CN105261773A - Methanol-water hydrogen production generator - Google Patents

Methanol-water hydrogen production generator Download PDF

Info

Publication number
CN105261773A
CN105261773A CN201510700191.7A CN201510700191A CN105261773A CN 105261773 A CN105261773 A CN 105261773A CN 201510700191 A CN201510700191 A CN 201510700191A CN 105261773 A CN105261773 A CN 105261773A
Authority
CN
China
Prior art keywords
hydrogen
methanol
water
liquid
fuel cell
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510700191.7A
Other languages
Chinese (zh)
Inventor
鄂树理
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shanghai Yiguo Environmental Protection Technology Co Ltd
Original Assignee
Shanghai Yiguo Environmental Protection Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shanghai Yiguo Environmental Protection Technology Co Ltd filed Critical Shanghai Yiguo Environmental Protection Technology Co Ltd
Priority to CN201510700191.7A priority Critical patent/CN105261773A/en
Publication of CN105261773A publication Critical patent/CN105261773A/en
Pending legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
    • H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
    • H01M8/0618—Reforming processes, e.g. autothermal, partial oxidation or steam reforming
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04007—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids related to heat exchange
    • H01M8/04029—Heat exchange using liquids
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0662—Treatment of gaseous reactants or gaseous residues, e.g. cleaning
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0662—Treatment of gaseous reactants or gaseous residues, e.g. cleaning
    • H01M8/0687—Reactant purification by the use of membranes or filters
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Fuel Cell (AREA)
  • Hydrogen, Water And Hydrids (AREA)

Abstract

The invention discloses a methanol-water hydrogen production generator, which comprises a liquid reservoir system, a hydrogen production system and a power generation system, which are sequentially connected with one another, wherein the liquid reservoir system is used for providing methanol water to the hydrogen production system; and the hydrogen production system is used for producing hydrogen from the methanol water and then conveying the hydrogen to the power generation system for carrying out power generation. Through the application of the methanol-water hydrogen production generator disclosed by the invention, the purity of the transmitted methanol water and hydrogen is improved to prevent a transmission pipeline from being damaged or blocked by adding a gas filter and a liquid filter; cooling is carried out on a fuel cell by a circulating water pipe which is communicated with a water storage tank; meanwhile, the water temperature in the water storage tank can be improved; the fuel cell can simultaneously carry out transformation and power generation in two forms, namely gaseous hydrogen and liquid hydrogen; the power generation efficiency is improved; and the methanol-water hydrogen production generator is simple in structure and easy to manufacture, install and use.

