CN105276864A - Variable-component refrigerant heat pump hot water unit - Google Patents

Variable-component refrigerant heat pump hot water unit Download PDF

Info

Publication number
CN105276864A
CN105276864A CN201410329417.2A CN201410329417A CN105276864A CN 105276864 A CN105276864 A CN 105276864A CN 201410329417 A CN201410329417 A CN 201410329417A CN 105276864 A CN105276864 A CN 105276864A
Authority
CN
China
Prior art keywords
heat exchanger
magnetic valve
rectifier
outlet
pump hot
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201410329417.2A
Other languages
Chinese (zh)
Other versions
CN105276864B (en
Inventor
余延顺
孙成龙
赵跃
吴加胜
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nanjing University of Science and Technology
Original Assignee
Nanjing University of Science and Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nanjing University of Science and Technology filed Critical Nanjing University of Science and Technology
Priority to CN201410329417.2A priority Critical patent/CN105276864B/en
Publication of CN105276864A publication Critical patent/CN105276864A/en
Application granted granted Critical
Publication of CN105276864B publication Critical patent/CN105276864B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Landscapes

  • Compression-Type Refrigeration Machines With Reversible Cycles (AREA)

Abstract

The invention discloses a variable-component refrigerant heat pump hot water unit which comprises a compressor, a condensing heat exchanger, a liquid storage tank, an outdoor heat exchanger, a gas-liquid separator, a rectifier filled with refrigerants and a coil arranged in the rectifier. The coil and a first electromagnetic valve are arranged between an outlet of the compressor and an inlet of the condensing heat exchanger in parallel. Two branches connected in parallel are arranged between the liquid storage tank and the outdoor heat exchanger. The first branch is formed by connecting an outlet of the liquid storage tank, a third electromagnetic valve, a first throttling valve and an inlet of the outdoor heat exchanger in sequence. The second branch is formed by connecting the outlet of the liquid storage tank, a fourth electromagnetic valve, a second throttling valve, the rectifier, a second electromagnetic valve and the inlet of the outdoor heat exchanger in sequence. The variable-component refrigerant heat pump hot water unit is additionally provided with the rectifier and the electromagnetic valves so that conversion of the refrigerants of different components can be achieved according to the outdoor environment temperature, and the variable-component refrigerant heat pump hot water unit has high adaptability to the environment temperature.

