CN105295273A - Film-forming composition and kit containing same - Google Patents
Film-forming composition and kit containing same Download PDFInfo
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- CN105295273A CN105295273A CN201510287375.5A CN201510287375A CN105295273A CN 105295273 A CN105295273 A CN 105295273A CN 201510287375 A CN201510287375 A CN 201510287375A CN 105295273 A CN105295273 A CN 105295273A
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- 239000000203 mixture Substances 0.000 title claims abstract description 123
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 44
- 229920000098 polyolefin Polymers 0.000 claims abstract description 17
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 30
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 26
- 229920001577 copolymer Polymers 0.000 claims description 26
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 25
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 25
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 23
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 20
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 20
- 239000000049 pigment Substances 0.000 claims description 18
- 239000003960 organic solvent Substances 0.000 claims description 16
- 150000001875 compounds Chemical class 0.000 claims description 15
- 229920002554 vinyl polymer Polymers 0.000 claims description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 235000013162 Cocos nucifera Nutrition 0.000 claims description 9
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 9
- 229940097411 palm acid Drugs 0.000 claims description 9
- 230000002087 whitening effect Effects 0.000 claims description 8
- 239000000976 ink Substances 0.000 claims description 7
- 238000007639 printing Methods 0.000 claims description 7
- 239000000080 wetting agent Substances 0.000 claims description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 6
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 claims description 6
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 6
- 229920001285 xanthan gum Polymers 0.000 claims description 5
- 244000215068 Acacia senegal Species 0.000 claims description 4
- 229920001817 Agar Polymers 0.000 claims description 4
- 239000004375 Dextrin Substances 0.000 claims description 4
- 229920001353 Dextrin Polymers 0.000 claims description 4
- 108010010803 Gelatin Proteins 0.000 claims description 4
- 229920000084 Gum arabic Polymers 0.000 claims description 4
- 229920002472 Starch Polymers 0.000 claims description 4
- 229920002494 Zein Polymers 0.000 claims description 4
- 235000010489 acacia gum Nutrition 0.000 claims description 4
- 239000000205 acacia gum Substances 0.000 claims description 4
- 239000008272 agar Substances 0.000 claims description 4
- 235000010419 agar Nutrition 0.000 claims description 4
- 238000006136 alcoholysis reaction Methods 0.000 claims description 4
- 239000001913 cellulose Substances 0.000 claims description 4
- 229920002678 cellulose Polymers 0.000 claims description 4
- 235000019425 dextrin Nutrition 0.000 claims description 4
- 239000008273 gelatin Substances 0.000 claims description 4
- 229920000159 gelatin Polymers 0.000 claims description 4
- 235000019322 gelatine Nutrition 0.000 claims description 4
- 235000011852 gelatine desserts Nutrition 0.000 claims description 4
- 235000019698 starch Nutrition 0.000 claims description 4
- 239000008107 starch Substances 0.000 claims description 4
- 235000010493 xanthan gum Nutrition 0.000 claims description 4
- 239000000230 xanthan gum Substances 0.000 claims description 4
- 229940082509 xanthan gum Drugs 0.000 claims description 4
- 239000005019 zein Substances 0.000 claims description 4
- 229940093612 zein Drugs 0.000 claims description 4
- BLSQLHNBWJLIBQ-OZXSUGGESA-N (2R,4S)-terconazole Chemical compound C1CN(C(C)C)CCN1C(C=C1)=CC=C1OC[C@@H]1O[C@@](CN2N=CN=C2)(C=2C(=CC(Cl)=CC=2)Cl)OC1 BLSQLHNBWJLIBQ-OZXSUGGESA-N 0.000 claims description 3
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 3
- 229920013701 VORANOL™ Polymers 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- BXOUVIIITJXIKB-UHFFFAOYSA-N ethene;styrene Chemical group C=C.C=CC1=CC=CC=C1 BXOUVIIITJXIKB-UHFFFAOYSA-N 0.000 claims description 3
- 229940089256 fungistat Drugs 0.000 claims description 3
- 235000013847 iso-butane Nutrition 0.000 claims description 3
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 claims description 3
- 150000002632 lipids Chemical class 0.000 claims description 3
- 239000004800 polyvinyl chloride Substances 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- IJDNQMDRQITEOD-UHFFFAOYSA-N sec-butylidene Natural products CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 235000002639 sodium chloride Nutrition 0.000 claims description 3
- 239000000516 sunscreening agent Substances 0.000 claims description 3
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 2
- 244000060011 Cocos nucifera Species 0.000 claims 1
- 239000000126 substance Substances 0.000 abstract description 9
- 239000004094 surface-active agent Substances 0.000 abstract 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 16
- 239000000463 material Substances 0.000 description 9
- 241000737241 Cocos Species 0.000 description 8
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 229920006243 acrylic copolymer Polymers 0.000 description 6
