CN105249576A - Manufacture method for multifunctional clothing material - Google Patents
Manufacture method for multifunctional clothing material Download PDFInfo
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- CN105249576A CN105249576A CN201510694530.5A CN201510694530A CN105249576A CN 105249576 A CN105249576 A CN 105249576A CN 201510694530 A CN201510694530 A CN 201510694530A CN 105249576 A CN105249576 A CN 105249576A
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- 239000000463 material Substances 0.000 title claims abstract description 37
- 238000000034 method Methods 0.000 title claims abstract description 20
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 10
- 239000000835 fiber Substances 0.000 claims abstract description 58
- 239000010410 layer Substances 0.000 claims abstract description 36
- 229920000742 Cotton Polymers 0.000 claims abstract description 30
- 239000004744 fabric Substances 0.000 claims abstract description 15
- 239000011229 interlayer Substances 0.000 claims abstract description 15
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims abstract description 7
- 235000017491 Bambusa tulda Nutrition 0.000 claims abstract description 7
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims abstract description 7
- 239000011425 bamboo Substances 0.000 claims abstract description 7
- 235000006679 Mentha X verticillata Nutrition 0.000 claims abstract description 5
- 235000002899 Mentha suaveolens Nutrition 0.000 claims abstract description 5
- 235000001636 Mentha x rotundifolia Nutrition 0.000 claims abstract description 5
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 48
- 239000000243 solution Substances 0.000 claims description 48
- 230000008859 change Effects 0.000 claims description 27
- 238000009987 spinning Methods 0.000 claims description 26
- 229920002678 cellulose Polymers 0.000 claims description 23
- 239000001913 cellulose Substances 0.000 claims description 23
- 235000011121 sodium hydroxide Nutrition 0.000 claims description 20
- 229920002101 Chitin Polymers 0.000 claims description 19
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 18
- 239000007864 aqueous solution Substances 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 12
- 239000012782 phase change material Substances 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 12
- 108010039918 Polylysine Proteins 0.000 claims description 10
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 10
- 229920000656 polylysine Polymers 0.000 claims description 10
- 229920000642 polymer Polymers 0.000 claims description 10
- 230000008569 process Effects 0.000 claims description 10
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 9
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims description 9
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 9
- 108010022355 Fibroins Proteins 0.000 claims description 8
- 239000003513 alkali Substances 0.000 claims description 8
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 8
- -1 sulphonic acid ester Chemical class 0.000 claims description 8
- 238000007796 conventional method Methods 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 244000118681 Iresine herbstii Species 0.000 claims description 5
- 238000001467 acupuncture Methods 0.000 claims description 5
- 238000010041 electrostatic spinning Methods 0.000 claims description 5
- 235000019253 formic acid Nutrition 0.000 claims description 5
- 239000011259 mixed solution Substances 0.000 claims description 5
- 238000009941 weaving Methods 0.000 claims description 5
- 230000032683 aging Effects 0.000 claims description 4
- 239000005030 aluminium foil Substances 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 4
- 238000001914 filtration Methods 0.000 claims description 4
- 239000012046 mixed solvent Substances 0.000 claims description 4
- 239000003960 organic solvent Substances 0.000 claims description 4
- 238000003825 pressing Methods 0.000 claims description 4
- 239000013557 residual solvent Substances 0.000 claims description 4
- 238000001291 vacuum drying Methods 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 238000009940 knitting Methods 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 150000002576 ketones Chemical class 0.000 claims description 2
- 150000007524 organic acids Chemical class 0.000 claims description 2
- 244000082204 Phyllostachys viridis Species 0.000 claims 1
- 241001330002 Bambuseae Species 0.000 abstract description 6
- 239000000203 mixture Substances 0.000 abstract description 5
- 108010082495 Dietary Plant Proteins Proteins 0.000 abstract description 3
- 239000002344 surface layer Substances 0.000 abstract 3
- 239000002202 Polyethylene glycol Substances 0.000 description 9
- 229920001223 polyethylene glycol Polymers 0.000 description 9
- 239000002131 composite material Substances 0.000 description 7
- 239000000126 substance Substances 0.000 description 6
- 230000009466 transformation Effects 0.000 description 6
- 239000004215 Carbon black (E152) Substances 0.000 description 5
