CN105326652A - Perm agent composition taking pure cysteamine as reducing agent - Google Patents
Perm agent composition taking pure cysteamine as reducing agent Download PDFInfo
- Publication number
- CN105326652A CN105326652A CN201510685230.0A CN201510685230A CN105326652A CN 105326652 A CN105326652 A CN 105326652A CN 201510685230 A CN201510685230 A CN 201510685230A CN 105326652 A CN105326652 A CN 105326652A
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- agent
- cysteamine
- pure
- hair
- reducing agent
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/04—Preparations for permanent waving or straightening the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/30—Characterized by the absence of a particular group of ingredients
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- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
Abstract
The invention discloses a perm agent composition taking pure cysteamine as a reducing agent. The perm agent composition with a pH (potential of hydrogen) value ranging from 8.5 to 10 is prepared from, by weight, 0.1-100% of the pure cysteamine, 1.0-5% of surfactants, 0.05-1% of hair protective agents, 0.1-3% of stabilizers, 3-15% of moisturizing agents, 0.1-3% of metal complexing agents and a proper quantity of purified water. The perm agent composition taking the pure cysteamine as the reducing agent has the advantages that by the aid of the pure cysteamine, the pH value can reach 8.5-10 without addition of any alkaline substance, so that epidermal layers of hair are expanded and softened; the pure cysteamine (HS-CH2-CH2-NH2) with salt removed is smaller in molecular weight, permeation and absorption are easier, and accordingly perming time is shortened; owing to no addition of any alkaline substance, byproducts are reduced greatly, hair damage degree is decreased, and residual unpleasant smell after perming is reduced to a great extent.
Description
Technical field
The present invention relates to agent for permanent hair waving applied technical field, especially a kind ofly comprise the agent for permanent hair waving compositions that pure cysteamine is reducing agent.
Background technology
Every root hair is by epidermal area, cortical layer, medullary substance layer composition.And account for 80% of hair as the cortical layer of the major part of hair, the keratin that cortical layer is enriched by elasticity forms, and the polypeptide link that keratin is made up of each seed amino acid is got up, hydrogen bond is dispersed with between polypeptide and polypeptide, sat linkage, the polymer substances such as disulfide bond, they form the abundant helicoidal structure of elasticity, also can return to original state so bending under external force.The principle of hair-waving first disulfide bond is interrupted, and then recombinates, make it permanent bend or stretching.The basic process of hair-waving is divided into two steps, and the first step is under the effect of agent for permanent hair waving potion, and the two fluidisation keys of nearly 45% are cut off, and become monosulfidic bond.These monosulfidic bonds, under the impact of core diameter and shape, produce extruding and are shifted, and leaving many spaces; Second step is after the oxidant in hair-waving two doses, water enters a body, expand in these spaces and become large, original monosulfidic bond is made to get back to original position, and the monosulfidic bond adjacent with it with other reformulates one group of new two fluidisation key, the angle of two fluidisation keys original in hair is changed, makes the permanent change volume of hair or straighten.
Agent for permanent hair waving (perm) is generally made up of reproducibility potion and oxidisability two doses.In the past as reproducibility agent, specifically there is TGA, TGA hydrochlorate, mercaptoacetate, cysteine, cysteine hydrochloride, cysteine acetyl derivative, Mercaptamine.As oxidant, specifically there are hydrogen peroxide and sodium bromate.Usually, in agent for permanent hair waving (perm) formula, in order to improve reduction rate and effect, alkaline matter can be used, penetrating agent, wetting agent, emulsifying agent, aromatic etc.
The reducing agent more than enumerated must be equipped with alkaline matter to improve pH value, and conventional alkaline matter has ammonia, ethanolamine, triethanolamine etc.This alkaline matter is used to make the pH value of reproducibility potion reach 8.9 ~ 10.Alkali is used to regulate the object of pH value to be to make epidermal area expand with softening, so that the infiltration of host and absorption.But using alkaline matter to improve pH value can make hair proteins sustain damage, cause that hair structure is lax, porous and nonelastic.And after use alkaline matter, ammonium salt or the monoethanolamine hydrochlorate of generation can leave unpleasant stink.
How to reduce the damage of hair in hair-waving process and niff residual after how reducing hair-waving, this is the difficult problem being all the time difficult to capture, so use various moisturizing agent and nutrient impaired to make up hair, cover niff with a large amount of aromatic that adds.Although such method can be with and serve improvement, be difficult to reach basic effect.The unpleasant taste particularly stayed after hair-waving just can not mask with aromatic merely.
