CN105252869A - Glass heat-insulating polyester fiber compound pasting film and processing technique thereof - Google Patents
Glass heat-insulating polyester fiber compound pasting film and processing technique thereof Download PDFInfo
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- CN105252869A CN105252869A CN201510815571.5A CN201510815571A CN105252869A CN 105252869 A CN105252869 A CN 105252869A CN 201510815571 A CN201510815571 A CN 201510815571A CN 105252869 A CN105252869 A CN 105252869A
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- polyester fiber
- layer
- polyester
- glass heat
- insulating
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/02—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by a sequence of laminating steps, e.g. by adding new layers at consecutive laminating stations
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/06—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/10—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/10—Interconnection of layers at least one layer having inter-reactive properties
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/10—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
- B32B2037/1072—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure using a fluid jet
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/02—Synthetic macromolecular fibres
- B32B2262/0276—Polyester fibres
Abstract
The invention discloses a glass heat-insulating polyester fiber compound pasting film and a processing technique thereof. The glass heat-insulating polyester fiber compound pasting film comprises an anti-radiation coating, a second BOPP layer, a second bonding layer, a polyester fiber middle layer, a first bonding layer and a first BOPP layer from top to bottom in turn. During a processing process, the polyester fiber middle layer is acquired according to the following steps: uniformly mixing functional fiber master batch with polyester polyol at the weight ratio of (85-95):10, fusing and extruding through a twin-screw extruder; the polyester adhesives, namely, a first adhering layer and a second adhering layer, are respectively coated to the two sides of the polyester fiber middle layer; the first BOPP layer and the second BOPP layer are respectively adhered to the side walls of the polyester fiber middle layer through the second adhering layer and the first adhering layer; the compound shaping in an oven and the cutting operation are performed, and then the glass heat-insulating polyester fiber compound pasting film is acquired. The glass heat-insulating polyester fiber compound pasting film has the advantages of ageing resistance, corrosion resistance, high transparency, high-efficient thermal storage and heat insulation, thermal insulation and noise reduction, breakage splashing prevention, radiation protection, and the like, is recyclable and reusable, and is nontoxic and non-stimulating.
Description
Technical field
The present invention relates to field of heat insulating materials, specifically a kind of glass heat-insulating polyester fiber composite film-stuck and processing technology thereof.
Background technology
Insulation material generally refers to that thermal conductivity factor is less than or equal to the material of 0.2.Insulation material Materials is very fast, adopts good heat preservation technology and material, often can play a multiplier effect in industry and building.Often use one ton of mineral wool insulating product in building, one ton of oil within 1 year, can be saved.Insulation material kind is extensive in the market.Wherein, glass heat-insulating material mainly polyvinyl chloride, polystyrene etc. to human body and respiratory system deleterious material, along with people are to the raising of quality of life, environmental protection, health care consciousness, highlight harm and the pollution of the glass heat-insulating film that various non-environmental protection material is made, therefore, be badly in need of wanting a kind of can substitute traditional deleterious materials such as polyvinyl chloride, polystyrene, polyethylene and possess that more superior heat-insulation and heat-preservation, reduction noise, anti-glass brokenly spatter, radiation-resistant environment-friendly products update.
Summary of the invention
The object of the invention is to utilize interlayer heat-insulating usefulness to strengthen principle, the polyester fiber of low thermal conductivity and biaxially oriented polypropylene film are formed six layers of composite integrated structure by polyester binder, further reduction thermal conductivity factor, there is provided a kind of there is more heat insulation, heat storing and heat preserving, reduction noise, breakage-proofly to spatter, radiation proof to human body without any stimulation or harm be specifically designed to indoor glass surface polyester fiber composite film-stuck and processing technology, to solve the problem proposed in above-mentioned background technology.
For achieving the above object, the invention provides following technical scheme:
A kind of glass heat-insulating polyester fiber composite film-stuck is six layers of composite construction, from top to bottom successively respectively: antiradiation coating, the 2nd BOPP layer, the second adhesive layer, polyester fiber intermediate layer, the first adhesive layer, a BOPP layer.
As the further scheme of the present invention: the first adhesive layer and the second adhesive layer adopt polyester binder.