Description

A kind of change component refrigerants heat-pump hot-water unit
Technical field
The invention belongs to heat pump water-heating machine technical group field, particularly a kind of change component refrigerants heat-pump hot-water unit.
Background technology
Along with improving constantly of living standards of the people, the requirement of people to living environment and thermal comfort is also increased day by day.Traditional building and heating mode energy consumption is high, seriously polluted, and the building and heating technology that development is cleaned becomes particularly urgent.Current heat pump techniques cannot conform temperature wide region change, especially at cold district, winter, outdoor temperature was low, traditional single-stage heat pump compression ratio is high, heating performance sharply declines, cisco unity malfunction, but heat relative to the whole year, time accounting in the whole year that winter environment temperature is low is especially less, only adopt high pressure ratio or Two-stage Compression system for solving heat supply in winter, the situation that system will break down at higher ambient temperatures or efficiency is lower, thus the economy of system becomes very poor.
Chinese patent ZL98118641.6 discloses a kind of heat pump becoming component refrigerants, the refrigerant heat rectifying column that this system adopts condenser to flow out, the cold-producing medium of low pressure component is isolated in rectifying column, thus allow more high pressure components participate in the middle of circulation, reach the effect strengthening heating capacity under low temperature environment, but there is following problem in this system: 1) refrigerant temperature of condenser outflow is not high, and rectification effect is poor; 2) to put into practice difficulty larger in anti-rectifying; 3) system complex, cost is too high.Chinese patent ZL98118646.7 discloses a kind of heat pump becoming component refrigerants, this system with the addition of the auxiliary coil pipe of connection in parallel below off-premises station, when heating mode is opened, bracket panel tube inlet is closed and outlet is opened, compressor is by high-pressure section sucking-off larger for volatility, then closing outlet valve stays low-pressure section inside auxiliary coil pipe, but there is following problem in this system: 1) rely on compressor vacuum to inhale high-pressure refrigerant, easy blending low pressure refrigerant, reduces regulating power; 2) auxiliary coil pipe will be enough to hold most of liquid refrigerant, and bracket panel pipe volume is bigger than normal, and cost is higher.
Summary of the invention
The object of the present invention is to provide and a kind ofly adapt to the change component refrigerants heat-pump hot-water unit that warm area is large, rectification effect is good.
The technical solution realizing the object of the invention is: a kind of change component refrigerants heat-pump hot-water unit, comprise for sucking gaseous refrigerant and carrying out compressing the compressor exported, be filled with the rectifier of cold-producing medium, condensing heat exchanger, the fluid reservoir be connected with condensing heat exchanger, first throttle valve, second throttle, first magnetic valve, second magnetic valve, 3rd magnetic valve, 4th magnetic valve, outdoor heat exchanger, the gas-liquid separator be connected with the outlet of outdoor heat exchanger and the coil pipe being arranged on rectifier inside, the outlet of described gas-liquid separator is connected with the entrance of compressor, described coil pipe and the first magnetic valve are arranged in parallel between the outlet and the entrance of condensing heat exchanger of compressor, two branch roads parallel with one another are provided with between described fluid reservoir and outdoor heat exchanger, the entrance of the i.e. outlet of fluid reservoir, the 3rd magnetic valve, first throttle valve, outdoor heat exchanger is connected formation first branch road successively, and the outlet of fluid reservoir, the 4th magnetic valve, second throttle, rectifier, the second magnetic valve and the entrance of outdoor heat exchanger are connected formation second branch road successively.
Compared with prior art, its remarkable advantage is in the present invention: (1) the present invention utilizes the superheated steam of compressor outlet, and temperature is higher, and heating rectifier successful, substantially reduces the time that refrigerant component changes, improve the heating performance of system; (2) the present invention with the addition of a rectifier and several magnetic valve on the basis of conventional heat pump, and system architecture is compact, and cost is lower; (3) the present invention isolates the superior cold-producing medium of heating performance in the winter time, effectively can improve the low-temperature heating ability of heat pump, and the conversion of different component cold-producing medium can be realized according to outdoor environment temperature, to the strong adaptability of environment temperature, particularly applicable in the heat pump applications of environment temperature wide region change.
Below in conjunction with accompanying drawing, the present invention is described in further detail.
Accompanying drawing explanation
Fig. 1 is the structural representation that the present invention becomes component refrigerants heat-pump hot-water unit.
Fig. 2 is the rectifier built-in immersion serpentine coil schematic diagram that the present invention becomes component refrigerants heat-pump hot-water unit.
Fig. 3 is the built-in parallel comb schematic diagram of rectifier that the present invention becomes component refrigerants heat-pump hot-water unit.
