 % by weight based on dispersion.Preferred drying aids is above-mentioned polyvinyl alcohol.In addition, antiblocking agent can be added during drying step or afterwards.
Water polymer powders redispersible can also be commercially available.The Vinnapas of such as WackerChemieAG
rdispersion powder.
One or more ether of cellulose can be used.They are preferably selected from alkyl cellulose ether, hydroxy alkyl cellulose ether, carboxyalkyl cellulose ether and have the mixed ether of at least two different substituents, described at least two different substituents are from alkyl, hydroxyalkyl, carboxyalkyl, and the alkyl in often kind of situation all has 1-10 carbon atom.Described alkyl preferable methyl, ethyl and/or propyl group, hydroxyalkyl is preferably methylol, hydroxyethyl and/or hydroxypropyl.The cloth viscosity (Brookfieldviscosity) of the ether of cellulose measured at 20 DEG C with 20rpm and with 2% aqueous solution is generally 100-100000mPas, preferably 1000-75000mPas, particularly preferably 5000-50000mPas.
Particularly preferred ether of cellulose is methylcellulose gum (MC), ethyl cellulose (EC), methyl hydroxyethylcellulose (MHEC), Type 3U (EHEC), methyl ethyl hydroxyethyl cellulose (MEHEC), Natvosol (HEC), hydroxypropylcellulose (HPC), methylhydroxypropylcellulose (MHPC), Vltra tears (HPMC), hydroxyethylmethyl-cellulose (HEMC), carboxymethyl cellulose (CMC).
Ether of cellulose can be commercially available.The Berocoll of such as AkzoNobelNV
r, WolffCellulosicsGmbH & Co.KG Walocel
r, DowChemical company Methocel
ror Cellosize
r, SETyloseGmbH & Co.KG Tylose
r, Ashland company Culminal
ror Natrosol
r.
Preferably, described additive substantially by the dry weight 50-95 % by weight based on compositions of additives one or more water polymer powders redispersibles a) and one or more Mierocrystalline celluloses-ether powder b of 5-50 % by weight) form.More preferably, described additive substantially by the dry weight 50-75 % by weight based on compositions of additives one or more water polymer powders redispersibles a) and one or more Mierocrystalline celluloses-ether powder b of 25-50 % by weight) form.In each case, described additive can also comprise other a small amount of composition of the dry weight 1-10 % by weight based on compositions of additives, and the numeral represented with % by weight in each case adds up to 100 % by weight.The example of other composition is filler, such as sand, silica powder and/or calcium carbonate; And/or dispersion stabilizer, such as sucrose; And/or setting accelerator, such as calcium formiate; And/or defoamer; And/or water repellent, such as fatty acid ester; And/or stablizer, such as polyvinyl alcohol.
In order to prepare described additive, can use be purchased mixing tank by component a) and b) and optional other composition existed mix in powder form each other.If the one in other composition is liquid form, so component a) and b) is mixed with other composition in liquid form with powder.Also described liquid component can be applied and be absorbed on solid powdery solid support material.
Additive according to the present invention make it possible to by with generally available basic material as cement, sand and water start and obtain high-quality aqueous sand.In order to even realize this goal when small-sized working-yard, and in addition in order to simplify the batching of additive, additive is packed with relatively little part (protion).Preferably, the part of the part, more preferably 50g to the 1kg that are 50g to 10kg by described additive packing (distribute).In less packing measurement, each several part of additive can be packaged in pouch.For larger packing measurement, each several part of additive can be packaged in bucket.
Additive agent modified mineral according to the present invention are utilized to solidify water-based cement composition in order to prepare, in a first step, by additive and mineral binder and filler blending in dry mixing step.In the second step, by the drying composite containing additive and water blending, solidify water-based cement composition for obtaining mineral.
Can will add in described cement composition based on the preferred 1-10 of dry weight % by weight of mineral binder, the more preferably additive of 1-5 % by weight in each case.
As generally available preferred mineral binder, cement can be used, particularly portland cement and/or aluminous cement; And/or gypsum; And/or lime; And/or pozzuolana (puzzolane), such as volcanic slag; And/or volcanic tuff; And/or flying dust; And/or blast-furnace slag.
As generally available preferred filler material, such as sand and/or chalk and/or clay can be used.
Utilize described additive agent modified mineral to solidify water-based cement composition and usually comprise the mineral binder of 5-80 weight part and the filler of 20-95 weight part, and the water of amount for the desirable consistency that reaches described aqueous sand.In given framework, the composition of aqueous sand depends on the Application Areas of mortar.Such as, utilize described additive agent modified mineral to solidify water-based cement composition can be used as plaster or prepare as thermopnore mortar or as mending mortar or as tile grout or as bedding screed (floorscreed).
