CN105265610A - Rapeseed oil using liquiritoside as antioxidant - Google Patents

Rapeseed oil using liquiritoside as antioxidant Download PDF

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Publication number
CN105265610A
CN105265610A CN201510207195.1A CN201510207195A CN105265610A CN 105265610 A CN105265610 A CN 105265610A CN 201510207195 A CN201510207195 A CN 201510207195A CN 105265610 A CN105265610 A CN 105265610A
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CN
China
Prior art keywords
rapeseed oil
antioxidant
radix glycyrrhizae
liquiritoside
glycyrrhizae glucosides
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Pending
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CN201510207195.1A
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Chinese (zh)
Inventor
郝再彬
蒋泽军
王彦超
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Individual
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Individual
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Priority to CN201510207195.1A priority Critical patent/CN105265610A/en
Publication of CN105265610A publication Critical patent/CN105265610A/en
Pending legal-status Critical Current

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Abstract

The present invention discloses a rapeseed oil using liquiritoside as an antioxidant. The rapeseed oil is characterized by being prepared by adding the liquiritoside into rapeseed oil. The advantages of the rapeseed oil are that the natural food sweetener liquiritoside is applied into the rapeseed oil. The test proves that the antioxidant effects of the liquiritoside are the same as the antioxidant effects of chemically synthesized antioxidant tertiary butyl hydroquinone (TBHQ), and the liquiritoside can extend the storage period of rapeseed oil, are free of harms to human body, and can also improve the quality of rapeseed oil.

Description

A kind of rapeseed oil making antioxidant with Radix Glycyrrhizae glucosides
Technical field
The present invention relates to edible oil, specifically a kind of rapeseed oil making antioxidant with Radix Glycyrrhizae glucosides.
Background technology
The rapeseed oil that market today is sold is after being squeezed by vegetable seed, through the edible oil that the subtractive processes such as decolouring, deodorization, interpolation chemical synthesis antioxidant obtain, known, rapeseed oil contains more unrighted acid, third contact of a total solar or lunar eclipse induction autoxidation is issued in room temperature and natural daylight condition, can produce free radical, the multiple harmful substances such as hydroperoxides, Small molecular aldehyde ketone acid, evident characteristic is become sour exactly.The rapeseed oil become sour, one is that its nutritive value reduces greatly, vitamin A, vitamin D, vitamin E (V a, V d, V e) first oxidized, the long-term edible rapeseed oil that becomes sour causes the shortage of essential fatty acid and occurs series of symptoms; Two be become sour produce free radical lead oncogenic generation by damage dna, destroy some enzyme systems simultaneously, can mitochondria dysfunction be caused, cause myocardial damage and cause the angiocardiopathies such as atherosclerotic.Rapeseed oil main cause of becoming sour creates free radical, in addition, be a kind of oxidation accelerator containing CLA, leukotrienes, arachidonic acid etc. in rapeseed oil, this makes the autoxidation of rapeseed oil aggravate further, and the antioxidant Neng You Xiao temper free radical that goes out prevents rapeseed oil from becoming sour.So in order to ensure the cating quality of rapeseed oil within the shelf-life and security, it is very necessary for adding a certain amount of antioxidant.
The antioxidant that rapeseed oil uses in the market is mainly TBHQ (TBHQ) (as shown in Figure 1) of chemical synthesis.Though TBHQ has anti-oxidant, delay rapeseed oil and to become sour rotten effect, if the mankind eat for a long time as edible oil additive, have the danger bringing out deformity, cancer.Research shows: taking 1g hydroquinones can stimulate esophagus and cause tinnitus, Nausea and vomiting, stomachache, collapse; Taking 5g can be lethal.Also there are some researches show, it may cause ADD and asthma, rhinitis and dermatitis, and it also may increase the weight of symptom and the dysphoria of hyperactivity further.Raise the animal used as test of adding high dose TBHQ, experiment proves, display is brought out cancer of the stomach, caused DNA damage.Research also shows, it may have impact to human female inner estrogen level.In addition, Long Term Contact TBHQ steam, dust or smog can chafe, mucous membranes, and cause the crystalline of eye muddy.Therefore the natural adding edible safety in rapeseed oil is extremely urgent.Through document and new patent searching, there is not yet with the report of wholefood sweetener-Radix Glycyrrhizae glucosides as the antioxidant of rapeseed oil.
Summary of the invention
The object of the invention is for overcoming the deficiencies in the prior art, and a kind of rapeseed oil making antioxidant with Radix Glycyrrhizae glucosides is provided.
The technical scheme realizing the object of the invention is:
Making a rapeseed oil for antioxidant with Radix Glycyrrhizae glucosides, is in the rapeseed oil squeezed, add Radix Glycyrrhizae glucosides be mixed.
The addition of described Radix Glycyrrhizae glucosides is by weight ratio: rapeseed oil: Radix Glycyrrhizae glucosides= 100: 0.1-6.0.
Described Radix Glycyrrhizae glucosides derives from herbaceous plant Radix Glycyrrhizae, and its sugariness is 80 times of sucrose.
Applicant is that the antioxidation of index to Radix Glycyrrhizae glucosides component has done following research with peroxide value (POV value) and acid value:
The rapeseed oil not adding antioxidant by just squeezing out is first blank, and second and third adds the TBHQ (TBHQ) of a certain amount of Radix Glycyrrhizae glucosides component and food standard level respectively.Three samples are put into certain insulating box, and certain interval of time sampling detects its peroxide value and acid value.Result shows:
(1) Radix Glycyrrhizae glucosides component has antioxidation, and effect is close with TBHQ; Add the stability that appropriate Radix Glycyrrhizae glucosides component effectively can improve rapeseed oil, nutrition is not oxidized;
(2) in rapeseed oil, quality percentage 5% Radix Glycyrrhizae glucosides constituent content is equivalent to the antioxidant effect of quality percentage 0.025%TBHQ;
(3) Radix Glycyrrhizae glucosides component can play antioxidation in rapeseed oil, and its antioxidant effect and Radix Glycyrrhizae glucosides concentration of component are dosage positive-effect relation;
(4) Radix Glycyrrhizae glucosides tool antioxidation, can extend the storage period of rapeseed oil, harmless, can also improve the quality of rapeseed oil.When natural storage stores 60 days without direct sunlight, rapeseed oil peroxide value (mmol/kg) without any antioxidant of interpolation is 100%, and the peroxide value (mmol/kg) of adding Radix Glycyrrhizae glucosides and TBHQ (english abbreviation: TBHQ) same period is respectively 49% and 42%.Visible, Radix Glycyrrhizae glucosides is the same with TBHQ (TBHQ) has antioxidant effect, although the former does not have the latter's antioxidant effect strong, the former is natural, harmless.The latter is synthetic, harmful.
Advantage of the present invention is: be applied in rapeseed oil by wholefood sweetener-Radix Glycyrrhizae glucosides, prove through test, the antioxidation of Radix Glycyrrhizae glucosides is the same with chemical synthesis antioxidant-TBHQ (TBHQ) has antioxidation, the storage period of rapeseed oil can be extended, harmless, the quality of rapeseed oil can also be improved.
Accompanying drawing explanation
Fig. 1 is the molecular structural formula of TBHQ;
fig. 2 is the molecular structural formula of Radix Glycyrrhizae glucosides of the present invention.
Detailed description of the invention
Embodiment 1:
Make a rapeseed oil for antioxidant with Radix Glycyrrhizae glucosides, be add Radix Glycyrrhizae glucosides in the rapeseed oil squeezed, the interpolation weight part ratio of Radix Glycyrrhizae glucosides is: rapeseed oil: Radix Glycyrrhizae glucosides=100: 4, mix and make.
Products obtained therefrom, detects after depositing 18 months, and non-oxidation is become sour phenomenon.
Embodiment 2:
Make a rapeseed oil for antioxidant with Radix Glycyrrhizae glucosides, be add Radix Glycyrrhizae glucosides in the rapeseed oil squeezed, the interpolation weight part ratio of Radix Glycyrrhizae glucosides is: rapeseed oil: Radix Glycyrrhizae glucosides=100: 5, mix and make.
Products obtained therefrom, detects after depositing 18 months, and non-oxidation is become sour phenomenon.