- 229930195733 hydrocarbon Natural products 0.000 description 5
- 150000002430 hydrocarbons Chemical class 0.000 description 5
- 239000004033 plastic Substances 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- 230000007704 transition Effects 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000012188 paraffin wax Substances 0.000 description 3
- 238000002135 phase contrast microscopy Methods 0.000 description 3
- 229920002239 polyacrylonitrile Polymers 0.000 description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 150000005846 sugar alcohols Polymers 0.000 description 3
- 239000004753 textile Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 229920002689 polyvinyl acetate Polymers 0.000 description 2
- 239000011118 polyvinyl acetate Substances 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 1
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 238000004378 air conditioning Methods 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
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- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 235000012489 doughnuts Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001523 electrospinning Methods 0.000 description 1
- 238000004146 energy storage Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000012510 hollow fiber Substances 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 238000002329 infrared spectrum Methods 0.000 description 1
- 238000011177 media preparation Methods 0.000 description 1
- 239000003094 microcapsule Substances 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000241 respiratory effect Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000011232 storage material Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000028016 temperature homeostasis Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 239000002918 waste heat Substances 0.000 description 1
Landscapes
- Artificial Filaments (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Multicomponent Fibers (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The invention discloses a manufacture method for a multifunctional clothing material. The multifunctional clothing material comprises an inner layer, a surface layer and an interlayer, wherein the interlayer is positioned between the inner layer and the surface layer; a piece of fabric woven by phase-change fibers is adopted as the interlayer; the manufacture method is characterized in that vegetable protein fibers, blend fibers of bamboo fibers and cotton fibers or blend fibers of mint fibers and cotton fibers are adopted as a material used for making the inner layer and/or surface layer fabrics, wherein the cotton fibers account for 60%-90% in the blend fibers of bamboo fibers and cotton fibers and the cotton fibers account for 70%-80% in the blend fibers of mint fibers and cotton fibers.
Description
the application is application number is 2014103693882, and denomination of invention is " a kind of multifunctional clothes package material and manufacture method thereof ", and the applying date is the divisional application of the application for a patent for invention on July 30th, 2014.
Technical field
The present invention relates to a kind of preparation method of multifunctional clothes package material, belong to phase transformation multifunctional clothes package material Synthesis and applications field.
Background technology
Existing knitted underwear clothes, great majority are made up of woven, although comfortable and easy to wear, warmth retention property is poor, and occur comparatively bad smell after wearing time length.Although make warmth retention property according to multiply cloth to increase, there is the problems such as summer is sultry.Along with growth in the living standard, people more and more pay attention to the quality of living, and wish the clothing that can obtain comfort, and the living environment of hygiene and health.Require more and more higher for various textile, particularly safely, feel at ease, comfortable, healthy, health, the formation of " green " idea such as to clean, the temperature adjusting performance of textile is subject to people's attention more.
Phase change fiber be to utilize in material phase transition process release or absorb latent heat, feature development a kind of heat-accumulation temperature-adjustment functional fibre out that temperature remains unchanged.Namely phase transformation shows the change of gas, solid, liquid tri-state and crystallization, crystal formation turns the physical process such as hydrocarbon, crystal melt, along with the change of molecular aggregation state structure, PCM is joined in fiber, utilize its solid → liquid, solid → solid-state phase transformation, show different Process of absorption or liberation of heat functions at different ambient temperatures, and keep the characteristic of temperature relative constancy, obtained phase change fiber.PCM have inorganic, organic, compound point.