A processing technology for glass heat-insulating polyester fiber composite film-stuck, is made up of following steps:
The first step: the preparation in polyester fiber intermediate layer:
Mixed according to the mass ratio of 85-95:10 by functional fibre masterbatch and saturated polyol polyester, after 250 DEG C of meltings, extrude through double screw extruder that thickness is even, the polyester fiber intermediate layer of weight between 100-150g of every square metre;
Second step: the preparation of polyester binder:
Polyester binder is by saturated polyol polyester and the ethyl acetate mass ratio Homogeneous phase mixing according to 70-75:27, stand-by as adhesive after heated sealed to 70 DEG C melting;
3rd step: the both sides, polyester fiber intermediate layer of the first step being prepared evenly apply polyester binder respectively, are namely respectively the first adhesive layer and the second adhesive layer;
4th step: the side of bidirectional stretching polypropylene film is applied antiradiation coating by coating machine, obtains the 2nd BOPP layer;
5th step: above-mentioned 2nd BOPP layer will pass through a side gluing in the second adhesive layer and polyester fiber intermediate layer without the side of antiradiation coating, by both sides all without a BOPP layer of antiradiation coating by the another side gluing in the first adhesive layer and polyester fiber intermediate layer, enter baking oven simultaneously, adopt two-region hot blast high-temperature hot Convective Heating mode, carry out composite setting, cutting, makes glass heat-insulating polyester fiber composite film-stuck.
As the further scheme of the present invention: the mass ratio of functional fibre masterbatch and saturated polyol polyester is 90:10.
As the further scheme of the present invention: the mass ratio of saturated polyol polyester and ethyl acetate is 73:27.
Above-mentioned functions fiber master batch require be adopt the process of copolymerization mixing method there is permanent functional fiber.
The preparation of above-mentioned saturated polyol polyester adopts batch process manufacturing process, and the preparation of ethyl acetate adopts direct esterification manufacturing process.
Compared with prior art, the invention has the beneficial effects as follows:
1, because product is all adopt the physical process moulding process that carries out of high-performance fiber, product, can 100% recycle and reuse except having the advantage such as ageing-resistant, corrosion-resistant, the high grade of transparency, shielding of ultraviolet, high heat insulating ability, noise reduction.Namely meet insulation, reduce the particular/special requirement of the special dimensions such as noise, anti-glass brokenly spatter, radiation proof, the degree of depth also meeting renewable resource utilization that state key helps and natural resources such as to make full use of at the encouragement project.
2, advanced free of contamination heat coating combination process is adopted, realize serialization and automated production, for the particular/special requirement meeting glass heat-insulating carries out deep processing compound, namely adopt low-melting point polyester product as adhesive, two-region high-temperature hot Convective Heating mode, makes firmly integrative-structure product by polyester fiber intermediate layer and BOPP compound.Strengthen radiation proof function, the heat-accumulating and-keeping effect of more outstanding product.
3, the present invention except it possess high-efficiency thermal storage insulation, heat-insulation noise-reduction, breakage-proofly to spatter, except the performance of radiation-resistant particular/special requirement, owing to not having chemical reaction in whole technical process, raw material can 100% recycle and reuse.Thus whole production process and product do not have toxicity and excitant, can not bring harm, do not pollute the environment yet to human body.
Glass heat-insulating polyester fiber composite film-stuck of the present invention is after testing: fusing point >=210 DEG C, thermal conductivity factor is less than or equal to 0.13w/mk, is suitable as the insulation material of indoor window glass.
Accompanying drawing explanation
Fig. 1 is the cross-section structure of the embodiment of the present invention;
Fig. 2 is the processing process figure of glass heat-insulating polyester fiber composite film-stuck embodiment of the present invention;
In figure: 1-the one BOPP layer, 2-first adhesive layer, 3-polyester fiber intermediate layer, 4-second adhesive layer, 5-the 2nd BOPP layer, 6-antiradiation coating.
Detailed description of the invention
Below in conjunction with the embodiment of the present invention, be clearly and completely described the technical scheme in the embodiment of the present invention, obviously, described embodiment is only the present invention's part embodiment, instead of whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art, not making the every other embodiment obtained under creative work prerequisite, belong to the scope of protection of the invention.