- 230000003796 beauty Effects 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 230000003712 anti-aging effect Effects 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 150000002148 esters Chemical class 0.000 description 4
- 239000003292 glue Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 229920001206 natural gum Polymers 0.000 description 4
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 3
- 238000013019 agitation Methods 0.000 description 3
- 239000000084 colloidal system Substances 0.000 description 3
- 229920002674 hyaluronan Polymers 0.000 description 3
- 238000012423 maintenance Methods 0.000 description 3
- 230000003020 moisturizing effect Effects 0.000 description 3
- 230000001737 promoting effect Effects 0.000 description 3
- KIUKXJAPPMFGSW-DNGZLQJQSA-N (2S,3S,4S,5R,6R)-6-[(2S,3R,4R,5S,6R)-3-Acetamido-2-[(2S,3S,4R,5R,6R)-6-[(2R,3R,4R,5S,6R)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2-carboxylic acid Chemical compound CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 KIUKXJAPPMFGSW-DNGZLQJQSA-N 0.000 description 2
- 229920002527 Glycogen Polymers 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 235000010418 carrageenan Nutrition 0.000 description 2
- 229920001525 carrageenan Polymers 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 229940096919 glycogen Drugs 0.000 description 2
- 229960003160 hyaluronic acid Drugs 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229960004063 propylene glycol Drugs 0.000 description 2
- 235000013772 propylene glycol Nutrition 0.000 description 2
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- 229920002101 Chitin Polymers 0.000 description 1
- 229920002148 Gellan gum Polymers 0.000 description 1
- 229920000161 Locust bean gum Polymers 0.000 description 1
- 101000611641 Rattus norvegicus Protein phosphatase 1 regulatory subunit 15A Proteins 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000000679 carrageenan Substances 0.000 description 1
- 229940113118 carrageenan Drugs 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 235000010492 gellan gum Nutrition 0.000 description 1
- 239000000216 gellan gum Substances 0.000 description 1
- 229940074047 glyceryl cocoate Drugs 0.000 description 1
- KIUKXJAPPMFGSW-MNSSHETKSA-N hyaluronan Chemical compound CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)C1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H](C(O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 KIUKXJAPPMFGSW-MNSSHETKSA-N 0.000 description 1
- 229940099552 hyaluronan Drugs 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- 235000013980 iron oxide Nutrition 0.000 description 1
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 description 1
- 235000010420 locust bean gum Nutrition 0.000 description 1
- 239000000711 locust bean gum Substances 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
Abstract
The invention provides a film-forming composition and a kit containing the same. The film-forming composition comprises polyolefin, a film-forming agent and a surfactant in a specific ratio. The film-forming composition of the present invention has excellent film-forming speed and strength, and thus can be used as a medium for transferring a substance to a surface of a user.
Description
Technical field
The present invention, about a kind of film-forming composition and the cover group containing it, refers in particular to a kind of film-forming composition be made up of several polymers and the cover group containing it.
Background technology
The use of colloid is very common in cosmetics.The natural gum that in field, known many kinds of bio-compatibilities are high, such as: carrageenin (Carrageenan), Xanthan gum (XanthamGum), Viscogum BE (LocustBeanGum), tie blue glue (GellanGum), sodium alginate, Amorphophalus rivieri powder, gelatin, gum arabic, agar, dextrin, zein, β Portugal gather candy, starch, glycogen (glycogen), Mierocrystalline cellulose (Hydroxycellulose), hyaluronic acid (Hyaluronan, hyaluronicacid), chitin (Chitn) etc.These natural gums are widely used in due to the bio-compatibility of its excellence in the purposes of multiple medicine or beauty treatment as carrier or base material.
Although these natural gums have many similar characteristics, still have sizable difference.Therefore according to different application, certainly will need therefrom to select, combine and adjust optimum proportioning to meet demand.In today of 21 century, beauty treatment is no longer only the patent of woman.Modern society impels beauty treatment industry to weed out the old and bring forth the new for the attention of beauty treatment, and has more demand for high-quality beauty treatment material.In view of the foregoing, be badly in need of in this area a kind of by natural gum form and have the colloidal materials of excellent durability.
Summary of the invention
So one object of the present invention is to provide one for film-forming composition in beauty treatment, and its film forming time is short, and the film formed has reliable intensity.
Another object of the present invention is to provide a kind of cover group, and it comprises aforementioned film-forming composition, and is able to desired substance (as pigment, whitening, the material such as anti-aging) to be transferred to equably with it user.