At present, phase-changing energy storage material (PCMs) is successfully applied to the fields such as passive solar house, energy saving building, air-conditioning system, Waste Heat Recovery, temperature-regulating fiber and textile.In the solution that the people such as Vigo start doughnut to be immersed in polyethylene glycol PEG or plastic crystal material from the mid-80 or melt, make polyethylene glycol or plastic crystal enter fibrous inside, obtain 40-60 DEG C of phase change fiber.The internal diameter of this fiber is comparatively large, and phase change material remains in fiber surface, and therefore, useful life longevity is poor.The microcapsule coated phase-change material of commercialization at present or powder.
In recent years, the research preparing composite phase change fiber by electrospinning process is also slightly reported.McCann etc. first reported that to be prepared by coaxial electrostatic spinning method with long chain hydrocarbon be sandwich layer, take TiO2-PVP as the superfine composite phase change fiber of cortex.The medium preparation reporting Static Spinning PEG/CA energy-saving and temperature-regulating superfine composite fiber of old length, and have studied different PEG content and the form of molecular weight on composite fibre and the impact of thermal property in spinning solution.Jointly make on multifunctional clothes package material at phase change fiber and other functional fiber at present and study slightly aobvious weakness, industrialization exists difficulty.
Summary of the invention
The object of the present invention is to provide a kind of multifunctional clothes package material, in specific temperature range, temperature can be regulated by absorbing, releasing heat, reach wearing comfort.
Above-mentioned purpose of the present invention is achieved by following technical solution:
A kind of multifunctional clothes package material, comprises internal layer, top layer and interlayer, it is characterized in that: interlayer between internal layer and top layer, the fabric that interlayer adopts phase change fiber to make.
A kind of multifunctional clothes package material as above, is characterized in that the material for the manufacture of internal layer and/or top layer fabric adopts artificial beef plant; Or bamboo fibre and cotton fiber blending, wherein cotton fiber accounts for 60%-90%; Or mint fibers and cotton fiber blending, wherein cotton fiber accounts for 70%-80%.
A kind of multifunctional clothes package material as above, is characterized in that containing phase change material in phase change fiber is paraffin hydrocarbon, polyalcohols.
A kind of multifunctional clothes package material as mentioned above, is characterized in that the spinning solution of phase change fiber comprises following component (by weight):
Phase change material 1-8 part
Silk-fibroin 6-9 part
Water-soluble substances 750-990 part
High molecular polymer 30-60 part
Polylysine 10-15 part
Wherein water-soluble substances is formed by cellulose and chitin, and weight part ratio is 10-14:3-6, and cellulose is native cellulose; High molecular polymer is one in polyvinyl alcohol, polyacrylonitrile, polyvinyl acetate or combination; The degree of polymerization of polylysine is 25-30, and its molecular weight is 3780-4290;
The main performance of described fiber:
Phase transition temperature is the 35-55 DEG C of hydroscopicity 15%-17% elongation at break that wets is 64.8%-70.2%.
A kind of multifunctional clothes package material as mentioned above, it is characterized in that the native cellulose degree of polymerization in phase change fiber is 800-2000, a-content of cellulose >96%, polyvinyl alcohol or polyacrylonitrile are homopolymers or copolymer, and its molecular weight is 42000-90000.