Detailed description of the invention
Composition graphs 1, Fig. 2, Fig. 3, a kind of change component refrigerants heat-pump hot-water unit, comprise for sucking gaseous refrigerant and carrying out compressing the compressor 1 exported, be filled with the rectifier 2 of cold-producing medium, condensing heat exchanger 3, the fluid reservoir 4 be connected with condensing heat exchanger 3, first throttle valve 5, second throttle 8, first magnetic valve F1, second magnetic valve F2, 3rd magnetic valve F3, 4th magnetic valve F4, outdoor heat exchanger 6, the gas-liquid separator 7 be connected with the outlet of outdoor heat exchanger 6 and the coil pipe 9 being arranged on rectifier 2 inside, the outlet of described gas-liquid separator 7 is connected with suction port of compressor 1-2, described coil pipe 9 and the first magnetic valve F1 are arranged in parallel between compressor outlet 1-1 and condensing heat exchanger entrance 3-1, two branch roads parallel with one another are provided with between described fluid reservoir 4 and outdoor heat exchanger 6, the entrance of the i.e. outlet of fluid reservoir 4, the 3rd magnetic valve F3, first throttle valve 5, outdoor heat exchanger 6 is connected formation first branch road successively, and the outlet of fluid reservoir 4, the 4th magnetic valve F4, second throttle 8, rectifier 2, second magnetic valve F2 and the entrance of outdoor heat exchanger 6 are connected formation second branch road successively.
Described first throttle valve 5 and second throttle 8 adopt heating power expansion valve, electric expansion valve or capillary.
Described coil pipe 9 is immersion serpentine coil or parallel comb.
Described outdoor heat exchanger 6 is air-cooled heat exchanger or water-cooled heat exchanger.
Described condensing heat exchanger 3 is made up of a water-cooled heat exchanger, or is made up of multiple water-cooled heat exchanger parallel connection.
Below in conjunction with specific embodiment, the present invention will be further described.
Embodiment 1
Composition graphs 1, Fig. 2, a kind of change component refrigerants heat-pump hot-water unit, comprise one for sucking gaseous refrigerant and carrying out compressing the compressor 1 exported, a condensing heat exchanger 3, a fluid reservoir 4 be connected with condensing heat exchanger 3, the gas-liquid separator 7, one that outdoor heat exchanger 6, is connected with the outlet of outdoor heat exchanger 6 is filled with the rectifier 2 of mixed non-azeotropic refrigerant and is arranged on the coil pipe 9 of rectifier 2 inside; The outlet of gas-liquid separator 7 is connected with suction port of compressor 1-2, and coil pipe 9 and the first magnetic valve F1 are arranged in parallel between compressor outlet 1-1 and condensing heat exchanger entrance 3-1; Two branch roads parallel with one another are provided with between fluid reservoir 4 and outdoor heat exchanger 6, the entrance of the outlet of fluid reservoir 4, the 3rd magnetic valve F3, first throttle valve 5, outdoor heat exchanger 6 is connected formation first branch road successively, and the outlet of fluid reservoir 4, the 4th magnetic valve F4, second throttle 8, rectifier 2, second magnetic valve F2 and the entrance of outdoor heat exchanger 6 are connected formation second branch road successively.Being used for the cold-producing medium of supply system circulation in rectifier 2 isolates lower boiling cold-producing medium and the high boiling cold-producing medium of storage after the heating selectively, or provides refrigerant vapour when suction port of compressor negative pressure.
Wherein, first throttle valve 5 and second throttle 8 all adopt heating power expansion valve, and coil pipe 9 is immersion serpentine coil, and outdoor heat exchanger 6 is air-cooled heat exchanger, and condensing heat exchanger 3 is made up of a water-cooled heat exchanger.
Rectifying low boiling point refrigerant can be realized according to the different open and-shut modes of the first magnetic valve F1, the second magnetic valve F2, the 3rd magnetic valve F3 and the 4th magnetic valve F4, refrigerant component recovers and unit normally works three kinds of operational modes.
The operational mode of (a) rectifying low boiling point refrigerant
When outdoor temperature is lower than switching temperature T1, close the first magnetic valve F1 and the 3rd magnetic valve F3, open the second magnetic valve F2 and the 4th magnetic valve F4, compressor outlet 1-1 superheated steam is through coil pipe 9 heat release of rectifier 2 li, then in condensing heat exchanger 3 condensation further, then, after being become low pressure liquid by choke valve 8 throttling, flow in rectifier 2; Meanwhile, rectifier 2 absorbs heat, and the low boiling point refrigerant evaporated is overheated further in outdoor heat exchanger 6, after gas-liquid separator 7, enters suction port of compressor 1-2.Through this process, the low boiling point refrigerant ratio run in system rises, and most of higher boiling cold-producing medium is stored in rectifier simultaneously.
B operational mode that () refrigerant component is recovered
When outdoor temperature is higher than switching temperature T2, close the first magnetic valve F1, the 3rd magnetic valve F3 and the 4th magnetic valve F4, open the second magnetic valve F2, compressor outlet 1-1 superheated steam is through the coil pipe heat release of rectifier 2 li, then condensation in condensing heat exchanger 3; Meanwhile, rectifier 2 absorbs heat, compressor suction 1-2 vacuum, and rectifier 2 li of higher boiling refrigerants vaporize, after outdoor heat exchanger 6 and gas-liquid separator 7, enter suction port of compressor 1-2.Through this process, cold-producing medium mixes in condensing heat exchanger, and low boiling point refrigerant ratio declines, and unnecessary cold-producing medium is stored in inside fluid reservoir.