Description

A kind of methanol-water preparing hydrogen, generating power machine
Technical field
The present invention relates to hydrogen gas generation technical field, particularly relate to a kind of methanol-water preparing hydrogen, generating power machine.
Background technology
As everyone knows, along with the scarcity day by day of earth resource, tellurian limited resources are more and more in short supply.Show that hydrogen likely becomes the following optimal energy according to science at present, when its chief reason is the burning coal of identical weight, gasoline and hydrogen, the energy that hydrogen produces is maximum, and combustion of hydrogen is water, residue or waste gas can not be produced, can not produce environment and pollute, what oil and burning of coal generated by contrast is carbon dioxide and sulfur dioxide is the principal element causing greenhouse effect and acid rain.The more important thing is reserves problem, coal and oil are limited resources, and hydrogen is mainly present in hydrone, product after the hydrogen burning in hydrone is complete is also water, on the earth, the area of 70 percent is awash, reserves are quite big, almost can think that hydrogen is the energy of " inexhaustible ".
Hydrogen is a kind of colourless gas.Distribute in the Nature also comparatively extensive.The content of the hydrogen that is right on earth just occupies 11%.The purposes of hydrogen also very wide, hydrogen fuel cell Haier can be directly changed into electric energy by hydrogen, and the utilization of Hydrogen Energy is divided for convenience.Simultaneously hydrogen is easy to become liquid under certain pressure and temperature, can so that traffic transport or directly use as fuel.
The global annual production of hydrogen is now about 3600 tons, wherein the overwhelming majority is all produce from coal, oil and natural gas, this method is to originally causing more consumption with regard to limited resources very in short supply, another kind method adopts the method for brine electrolysis to produce, this has larger consumption to electric energy, does not calculate very much.Also constantly exploring new hydrogen production process these people, showing according to the study to utilize methyl alcohol and water reformation hydrogen production, can production cost be reduced.Utilizing advanced methanol gasifying to reform by pressure swing adsorption making pure hydrogen and the mist being rich in CO2, through further processing, hydrogen and carbon dioxide can be obtained simultaneously.
This technique is with the methyl alcohol of convenient sources and desalted water for raw material, and at 220 ~ 280 DEG C, special-purpose catalyst is catalytically conveted to and consists of mainly hydrogeneous and carbon dioxide conversion gas, its principle is as follows:
CH 3OH＝CO+2H 2(1)
CO+H 2O＝CO 2+H 2(2)
CH 3OH+H 2O＝CO 2+3H 2(3)
The CO produced after reforming reaction 2and H 2,through palladium UF membrane by CO 2and H 2separately, obtain high-purity hydrogen, the power consumption of pressure swing adsorption method is high, the large and improper small-scale hydrogen gas generation preparation of equipment.Also there is following defect: 1, can containing the easy blocking pipes of harmful substance such as S, P, CL, wearing and tearing pipeline in original methyl alcohol simultaneously; 2, the unreacted methyl alcohol of fraction can be produced after methyl alcohol distillation and cause wastage of material; 3, methyl alcohol has inflammable characteristic, and its steam is once mix with air and can form explosive mixture, if run into high temperature, danger that naked light has combustion explosion.
Therefore we need a kind of can realize safety and stability start fast, again can the preparing hydrogen, generating power machine of energy savings.
Summary of the invention
The invention discloses a kind of methanol-water preparing hydrogen, generating power machine, not highly cause line clogging or corrosion pipeline in order to solve in prior art the purity that there is preparing hydrogen, generating power mechanism hydrogen, have fraction methyl alcohol not react to cause the waste of raw material, methanol steam at high temperature can be mixed into the problem in the urgent need to address such as unstable combustion explosion thing with air.
For achieving the above object, the technical solution used in the present invention is:
A kind of methanol-water preparing hydrogen, generating power machine, wherein, comprising: the liquid memory system, hydrogen generating system and the electricity generation system that connect successively;
Be provided with liquid filter between described liquid memory system and described hydrogen generating system, between described hydrogen generating system and described electricity generation system, be provided with pneumatic filter;
Described liquid memory system, comprises methanol feedstock case, storage tank, methanol-water blending bin, and described methanol feedstock case and described storage tank are all connected with described methanol-water blending bin;
Described hydrogen generating system, comprises ultrasonic vibration installation, palladium membrane hydrogen separation device, and described methanol-water blending bin circulates with described ultrasonic vibration installation and is connected, and is connected with the input of described palladium membrane hydrogen separation device with the output of described ultrasonic vibration installation;
Described electricity generation system, comprise fuel cell and the hydrogen storage case connected successively, liquefaction of hydrogen device, liquefaction of hydrogen storage bin, the input of described hydrogen storage case is connected with described palladium membrane hydrogen separation device, the output of described hydrogen storage case is connected with the gaseous state interface of described fuel cell, and the output of described liquefaction of hydrogen storage bin is connected with the liquid interface of described fuel cell;
