CN105289272B - A kind of low-temperature denitration device and the method using its denitration - Google Patents

A kind of low-temperature denitration device and the method using its denitration Download PDF

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Publication number
CN105289272B
CN105289272B CN201510707691.3A CN201510707691A CN105289272B CN 105289272 B CN105289272 B CN 105289272B CN 201510707691 A CN201510707691 A CN 201510707691A CN 105289272 B CN105289272 B CN 105289272B
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spray gun
denitration
low
reaction unit
pulvis
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CN105289272A (en
Inventor
林海
冯翀
吴国圣
李文超
张东年
章诗杰
徐慧娟
朱万方
李科
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Jiangsu Hai Lanzhenghe Environmental Science And Technology Co Ltd
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Jiangsu Hai Lanzhenghe Environmental Science And Technology Co Ltd
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Abstract

The present invention relates to a kind of low-temperature denitration device and using the method for its denitration, belong to air environmental technology field.Including powder adding device, ammonifying device, mixing arrangement and reaction unit, the powder adding device includes digester and storage arrangement, the outlet of the digester is connected with the entrance of the storage arrangement, the outlet of the storage arrangement connects spreading device by regulating valve, the spreading device includes at least one set of vaporific spray gun, the impact spray gun of one group of nozzle upwards is correspondingly arranged immediately below every group of vaporific spray gun, V-type support is set between the vaporific spray gun and impact spray gun, set between circular groove uniform board, the uniform board and connected by spring on the V-type support.Compared with prior art, using the method for device denitration of the present invention, unfavorable interference serious during catalyst operation is eliminated, the normal operation of catalyst is realized, so that the low-temperature denitration ability of denitrification apparatus is improved, the real trouble and worry for solving associated emissions enterprise.