C operational mode that () unit normally works
After refrigerant component reaches requirement, open the first magnetic valve F1 and the 3rd magnetic valve F3, close the second magnetic valve F2 and the 4th magnetic valve F4, refrigerant vapour becomes the superheated steam of HTHP after compressor 1 compresses, and enters condensing heat exchanger 3 exothermic condensation, is then become the liquid of low-pressure low-temperature by choke valve 5 throttling, enter in outdoor heat exchanger 6 and absorb heat, after gas-liquid separator 7, come back to compressor 1, complete a kind of refrigeration cycle.
Embodiment 2
Composition graphs 1, Fig. 3, a kind of change component refrigerants heat-pump hot-water unit, comprise one for sucking gaseous refrigerant and carrying out compressing the compressor 1 exported, a condensing heat exchanger 3, a fluid reservoir 4 be connected with condensing heat exchanger 3, an outdoor heat exchanger 6, a gas-liquid separator 7 be connected with the outlet of outdoor heat exchanger 6, the outlet of described gas-liquid separator 7 is connected with suction port of compressor 1-2, and described change component refrigerants heat-pump hot-water unit also comprises one and is filled with the rectifier 2 of mixed non-azeotropic refrigerant and is arranged on the coil pipe 9 of rectifier 2 inside; Described coil pipe 9 and the first magnetic valve F1 are arranged in parallel between compressor outlet 1-1 and condensing heat exchanger entrance 3-1; Two branch roads parallel with one another are provided with between described fluid reservoir 4 and outdoor heat exchanger 6, the entrance of the outlet of fluid reservoir 4, the 3rd magnetic valve F3, first throttle valve 5, outdoor heat exchanger 6 is connected formation first branch road successively, and the outlet of fluid reservoir 4, the 4th magnetic valve F4, second throttle 8, rectifier 2, second magnetic valve F2 and the entrance of outdoor heat exchanger 6 are connected formation second branch road successively.Being used for the cold-producing medium of supply system circulation in rectifier 2 isolates lower boiling cold-producing medium and the high boiling cold-producing medium of storage after the heating selectively, or provides refrigerant vapour when suction port of compressor negative pressure.
Wherein, first throttle valve 5 and second throttle 8 all adopt electric expansion valve, and coil pipe 9 adopts parallel comb, and outdoor heat exchanger 6 is water-cooled heat exchanger, and condensing heat exchanger 3 is made up of multiple water-cooled heat exchanger parallel connection.
Rectifying low boiling point refrigerant can be realized according to the different open and-shut modes of the first magnetic valve F1, the second magnetic valve F2, the 3rd magnetic valve F3 and the 4th magnetic valve F4, refrigerant component recovers and unit normally works three kinds of operational modes.
The operational mode of (a) rectifying low boiling point refrigerant
When outdoor temperature is lower than switching temperature T1, close the first magnetic valve F1 and the 3rd magnetic valve F3, open the second magnetic valve F2 and the 4th magnetic valve F4, compressor outlet 1-1 superheated steam is through coil pipe 9 heat release of rectifier 2 li, then in condensing heat exchanger 3 condensation further, then, after being become low pressure liquid by choke valve 8 throttling, flow in rectifier 2; Meanwhile, rectifier 2 absorbs heat, and the low boiling point refrigerant evaporated is overheated further in outdoor heat exchanger 6, after gas-liquid separator 7, enters suction port of compressor 1-2.Through this process, the low boiling point refrigerant ratio run in system rises, and most of higher boiling cold-producing medium is stored in rectifier simultaneously.
B operational mode that () refrigerant component is recovered
When outdoor temperature is higher than switching temperature T2, closes the first magnetic valve F1, the 3rd magnetic valve F3 and the 4th magnetic valve F4, open the second magnetic valve F2, compressor outlet 1-1 superheated steam through coil pipe 9 heat release of rectifier 2 li, then condensation in condensing heat exchanger 3; Meanwhile, rectifier 2 absorbs heat, suction port of compressor 1-2 vacuum, and rectifier 2 li of higher boiling refrigerants vaporize, after outdoor heat exchanger 6 and gas-liquid separator 7, enter suction port of compressor 1-2.Through this process, cold-producing medium mixes in condensing heat exchanger 3, and low boiling point refrigerant ratio declines, and unnecessary cold-producing medium is stored in inside fluid reservoir 4.
C operational mode that () unit normally works
After refrigerant component reaches requirement, open the first magnetic valve F1 and the 3rd magnetic valve F3, close the second magnetic valve F2 and the 4th magnetic valve F4, refrigerant vapour becomes the superheated steam of HTHP after compressor 1 compresses, and enters condensing heat exchanger 3 exothermic condensation, is then become the liquid of low-pressure low-temperature by choke valve 5 throttling, enter in outdoor heat exchanger 6 and absorb heat, after gas-liquid separator 7, come back to compressor 1, complete a kind of refrigeration cycle.
The present invention has set up rectifier and magnetic valve, can realize the conversion of different component cold-producing medium, to the strong adaptability of environment temperature according to outdoor environment temperature; Under expansion heat-pump hot-water unit adapts to the prerequisite of warm area, greatly rectification effect must be improve.