Described liquid memory system provides described hydrogen generating system methanol-water, is generated electricity to being sent to electricity generation system after methanol-water hydrogen manufacturing by hydrogen generating system.
Above-mentioned methanol-water preparing hydrogen, generating power machine, wherein, described storage tank is communicated with a circulating water pipe, and described circulating water pipe has part by described fuel battery inside.
Above-mentioned methanol-water preparing hydrogen, generating power machine, wherein, is provided with liquid filter between described methanol-water blending bin and described ultrasonic vibration installation.
Above-mentioned methanol-water preparing hydrogen, generating power machine, wherein, is provided with pneumatic filter between described palladium membrane hydrogen separation device and described hydrogen reservoir.
Above-mentioned methanol-water preparing hydrogen, generating power machine, wherein, the output of described methanol feedstock case, the output of described storage tank are all communicated with a water flow regulating device, and the output of described water flow regulating device connects methanol-water blending bin.
Above-mentioned methanol-water preparing hydrogen, generating power machine, wherein, described fuel cell connects an accumulate case.
Above-mentioned methanol-water preparing hydrogen, generating power machine, wherein, a regulating and controlling valve is equipped with between described methanol-water blending bin and described liquid filter, between described pneumatic filter and described hydrogen storage case, between described hydrogen storage case and described gaseous state interface, between described liquefaction of hydrogen storage bin and described liquid interface.
A kind of methanol-water preparing hydrogen, generating power machine of the present invention, the scheme that have employed as above has following effect:
1, improve by increasing pneumatic filter and liquid filter damage or the blocking that transmission methanol-water and hydrogen purity prevent transmission pipeline;
2, the circulating water pipe utilizing storage tank to be communicated with is lowered the temperature to fuel cell, can improve the water temperature in storage tank simultaneously;
3, fuel cell can adopt gaseous hydrogen and liquid hydrogen two kinds of forms to input to carry out conversion generating simultaneously, improves generating efficiency;
4, its structure is simple, is easy to manufacture, installs, uses.
Accompanying drawing explanation
By reading the detailed description done non-limiting example with reference to following accompanying drawing, the further feature of invention, object and advantage will become more obvious.
Fig. 1 is the structural representation of a kind of methanol-water preparing hydrogen, generating power of the present invention machine.
As schemed reference: liquid filter 1, pneumatic filter 2, regulating and controlling valve 3, accumulate case 4, circulating water pipe 5, liquid memory system 100, methanol feedstock case 101, storage tank 102, methanol-water blending bin 103, water flow regulating device 104, hydrogen generating system 200, ultrasonic vibration installation 201, palladium membrane hydrogen separation device 202, electricity generation system 300, hydrogen storage case 301, liquefaction of hydrogen device 302, liquefaction of hydrogen storage bin 303, gaseous state interface 304, liquid interface 305.
Embodiment
The technological means realized to make invention, creating feature, reach object and effect is easy to understand, lower combination specifically illustrates, and sets forth the present invention further.
Shown in Fig. 1, a kind of methanol-water preparing hydrogen, generating power machine, wherein, comprising: the liquid memory system 100 connected successively, hydrogen generating system 200 and electricity generation system 300;
Liquid filter 1 is provided with between liquid memory system 100 and hydrogen generating system 200, pneumatic filter 2 is provided with between hydrogen generating system 200 and electricity generation system 300, the methanol-water further sent by liquid filter 1 pair of liquid memory system 100 filters the purity improving methanol-water with this, carries out adsorption filtration simultaneously and discharge isolated carbon dioxide by the hydrogen of pneumatic filter 2 pairs of hydrogen generating systems 200;
Liquid memory system 100, comprise methanol feedstock case 101, storage tank 102, methanol-water blending bin 103, methanol feedstock case 101 is all connected with methanol-water blending bin 103 with storage tank 102, utilizes methanol-water blending bin 103 pairs of methyl alcohol and water to carry out proportioning and reaches best admixture;
Hydrogen generating system 200, comprises ultrasonic vibration installation 201, palladium membrane hydrogen separation device 202, and methanol-water blending bin 103 circulates with ultrasonic vibration installation 201 and is connected, and is connected with the input of palladium membrane hydrogen separation device 202 with the output of ultrasonic vibration installation 201.Further, carry out gaseous state transformation by ultrasonic vibration installation 201 pairs of methanol-waters, the gaseous state that methanol-water produces after ultrasonic vibration installation 201 is changed contains hydrogen and carbon dioxide, is normal temperature in the temperature of this hydrogen.Further in the past methanol-water gaseous state transfer process in usually use the method that high-temperature heating produces steam carried out to methanol-water, it improves the temperature of hydrogen, once high-temperature hydrogen has merged other unstable gases or naked light, electrostatic etc. can be blasted, this brings great potential safety hazard to production, and the low temperature hydrogen compared in the present invention then can avoid the generation of this type of thing.