In order to reach aforementioned object, the invention provides a kind of film-forming composition, it comprises: the polyolefine of 5 to 25 weight percents; The membrane-forming agent of 2 to 10 weight percents; The interfacial agent of 2 to 10 weight percents; The polyvalent alcohol of 5 to 40 weight percents; And account for the water of all the other weight percents; Wherein aforementioned weight per-cent is based on the gross weight of aforementioned film-forming composition.
In film-forming composition provided by the invention, preferably, aforementioned polyolefins is polyvinyl compound.Preferably, aforementioned polyvinyl compound comprises: polyvinyl alcohol (polyvinylalcohol, PVA), polyvinylpyrrolidone (polyvinylpyrrolidone, PVP), polyvinyl chloride (PVC), V-Pyrol RC/vinyl acetate copolymer (vinylpyrrolidone/vinylacetatecopolymer; VP/VAcopolymer), polyvinylpyrrolidone//vinyl acetate copolymer (polyvinylpyrrolidone/vinylacetatecopolymer, PVP/VAcopolymer) or its combination.
In film-forming composition provided by the invention, preferably, the weight average molecular weight of aforementioned polyvinyl compound is 2.5 ten thousand to 360 ten thousand.Preferably, the basicity of aforementioned polyvinyl compound is 82 to 99mol%.Preferably, the alcoholysis degree of aforementioned polyvinyl compound is 78 to 100mol%.Preferably, the viscosity of aforementioned polyvinyl compound is 3 to 95cps.
In film-forming composition provided by the invention, preferred, aforementioned polyvinyl compound comprises: polyvinyl alcohol and polyvinylpyrrolidone; Wherein the weight ratio of aforementioned polyvinyl alcohol and aforementioned polyvinylpyrrolidone is: 0.3 to 2.
In film-forming composition provided by the invention, preferably, aforementioned membrane-forming agent comprises: acrylate copolymer (acrylatescopolymer), Xanthan gum, gelatin, gum arabic, agar, Lalgine or its salt, starch, dextrin, zein, derivatived cellulose or its combination.Preferably, foregoing acrylates multipolymer comprises: methacrylic acid/acrylamido methylpropane base sodium sulfonate copolymers, acrylate/ethylhexyl acrylate multipolymer, phenylethylene ethylene/propenoic acid ester copolymer or its combination.
In film-forming composition provided by the invention, preferably, foregoing interface promoting agent comprises: the lipid acid of coconut palm acid glycerol (glycerylcocoate), Voranol EP 2001, polyvalent alcohol or its combination.
In film-forming composition provided by the invention, preferably, aforementioned film-forming composition comprises the organic solvent of 5 to 40 weight percents further; Wherein aforementioned weight per-cent is based on the gross weight of aforementioned film-forming composition.Preferably, aforementioned organic solvents comprises: methyl alcohol, ethanol, propyl alcohol or its combination.
In film-forming composition provided by the invention, preferably, aforementioned film-forming composition comprises the pigment of 0.001 to 1.0 weight percent, sanitas, fungistat, essence, wetting Agent for Printing Inks, whitening agent, sour agent, sun-screening agent or its combination further; Wherein aforementioned weight per-cent is based on the gross weight of aforementioned film-forming composition.Preferably, aforementioned wetting Agent for Printing Inks is polyvalent alcohol.
In film-forming composition provided by the invention, preferably, aforementioned film-forming composition, it comprises: the polyvinyl alcohol of 2 to 12 weight percents; The polyvinylpyrrolidone of 3 to 13 weight percents; The acrylate copolymer of 2 to 10 weight percents; The interfacial agent of 2 to 10 weight percents; The organic solvent of 5 to 40 weight percents; And account for the water of all the other weight percents; Wherein aforementioned weight per-cent is based on the gross weight of aforementioned film-forming composition.
The invention provides another cover group, it comprises: container; And be placed in the foregoing film-forming composition of aforesaid receptacle.
In cover group provided by the invention, preferably, aforesaid receptacle is flexible pipe, box or bottle.
In sum, film-forming composition of the present invention may be quickly formed film with it user, thus the desired substance in composition (as pigment, whitening, the material such as anti-aging) is evenly passed to it user.In addition, the film that film-forming composition of the present invention is formed has reliable intensity, therefore user can easily by this film from removing with it.
Accompanying drawing explanation
An embodiment and the use procedure thereof of what Figure 1A represented is film-forming composition of the present invention.
The process of what Figure 1B represented the is film that the film-forming composition taking off Figure 1A is formed.
Another embodiment and the use procedure thereof of what Fig. 2 A represented is film-forming composition of the present invention.
The process of what Fig. 2 B represented the is film that the film-forming composition taking off Fig. 2 A is formed.