A kind of manufacture method of multifunctional clothes package material described above, conventional method is adopted by phase change fiber to make knitting, woven or non-weaving cloth, adopt acupuncture or bonding combination process that internal layer, top layer and interlayer are compounded to form underwear material, it is characterized in that the preparation method of phase change fiber comprises the steps:
1. configure solution A
Directly be dissolved in by silk-fibroin in the mixed solvent of phosphoric acid/formic acid, phosphoric acid/formic acid part by weight is 50/80-30/70, stirs and is prepared into solution A;
2. configure solution B
1. at room temperature, chitin alkalizes through sodium hydrate aqueous solution and generates alkali chitin in 3 hours, press dry rear and CS
2chitin sulphonic acid ester is generated, wherein chitin, NaOH and CS 0-30 DEG C of reaction
2weight ratio be 1:1:2;
2. at room temperature, Cotton Pulp generates alkali cellulose through sodium hydrate aqueous solution alkalization, at room temperature aging 6-8 hour after pressing dry, then with CS
2react and generate cellulose sulfonate in 0.5-2 hour, wherein the weight ratio of Cotton Pulp and sodium hydrate aqueous solution is 0.1-0.8:3-10;
3. described chitin sulphonic acid ester, cellulose sulfonate, NaOH and water are carried out blended, stir 30-60 minute, add high molecular polymer, polylysine mixes, obtain solution B;
3. configure solution C
Be dissolved in by phase change material in ketone, organic acid or DMSO organic solvent, stir, weight concentration is 3-20%, makes solution C;
4. mixed solution
Solution A, B, C mixing is at room temperature even by magnetic stirrer, and after filtration, deaeration makes spinning solution;
5. electrostatic spinning
By in the syringe of the 20-25mL of spinning solution liquid tape loaded syringe needle for preparing, with being covered with the cylinder of aluminium foil as receiving system, the rotating speed of cylinder is 100-150r/min, spinning head is fixed on 7-18cm to the receiving range of cylinder, feeding of spinning solution is 2-4mL/h to speed, and spinning voltage is 10-16kV; At ambient temperature, the fibrofelt prepared to be placed in vacuum drying chamber dry 12-24h to remove residual solvent.
Described artificial beef plant can be conventional vegetable protein composite fibre, also can adopt as CN1544729A(application number 2003101135578) as described in plant compound protein fiber.
Described phase change material is paraffin hydrocarbon, polyalcohols, such as polyethylene glycol (PEG), pentaerythrite, neopentyl glycol or penta glycerine etc.
Part by weight is adopted to be that the phosphoric acid/formic acid mixed solution of 50/80-30/70 can be good at ensureing the concentration of solution and stability as dissolution with solvents silk-fibroin, make the fiber made have desirable morphosis and crystalline texture, have good mechanical property.
Conventional method is adopted to make knitting, woven or non-weaving cloth, preferred woven materials phase change fiber obtained for described method.Internal layer, top layer and interlayer are compounded to form underwear material.Adopt the conventional combination process such as acupuncture, bonding.
Multifunctional clothes package material provided by the present invention, compared with prior art has following advantage:
1) the multifunctional clothes package material obtained by the present invention absorbs energy cooling when having high temperature, release energy during low temperature warming effect, the use of the fabrics such as internal layer, top layer vegetable protein, while guarantee is comfortable, has antibacterial effect, is desirable to take fabric.
2) fiber obtained by the present invention has more excellent flexility and intensity than common phase change fiber, and it is significantly better than the phase transformation blended fiber obtained by prior art at hygroscopicity, dry wet breaking strength, dry wet elongation at break;
3) raw material of the present invention is clear and definite, and environment friendly is high, has good spinnability, is applicable to industrialization.
Embodiment:
Below by embodiment, the present invention is specifically described, but must be pointed out embodiment further illustrating just to invention, can not limiting the scope of the invention be interpreted as.
method of testing
Adopt NicoletiS10 Fourier transform infrared spectrometer (Sai Mo flies Co., Ltd in your science and technology of generation) to carry out infrared spectrum analysis to fiber, KBr compressing tablet, wave-number range is 400 ~ 4000cm
-1; SU1510 SEM (HIT) appearance structure to Static Spinning phase transformation composite fibre is adopted to characterize; DSCQ200 differential scanning calorimeter (water generation science and technology Shanghai Co., Ltd) is adopted to analyze phase transition temperature and the phase transformation enthalpy of composite phase change fiber, the quality of test sample is about 5mg, scanning temperature range is 0 ~ 100 DEG C, and sweep speed is 8 DEG C/min, and nitrogen flow is 50mL/min.