Embodiment
Embodiment:
The tile adhesives utilizing the dry mortar mixture of pre-mixing to obtain (comparing embodiment 1) and the tile adhesives (embodiment 2) obtained by mixed cement, sand, additive of the present invention and water are compared.
Comparing embodiment 1:
There is the dry mortar mixture of following material:
300.0g cement (OPCCEM42.5, MilkeZementGmbH & Co.KG)
686.5g quartz sand (quartz sand F31/F36,1:1, QuarzwerkeGmbH)
3.5g ether of cellulose (TyloseMB3003P4, ShinEtsuSE)
5.0g redispersible powder (the vinyl multipolymer that polyvinyl alcohol is stable, the Vinnapas4023N of WackerChemieAG)
5.0g calcium formiate (FlukaGmbH)
Dry mortar preparation is mixed to form tile adhesives with 265g water.
Embodiment 2:
300.0g cement (OPCCEM42.5, MilkeZementGmbH & Co.KG)
686.5g quartz sand (quartz sand F31/F36,1:1, QuarzwerkeGmbH)
8.5g additive
Described additive is obtained by mixing 3.5g ether of cellulose (TyloseMB3003P4) and 5.0g redispersible powder (Vinnapas4023N).
Cement, sand and additive are mixed, and blending 265g water is to form tile adhesives.
The mensuration of resisting binding strength:
In order to test, 5mm is used to be with tooth trowel to be administered to separately on concrete paving plate by the tile adhesives composition of comparing embodiment 1 and embodiment 2.Then 5 pieces of ceramic tiles (5 × 5cm) are layed on each plate, and use 2kg weight to be pressed down 30 seconds.
Resisting binding strength is tested in each case under following condition of storage:
Store under standard conditions (SC):
28 days are stored under 23 DEG C and 50% humidity.
Wet storage (WS):
Store 7 days at the standard conditions, in water, at 20 DEG C, store 21 days afterwards.
After above-mentioned storage, measure resisting binding strength according to DINEN1348 in each case, which use and be pulled away from device (pulloffdevice) from Herion, load is advanced the speed as 250N/s.Observed value (N/mm
2) represent the mean value measured for 5 times.
| Embodiment | Tensile strength (SC) | Tensile strength (WS) |
| Comparing embodiment 1 | 1.17N/mm 2 | 0.97N/mm 2 |
| Embodiment 2 | 1.16N/mm 2 | 0.93N/mm 2 |
Claims (9)
1. solidify an additive for water-based cement composition for mineral, wherein said additive consists of the following composition substantially:
A) water polymer powders redispersible, and
B) Mierocrystalline cellulose-ether powder.
2. additive according to claim 1, wherein said water polymer powders redispersible comprises the polymkeric substance of one or more ethylenically unsaturated monomers, described ethylenically unsaturated monomers is selected from vinyl acetate, (methyl) acrylate, vinyl aromatic compounds, alkene, 1,3-diene and vinyl halide, and optional exist can with other monomer of its copolymerization.
3. additive according to claim 1, wherein said water polymer powders redispersible comprises the polymkeric substance be selected from following group: leifa, the multipolymer of vinyl-acetic ester and ethene, the multipolymer of vinyl-acetic ester and ethene and one or more other vinyl acetate, the multipolymer of vinyl-acetic ester and one or more other vinyl acetate, the multipolymer of vinyl-acetic ester and ethene and acrylate, the multipolymer of vinyl-acetic ester and ethene and vinylchlorid, the multipolymer of vinylchlorid and ethene and optional one or more other vinyl acetate existed, the multipolymer of cinnamic acrylic ester, vinylbenzene-1, the multipolymer of 3-divinyl, all optional in each case exist other monomer with its copolymerization.
4. the additive that one of claim 1-3 is described, wherein said cellulose ether powder is selected from alkyl cellulose ether, hydroxy alkyl cellulose ether, carboxyalkyl cellulose ether and has the mixed ether of at least two different substituents, described at least two different substituents are derived from alkyl, hydroxyalkyl, carboxyalkyl, and alkyl in each case all has 1-10 carbon atom.
5. the additive that one of claim 1-3 is described, wherein said cellulose ether powder is selected from methylcellulose gum (MC), ethyl cellulose (EC), methyl hydroxyethylcellulose (MHEC), Type 3U (EHEC), methyl ethyl hydroxyethyl cellulose (MEHEC), Natvosol (HEC), hydroxypropylcellulose (HPC), methylhydroxypropylcellulose (MHPC), Vltra tears (HPMC), hydroxyethylmethyl-cellulose (HEMC), carboxymethyl cellulose (CMC).