Nomenclature
10 flexible pipes
20 film-forming compositions
30 lips
40 films
50 nails
Embodiment
The present invention, about a kind of film-forming composition be made up of polymkeric substance, can form the film of sufficient intensity rapidly from the teeth outwards.Although there is many film-forming compositions be made up of polymkeric substance in this area, these film-forming compositions have often had that film formation time is long and/or the film strength that formed not enough and have been difficult to the shortcoming removed on the surface from this.The present invention specifically finds out suitable combination of polymers and proportioning thereof, and these suitable polymkeric substance, under specific proportioning, can be worked in coordination with out excellent crosslinking reaction, thus reach the moderate advantage of film formation time film strength that is short and that formed.
In a scheme of the present invention, the invention provides a kind of 3 composition film-forming compositions, it comprises: the polyolefine of 5 to 25 weight percents; The membrane-forming agent of 2 to 10 weight percents; The interfacial agent of 2 to 10 weight percents; And account for the water of all the other weight percents; Wherein aforementioned weight per-cent is based on the gross weight of aforementioned film-forming composition." 3 composition film-forming composition " of the present invention refers in said composition containing 3 kinds of main components.This word is conducive to the characteristic of the sample comparing different ratio in the description of the present invention, and and only containing 3 kinds of compositions in non-limiting said composition.For example, in aforementioned schemes of the present invention, aforementioned 3 compositions are polyolefine, membrane-forming agent and interfacial agent.
Though can not be limited by any theory, aforementioned polyolefins in film-forming composition of the present invention mainly as thickening material.In a preferred embodiment, aforementioned polyolefins comprises: polyvinyl alcohol, polyvinylpyrrolidone, polyvinyl chloride, V-Pyrol RC/vinyl acetate copolymer, polyvinylpyrrolidone//vinyl acetate copolymer or its combination.In a preferred embodiment, film-forming composition of the present invention comprises two or more aforementioned polyolefins.In a preferred embodiment, aforementioned polyvinyl compound meets at least one in following condition: weight average molecular weight is 2.5 ten thousand to 360 ten thousand, basicity is 82 to 99mol%, alcoholysis degree is 78 to 100mol% or under room temperature, viscosity is 3 to 95cps.
In preferred embodiment, aforementioned polyolefins is the combination of polyvinyl alcohol and polyvinylpyrrolidone; Preferably, the weight ratio of aforementioned polyvinyl alcohol and aforementioned polyvinylpyrrolidone is 0.3 to 2.In preferred embodiment, aforementioned polyvinyl alcohol meets at least one in following condition: weight average molecular weight is 2.5 ten thousand to 3.5 ten thousand, basicity is 86 to 89mol%, alcoholysis degree is 86.5 to 89mol% or under room temperature, viscosity is 4.6 to 6cps; And/or aforementioned polyvinylpyrrolidone meets at least one in following condition: weight average molecular weight is 100 ten thousand to 360 ten thousand.
In a preferred embodiment, aforementioned membrane-forming agent comprises: acrylate copolymer, Xanthan gum, gelatin, gum arabic, agar, Lalgine or its salt, starch, dextrin, zein, derivatived cellulose or its combination.In preferred embodiment, aforementioned membrane-forming agent is acrylate copolymer.Foregoing acrylates multipolymer is such as, but not limited to: methacrylic acid/acrylamido methylpropane base sodium sulfonate copolymers, acrylate/ethylhexyl acrylate multipolymer, phenylethylene ethylene/propenoic acid ester copolymer or its combination.Feasiblely, foregoing acrylates multipolymer adopts obtainable acrylate copolymer product on market, such as but not limited to: DAITOSOL5000AD, DAITOSOL5000SJ, DAITOSOL4000SJT, DAITOSOL5000STY or DAITOSOL3000VP3.
In feasible embodiment, foregoing interface promoting agent comprises: the lipid acid of coconut palm acid glycerol, Voranol EP 2001, polyvalent alcohol or its combination.Aforementioned coconut palm acid glycerol such as, but not limited to: PEG-7, PEG-3, PEG-80 or its combination.
In another scheme of the present invention, the invention provides a kind of 4 composition film-forming compositions, namely comprise the organic solvent of 5 to 40 weight percents at aforementioned 3 composition film-forming compositions further; Wherein aforementioned weight per-cent is based on the gross weight of aforementioned film-forming composition.Though can not be limited by any theory, aforementioned organic solvents contributes to promoting film forming speed.But one of ordinary skill in the art should be appreciated that and add the proportioning that aforementioned organic solvents still must notice various composition in film-forming composition of the present invention.
Preferably, aforementioned organic solvents comprises: methyl alcohol, ethanol, propyl alcohol or its combination." 4 composition film-forming composition " of the present invention refers in said composition containing 4 kinds of main components.This word is conducive to the characteristic of the sample comparing different ratio in the description of the present invention, and and only containing 4 kinds of compositions in non-limiting said composition.For example, in aforementioned schemes of the present invention, aforementioned 4 compositions are polyolefine, membrane-forming agent, interfacial agent and organic solvent.