Summary of the invention
Prior art is difficult to the productive life needs meeting people, in order to solve above-mentioned Problems existing, the present invention proposes and a kind ofly comprise the agent for permanent hair waving compositions that pure cysteamine is reducing agent.
For realizing this technical purpose, the technical solution used in the present invention is: one comprises the agent for permanent hair waving compositions that pure cysteamine (HS-CH2-CH2-NH2) is reducing agent, and it makes raw material and comprises pure cysteamine (HS-CH2-CH2-NH2), surfactant, hair-protecting agent, stabilizing agent, wetting agent, metal chelating agent and pure water; Making raw material each component accounts for weight ratio and is: pure cysteamine (HS-CH2-CH2-NH2) 0.1-100%; Surfactant 1.0 ~ 5%; Hair-protecting agent 0.05 to 1%; Stabilizing agent 0.1 ~ 3%; Wetting agent 3 ~ 15%; Metal chelating agent 0.1 ~ 3%; Pure water is appropriate; Agent for permanent hair waving pH value is 8.5 ~ 10.
As further technical scheme of the present invention, described pure cysteamine (HS-CH2-CH2-NH2) molecular weight is 77.15, and pH value is 9.5-10.
As further technical scheme of the present invention, described surfactant is polysorbate, sodium lauryl tri(oxyethyl) sulfate, stereth or cetearyl alcohol.
As further technical scheme of the present invention, described stabilizing agent is Carbomer, citric acid and its esters, phosphoric acid and its esters or cellulose family.
As further technical scheme of the present invention, described wetting agent can use glycerol, propylene glycol, butanediol or carbamide.
As further technical scheme of the present invention, described metal chelating agent is HEDP, etidronate disodium, EDTA-2 sodium or EDTA-4 sodium.
Compared with prior art, the present invention has following beneficial effect: this comprises the agent for permanent hair waving compositions that pure cysteamine (HS-CH2-CH2-NH2) is reducing agent,
1. because employing pure cysteamine (HS-CH2-CH2-NH2), just can reach 8.5 ~ 10 without the need to adding any alkaline matter pH value, epidermal area being expanded and softens.
2. pure cysteamine (HS-CH2-CH2-NH2) molecular weight removing salt is less, more easily infiltration and absorption, thus reduces the hair-waving time.
3. do not add alkaline matter, greatly reduce the by-product of generation, not only reduce hair impaired, niff residual after also reducing hair-waving significantly.
Detailed description of the invention
Be clearly and completely described to the technical scheme in the embodiment of the present invention below, obviously, described embodiment is only the present invention's part embodiment, instead of whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art, not making other embodiments all obtained under creative work prerequisite, belong to the scope of protection of the invention.
In the embodiment of the present invention, comprise the agent for permanent hair waving compositions that pure cysteamine is reducing agent, it makes raw material and comprises pure cysteamine (HS-CH2-CH2-NH2), surfactant, hair-protecting agent, stabilizing agent, wetting agent, metal chelating agent and pure water; Making raw material each component accounts for weight ratio and is: pure cysteamine (HS-CH2-CH2-NH2) 0.1-100%; Surfactant 1.0 ~ 5%; Hair-protecting agent 0.05 to 1%; Stabilizing agent 0.1 ~ 3%; Wetting agent 3 ~ 15%; Metal chelating agent 0.1 ~ 3%; Pure water is appropriate; Agent for permanent hair waving pH value is 8.5 ~ 10.
Further, described pure cysteamine (HS-CH2-CH2-NH2) molecular weight is 77.15, and pH value is 9.5-10.
Further, described surfactant is polysorbate, sodium lauryl tri(oxyethyl) sulfate, stereth or cetearyl alcohol.
Further, described stabilizing agent is Carbomer, citric acid and its esters, phosphoric acid and its esters or cellulose family.
Further, described wetting agent can use glycerol, propylene glycol, butanediol or carbamide.
Further, described metal chelating agent is HEDP, etidronate disodium, EDTA-2 sodium or EDTA-4 sodium.
Embodiment 1:
Form one: when using different reducing agent in agent for permanent hair waving, equal reductant concentration, equal PH require the lower required alkaline matter added with scale:
| Title | Molecular weight | The pH value of 10% solution |
| L-cysteine hydrochloride sulfuric monohydrate | 175.63 | 1.0～1.5 |
| Cys | 121.13 | 4.0～5.0 |
| TGA | 92.19 | 1.0～2.0 |
| Mercaptamine | 113.65 | 3.5～4.5 |
| Pure cysteamine (HS-CH2-CH2-NH2) | 77.15 | 9.0～10.0 |
Test condition: reductant concentration: 0.5 equivalent, pH value: 9.5, alkaline matter: monoethanolamine, capacity: 100 grams of agent for permanent hair waving.