Description

A kind of low-temperature denitration device and the method using its denitration
Technical field
The present invention relates to a kind of denitrification apparatus and method of denitration, and in particular to a kind of low-temperature denitration device and utilize its denitration Method, belong to air environmental technology field.
Background technology
Electric power, including metallurgical, cement and glass industry, due to operational characteristic, its Industrial Stoves operating temperature is usually in Below low temperature;Although some kiln associated hot combustion reactions have high temperature, only office is confined to small space;1~2 meter of flame kernel Outer temperature drastically declines;Especially as rotary kiln high temperature section or rotating operation mode;SNCR denitration technology can be operated in Burner hearth, but need 900 DEG C~1000 DEG C temperature sections of burner hearth and need a certain size space.
The waste gas of a large amount of nitrogen-containing oxides can be produced in production process, its concentration usually has been out the discharge standard of country, Therefore need to carry out denitration process, the flue gas of the above-mentioned nearly all burner afterbody discharge of these industries is approximately less than 220 DEG C Temperature;And traditional denitration reaction (SCR) needs reaction temperature 300 DEG C~420 DEG C higher interval.
A kind of current relatively advanced gas method of denitration is selective catalytic reduction denitration technology (SCR), will be contained The waste gas of nitrogen oxides carries out mixing feeding SCR reactors with ammonia according to a certain percentage, at a certain temperature and passes through SCR The effect of catalyst in reactor, makes nitrogen oxides with ammonia reaction generation ammonia and water, realizes the purpose of gas denitration, still Existing denitration reaction device be mainly for the denitration of high temperature catalyst design, its temperature in use be 300 DEG C~420 DEG C even It is higher, and the flue gas of the almost all of burner afterbody discharge of these above-mentioned industries is less than 220 DEG C, at this temperature, denitration SO2 is oxidized to SO3 by the catalyst in reaction unit, and SO3 reacts rapidly with ammonia and produces ammonium sulfate and ammonium hydrogen sulfate, sulfuric acid Ammonium and ammonium hydrogen sulfate can be covered in denitration reaction device at the micropore of production catalyst, cause rapid catalyst deactivation, therefore, The research and development of low temperature section denitration technology will open huge Environmental Protection Market.
The content of the invention
Goal of the invention:For currently available technology not enough, there is provided a kind of device that can adapt to denitration under lower temperature And utilize the method for its denitration.
Technical scheme:A kind of low-temperature denitration device, including ammonifying device, mixing arrangement and reaction unit, the ammonification dress Put to embed and be connected in flue, the mixing arrangement and reaction unit are placed in outside flue, the outlet of the ammonifying device and institute State the entrance connection of mixing arrangement, the outlet of the entrance of the reaction unit and the mixing arrangement;Also include being placed in cigarette Powder adding device inside road, the outlet of the powder adding device is connected with the entrance of the mixing arrangement;The powder adding device includes At least one set of spreading device, the spreading device includes vaporific spray gun and impact spray gun, and the vaporific spray gun is set vertically downward, The impact spray gun is arranged at the underface of the vaporific spray gun, and the vaporific spray gun is relative with the spray outlet of impact spray gun to be set Put, also, circular groove shape uniform board be set above the shower nozzle of the impact spray gun, the uniform board and the vaporific spray gun it Between form uniform cavity.
Further, it is that resistance to break-in is set at one-shot forming eccentric screw structure, end nozzle inside the vaporific spray gun Gold five ties up channel-type blade.
Further, it is that antifriction alloy three-dimensional channel is set at hollow wimble structure, end nozzle inside the impact spray gun Formula blade.
Further, the uniform board is fixedly installed by V-type support.
Further, when the spreading device is more than 2 groups, connected between the uniform board by spring.
Further, at least provided with one layer of catalyst module in the reaction unit.
Further, the catalyst module of the reaction unit is 3 layers.
Further, the catalyst module of the reaction unit is V-Ti series ceramic homogeneous materials.
Further, the reaction unit designs for flow fieldization, its velocity vector angle<10°.
The invention also discloses a kind of method using above-mentioned low-temperature denitration device denitration, comprise the following steps:
(1) the denitration pulvis prepared by digester is by Geldart-D particle to storage arrangement, through smoke components feedback signal The PLC control centres of afferent module, PLC control centres analysis sends signal, and commander's adjustment unit controls this module to run, entirely Module passes through flow field analysis, under the instruction of PLC control centres, denitration pulvis is injected to powder adding device, in vaporific spray gun and punching Hit under the collective effect of spray gun, form diffused pulvis group, when reaching the concentration of default diffused pulvis group, stop sprinkling de- Nitre pulvis;Occur to start to spray pulvis again after changing features cause interlocking action in parameter, so go round and begin again;