In a preferred embodiment, aforementioned film-forming composition comprises: the polyvinyl alcohol of 2 to 12 weight percents; The polyvinylpyrrolidone of 3 to 13 weight percents; The acrylate copolymer of 2 to 10 weight percents; The interfacial agent of 2 to 10 weight percents; The organic solvent of 5 to 40 weight percents; And account for the water of all the other weight percents; Wherein aforementioned weight per-cent is based on the gross weight of aforementioned film-forming composition.Feasiblely, the various compositions in aforementioned film-forming composition can use commercial obtainable product.According to disclosure of the present invention, one of ordinary skill in the art by day to day tests commercially obtainable product mix go out film-forming composition of the present invention.
In feasible embodiment, film-forming composition of the present invention can be considered a kind of carrier.Pigment, whitening, maintenance (as moisturizing, anti-aging etc.) or other desired substances are added further, the film formed by film-forming composition of the present invention and being passed to by aforementioned desired substance with it user in film-forming composition of the present invention.Therefore, in feasible embodiment, film-forming composition of the present invention can comprise further 0.001 to 1 weight percent pigment (such as but not limited to, edible red No. 6 or edible red No. 8), sanitas, fungistat, essence, wetting Agent for Printing Inks, whitening agent, sour agent, sun-screening agent or its combination; Wherein aforementioned weight per-cent is based on the gross weight of aforementioned film-forming composition.Aforementioned wetting Agent for Printing Inks is such as but not limited to polyvalent alcohol.Feasiblely, foregoing polyols is such as, but not limited to propylene glycol, butyl cellosolve, glycerol or its combination.Aforementioned pigment is such as, but not limited to organic pigment, mineral-type pigment, iron oxides pigment or its combination.
In another scheme of the present invention, the invention provides a kind of cover group, it comprises container; And be placed in the foregoing film-forming composition of aforesaid receptacle.In feasible embodiment, aforesaid receptacle is flexible pipe, box or bottle.
Please refer to Figure 1A and Figure 1B, in embodiment shown in the figure, cover group of the present invention comprises flexible pipe 10 and is placed in the film-forming composition of the present invention 20 of aforementioned flexible pipe 10; Wherein contain pigment in aforementioned film-forming composition 20.In use, aforementioned film-forming composition 20 can be extruded by user in aforementioned flexible pipe 10, and coordinates the shape of lip 30, is applied in equably on lip 30 by aforementioned film-forming composition 20.After in due course, aforementioned film-forming composition 20 can form film 40 (Figure 1A) on lip 30.Pigment in aforementioned film-forming composition 20 to be added is passed to after on aforementioned lip 30 smoothly, and aforementioned film 40 just can take off (Figure 1B) by user on aforementioned lip 30.Therefore, film-forming composition of the present invention can be considered that a kind of pigment of marrying again is to the medium on user's lip.
Please refer to Fig. 2 A and Fig. 2 B again, in embodiment shown in the figure, cover group of the present invention comprises flexible pipe 10 and is placed in the film-forming composition of the present invention 20 of aforementioned flexible pipe 10; Wherein contain pigment in aforementioned film-forming composition 20.In use, aforementioned film-forming composition 20 can be extruded by user in aforementioned flexible pipe 10, and coordinates the shape of nail 50, is applied in equably on nail 50 by aforementioned film-forming composition 20.After in due course, aforementioned film-forming composition 20 can form film 40 (Fig. 2 A) on nail 50.Pigment in aforementioned film-forming composition 20 to be added is passed to after on previous nail 50 smoothly, and aforementioned film 40 just can take off (Fig. 2 B) by user on previous nail 50.Therefore, film-forming composition of the present invention can be considered that a kind of pigment of marrying again is to the medium on user's nail.
Embodiment 1: the preparation of 3 component glues of the present invention and Nature comparison.
The present embodiment is attempted being prepared into film composition with 3 different composition proportion.The composition proportion of the sample of the present embodiment is as shown in the table, and in each form, notes down the film forming speed of each sample and remove easness (appraising through comparison according to following table 1).In the present embodiment, polyolefine adopts commercially available prod: PVA205 (polyvinyl alcohol) and PVPK-90 (polyvinylpyrrolidone).According to the description of product, the weight average molecular weight of PVA205 is: 2.7 ten thousand-3.5 ten thousand, and basicity is: 86-89, and under room temperature, viscosity is 5-6; The weight average molecular weight of PVPK-90 is: 3,600,000.
