CN105315108A - Rice long-acting nitrogen fertilizer applicable to low-temperature cold region - Google Patents
Rice long-acting nitrogen fertilizer applicable to low-temperature cold region Download PDFInfo
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- CN105315108A CN105315108A CN201510877915.5A CN201510877915A CN105315108A CN 105315108 A CN105315108 A CN 105315108A CN 201510877915 A CN201510877915 A CN 201510877915A CN 105315108 A CN105315108 A CN 105315108A
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Abstract
The invention discloses rice long-acting nitrogen fertilizer applicable to a low-temperature cold region. The rice long-acting nitrogen fertilizer applicable to the low-temperature cold region is made from 3,4-dimethylpyrazole phosphate, humic acid, sulphuric acid, ammonium hydrogen carbonate, urea and calcium nitrate. The rice long-acting nitrogen fertilizer applicable to the low-temperature cold region has the beneficial effects that the validity of the nitrogen fertilizer is prolonged, the utilization rate is improved, temperatures of soil and a water layer can be obviously improved after the rice long-acting nitrogen fertilizer is applied, and good low-temperature resistance and rice seedling rapid growth promotion effect in a rice seedling stage can be realized.
Description
Technical field
The present invention relates to a kind of chemical fertilizer, in particular to a kind of paddy rice long-acting nitrogen fertilizer being applicable to low temperature Han Qu.
Background technology
Low temperature Han Qu in latitude district or high altitude localities higher, as northeast and the Northwest of China.At low temperature Han Qu because accumulated temperature is less, be generally 1 year one season of plantation.China waits low temperature district's Monitoring of Paddy Rice Plant Area of trembling with fear day by day to become large at present northeastward, these Soils In The Regions are fertile, rain hot same season, prepartion of land, be applicable to implant mass paddy rice.But in the paddy fields of low temperature Han Qu, except there is the problems such as the loss that summer, chemical fertilizer caused due to reasons such as rainwater are many, temperature is high is serious, utilization ratio is low, also exist when planting spring, the problem of nutrient removal and paddy growth is unfavorable for because temperature is lower, if delay implantation time, subject to frost damage time then in the fall, this point becomes restriction low temperature and to tremble with fear the principal element of district's paddy growth and output.At present except adopting the required accumulated temperature kind that production phase is shorter less, the good production means and method is not had to go to overcome this limiting factor.
Summary of the invention
Technical problem to be solved by this invention is to provide a kind of paddy rice long-acting nitrogen fertilizer being applicable to low temperature Han Qu, this paddy rice long-acting nitrogen fertilizer can extend the fertilizer effectiveness phase, improve utilization rate of nitrogen fertilizer, more effectively can improve the temperature of soil and water layer in rice terrace after being manured into soil, be beneficial to rice seedling growth.
To achieve these goals, the present invention takes following technical scheme:
A kind of paddy rice long-acting nitrogen fertilizer being applicable to low temperature Han Qu, be made up by weight ratio of following raw material: 3,4-dimethyl pyrazole phosphoric acid salt 1.5 ~ 2 parts, Ulmic acids 250 ~ 300 parts, 400 ~ 500 parts, sulfuric acid, 350 ~ 400 parts, bicarbonate of ammonia, 500 ~ 550 parts, urea, 80 ~ 100 parts, nitrocalcite.
Preferably, the weight proportion of described raw material is: 3,4-dimethyl pyrazole phosphoric acid salt 1.8 parts, Ulmic acids 280 parts, 450 parts, sulfuric acid, 430 parts, bicarbonate of ammonia, 520 parts, urea, 90 parts, nitrocalcite.
The above-mentioned paddy rice long-acting nitrogen fertilizer being applicable to low temperature Han Qu is prepared as by the following method: first the Ulmic acids of described weight is crushed to more than 500 orders, urea is crushed to more than 200 orders; Then react in reactor Ulmic acids being joined the sulfuric acid that described weight is housed, after reaction terminating, urea is joined in reactor and continue reaction; Add the water that weight is mixture weight 20% in reactor after reaction terminating, after being cooled to room temperature, the bicarbonate of ammonia of described weight is joined in reactor and continue reaction; After reaction terminating, the nitrocalcite of described weight and 3,4-dimethyl pyrazole phosphoric acid salt are joined reactor, after stirring, material is imported granulator granulation and namely obtain the paddy rice long-acting nitrogen fertilizer that this is applicable to low temperature Han Qu.