Form two,
Form two result, pure cysteamine (HS-CH2-CH2-NH2) for during reducing agent without the need to adding alkaline matter.
Embodiment 2:
In form one, listed material is as the reducing agent in agent for permanent hair waving potion, and use comparable sodium, detect their hair-waving effect under the following conditions, list is in form three.(D: represent weak, C: represent general, B: represent good, A: represent outstanding)
Test condition: hair: healthy, reductant concentration: 0.5 equivalent, pH value: 9.5, alkaline matter: monoethanolamine, standing time after curly hair: 30 minutes, without the need to heating, oxidant: hydrogen peroxide;
Form three, the present invention reaches outstanding rank with the curling effect of the agent for permanent hair waving that pure cysteamine (HS-CH2-CH2-NH2) is reducing agent.
The mensuration of effect of perming when reductant concentration is identical in agent for permanent hair waving;
Example three: the degree of injury of hair is test with the agent for permanent hair waving agent that pure cysteamine (HS-CH2-CH2-NH2) is reducing agent;
Under the following conditions, detect the present invention with pure cysteamine (HS-CH2-CH2-NH2) agent for permanent hair waving that is reducing agent to the degree of injury list of hair in form four, in order to compare the extent of damage, comparison other have selected Mercaptamine.
Test condition: hair: healthy, reductant concentration: 0.5 equivalent, pH value: 9.5, alkaline matter: monoethanolamine, standing time after curly hair: 30 minutes, without the need to heating, oxidant: hydrogen peroxide;
Form four
Embodiment 4:
The test of residual aftertaste after the agent for permanent hair waving being reducing agent with pure cysteamine (HS-CH2-CH2-NH2) hair-waving;
Under following condition, detect after the present invention perms with the agent for permanent hair waving potion that pure cysteamine (HS-CH2-CH2-NH2) is reducing agent and remain the list of aftertaste degree in form five, in order to relatively more residual aftertaste, comparison other have selected Mercaptamine.
Test condition: hair: healthy, reductant concentration: 0.5 equivalent, pH value: 9.5, alkaline matter: monoethanolamine, standing time after curly hair: 30 minutes, without the need to heating, oxidant: hydrogen peroxide;
Form five
As above listed by form five, the present invention with pure cysteamine (HS-CH2-CH2-NH2) agent for permanent hair waving (perm) potion that is reducing agent with use compared with agent for permanent hair waving that Mercaptamine is reducing agent, abnormal smells from the patient residual after hair-waving reduces a lot.
There is above embodiment to draw, provided by the inventionly comprise the agent for permanent hair waving that pure cysteamine is reducing agent:
1. because employing pure cysteamine (HS-CH2-CH2-NH2), just can reach 8.5 ~ 10 without the need to adding any alkaline matter pH value, epidermal area being expanded and softens.
2. pure cysteamine (HS-CH2-CH2-NH2) molecular weight removing salt is less, more easily infiltration and absorption, thus reduces the hair-waving time.
3.3. do not add alkaline matter, greatly reduce the by-product of generation, not only reduce hair impaired, niff residual after also reducing hair-waving significantly.Therefore the present invention comprises agent for permanent hair waving (perm) potion that pure cysteamine (HS-CH2-CH2-NH2) is reducing agent will be once leap and the change in hair-waving field.
To those skilled in the art, but the invention is not restricted to the details of above-mentioned one exemplary embodiment, and when not deviating from spirit of the present invention or basic feature, the present invention can be realized in other specific forms.Therefore, no matter from which point, all should embodiment be regarded as exemplary, and be nonrestrictive, scope of the present invention is limited by claims instead of above-mentioned explanation, and all changes be therefore intended in the implication of the equivalency by dropping on claim and scope are included in the present invention.Any labelling in claim should be considered as the claim involved by limiting.
The above; be only preferred embodiment of the present invention; not in order to limit the present invention, every above embodiment is done according to technical spirit of the present invention any trickle amendment, equivalently replace and improve, within the protection domain that all should be included in technical solution of the present invention.