Claims (2)

1. make a rapeseed oil for antioxidant with Radix Glycyrrhizae glucosides, it is characterized in that: in rapeseed oil, add Radix Glycyrrhizae glucosides make.
2. rapeseed oil according to claim 1, is characterized in that: the addition of described Radix Glycyrrhizae glucosides is by weight: rapeseed oil: Radix Glycyrrhizae glucosides=100: 0.1-6.0.
CN201510207195.1A 2015-04-28 2015-04-28 Rapeseed oil using liquiritoside as antioxidant Pending CN105265610A (en)

Priority Applications (1)

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CN201510207195.1A CN105265610A (en) 2015-04-28 2015-04-28 Rapeseed oil using liquiritoside as antioxidant

Publications (1)

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CN105265610A true CN105265610A (en) 2016-01-27

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108477308A (en) * 2018-02-22 2018-09-04 安徽中盛食用油科技有限公司 A kind of anti-oxidant rapeseed oil

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1747657A (en) * 2002-12-10 2006-03-15 维加奥尔斯有限公司 Food oil product and the use of the same
CN1871332A (en) * 2003-08-22 2006-11-29 维加奥尔斯有限公司 Antioxidant and its use
CN104629896A (en) * 2015-01-30 2015-05-20 安徽赵老五油脂有限公司 Processing method of aromatic oxidation-resistant rapeseed oil

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1747657A (en) * 2002-12-10 2006-03-15 维加奥尔斯有限公司 Food oil product and the use of the same
CN1871332A (en) * 2003-08-22 2006-11-29 维加奥尔斯有限公司 Antioxidant and its use
CN104629896A (en) * 2015-01-30 2015-05-20 安徽赵老五油脂有限公司 Processing method of aromatic oxidation-resistant rapeseed oil

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
洪庆慈: "甘草的抗氧化性能及其它", 《粮食储藏》 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108477308A (en) * 2018-02-22 2018-09-04 安徽中盛食用油科技有限公司 A kind of anti-oxidant rapeseed oil

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Application publication date: 20160127