Originally the paddy rice long-acting nitrogen fertilizer being applicable to low temperature Han Qu has following advantage: 1, the present invention utilizes sulfuric acid and tailing Ulmic acids to react, reduce Ulmic acids molecular weight, improve it active, fineness simultaneously more than 500 orders is also conducive to rapid diffusion in water body, one deck black layer can be formed bottom rice terrace water layer after being manured into soil, improve the absorption to sun power, effectively can improve the temperature of upper soll layer and water layer, for the quick growth of rice seedling provides more suitably temperature condition; The growing environment of rice seedling can be adjusted to micro-acid environment by the ureasulfuric acid that 2, this product contains, coordinate the nitric nitrogen that this product contains to promote that the seedling stage of paddy rice grows and tillers better simultaneously, reduce the pH of rice seedlings rhizosphere soil, the nutritive elements such as the phosphorus in activating soil simultaneously; 3, ureasulfuric acid slowly decomposes in paddy field, reduce the hydrolysis rate of urea, 3,4-dimethyl pyrazole phosphoric acid salt reduces the activity of nitrite bacteria, reduces nitrogen loss, and both synergies improve utilization ratio and the working lipe of nitrogen nutrient, decrease topdressing of later stage, save artificial, and the later stage is not de-fertile, improves output.This paddy rice long-acting nitrogen fertilizer production technique being applicable to low temperature Han Qu is simple, without the need to processing sequence and the expensive machine of complexity, is convenient to promote.
Embodiment
Embodiment 1 is applicable to the paddy rice long-acting nitrogen fertilizer formula 1 of low temperature Han Qu:
3,4-dimethyl pyrazole phosphoric acid salt 2 parts, Ulmic acids 300 parts, 500 parts, sulfuric acid, 350 parts, bicarbonate of ammonia, 500 parts, urea, 100 parts, nitrocalcite.
Embodiment 2 is applicable to the paddy rice long-acting nitrogen fertilizer formula 2 of low temperature Han Qu:
3,4-dimethyl pyrazole phosphoric acid salt 1.5 parts, Ulmic acids 250 parts, 400 parts, sulfuric acid, 400 parts, bicarbonate of ammonia, 550 parts, urea, 80 parts, nitrocalcite.
Embodiment 3 is applicable to the paddy rice long-acting nitrogen fertilizer formula 3 of low temperature Han Qu:
3,4-dimethyl pyrazole phosphoric acid salt 1.8 parts, Ulmic acids 280 parts, 450 parts, sulfuric acid, 430 parts, bicarbonate of ammonia, 520 parts, urea, 90 parts, nitrocalcite.
Embodiment 4 is applicable to the paddy rice long-acting nitrogen fertilizer formula 4 of low temperature Han Qu:
3,4-dimethyl pyrazole phosphoric acid salt 1.5 parts, Ulmic acids 300 parts, 480 parts, sulfuric acid, 360 parts, bicarbonate of ammonia, 525 parts, urea, 100 parts, nitrocalcite.
The preparation method of embodiment 5 embodiment 1-4
First the Ulmic acids of described weight is crushed to more than 500 orders in dry conditions, granular urea is crushed to more than 200 orders; Fineness is not less than 500 object Ulmic acidss to drop into and be equipped with in the reactor of sulfuric acid, stirs while adding, drop into complete stirring after 60 minutes to reaction terminating, fineness is not less than 200 object urea and puts in reactor, continue stirring 40 minutes; Slowly add the water of mixture weight 20% after reaction terminating, add while vigorous stirring, be down to after room temperature until temperature, the bicarbonate of ammonia of described weight is dropped in reactor, stirs while adding; Nitrocalcite and 3,4-dimethyl pyrazole phosphoric acid salt are added reactor, after stirring, material are imported granulator granulation and namely obtain the paddy rice long-acting nitrogen fertilizer that this is applicable to low temperature Han Qu after stopping by question response.