Electricity generation system 300, comprise fuel cell 306 and the hydrogen storage case 301 connected successively, liquefaction of hydrogen device 302, liquefaction of hydrogen storage bin 303, the input of hydrogen storage case 301 is connected with palladium membrane hydrogen separation device 202, the output of hydrogen storage case 100 is connected with the gaseous state interface 304 of fuel cell 306, and the output of liquefaction of hydrogen storage bin 303 is connected with the liquid interface 305 of fuel cell 306.Further, the hydrogen after pneumatic filter 2 filters is stored by hydrogen storage case 301, at gaseous state interface 304 and liquefaction of hydrogen device 302 that the output of hydrogen storage case 301 is two difference connecting fuel batteries 306, realize supplying the hydrogen of fuel cell 306 with this, utilize liquefaction of hydrogen device 302 pairs of hydrogen liquefy and be stored in liquefaction of hydrogen storage bin 303 simultaneously, be connected to the liquid interface 305 of fuel cell 306, to realize supplying the hydrogen liquid of fuel cell 306 at this liquefaction of hydrogen storage bin 303 simultaneously.At for subsequent use use storage bin of this liquefaction of hydrogen storage bin 303 as hydrogen storage case 301;
Liquid memory system 100 will provide hydrogen generating system 200 methanol-water after mixing, generate electricity by being sent to electricity generation system 300 after hydrogen generating system 200 pairs of methanol-water hydrogen manufacturing.
In a particular embodiment of the present invention, storage tank 102 is communicated with a circulating water pipe 5, circulating water pipe 5 has part inner by fuel cell 306, further, circulating water pipe 5 is mainly lowered the temperature to fuel cell 306, circulating water pipe 5 is that circulating type is enclosed in outside fuel cell 306 in the structure of storage tank 102 inside, and the water in this storage tank 102 heats up under the transmission of circulating water pipe 5, makes it can merge with methyl alcohol more quickly in methanol-water blending bin 103.
In a particular embodiment of the present invention, between methanol-water blending bin 103 and ultrasonic vibration installation 201, be provided with liquid filter 1, carry out filtration by the methanol-water of liquid filter 1 pair of methanol-water blending bin 103 and remove other materials.
In a particular embodiment of the present invention, be provided with pneumatic filter 2 between palladium membrane hydrogen separation device 202 and hydrogen reservoir 301, filter the isolated hydrogen of palladium membrane hydrogen separation device 202 by pneumatic filter 2, the purity of hydrogen improves.
In a particular embodiment of the present invention, the output of methanol feedstock case 101, the output of storage tank 102 are all communicated with a water flow regulating device 104, the output of water flow regulating device 104 connects methanol-water blending bin 103, further, control water flow regulating device 104 to allocate the ratio of both the water that the methyl alcohol of methanol feedstock case 101 output, storage tank 102 export.
In a particular embodiment of the present invention, fuel cell 306 connects an accumulate case 4, is stored by the electric energy that fuel cell 306 is changed by accumulate case 4.
In a particular embodiment of the present invention, be equipped with a regulating and controlling valve 3 between methanol-water blending bin 103 and liquid filter 1, between pneumatic filter 2 and hydrogen storage case 301, between hydrogen storage case 301 and gaseous state interface 304, between liquefaction of hydrogen storage bin 303 and liquid interface 305, regulated and controled by the pipeline of regulating and controlling valve 3 pairs of transport gas or liquid.
In the specific embodiment of the present invention, water in methyl alcohol in methanol feedstock case 101 and storage tank 102 inputs in methanol-water blending bin 103 by regulation and control water flow regulating device 104 in proportion to be allocated, the methanol-water of the fusion in methanol-water blending bin 103 enters ultrasonic vibration installation 201 through liquid filter 1 and is atomized, methanol-water after atomization enters palladium membrane hydrogen separation device 202 and carries out being separated of carbon dioxide and hydrogen, hydrogen after separation enters hydrogen storage case 301 and stores, in the gaseous state interface 304 hydrogen being transported to fuel cell 306 respectively at this hydrogen storage case 301 and liquefaction of hydrogen device 302, low-temperature liquefaction process is carried out after entering liquefaction of hydrogen device 302, liquid hydrogen after process is stored in liquefaction of hydrogen storage bin 301, gas liquefaction storage bin 301 is by the liquid interface 305 of liquid hydrogen input fuel cell.Further, enter hydrogen in fuel cell 306 and liquid hydrogen is converted to electric energy by fuel cell 306, be mainly in the present invention supplied as master with hydrogen, liquid hydrogen is auxiliary.
In sum, a kind of methanol-water preparing hydrogen, generating power of the present invention machine, damage or the blocking that transmission methanol-water and hydrogen purity prevent transmission pipeline is improved by increasing pneumatic filter and liquid filter, the circulating water pipe utilizing storage tank to be communicated with is lowered the temperature to fuel cell, can improve the water temperature in storage tank, fuel cell can adopt gaseous hydrogen and liquid hydrogen two kinds of forms to input to carry out conversions generating, raising generating efficiency simultaneously simultaneously, its structure is simple, is easy to manufacture, installs, uses.
Above the specific embodiment of invention is described.It is to be appreciated that invention is not limited to above-mentioned particular implementation, the equipment wherein do not described in detail to the greatest extent and structure are construed as to be implemented with the common mode in this area; Those skilled in the art can make various distortion or amendment within the scope of the claims, and this does not affect essence of an invention content.