Claims (6)
1. comprise the agent for permanent hair waving compositions that pure cysteamine is reducing agent, it makes raw material and comprises pure cysteamine (HS-CH2-CH2-NH2), surfactant, hair-protecting agent, stabilizing agent, wetting agent, metal chelating agent and pure water; It is characterized in that: making raw material each component accounts for weight ratio and is: pure cysteamine 0.1-100%; Surfactant 1.0 ~ 5%; Hair-protecting agent 0.05 to 1%; Stabilizing agent 0.1 ~ 3%; Wetting agent 3 ~ 15%; Metal chelating agent 0.1 ~ 3%; Pure water is appropriate; Agent for permanent hair waving pH value is 8.5 ~ 10.
2. according to claim 1ly a kind ofly comprise the agent for permanent hair waving compositions that pure cysteamine is reducing agent, it is characterized in that: described pure cysteamine (HS-CH2-CH2-NH2) molecular weight is 77.15, and pH value is 9.5-10.
3. according to claim 1ly a kind ofly comprise the agent for permanent hair waving compositions that pure cysteamine is reducing agent, it is characterized in that: described surfactant is polysorbate, sodium lauryl tri(oxyethyl) sulfate, stereth or cetearyl alcohol.
4. according to claim 1ly a kind ofly comprise the agent for permanent hair waving compositions that pure cysteamine is reducing agent, it is characterized in that: described stabilizing agent is Carbomer, citric acid and its esters, phosphoric acid and its esters or cellulose family.
5. according to claim 1ly a kind ofly comprise the agent for permanent hair waving compositions that pure cysteamine is reducing agent, it is characterized in that: described wetting agent can use glycerol, propylene glycol, butanediol or carbamide.
6. according to claim 1ly a kind ofly comprise the agent for permanent hair waving compositions that pure cysteamine is reducing agent, it is characterized in that: described metal chelating agent is HEDP, etidronate disodium, EDTA-2 sodium or EDTA-4 sodium.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510685230.0A CN105326652A (en) | 2015-10-22 | 2015-10-22 | Perm agent composition taking pure cysteamine as reducing agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510685230.0A CN105326652A (en) | 2015-10-22 | 2015-10-22 | Perm agent composition taking pure cysteamine as reducing agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105326652A true CN105326652A (en) | 2016-02-17 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510685230.0A Pending CN105326652A (en) | 2015-10-22 | 2015-10-22 | Perm agent composition taking pure cysteamine as reducing agent |
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| CN (1) | CN105326652A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108743429A (en) * | 2018-06-21 | 2018-11-06 | 王庆仙 | Settle environmentally friendly blanching agent for permanent hair waving and its application method at one go |
| CN111329777A (en) * | 2020-03-27 | 2020-06-26 | 华欧研创生物科技(深圳)有限公司 | Permanent perming agent composition under acidic condition and perming method |
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| JP2011084582A (en) * | 2004-04-19 | 2011-04-28 | Arimino Kagaku Kk | Hair transformation agent (design forming), hair softening agent and penetrating agent for hair of low cysteamine concentration, and a hair treating method using these agents |
| CN102090995A (en) * | 2009-12-14 | 2011-06-15 | 上海兴博隆精细化工有限公司 | Hair-waving agent containing cysteamine or salt of cysteamine |
| CN103006466A (en) * | 2012-12-21 | 2013-04-03 | 上海章华保健化妆品有限公司 | Timing permanent agent and preparation method thereof |
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2015
- 2015-10-22 CN CN201510685230.0A patent/CN105326652A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| JP2011084582A (en) * | 2004-04-19 | 2011-04-28 | Arimino Kagaku Kk | Hair transformation agent (design forming), hair softening agent and penetrating agent for hair of low cysteamine concentration, and a hair treating method using these agents |
| JP2013241474A (en) * | 2004-04-19 | 2013-12-05 | Arimino Kagaku Kk | Hair deformation (design formation) agent containing low concentration cysteamine, hair softening agent, and hair penetration enhancer |
| JP2015129196A (en) * | 2004-04-19 | 2015-07-16 | 株式会社アリミノ | Low concentration cysteamine-containing hair deformation (design formation) agent |
| CN102090995A (en) * | 2009-12-14 | 2011-06-15 | 上海兴博隆精细化工有限公司 | Hair-waving agent containing cysteamine or salt of cysteamine |
| CN103006466A (en) * | 2012-12-21 | 2013-04-03 | 上海章华保健化妆品有限公司 | Timing permanent agent and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108743429A (en) * | 2018-06-21 | 2018-11-06 | 王庆仙 | Settle environmentally friendly blanching agent for permanent hair waving and its application method at one go |
| CN111329777A (en) * | 2020-03-27 | 2020-06-26 | 华欧研创生物科技(深圳)有限公司 | Permanent perming agent composition under acidic condition and perming method |
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Application publication date: 20160217 |