Embodiment 6 the present invention is to the result of use improving rice terrace earth's surface water layer temperature
1, proof test:
For embodiment 1, place is in Wuchang City of Heilongjiang Province.Rice terrace is applied as base fertilizer using after the potash fertilizer be applicable to needed for the paddy rice long-acting nitrogen fertilizer 20kg of low temperature Han Qu and peasant's conventional fertilizer application and phosphate fertilizer even blend.
2, simultaneous test:
Wuchang City of place Heilongjiang Province, condition is consistent with proof test.Rice terrace is applied as base fertilizer using after the potash fertilizer needed for 20kg urea and peasant's conventional fertilizer application and phosphate fertilizer even blend.
3, result:
Use chemical fertilizer measures rice terrace on two in the afternoon water layer temperature after 10 days, the water layer temperature of proof test is 13.4 DEG C, and simultaneous test water layer temperature is 11.7 DEG C.After showing to use this paddy rice long-acting nitrogen fertilizer, improve the earth's surface water layer temperature of rice terrace, for paddy growth provides better temperature condition.
The result of use that embodiment 7 the present invention promotes rice seedlings to grow fast
1, proof test:
For embodiment 2, place is at Jilin Province's Yanji, and in the rice striking root phase, this paddy rice long-acting nitrogen fertilizer of 15kg is applied rice terrace as dressing of turnning green stage, the later stage no longer imposes other fertilizer.
2, simultaneous test:
Place is at Jilin Province's Yanji, and condition is consistent with proof test, in the rice striking root phase, the ammonium sulfate of 25kg is applied rice terrace as dressing of turnning green stage, and the later stage no longer imposes other fertilizer.
3, result:
Apply fertilizer after 15 days, the plant height of observation water rice seedling and tillering: the average plant height 23.0cm of proof test rice seedlings 20 strain, the average plant height 20.4cm of simultaneous test rice seedlings 20 strain; Proof test paddy rice 20 strain the mean tillering number 7.6, simultaneous test paddy rice 20 strain the mean tillering number 7.1.Illustrate that this paddy rice long-acting nitrogen fertilizer has unusual effect for the growth of raising rice seedling and initial stage effective tillering.
Embodiment 8 the present invention is to the result of use extending the fertilizer effectiveness phase
1, proof test:
For embodiment 3, place is in Inner Mongolia Autonomous Region Chifeng City, and paddy rice long-acting nitrogen fertilizer 18kg being applicable to low temperature Han Qu applies rice terrace as dressing of turnning green stage, and the later stage no longer uses other fertilizer.
2, simultaneous test:
Place is in Inner Mongolia Autonomous Region Chifeng City, and condition is consistent with proof test, and 20kg urea is applied rice terrace as dressing of turnning green stage, treats that boot stage uses 8kg urea again.
3, result:
When rice harves, proof test plot rice leaf still greening, not de-fertile phenomenon, there is yellow in paddy rice top, simultaneous test plot leaf, starts de-fertile.Show that this paddy rice long-acting nitrogen fertilizer has longer fertilizer efficiency period than common urea.
Embodiment 9 the present invention is to the result of use improving rice yield
1, proof test:
For embodiment 4, place is at Liaoning Province's Panjin City, and paddy rice long-acting nitrogen fertilizer 20kg being applicable to low temperature Han Qu applies rice terrace as dressing of turnning green stage, and the later stage no longer uses other fertilizer.
3, simultaneous test:
Place is at Liaoning Province's Panjin City, and condition is consistent with proof test, and 25kg urea is applied rice terrace as dressing of turnning green stage, and the later stage no longer imposes other fertilizer.
3, result:
During rice harves, the thousand seed weight measuring proof test is higher than simultaneous test by 1.3%, and the average grain number per spike of 150 fringe many 1.7%, 50 strain average effective tiller number many 4.3%, actual output is high by 6.8%.