(2) in the presence of dilution air, the ammonia that ammonifying device is produced reaches preset concentration, with being produced in step (1) Raw diffused pulvis group is sufficiently mixed in mixing arrangement and sequentially enters reaction unit;
(3) in reaction unit in the presence of catalyst module, occurs denitration reduction reaction.
Beneficial effect:Compared with prior art, advantages of the present invention:Denitration pulvis is by spreading device formation diffused powder Group, spreads in smoke space, the SO2 and SO3 in flue gas is sponged, so as to prevent sticky sulfate from being formed in catalyst surface Shielding, eliminates unfavorable interference serious during catalyst operation, realizes the normal operation of catalyst;3 layers of catalyst module are set, The reaction contact surface and probability of catalyst are considerably increased, the denitration efficiency of catalyst is improved, so as to improve denitrification apparatus Low-temperature denitration ability, the real trouble and worry for solving associated emissions enterprise.
Brief description of the drawings
Fig. 1 is a kind of low-temperature denitration device of the present invention and the process chart using its denitration;
Fig. 2 is a kind of structural representation of the powder adding device of low-temperature denitration device of the present invention.
Embodiment
Technical solution of the present invention is described in detail below by accompanying drawing:
Embodiment 1:A kind of low-temperature denitration device, its structure are as shown in figure 1, including ammonifying device 2, mixing arrangement 3 and anti- Device 4 is answered, the ammonifying device 2 is embedded to be connected in flue, and the mixing arrangement 3 and reaction unit 4 are placed in outside flue, institute The outlet for stating ammonifying device 2 is connected with the entrance of the mixing arrangement 3, the entrance of the reaction unit 4 and the mixing arrangement 3 Outlet;Also include the powder adding device 1 being placed in inside flue, outlet and the mixing arrangement 3 of the powder adding device 1 Entrance is connected;The structure of the powder adding device 1 is as shown in Fig. 2 including at least one set of spreading device, the spreading device includes mist Shape spray gun 6 and impact spray gun 7, the vaporific spray gun 6 are set vertically downward, and the impact spray gun 7 is arranged at the vaporific spray gun 6 Underface, the vaporific spray gun 6 and impact spray gun 7 spray outlet be oppositely arranged, also, it is described impact spray gun 7 shower nozzle Top sets circular groove shape uniform board 9, and uniform cavity is formed between the uniform board 9 and the vaporific spray gun 6.It is described uniform Plate 9 is stainless steel uniform board, and is fixedly installed by V-type support 8, when the spreading device is more than 2 groups, the uniform board 9 Between connected by spring 10, it is ensured that uniform board 9 is indeformable.
Complete unit is arranged for dispersiveness, and leaves other module mating interfaces.The powder adding device 1 is that absorption plant is special Levy, it is embedded;The ammonifying device 2 is put for distribution shape dress, embedded;The mixing arrangement 3 is externally positioned type equipment, special gas Device;The reaction unit 4 is multimode combined unit, interior insert-type.
The powder adding device 1, ammonifying device 2 are originated for the reducing agent of the reaction unit 4.In the presence of catalyst, Former flue gas obtains denitration reduction reaction;Bad air from interference source can not produce sticky sulphur under the obstruction of calcium hydroxide pulvis Hydrochlorate;So as to prevent shielding in catalyst surface formation, catalyst poisoning is caused;The present invention is eliminated by powder adding device 1 to be urged Serious unfavorable interference when agent is run, realizes that catalyst is normally run, and prevents flow velocity radical ion from reacting the screen to catalyst Cover, considerably increase catalyst reaction contact surface, improve the denitration efficiency of catalyst;So as to really improve the low of denitrification apparatus Temperature section denitration ability.
In the present embodiment, the powder adding device 1 is rectangle high temperature resistant stainless steel device, and the perpendicular bisector in its section is perpendicular to institute The middle part of flue is stated, through Flow Field Calculation, supporting DCS switch boards operation;Its process upstream is preparation and storage arrangement;It is external airtight Two-phase flow fluid.The device is according to flue gas flow size, flow velocity height;Gas, fixed double phase flow spray gun special are configured after being computed;This In embodiment, the vaporific inside of spray gun 6 is to set antifriction alloy five to tie up at one-shot forming eccentric screw structure, end nozzle to lead to Road formula blade.The inside of impact spray gun 7 is that antifriction alloy three-dimensional channel formula blade is set at hollow wimble structure, end nozzle, By the collective effect of vaporific spray gun 6 and impact spray gun 7, maximized powder diffused can be made to be scattered in flue.
In the present embodiment, the pulvis be slaked lime powder, its particle diameter be 5~8 μm, particle diameter is excessive, can not react in time or Reach on the inside of honeycomb, particle diameter is too small to be gone out from " floaing " on the inside of honeycomb;Therefore, pulvis alkali material injection simpler than conventional art Want many of science;The pulvis is special pulvis, is prepared by digester, control time, humidity are needed during storage.The pulvis is manufactured Standard is moral mark T40/T60, and in the market is fully able to buy.Boiler emission original flue gas injects at powder adding device meets specification Calcium hydroxide pulvis, as a kind of diffused smog.