Embodiment 1
Refer to Fig. 1-Fig. 2, in the embodiment of the present invention, a kind of glass heat-insulating polyester fiber composite film-stuck is six layers of composite construction, from top to bottom successively respectively: antiradiation coating 6, the 2nd BOPP layer 5, second adhesive layer 4, polyester fiber intermediate layer 3, first adhesive layer 2, a BOPP layer 1.BOPP is the abbreviation of " BiaxiallyOrientedPolypropylene ", i.e. bidirectional stretching polypropylene film.First adhesive layer 2 and the second adhesive layer 4 adopt polyester binder.For improving heat insulation effect, strengthen cohesive force, above-mentioned polyester fiber intermediate layer 3 is full coated structure.
The processing technology of described glass heat-insulating polyester fiber composite film-stuck, is made up of following steps:
The first step: the preparation in polyester fiber intermediate layer 3:
Mixed according to the mass ratio of 85:10 by functional fibre masterbatch and saturated polyol polyester, after 250 DEG C of meltings, extrude through double screw extruder that thickness is even, the polyester fiber intermediate layer 3 of weight between 100-150g of every square metre.
Second step: the preparation of polyester binder:
Polyester binder is by saturated polyol polyester and the ethyl acetate mass ratio Homogeneous phase mixing according to 70:27, stand-by as adhesive after heated sealed to 70 DEG C melting.
3rd step: the both sides, polyester fiber intermediate layer 3 of the first step being prepared evenly apply polyester binder respectively, is namely respectively the first adhesive layer 2 and the second adhesive layer 4;
4th step: by the side of bidirectional stretching polypropylene film by coating machine coating antiradiation coating 6.
5th step: by above-mentioned bidirectional stretching polypropylene film without antiradiation coating 6(i.e. the 2nd BOPP layer 5) side by the side gluing of the second adhesive layer 4 with polyester fiber intermediate layer 3, by both sides all without the bidirectional stretching polypropylene film (i.e. a BOPP layer 1) of antiradiation coating 6 by the another side gluing of the first adhesive layer 2 with polyester fiber intermediate layer 3, enter baking oven simultaneously, adopt two-region hot blast high-temperature hot Convective Heating mode, carry out composite setting, cutting, makes glass heat-insulating polyester fiber composite film-stuck.
Embodiment 2
In the embodiment of the present invention, identical with embodiment 1, mixed according to the mass ratio of 95:10 by functional fibre masterbatch and saturated polyol polyester unlike polyester fiber intermediate layer 3.Polyester binder by saturated polyol polyester and ethyl acetate mixed uniformly according to the mass ratio of 75:27.
Embodiment 3
In the embodiment of the present invention, identical with embodiment 1, mixed according to the mass ratio of 90:10 by functional fibre masterbatch and saturated polyol polyester unlike polyester fiber intermediate layer 3.Polyester binder by saturated polyol polyester and ethyl acetate mixed uniformly according to the mass ratio of 73:27.
To those skilled in the art, obviously the invention is not restricted to the details of above-mentioned one exemplary embodiment, and when not deviating from spirit of the present invention or essential characteristic, the present invention can be realized in other specific forms.Therefore, no matter from which point, all should embodiment be regarded as exemplary, and be nonrestrictive, scope of the present invention is limited by claims instead of above-mentioned explanation, and all changes be therefore intended in the implication of the equivalency by dropping on claim and scope are included in the present invention.
In addition, be to be understood that, although this description is described according to embodiment, but not each embodiment only comprises an independently technical scheme, this narrating mode of description is only for clarity sake, those skilled in the art should by description integrally, and the technical scheme in each embodiment also through appropriately combined, can form other embodiments that it will be appreciated by those skilled in the art that.
Claims (5)
1. a glass heat-insulating polyester fiber composite film-stuck, is characterized in that, is six layers of composite construction, from top to bottom successively respectively: antiradiation coating, the 2nd BOPP layer, the second adhesive layer, polyester fiber intermediate layer, the first adhesive layer, a BOPP layer.
2. glass heat-insulating polyester fiber composite film-stuck according to claim 1, is characterized in that, the first adhesive layer and the second adhesive layer adopt polyester binder.