embodiment 1
Configuration spinning solution, comprising following component:
Phase change material 8 parts
Silk-fibroin 9 parts
Water-soluble substances 750 parts
High molecular polymer 60 parts
Polylysine 10 parts
Wherein water-soluble substances is formed by cellulose and chitin, and weight part ratio is 10:6, and cellulose is native cellulose; High molecular polymer is polyvinyl alcohol; The degree of polymerization of polylysine is 25, and its molecular weight is 3780;
Concrete steps are as follows:
1. configure solution A
Directly be dissolved in by silk-fibroin in the mixed solvent of phosphoric acid/formic acid, phosphoric acid/formic acid part by weight is 50:70, stirs and is prepared into solution A;
2. configure solution B
1. at room temperature, chitin alkalizes through sodium hydrate aqueous solution and generates alkali chitin in 3 hours, press dry rear and CS
2chitin sulphonic acid ester is generated, wherein chitin, NaOH and CS 0-30 DEG C of reaction
2weight ratio be 1:1:2;
2. at room temperature, Cotton Pulp generates alkali cellulose through sodium hydrate aqueous solution alkalization, at room temperature aging 6-8 hour after pressing dry, then with CS
2react and generate cellulose sulfonate in 0.5-2 hour, wherein the weight ratio of Cotton Pulp and sodium hydrate aqueous solution is 0.8:3;
3. described chitin sulphonic acid ester, cellulose sulfonate, NaOH and water are carried out blended, stir 60 minutes, add high molecular polymer, polylysine mixes, obtain solution B;
3. configure solution C
Be dissolved in methyl ethyl ketone organic solvent by phase change material paraffin hydrocarbon, stir, concentration is 3-20%, makes solution C;
4. mixed solution
Solution A, B, C mixing is at room temperature even by magnetic stirrer, and after filtration, deaeration makes spinning solution;
5. electrostatic spinning
By in the syringe of the 20mL of spinning solution liquid tape loaded syringe needle for preparing, with being covered with the cylinder of aluminium foil as receiving system, the rotating speed of cylinder is 150r/min, and spinning head is fixed on 7cm to the receiving range of cylinder, feeding of spinning solution is 4mL/h to speed, and spinning voltage is 10kV; At ambient temperature, the fibrofelt prepared to be placed in vacuum drying chamber dry 12-24h to remove residual solvent.
Adopt conventional method to make looped fabric phase change fiber, adopt bonding combination process that internal layer, top layer and interlayer are compounded to form underwear material.Internal layer is artificial beef plant; Top layer is bamboo fibre and cotton fiber blending, and wherein cotton fiber accounts for 60%-90%.
embodiment 2
Configuration spinning solution, comprising following component:
Phase change material 5 parts
Silk-fibroin 7 parts
Water-soluble substances 800 parts
High molecular polymer 30 parts
Polylysine 10 parts
Wherein water-soluble substances is formed by cellulose and chitin, and weight part ratio is 12:5, and cellulose is native cellulose; High molecular polymer is polyvinyl acetate; The degree of polymerization of polylysine is 28, and its molecular weight is 4000;
Concrete steps are as follows:
1. configure solution A
Directly be dissolved in by silk-fibroin in the mixed solvent of phosphoric acid/formic acid, phosphoric acid/formic acid part by weight is 80:30, stirs and is prepared into solution A;
2. configure solution B
1. at room temperature, chitin alkalizes through sodium hydrate aqueous solution and generates alkali chitin in 3 hours, press dry rear and CS
2chitin sulphonic acid ester is generated, wherein chitin, NaOH and CS 0-30 DEG C of reaction
2weight ratio be 1:1:2;
2. at room temperature, Cotton Pulp generates alkali cellulose through sodium hydrate aqueous solution alkalization, at room temperature aging 6-8 hour after pressing dry, then with CS
2react and generate cellulose sulfonate in 0.5-2 hour, wherein the weight ratio of Cotton Pulp and sodium hydrate aqueous solution is 0.6:7;
3. by described chitin sulphonic acid ester, cellulose sulfonate, NaOH and who carry out blended, stir 30-60 minute, add high molecular polymer, polylysine mix, obtain solution B;
3. configure solution C
Be dissolved in DMSO organic solvent by phase change material polyalcohols, stir, concentration is 3-20%, makes solution C;
4. mixed solution
Solution A, B, C mixing is at room temperature even by magnetic stirrer, and after filtration, deaeration makes spinning solution;
5. electrostatic spinning
By in the syringe of the 20-25mL of spinning solution liquid tape loaded syringe needle for preparing, with being covered with the cylinder of aluminium foil as receiving system, the rotating speed of cylinder is 100-150r/min, spinning head is fixed on 7-18cm to the receiving range of cylinder, feeding of spinning solution is 2-4mL/h to speed, and spinning voltage is 10-16kV; At ambient temperature, the fibrofelt prepared to be placed in vacuum drying chamber dry 12-24h to remove residual solvent.