In the present embodiment, membrane-forming agent adopts commercially available prod Fixomer
tMa-30Polymer (Lubrizol, according to its operation instruction, this product comprises: methyl acrylate-methyl acrylic copolymer) and/or commercially available prod
aquaSF-1Polymer (Lubrizol, according to its operation instruction, this product comprises: vinylformic acid (ester) analog copolymer).Interfacial agent adopts commercially available prod
gC (PEG-7 coconut palm acid glycerol).
In preparation, according to the proportioning in form, polyolefine and membrane-forming agent are dissolved in deionized water at the temperature of about 80 to 100 DEG C.Then, at the temperature of about 50 to 75 DEG C, add interfacial agent, and Keep agitation makes all the components uniform dissolution, the sample of obtained the present embodiment.
Table 1: film forming speed and remove easness comparation and assessment table
Table 2: the proportioning of sample 1-1,1-2,1-3,1-4 and 1-5 and characteristic
| Sample | 1-1 | 1-2 | 1-3 | 1-4 | 1-5 |
| Polyvinyl alcohol | 3.00 | 4.00 | 5.00 | 6.00 | 8.00 |
| Polyvinylpyrrolidone | 8.00 | 8.00 | 8.00 | 8.00 | 8.00 |
| Membrane-forming agent-methyl acrylate-methyl acrylic copolymer | 5.00 | 5.00 | 5.00 | 5.00 | 5.00 |
| PEG-7 coconut palm acid glycerol | 3.00 | 3.00 | 3.00 | 3.00 | 3.00 |
| Water | 81.00 | 80.00 | 79.00 | 78.00 | 76.00 |
| Film forming speed | Can | Can | Can | Good | Good |
| Remove easness | Can | Can | Can | Good | Good |
Table 3: the proportioning of sample 2-1,2-2,2-3,2-4 and 2-5 and characteristic
Table 4: the proportioning of sample 3-1,3-2,3-3,3-4 and 3-5 and characteristic
Table 5: the proportioning of sample 4-1,4-2,4-3,4-4 and 4-5 and characteristic
Table 6: the proportioning of sample 5-1,5-2,5-3,5-4 and 5-5 and characteristic
By the better content range of each composition in the known 3 composition samples of the present invention of previous experiments data.In addition, according to above-mentioned experimental result, 3 composition samples of the present invention have had good film forming speed and have removed easness.
Embodiment 2: the preparation of 4 component glues of the present invention and Nature comparison.
The present embodiment is attempted being prepared into film composition with 4 different composition proportion, and attempts adding the materials such as pigment, whitening, maintenance (as moisturizing, anti-aging etc.).The composition proportion of the sample of the present embodiment is as shown in the table, and in each form, notes down the film forming speed of each sample and remove easness (appraising through comparison according to upper table 1).In the present embodiment, polyolefine adopts commercially available prod: PVA205 (polyvinyl alcohol) and PVPK-90 (polyvinylpyrrolidone).Membrane-forming agent adopts commercially available prod Fixomer
tMa-30Polymer (Lubrizol, according to its operation instruction, this product comprises: methyl acrylate-methyl acrylic copolymer) and/or commercially available prod EPITEX
tM66 (DowHome, InstitutionalandPersonalCareSolutions, according to its operation instruction, this product comprises: vinylformic acid (ester) analog copolymer).Interfacial agent adopts commercially available prod Chemonic
tMlI-7Surfactant (Lubrizol, PEG-7 coconut palm acid glycerol).Organic solvent adopts alcohol (95%).Adopt polyvalent alcohol as wetting Agent for Printing Inks in the present embodiment.
In preparation, according to the proportioning in form, polyolefine and membrane-forming agent are dissolved in deionized water at the temperature of about 80 to 100 DEG C.Then, at the temperature of about 50 to 75 DEG C, add interfacial agent and organic solvent, and Keep agitation makes all the components uniform dissolution i.e. sample of obtained the present embodiment.In the sample adding polyvalent alcohol, after interpolation interfacial agent and organic solvent, add polyvalent alcohol further, and Keep agitation makes all the components fully dissolve and mix.