Claims (5)

1. one kind becomes component refrigerants heat-pump hot-water unit, it is characterized in that, comprise for sucking gaseous refrigerant and carrying out compressing the compressor [1] exported, be filled with the rectifier [2] of cold-producing medium, condensing heat exchanger [3], the fluid reservoir [4] be connected with condensing heat exchanger [3], first throttle valve [5], second throttle [8], first magnetic valve [F1], second magnetic valve [F2], 3rd magnetic valve [F3], 4th magnetic valve [F4], outdoor heat exchanger [6], the gas-liquid separator [7] be connected with the outlet of outdoor heat exchanger [6] and be arranged on the inner coil pipe [9] of rectifier [2], the outlet of described gas-liquid separator [7] is connected with suction port of compressor [1-2], described coil pipe [9] and the first magnetic valve [F1] are arranged in parallel between compressor outlet [1-1] and condensing heat exchanger entrance [3-1], two branch roads parallel with one another are provided with between described fluid reservoir [4] and outdoor heat exchanger [6], the entrance of the i.e. outlet of fluid reservoir [4], the 3rd magnetic valve [F3], first throttle valve [5], outdoor heat exchanger [6] is connected formation first branch road successively, and the outlet of fluid reservoir [4], the 4th magnetic valve [F4], second throttle [8], rectifier [2], the second magnetic valve [F2] and the entrance of outdoor heat exchanger [6] are connected formation second branch road successively.
2. change component refrigerants heat-pump hot-water unit according to claim 1, is characterized in that, described first throttle valve [5] and second throttle [8] adopt heating power expansion valve, electric expansion valve or capillary.
3. change component refrigerants heat-pump hot-water unit according to claim 1, is characterized in that, described coil pipe [9] is immersion serpentine coil or parallel comb.
4. change component refrigerants heat-pump hot-water unit according to claim 1, is characterized in that, described outdoor heat exchanger [6] is air-cooled heat exchanger or water-cooled heat exchanger.
5. change component refrigerants heat-pump hot-water unit according to claim 1, it is characterized in that, described condensing heat exchanger [3] is made up of a water-cooled heat exchanger, or is made up of multiple water-cooled heat exchanger parallel connection.
CN201410329417.2A 2014-07-10 2014-07-10 One kind becomes component refrigerants heat-pump hot-water unit Expired - Fee Related CN105276864B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410329417.2A CN105276864B (en) 2014-07-10 2014-07-10 One kind becomes component refrigerants heat-pump hot-water unit

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410329417.2A CN105276864B (en) 2014-07-10 2014-07-10 One kind becomes component refrigerants heat-pump hot-water unit