Adopt conventional method to make non-weaving cloth phase change fiber, adopt acupuncture combination process that internal layer, top layer and interlayer are compounded to form underwear material.Internal layer is bamboo fibre and cotton fiber blending, and wherein cotton fiber accounts for 60%-90%.
Top layer is mint fibers and cotton fiber blending, and wherein cotton fiber accounts for 70%-80%.
comparative example
In solution polyacrylonitrile hollow fiber being immersed in PEG or plastic crystal material or melt, make polyethylene glycol or plastic crystal enter fibrous inside, obtain phase change fiber.
Adopt conventional method to make non-weaving cloth phase change fiber, adopt acupuncture combination process that internal layer, top layer and interlayer are compounded to form underwear material.Internal layer is bamboo fibre and cotton fiber blending, and wherein cotton fiber accounts for 60%-90%.
Top layer is artificial beef plant.
experimental result
| Embodiment 1 | Embodiment 2 | Comparative example | |
| Dress materials phase transition temperature (DEG C) | 34 | 53 | 39 |
| Dress materials enthalpy of phase change (J/g) | 103.35 | 108.10 | 108 |
| Phase change fiber wet breaking strength (CN/dtex) | 2.5 | 3 | 1.5 |
| Phase change fiber wets elongation at break (%) | 64.8 | 70.2 | 52 |
| Dress materials hydroscopicity (%) | 16 | 14 | 10 |
Multifunctional clothes package material of the present invention has excellent thermoregulation energy, and having concurrently can respiratory and comfortableness, durability.
Claims (2)
1. the manufacture method of a multifunctional clothes package material, described multifunctional clothes package material comprises internal layer, top layer and interlayer, interlayer is between internal layer and top layer, the fabric that interlayer adopts phase change fiber to make, is characterized in that: the material for the manufacture of internal layer and/or top layer fabric adopts artificial beef plant; Or bamboo fibre and cotton fiber blending, wherein cotton fiber accounts for 60%-90%; Or mint fibers and cotton fiber blending, wherein cotton fiber accounts for 70%-80%.
2. the manufacture method of a multifunctional clothes package material as claimed in claim 1, it is characterized in that: adopted by phase change fiber conventional method to make knitting, woven or non-weaving cloth, adopt acupuncture or bonding combination process that internal layer, top layer and interlayer are compounded to form underwear material, the preparation method of phase change fiber comprises the steps:
1. configure solution A
Directly be dissolved in by silk-fibroin in the mixed solvent of phosphoric acid/formic acid, phosphoric acid/formic acid part by weight is 50/80-30/70, stirs and is prepared into solution A;
2. configure solution B
1. at room temperature, chitin alkalizes through sodium hydrate aqueous solution and generates alkali chitin in 3 hours, press dry rear and CS
2chitin sulphonic acid ester is generated, wherein chitin, NaOH and CS 0-30 DEG C of reaction
2weight ratio be 1:1:2;
2. at room temperature, Cotton Pulp generates alkali cellulose through sodium hydrate aqueous solution alkalization, at room temperature aging 6-8 hour after pressing dry, then with CS
2react and generate cellulose sulfonate in 0.5-2 hour, wherein the weight ratio of Cotton Pulp and sodium hydrate aqueous solution is 0.1-0.8:3-10;
3. described chitin sulphonic acid ester, cellulose sulfonate, NaOH and water are carried out blended, stir 30-60 minute, add high molecular polymer, polylysine mixes, obtain solution B;
3. configure solution C