6. the additive that one of claim 1-5 is described, wherein said additive substantially by the dry weight 50-95 % by weight based on described compositions of additives one or more water polymer powders redispersibles a) and one or more Mierocrystalline celluloses-ether powder b of 5-50 % by weight) form.
7. the additive that one of claim 1-6 is described, wherein said additive is packed as the part of 50g to 10kg.
8. described additive solidifies the purposes in water-based cement composition at the mineral that preparation comprises one or more mineral binder and one or more fillers, is wherein added in described cement composition by the additive one of the claim 1-7 of the dry weight 0.5-10 % by weight based on described mineral binder Suo Shu.
9. the additive agent modified mineral utilizing one of claim 1-7 described solidify a water-based cement composition, and it comprises the mineral binder of 5-80 weight part and the filler of 20-95 weight part, and for the water of the amount that reaches aqueous sand desirable consistency.
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410352609.5A CN105330195A (en) | 2014-07-23 | 2014-07-23 | Additive for mineral solidification aqueous mortar composition |
| MX2017000989A MX2017000989A (en) | 2014-07-23 | 2015-07-23 | Additive for minerally setting aqueous mortar compositions. |
| BR112017001425A BR112017001425A2 (en) | 2014-07-23 | 2015-07-23 | mineral hardening additive of aqueous mortar compositions |
| PCT/CN2015/084879 WO2016011955A1 (en) | 2014-07-23 | 2015-07-23 | Additive for minerally setting aqueous mortar compositions |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410352609.5A CN105330195A (en) | 2014-07-23 | 2014-07-23 | Additive for mineral solidification aqueous mortar composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105330195A true CN105330195A (en) | 2016-02-17 |
Family
ID=55162524
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410352609.5A Pending CN105330195A (en) | 2014-07-23 | 2014-07-23 | Additive for mineral solidification aqueous mortar composition |
Country Status (4)
| Country | Link |
|---|---|
| CN (1) | CN105330195A (en) |
| BR (1) | BR112017001425A2 (en) |
| MX (1) | MX2017000989A (en) |
| WO (1) | WO2016011955A1 (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111032593B (en) | 2017-08-17 | 2022-04-05 | 诺力昂化学品国际有限公司 | Methyl ethyl hydroxyalkyl cellulose and use thereof in building compositions |
| CN111533497B (en) * | 2020-05-14 | 2021-08-20 | 武汉大学 | Cementing material for enhancing stability of tailing dam and application thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1951858A (en) * | 2005-10-20 | 2007-04-25 | 王红 | Mortar |
| CN101229968A (en) * | 2007-01-25 | 2008-07-30 | 扬州荣佳建材科技有限公司 | Polymer reinforced aerated concrete light-brick adhesives and preparation method thereof |
| CN101541706A (en) * | 2006-12-20 | 2009-09-23 | 瓦克化学有限公司 | Hydrophobic laying of tiles |
| CN102295429A (en) * | 2010-05-17 | 2011-12-28 | 陶氏环球技术有限公司 | Cellulose ether composition for dry mortar formulations |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SE520651C2 (en) * | 2001-12-03 | 2003-08-05 | Akzo Nobel Nv | Aqueous cement composition |
-
2014
- 2014-07-23 CN CN201410352609.5A patent/CN105330195A/en active Pending
-
2015
- 2015-07-23 BR BR112017001425A patent/BR112017001425A2/en not_active IP Right Cessation
- 2015-07-23 WO PCT/CN2015/084879 patent/WO2016011955A1/en active Application Filing
- 2015-07-23 MX MX2017000989A patent/MX2017000989A/en unknown
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1951858A (en) * | 2005-10-20 | 2007-04-25 | 王红 | Mortar |
| CN101541706A (en) * | 2006-12-20 | 2009-09-23 | 瓦克化学有限公司 | Hydrophobic laying of tiles |
| CN101229968A (en) * | 2007-01-25 | 2008-07-30 | 扬州荣佳建材科技有限公司 | Polymer reinforced aerated concrete light-brick adhesives and preparation method thereof |
| CN102295429A (en) * | 2010-05-17 | 2011-12-28 | 陶氏环球技术有限公司 | Cellulose ether composition for dry mortar formulations |
Also Published As
| Publication number | Publication date |
|---|---|
| MX2017000989A (en) | 2017-05-01 |
| WO2016011955A1 (en) | 2016-01-28 |
| BR112017001425A2 (en) | 2017-11-28 |
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