The powder adding device 1 is additionally provided with distribution apparatus, deposition blow device and deposit retracting device, heavy for reclaiming Product reactant.
The denitration pulvis prepared by digester extremely adds powder to fill by Geldart-D particle to storage arrangement by Geldart-D particle Put, the PLC control centres through smoke components feedback signal afferent module, control centre's analysis sends command signal, commander's regulation Unit control present apparatus operation;Through flow field analysis, spray gun technique is designed using special type in advance for whole module, sets equal in flue Flow module device, vaporific spray gun 6 and the impact scientific matching of spray gun 7, Special composition scattered distribution, the science under feedback signal commander Plus powder, and diffused powder ball is formed, smoke space is spread in, whole space does not have bubble, section alveolation, inequality to homogenize;Can Reach the reverse side of catalyst in reaction unit;And traditional powder adding device is only simply to blow;Its effect necessarily has very big inequality Even property, and can not reach the reverse side of catalyst.Diffused powder ball sponges the SO2 and SO3 in flue gas, so that anti- Only sticky sulfate is shielded in catalyst surface formation, is eliminated unfavorable interference serious during catalyst operation, is realized catalyst Normal operation.
The perpendicular bisector in section is perpendicular to the middle part of the flue described in the ammonifying device 2, and module of the invention is through flow field Calculate, operation can far be operated by DCS.Dilution air is inside set, because ammonia is special gas, the device also has anti-riot work(concurrently Energy;By the device, under the monitoring of instrument, preset requirement is fully achieved in ammonia, without occurring layering, point group, cutout.
The mixing arrangement 3 is arranged against device 4;Without operation after parameter preset when equipment is produced.
The reaction unit 4 is low-temperature denitration of flue gas main region, is designed using rectangle flow fieldization, and the perpendicular bisector in its section hangs down Directly in the middle part of the flue, it is mainly characterized by concordant flow field, is calculated by flow field computer simulation, velocity vector angle< 10°;Without operation after parameter preset when equipment is produced;In the present embodiment, the catalyst module that haves three layers is set in the reaction unit 4 11, the catalyst module 11 is low temperature catalyst, using V-Ti series ceramics homogeneous material, it is necessary to customize.In device 4 tiltedly Under the drive of air-flow technology, accordingly attach interference source microparticle occur it is secondary kick up phenomenon, and can be exited from micropore, pot Stove original flue gas completes denitration reaction as neat stress behind the region, and delivers to following device through flow field according to technological requirement.
In addition, the predeterminable reserved layer of reaction unit 4, prevents inconvenience when boiler ultra-long time is run.
Using the method for above-mentioned low-temperature denitration device denitration, comprise the following steps:
(1) pulvis prepared by digester is incoming through smoke components feedback signal by Geldart-D particle to storage arrangement The PLC control centres of module, PLC control centres analysis sends signal, and commander's adjustment unit controls this module to run, whole module By flow field analysis, under the instruction of PLC control centres, denitration pulvis is injected to powder adding device 2, in vaporific spray gun 6 and impact Under the collective effect of spray gun 7, diffused pulvis group is formed, when reaching the concentration of default diffused pulvis group, stops sprinkling de- Nitre pulvis;Occur to start to spray pulvis again after changing features cause interlocking action in parameter, so go round and begin again;
(2) in the presence of dilution air, the ammonia that ammonifying device 2 is produced reaches preset concentration, with being produced in step (1) Raw diffused pulvis group is sufficiently mixed in mixing arrangement 3 and sequentially enters reaction unit 4;
(3) in the presence of the catalyst module 11 of reaction unit 4, occurs denitration reduction reaction.
The absorbent that the present invention is prepared by digester spreads in flue gas empty by spreading device formation diffused powder ball Between, the SO2 and SO3 in flue gas are sponged, so as to prevent sticky sulfate from being shielded in catalyst surface formation, catalysis is eliminated Serious unfavorable interference, realizes the normal operation of catalyst when agent is run;3 layers of catalyst module 1 are set, catalysis is considerably increased The reaction contact surface and probability of agent, improve the denitration efficiency of catalyst, so as to improve the low-temperature denitration ability of denitrification apparatus, very The positive trouble and worry for solving associated emissions enterprise.
As described above, although the present invention has been represented and described with reference to specific preferred embodiment, it must not be explained For to the limitation of itself of the invention., can be right under the premise of the spirit and scope of the present invention that appended claims are defined are not departed from Various changes can be made in the form and details for it.