Table 7: the proportioning of sample 6-1,6-2,6-3,6-4 and 6-5 and characteristic
Table 8: the proportioning of sample 7-1,7-2,7-3,7-4 and 7-5 and characteristic
Table 9: the proportioning of sample 8-1,8-2,8-3,8-4 and 8-5 and characteristic
| Sample | 8-1 | 8-2 | 8-3 | 8-4 | 8-5 |
| Polyvinyl alcohol | 6.00 | 6.00 | 6.00 | 6.00 | 6.00 |
| Polyvinylpyrrolidone | 8.00 | 8.00 | 8.00 | 8.00 | 8.00 |
| Membrane-forming agent 1-methyl acrylate-methyl | 5.00 | 5.00 | 5.00 | 5.00 | 5.00 |
| Acrylic copolymer | |||||
| Membrane-forming agent 2-vinylformic acid (ester) analog copolymer | 3.00 | 3.00 | 3.00 | 3.00 | 3.00 |
| PEG-7 coconut palm acid glycerol | 3.00 | 3.00 | 3.00 | 3.00 | 3.00 |
| Alcohol | 15.00 | 15.00 | 15.00 | 15.00 | 15.00 |
| Red No. 8 | 0.0001 | 0.0010 | 0.0100 | 0.1000 | 1.0000 |
| Polyvalent alcohol | 5.00 | 5.00 | 5.00 | 5.00 | 5.00 |
| Water | 54.9999 | 54.9990 | 54.9900 | 54.9000 | 54.0000 |
| Film forming speed | Good | Good | Good | Good | Good |
| Remove easness | Good | Good | Good | Good | Good |
| Film forming brightness | Good | Good | Good | Good | Good |
From above-mentioned data, adding alcohol can promote film forming speed, and does not affect the film forming speed of sample of the present invention after adding polyvalent alcohol and/or pigment further and remove easness.In other words, according to the demand in cosmetology, can using sample of the present invention as the medium married again, in sample of the present invention, add the materials such as required pigment, whitening, maintenance (as moisturizing, anti-aging etc.), be beneficial to these materials to be passed to equably on the skin of user.
Embodiment three: the preparation of colloid of the present invention and Nature comparison.
Based on the known 3 component glues character that tool is pretty good of the present invention of previous experiments content, and 4 compositions tested further and 5 compositions are at film forming speed and remove on easness and also have lifting.The present embodiment will test membrane-forming agent and interfacial agent further for film forming speed and the impact removing easness.
As shown in the table in the composition proportion of the sample of the present embodiment, and note down the film forming speed of each sample in the table and remove easness (appraising through comparison according to upper table 1).In the present embodiment, polyolefine adopts commercially available prod: PVA205 (polyvinyl alcohol) and PVPK-90 (polyvinylpyrrolidone).Membrane-forming agent adopts commercially available prod
aquaSF-1OSPolymer (Lubrizol, according to its operation instruction, this product comprises: methyl acrylate-methyl acrylic copolymer) and/or commercially available prod EPITEX
tM66 (DowHome, InstitutionalandPersonalCareSolutions, according to its operation instruction, this product comprises: vinylformic acid (ester) analog copolymer).Interfacial agent adopts commercially available prod
hE (the husky rope performance chemicals of SasolPerformanceChemicals, PEG-7 coconut palm acid glycerol).Organic solvent adopts alcohol (95%).Polyvalent alcohol adopts PropyleneGlycol.
Table 10: the proportioning of sample 9-1,9-2,9-3,9-4,9-5,9-6,9-7 and 9-8 and characteristic
From afore-mentioned test, in the present embodiment, two kinds of membrane-forming agents (methyl acrylate-methyl acrylic copolymer and acrylic acid esters co-polymer) used select any one under test content, all contribute to the lifting of film forming speed.Interfacial agent then contributes to stable bond between each composition, makes it remove and is more prone to, and not easily remains in the skin of user, also not easily produces pain.
After a large amount of test, the present embodiment tests out the proper ratio scope of each composition of colloid of the present invention respectively, and list respectively preferably embodiment as shown in aforementioned table 2 to table 10.Shown in these forms, sample all has suitable film forming speed and removes easness.
Claims (18)
1. a film-forming composition, it comprises:
The polyolefine of 5 to 25 weight percents;
The membrane-forming agent of 2 to 10 weight percents;
The interfacial agent of 2 to 10 weight percents; And
Account for the water of all the other weight percents;
Wherein, described weight percent is based on the gross weight of described film-forming composition.
2. film-forming composition as claimed in claim 1, wherein, described polyolefine is polyvinyl compound.
3. film-forming composition as claimed in claim 2, wherein, described polyvinyl compound comprises: polyvinyl alcohol, polyvinylpyrrolidone, polyvinyl chloride, V-Pyrol RC/vinyl acetate copolymer, polyvinylpyrrolidone//vinyl acetate copolymer or its combination.
4. film-forming composition as claimed in claim 2, wherein, the weight average molecular weight of described polyvinyl compound is 2.5 ten thousand to 360 ten thousand.
5. film-forming composition as claimed in claim 2, wherein, the basicity of described polyvinyl compound is 82 to 99mol%.
6. film-forming composition as claimed in claim 2, wherein, the alcoholysis degree of described polyvinyl compound is 78 to 100mol%.
7. film-forming composition as claimed in claim 2, wherein, under the room temperature of described polyvinyl compound, viscosity is 3 to 95cps.