3. a processing technology for the glass heat-insulating polyester fiber composite film-stuck as described in as arbitrary in claim 1-2, is characterized in that, be made up of following steps:
The first step: the preparation in polyester fiber intermediate layer:
Mixed according to the mass ratio of 85-95:10 by functional fibre masterbatch and saturated polyol polyester, after 250 DEG C of meltings, extrude even, every square metre the material of weight between 100-150g of thickness through double screw extruder namely obtain polyester fiber intermediate layer;
Second step: the preparation of polyester binder:
Polyester binder is by saturated polyol polyester and the ethyl acetate mass ratio Homogeneous phase mixing according to 70-75:27, stand-by as adhesive after heated sealed to 70 DEG C melting;
3rd step: the both sides, polyester fiber intermediate layer of the first step being prepared evenly apply polyester binder respectively, are namely respectively the first adhesive layer and the second adhesive layer;
4th step: the side of bidirectional stretching polypropylene film is applied antiradiation coating by coating machine, obtains the 2nd BOPP layer;
5th step: above-mentioned 2nd BOPP layer will pass through a side gluing in the second adhesive layer and polyester fiber intermediate layer without the side of antiradiation coating, by both sides all without a BOPP layer of antiradiation coating by the another side gluing in the first adhesive layer and polyester fiber intermediate layer, enter baking oven simultaneously, adopt two-region hot blast high-temperature hot Convective Heating mode, carry out composite setting, cutting, makes glass heat-insulating polyester fiber composite film-stuck.
4. the processing technology of glass heat-insulating polyester fiber composite film-stuck according to claim 3, is characterized in that, the mass ratio of functional fibre masterbatch and saturated polyol polyester is 90:10.
5. the processing technology of glass heat-insulating polyester fiber composite film-stuck according to claim 3, is characterized in that, the mass ratio of saturated polyol polyester and ethyl acetate is 73:27.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510815571.5A CN105252869A (en) | 2015-11-23 | 2015-11-23 | Glass heat-insulating polyester fiber compound pasting film and processing technique thereof |
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| CN201510815571.5A CN105252869A (en) | 2015-11-23 | 2015-11-23 | Glass heat-insulating polyester fiber compound pasting film and processing technique thereof |
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| CN105252869A true CN105252869A (en) | 2016-01-20 |
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| CN201510815571.5A Pending CN105252869A (en) | 2015-11-23 | 2015-11-23 | Glass heat-insulating polyester fiber compound pasting film and processing technique thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109996657A (en) * | 2016-11-29 | 2019-07-09 | 塞特工业公司 | The automated manufacturing of fiber preform |
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| WO2009010393A1 (en) * | 2007-07-18 | 2009-01-22 | Basf Se | Coating compositions |
| CN201693817U (en) * | 2010-06-22 | 2011-01-05 | 长沙灵达塑印包装有限公司 | Composite glass film |
| US20110253296A1 (en) * | 2004-05-24 | 2011-10-20 | E. I. Du Pont De Nemours And Company | Polymer blends for peelable and/or permanent seals |
| CN202702742U (en) * | 2012-07-10 | 2013-01-30 | 苏州斯迪克新材料科技股份有限公司 | Multi-layer heat insulating and anti-static glass protective film |
| CN103009744A (en) * | 2012-12-19 | 2013-04-03 | 苏州威仕科贸有限公司 | Glass building adhering film |
| CN204586024U (en) * | 2015-03-09 | 2015-08-26 | 上海浩驰科技股份有限公司 | Double-sided spray painting is without shadow glue adhering film to glass |
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2015
- 2015-11-23 CN CN201510815571.5A patent/CN105252869A/en active Pending
Patent Citations (6)
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|---|---|---|---|---|
| US20110253296A1 (en) * | 2004-05-24 | 2011-10-20 | E. I. Du Pont De Nemours And Company | Polymer blends for peelable and/or permanent seals |
| WO2009010393A1 (en) * | 2007-07-18 | 2009-01-22 | Basf Se | Coating compositions |
| CN201693817U (en) * | 2010-06-22 | 2011-01-05 | 长沙灵达塑印包装有限公司 | Composite glass film |
| CN202702742U (en) * | 2012-07-10 | 2013-01-30 | 苏州斯迪克新材料科技股份有限公司 | Multi-layer heat insulating and anti-static glass protective film |
| CN103009744A (en) * | 2012-12-19 | 2013-04-03 | 苏州威仕科贸有限公司 | Glass building adhering film |
| CN204586024U (en) * | 2015-03-09 | 2015-08-26 | 上海浩驰科技股份有限公司 | Double-sided spray painting is without shadow glue adhering film to glass |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN109996657A (en) * | 2016-11-29 | 2019-07-09 | 塞特工业公司 | The automated manufacturing of fiber preform |
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