Claims (7)

1. a methanol-water preparing hydrogen, generating power machine, is characterized in that, comprising: the liquid memory system, hydrogen generating system and the electricity generation system that connect successively;
Be provided with liquid filter between described liquid memory system and described hydrogen generating system, between described hydrogen generating system and described electricity generation system, be provided with pneumatic filter;
Described liquid memory system, comprises methanol feedstock case, storage tank, methanol-water blending bin, and described methanol feedstock case and described storage tank are all connected with described methanol-water blending bin;
Described hydrogen generating system, comprises ultrasonic vibration installation, palladium membrane hydrogen separation device, and described methanol-water blending bin circulates with described ultrasonic vibration installation and is connected, and is connected with the input of described palladium membrane hydrogen separation device with the output of described ultrasonic vibration installation;
Described electricity generation system, comprise fuel cell and the hydrogen storage case connected successively, liquefaction of hydrogen device, liquefaction of hydrogen storage bin, the input of described hydrogen storage case is connected with described palladium membrane hydrogen separation device, the output of described hydrogen storage case is connected with the gaseous state interface of described fuel cell, and the output of described liquefaction of hydrogen storage bin is connected with the liquid interface of described fuel cell;
Described liquid memory system provides described hydrogen generating system methanol-water, is generated electricity to being sent to electricity generation system after methanol-water hydrogen manufacturing by hydrogen generating system.
2. methanol-water preparing hydrogen, generating power machine according to claim 1, it is characterized in that, described storage tank is communicated with a circulating water pipe, and described circulating water pipe has part by described fuel battery inside.
3. methanol-water preparing hydrogen, generating power machine according to claim 1, is characterized in that, is provided with liquid filter between described methanol-water blending bin and described ultrasonic vibration installation.
4. methanol-water preparing hydrogen, generating power machine according to claim 1, is characterized in that, be provided with pneumatic filter between described palladium membrane hydrogen separation device and described hydrogen reservoir.
5. methanol-water preparing hydrogen, generating power machine according to claim 1, is characterized in that, the output of described methanol feedstock case, the output of described storage tank are all communicated with a water flow regulating device, and the output of described water flow regulating device connects methanol-water blending bin.
6. methanol-water preparing hydrogen, generating power machine according to claim 1, is characterized in that, described fuel cell connects an accumulate case.
7. methanol-water preparing hydrogen, generating power machine according to claim 1, it is characterized in that, between described methanol-water blending bin and described liquid filter, between described pneumatic filter and described hydrogen storage case, between described hydrogen storage case and described gaseous state interface, between described liquefaction of hydrogen storage bin and described liquid interface, be equipped with a regulating and controlling valve.
CN201510700191.7A 2015-10-26 2015-10-26 Methanol-water hydrogen production generator Pending CN105261773A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510700191.7A CN105261773A (en) 2015-10-26 2015-10-26 Methanol-water hydrogen production generator