Claims (8)

1. a kind of low-temperature denitration device, including ammonifying device (2), mixing arrangement (3) and reaction unit (4), the ammonifying device (2) embed and be connected in flue, the mixing arrangement (3) and reaction unit (4) are placed in outside flue, the ammonifying device (2) Outlet connected with the entrance of the mixing arrangement (3), the entrance of the reaction unit (4) and going out for the mixing arrangement (3) Mouth connection;Characterized in that, also include the powder adding device (1) that is placed in inside flue, the outlet of the powder adding device (1) with it is described The entrance connection of mixing arrangement (3);The powder adding device (1) includes at least one set of spreading device, and the spreading device includes mist Shape spray gun (6) and impact spray gun (7), the vaporific spray gun (6) are set vertically downward, and the impact spray gun (7) is arranged at described The spray outlet of the underface of vaporific spray gun (6), the vaporific spray gun (6) and impact spray gun (7) is oppositely arranged, also, described Impact and circular groove shape uniform board (9) be set above the shower nozzle of spray gun (7), the uniform board (9) and the vaporific spray gun (6) it Between form uniform cavity;
It is to set antifriction alloy five to tie up passage at one-shot forming eccentric screw structure, end nozzle inside the vaporific spray gun (6) Formula blade;It is that antifriction alloy three-dimensional channel formula blade is set at hollow wimble structure, end nozzle inside the impact spray gun (7).
2. a kind of low-temperature denitration device according to claim 1, it is characterised in that the uniform board (9) passes through V-type support (8) it is fixedly installed.
3. a kind of low-temperature denitration device according to claim 1, it is characterised in that when the spreading device is more than 2 groups, Connected between the uniform board (9) by spring (10).
4. a kind of low-temperature denitration device according to claim 1, it is characterised in that at least set in the reaction unit (4) There is one layer of catalyst module (11).
5. a kind of low-temperature denitration device according to claim 4, it is characterised in that the catalyst of the reaction unit (4) Module (11) is 3 layers.
6. a kind of low-temperature denitration device according to claim 4, it is characterised in that the catalyst of the reaction unit (4) Module (11) is V-Ti series ceramic homogeneous materials.
7. a kind of low-temperature denitration device according to claim 4, it is characterised in that the reaction unit (4) is flow field Design, its velocity vector angle<10°.
8. utilize a kind of method of low-temperature denitration device denitration described in claim 1-7 any claims, it is characterised in that Comprise the following steps:
(1) the denitration pulvis prepared by digester is incoming through smoke components feedback signal by Geldart-D particle to storage arrangement The PLC control centres of module, PLC control centres analysis sends signal, and commander's adjustment unit controls this module to run, whole module By flow field analysis, under the instruction of PLC control centres, denitration pulvis is injected to powder adding device (1), in vaporific spray gun (6) and Under the collective effect for impacting spray gun (7), diffused pulvis group is formed, when reaching the concentration of default diffused pulvis group, is stopped Spray denitration pulvis;Occur to start to spray pulvis again after changing features cause interlocking action in parameter, so go round and begin again;
(2) in the presence of dilution air, the ammonia that ammonifying device (2) is produced reaches preset concentration, and with being produced in step (1) Raw diffused pulvis group is sufficiently mixed in mixing arrangement (3) and sequentially enters reaction unit (4);
(3) in reaction unit (4) in the presence of catalyst module (11), occurs denitration reduction reaction.
CN201510707691.3A 2015-10-27 2015-10-27 A kind of low-temperature denitration device and the method using its denitration Expired - Fee Related CN105289272B (en)

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CN108854528A (en) * 2018-08-17 2018-11-23 深圳市凯盛科技工程有限公司 Cement industry kiln low-temperature denitration dust removal integrated plant
CN116768299B (en) * 2023-08-23 2023-10-20 南京旺德福环保科技有限公司 Sewage treatment equipment based on environment protection and control method thereof

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CN203678250U (en) * 2013-12-26 2014-07-02 浙江德创环保科技股份有限公司 Selective non-catalytic reduction (SNCR) denitration reactor provided with double-fluid spray gun
CN104971613B (en) * 2015-07-24 2017-06-23 江苏揽山环境科技股份有限公司 Denitration method for flue gas and the powder material spray gun suitable for flue-gas denitration process
CN205095643U (en) * 2015-10-27 2016-03-23 江苏海澜正和环境科技有限公司 Low temperature denitrification facility

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