More than test shows, this utilization ratio and rice yield that paddy rice long-acting nitrogen fertilizer is improving rice seedling soil layer and water layer temperature and rice terrace later stage nitrogenous fertilizer being applicable to low temperature Han Qu has obvious effect.
Claims (3)
1. one kind is applicable to the paddy rice long-acting nitrogen fertilizer of low temperature Han Qu, be made up by weight ratio of following raw material: 3,4-dimethyl pyrazole phosphoric acid salt 1.5 ~ 2 parts, Ulmic acids 250 ~ 300 parts, 400 ~ 500 parts, sulfuric acid, 350 ~ 400 parts, bicarbonate of ammonia, 500 ~ 550 parts, urea, 80 ~ 100 parts, nitrocalcite.
2. the paddy rice long-acting nitrogen fertilizer being applicable to low temperature Han Qu according to claim 1, it is characterized in that the weight proportion of described raw material is: 3,4-dimethyl pyrazole phosphoric acid salt 1.8 parts, Ulmic acids 280 parts, 450 parts, sulfuric acid, 430 parts, bicarbonate of ammonia, 520 parts, urea, 90 parts, nitrocalcite.
3. the paddy rice long-acting nitrogen fertilizer being applicable to low temperature Han Qu according to claim 1 and 2, is characterized in that preparing by the following method: first the Ulmic acids of described weight is crushed to more than 500 orders, urea is crushed to more than 200 orders; Then react in reactor Ulmic acids being joined the sulfuric acid that described weight is housed, after reaction terminating, urea is joined in reactor and continue reaction; Add the water that weight is mixture weight 20% in reactor after reaction terminating, after being cooled to room temperature, the bicarbonate of ammonia of described weight is joined in reactor and continue reaction; After reaction terminating, the nitrocalcite of described weight and 3,4-dimethyl pyrazole phosphoric acid salt are joined reactor, after stirring, material is imported granulator granulation and namely obtain the paddy rice long-acting nitrogen fertilizer that this is applicable to low temperature Han Qu.
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CN111116259A (en) * | 2019-12-13 | 2020-05-08 | 沈阳农业大学 | Stable fertilizer and preparation method thereof |
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AU2006207886A1 (en) * | 2005-09-27 | 2007-04-19 | John Pashai | Fertiliser |
CN103073364A (en) * | 2013-01-21 | 2013-05-01 | 山东普金肥料有限公司 | Long-acting humic acid compound fertilizer and production method thereof |
CN103193548A (en) * | 2013-05-03 | 2013-07-10 | 辽宁施壮肥业有限公司 | Organic-inorganic multi-element pollution-free compound fertilizer and preparation method thereof |
CN103936493A (en) * | 2013-01-21 | 2014-07-23 | 河北农业大学 | Novel sustained-release long-acting compound fertilizer and preparation method thereof |
CN104671985A (en) * | 2015-01-26 | 2015-06-03 | 张彬 | Tower type melt granulation stable nitrogen fertilizer and preparation method |
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Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
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AU2006207886A1 (en) * | 2005-09-27 | 2007-04-19 | John Pashai | Fertiliser |
CN103073364A (en) * | 2013-01-21 | 2013-05-01 | 山东普金肥料有限公司 | Long-acting humic acid compound fertilizer and production method thereof |
CN103936493A (en) * | 2013-01-21 | 2014-07-23 | 河北农业大学 | Novel sustained-release long-acting compound fertilizer and preparation method thereof |
CN103193548A (en) * | 2013-05-03 | 2013-07-10 | 辽宁施壮肥业有限公司 | Organic-inorganic multi-element pollution-free compound fertilizer and preparation method thereof |
CN104671985A (en) * | 2015-01-26 | 2015-06-03 | 张彬 | Tower type melt granulation stable nitrogen fertilizer and preparation method |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN111116259A (en) * | 2019-12-13 | 2020-05-08 | 沈阳农业大学 | Stable fertilizer and preparation method thereof |
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