8. film-forming composition as claimed in claim 3, wherein, described polyvinyl compound comprises: polyvinyl alcohol and polyvinylpyrrolidone; The weight ratio of described polyvinyl alcohol and described polyvinylpyrrolidone is: 0.3 to 2.
9. film-forming composition as claimed in claim 1, wherein, described membrane-forming agent comprises: acrylate copolymer, Xanthan gum, gelatin, gum arabic, agar, Lalgine or its salt, starch, dextrin, zein, derivatived cellulose or its combination.
10. film-forming composition as claimed in claim 9, wherein, described acrylate copolymer comprises: methacrylic acid/acrylamido methylpropane base sodium sulfonate copolymers, acrylate/ethylhexyl acrylate multipolymer, phenylethylene ethylene/propenoic acid ester copolymer or its combination.
11. film-forming compositions as claimed in claim 1, wherein, described interfacial agent comprises: the lipid acid of coconut palm acid glycerol, Voranol EP 2001, polyvalent alcohol or its combination.
12. film-forming compositions as claimed in claim 1, it comprises the organic solvent of 5 to 40 weight percents further; Wherein said weight percent is based on the gross weight of described film-forming composition.
13. film-forming compositions as claimed in claim 12, wherein, described organic solvent comprises: methyl alcohol, ethanol, propyl alcohol or its combination.
14. film-forming compositions as claimed in claim 1, it comprises the pigment of 0.001 to 1.0 weight percent, sanitas, fungistat, essence, wetting Agent for Printing Inks, whitening agent, sour agent, sun-screening agent or its combination further; Wherein said weight percent is based on the gross weight of described film-forming composition.
15. film-forming compositions as claimed in claim 14, wherein, described wetting Agent for Printing Inks is polyvalent alcohol.
16. film-forming compositions as claimed in claim 1, it comprises:
The polyvinyl alcohol of 2 to 12 weight percents;
The polyvinylpyrrolidone of 3 to 13 weight percents;
The acrylate copolymer of 2 to 10 weight percents;
The interfacial agent of 2 to 10 weight percents;
The organic solvent of 5 to 40 weight percents; And
Account for the water of all the other weight percents;
Wherein, described weight percent is based on the gross weight of described film-forming composition.
17. 1 kinds of cover groups, it comprises:
Container; And
Be placed in the film-forming composition as described in any one of claim 1 to 16 of described container.
18. cover groups as claimed in claim 17, wherein, described container is flexible pipe, box or bottle.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
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| TW103119008 | 2014-05-30 | ||
| TW103119008 | 2014-05-30 |
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| CN105295273A true CN105295273A (en) | 2016-02-03 |
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| CN201510287375.5A Pending CN105295273A (en) | 2014-05-30 | 2015-05-29 | Film-forming composition and kit containing same |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1094441A (en) * | 1993-04-21 | 1994-11-02 | 中国地质大学武汉管理干部学院 | Anti-stain aromatic for clothes |
| CN1221023A (en) * | 1997-12-24 | 1999-06-30 | 哈尔滨诚智实业工贸有限责任公司 | Perfumed soap membrane and processing technology |
| WO2001024770A1 (en) * | 1999-10-05 | 2001-04-12 | Henkel Kommanditgesellschaft Auf Aktien | Film-forming skin cleansing agent |
| CN103232908A (en) * | 2013-04-25 | 2013-08-07 | 金红叶纸业集团有限公司 | Cleaning composition and wet tissue with same |
| CN103966899A (en) * | 2014-05-07 | 2014-08-06 | 重庆锐今生物制品有限公司 | Film-forming material, preparation method thereof, and test paper with film formed through film-forming material |
-
2015
- 2015-05-28 TW TW104117129A patent/TW201544128A/en unknown
- 2015-05-29 CN CN201510287375.5A patent/CN105295273A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1094441A (en) * | 1993-04-21 | 1994-11-02 | 中国地质大学武汉管理干部学院 | Anti-stain aromatic for clothes |
| CN1221023A (en) * | 1997-12-24 | 1999-06-30 | 哈尔滨诚智实业工贸有限责任公司 | Perfumed soap membrane and processing technology |
| WO2001024770A1 (en) * | 1999-10-05 | 2001-04-12 | Henkel Kommanditgesellschaft Auf Aktien | Film-forming skin cleansing agent |
| CN103232908A (en) * | 2013-04-25 | 2013-08-07 | 金红叶纸业集团有限公司 | Cleaning composition and wet tissue with same |
| CN103966899A (en) * | 2014-05-07 | 2014-08-06 | 重庆锐今生物制品有限公司 | Film-forming material, preparation method thereof, and test paper with film formed through film-forming material |
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| TW201544128A (en) | 2015-12-01 |
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Application publication date: 20160203 |