Publications (2)

Publication Number Publication Date
CN105276864A true CN105276864A (en) 2016-01-27
CN105276864B CN105276864B (en) 2018-01-05

Family

ID=55146326

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201410329417.2A Expired - Fee Related CN105276864B (en) 2014-07-10 2014-07-10 One kind becomes component refrigerants heat-pump hot-water unit

Country Status (1)

Country Link
CN (1) CN105276864B (en)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1118058A (en) * 1994-08-30 1996-03-06 株式会社东芝 Refrigerating apparatus
JP2001133059A (en) * 1999-11-10 2001-05-18 Matsushita Refrig Co Ltd Heat pump system
CN1514193A (en) * 2003-07-08 2004-07-21 浙江大学 Low temperature heat source heat pump system and its capacity regulating method
CN2725773Y (en) * 2004-09-13 2005-09-14 上海理工大学 Ternary non-azeotropic mixed working medium variable composition volume control air conditioner
CN1776325A (en) * 2005-11-25 2006-05-24 西安交通大学 High-low temperature changeable graded evaporation air-conditioner heat pump water heater

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1118058A (en) * 1994-08-30 1996-03-06 株式会社东芝 Refrigerating apparatus
JP2001133059A (en) * 1999-11-10 2001-05-18 Matsushita Refrig Co Ltd Heat pump system
CN1514193A (en) * 2003-07-08 2004-07-21 浙江大学 Low temperature heat source heat pump system and its capacity regulating method
CN2725773Y (en) * 2004-09-13 2005-09-14 上海理工大学 Ternary non-azeotropic mixed working medium variable composition volume control air conditioner
CN1776325A (en) * 2005-11-25 2006-05-24 西安交通大学 High-low temperature changeable graded evaporation air-conditioner heat pump water heater

Also Published As

Publication number Publication date
CN105276864B (en) 2018-01-05

Similar Documents

Publication Publication Date Title
CN103175344B (en) Cold-region used multi-connected heat pump system and control method thereof
CN106016771A (en) Solar air source heat pump triple co-generation system and control method thereof
CN107388621B (en) Heat-storage solar energy couples air injection enthalpy-increasing type air source heat pump system and its control method
CN202002391U (en) Water heater unit with spray liquid enthalpy-increasing heat pump
US9671143B2 (en) Heat pump of heat source tower for realizing solution regeneration and heat reutilization based on vacuum boiling
CN101571330B (en) Multifunctional frost-free solar-assisted heat pump system
CN105222404B (en) It is a kind of to utilize solar energy-air energy heat pump system
CN105318466B (en) A kind of heat accumulating type air-source heat pump water chiller-heater system and its operation method
CN102645022B (en) Energy-saving multiple temperature section water boiler
CN203586629U (en) Air source heat pump air conditioning unit with multiple switchable heat exchangers
CN103388905A (en) Evaporator flow-adjustable heat-pump water heater system
CN102563947B (en) A kind of heat pipe hot pump combination type refrigerating plant
CN105333641B (en) Air-source air conditioning and water heating system
CN205897575U (en) Solar energy air source heat pump trigeminy supplies system
CN105157274B (en) cooling/heating system
CN205641133U (en) Multi -functional solar thermal energy pumping system
CN108007009B (en) A kind of the solar-energy jet-type waring and cooling air conditioning system and operational mode of waste heat auxiliary
CN203731741U (en) Air conditioning water heater system
CN103017410B (en) A kind of heating-refrigerating heat-pipe heat-pump type combined cycle system
CN101699184B (en) Air source heat pump water heater
CN101566408B (en) Indirect-expansion multifunctional solar energy auxiliary air condition system
CN207751197U (en) A kind of novel hot water heating refrigeration multifunctional unit system
CN203533671U (en) Integrated air energy heat pump set used for floor heating
CN202660808U (en) Novel heat pipe and heat pump combined refrigerating device
CN105526735B (en) A kind of efficient big temperature rise two-stage throttling two stages of compression heat pump water-heating machine

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20180105

Termination date: 20200710