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510700191.7A CN105261773A (en) 2015-10-26 2015-10-26 Methanol-water hydrogen production generator

Publications (1)

Publication Number Publication Date
CN105261773A true CN105261773A (en) 2016-01-20

Family

ID=55101349

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201510700191.7A Pending CN105261773A (en) 2015-10-26 2015-10-26 Methanol-water hydrogen production generator

Country Status (1)

Country Link
CN (1) CN105261773A (en)

Similar Documents

Publication Publication Date Title
CA2930469C (en) Plant complex for steel production and method for operating the plant complex
Schiebahn et al. Power to gas
CN103999277A (en) Method and a system for combined hydrogen and electricity production using petroleum fuels
CN102897712B (en) Methanol-water hydrogen production system and hydrogen production method thereof
CN108884761A (en) ammonia cracking
CN102616740B (en) Methanol-water reforming hydrogen production device and method for preparing hydrogen by using same
CN101676368A (en) A chemical product providing system and method for providing a chemical product
CN103626128A (en) Quick-start system for preparing hydrogen from methanol and water and hydrogen preparation method by using system
CN107461606A (en) A kind of method that electric energy is stored in natural gas pipeline
CN113451612B (en) Green and efficient power-ammonia-power energy system
CN102874754A (en) System and method for preparing hydrogen by using methanol water
CN103058137B (en) Movable type methanol water hydrogen manufacturing system and method
TR201815229T4 (en) A method of gas preparation with very high methane content and a system for this purpose.
CN103579653B (en) The instant hydrogen manufacturing electricity generation system of methanol-water and control method thereof
JP5557255B2 (en) Reactant manufacturing method and manufacturing system using exhaust heat and renewable energy
CN203998946U (en) Carbonated gas returns to the device of on-catalytic converter energy-saving and production-increase synthetic gas
CN112531185A (en) Power generation system and method using methanol as raw material
CN202596893U (en) Electricity-synthetic natural gas peak shaving power generation system based on catalytic gasification
CN205122695U (en) Methanol -water hydrogen manufacturing generator
CN105261773A (en) Methanol-water hydrogen production generator
CN213936267U (en) Power generation system with methanol as raw material
CN102849679B (en) Hydrogen-producing device and hydrogen-producing method thereof
CN102897713B (en) Apparatus and method for hydrogen production through methanol steam reforming
CN203006938U (en) Movable type methanol-water hydrogen production system
CN203938646U (en) A kind of integrated refining system with oil shale distillation gas hydrogen manufacturing upgrading

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
WD01 Invention patent application deemed withdrawn after publication
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20160120