Be dissolved in by phase change material in ketone, organic acid or DMSO organic solvent, stir, weight concentration is 3-20%, makes solution C;
4. mixed solution
Solution A, B, C mixing is at room temperature even by magnetic stirrer, and after filtration, deaeration makes spinning solution;
5. electrostatic spinning
By in the syringe of the 20-25mL of spinning solution liquid tape loaded syringe needle for preparing, with being covered with the cylinder of aluminium foil as receiving system, the rotating speed of cylinder is 100-150r/min, spinning head is fixed on 7-18cm to the receiving range of cylinder, feeding of spinning solution is 2-4mL/h to speed, and spinning voltage is 10-16kV; At ambient temperature, the fibrofelt prepared to be placed in vacuum drying chamber dry 12-24h to remove residual solvent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510694530.5A CN105249576B (en) | 2014-07-30 | 2014-07-30 | A kind of manufacture method of multifunctional clothes package material |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410369388.2A CN104146356B (en) | 2014-07-30 | 2014-07-30 | A kind of multifunctional clothes package material and manufacture method thereof |
| CN201510694530.5A CN105249576B (en) | 2014-07-30 | 2014-07-30 | A kind of manufacture method of multifunctional clothes package material |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410369388.2A Division CN104146356B (en) | 2014-07-30 | 2014-07-30 | A kind of multifunctional clothes package material and manufacture method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105249576A true CN105249576A (en) | 2016-01-20 |
| CN105249576B CN105249576B (en) | 2016-10-19 |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105525406A (en) * | 2016-01-29 | 2016-04-27 | 威海魏桥科技工业园有限公司 | Mint fiber and cotton fiber blended yarn and spinning technology thereof |
| CN105568500A (en) * | 2016-01-29 | 2016-05-11 | 威海魏桥科技工业园有限公司 | Mint fiber and cotton fiber blended fabric and weaving technology thereof |
| CN106120010A (en) * | 2016-06-21 | 2016-11-16 | 深圳市乐乐趣文化科技有限公司 | A kind of clothes of temp. controllable insulation |
| CN110171173A (en) * | 2019-05-05 | 2019-08-27 | 江阴芗菲服饰有限公司 | A kind of full season functional fabric and preparation method thereof |
| CN110331511A (en) * | 2019-07-24 | 2019-10-15 | 青岛威达体育用品有限公司 | A kind of mint fibers add hollow polyester fibre garment material |
| CN113829692A (en) * | 2021-09-28 | 2021-12-24 | 浙江普娜拉纺织科技有限公司 | Underwear fabric based on microcapsule phase change heat preservation |
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| CN105525406A (en) * | 2016-01-29 | 2016-04-27 | 威海魏桥科技工业园有限公司 | Mint fiber and cotton fiber blended yarn and spinning technology thereof |
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| CN110171173A (en) * | 2019-05-05 | 2019-08-27 | 江阴芗菲服饰有限公司 | A kind of full season functional fabric and preparation method thereof |
| CN110171173B (en) * | 2019-05-05 | 2021-12-21 | 江阴芗菲纺织科技有限公司 | All-season functional fabric and preparation method thereof |
| CN110331511A (en) * | 2019-07-24 | 2019-10-15 | 青岛威达体育用品有限公司 | A kind of mint fibers add hollow polyester fibre garment material |
| CN113829692A (en) * | 2021-09-28 | 2021-12-24 | 浙江普娜拉纺织科技有限公司 | Underwear fabric based on microcapsule phase change heat preservation |
| CN113829692B (en) * | 2021-09-28 | 2023-11-07 | 浙江普娜拉纺织科技有限公司 | Underwear fabric based on microcapsule phase change heat preservation |
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| Publication number | Publication date |
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| CN104146356A (en) | 2014-11-19 |
| CN105249576B (en) | 2016-10-19 |
| CN104146356B (en) | 2016-02-10 |
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