CN105236755A - Tempered glass thinning method - Google Patents

Tempered glass thinning method Download PDF

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Publication number
CN105236755A
CN105236755A CN201510532333.3A CN201510532333A CN105236755A CN 105236755 A CN105236755 A CN 105236755A CN 201510532333 A CN201510532333 A CN 201510532333A CN 105236755 A CN105236755 A CN 105236755A
Authority
CN
China
Prior art keywords
acid
chilled glass
tempered glass
proof
thinning
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510532333.3A
Other languages
Chinese (zh)
Inventor
高志文
刘玉华
林虹云
赵贤祥
代琴峰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
YICHANG NANBO DISPLAY DEVICES CO., LTD.
Original Assignee
SHENZHEN NANBO WELLLIGHT CONDUCTIVE COATING CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SHENZHEN NANBO WELLLIGHT CONDUCTIVE COATING CO Ltd filed Critical SHENZHEN NANBO WELLLIGHT CONDUCTIVE COATING CO Ltd
Priority to CN201510532333.3A priority Critical patent/CN105236755A/en
Publication of CN105236755A publication Critical patent/CN105236755A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a tempered glass thinning method. The method comprises the following steps: tempered glass to be treated is provided; acid-resisting printing ink is printed on one surface of the tempered glass; the tempered glass with the acid-resisting printing ink printed on the surface is subjected to heat treatment, such that the acid-resisting printing ink is cured into an acid-resisting protection layer attached to a surface of the tempered glass; the tempered glass with the acid-resisting protection layer attached to the surface is subjected to chemical acid thinning; when thinning is finished, the acid-resisting protection layer attached to the surface of the tempered glass is removed with a cleaning agent; and the tempered glass is washed and dried, such that the thinning process of the tempered glass is finished. With the tempered glass thinning method, operation can be carried out directly on a large sheet of tempered glass, and the large sheet of tempered glass does not need to be cut into small sheets. Compared to a traditional tempered glass thinning method, the tempered glass thinning method has the advantages of simple operation, high processing efficiency, and low processing cost.

Description

The thining method of chilled glass
Technical field
Glass working arts field of the present invention, particularly relates to a kind of thining method of chilled glass.
Background technology
After prepared by chilled glass, in order to reach certain flexibility, and making its surface seem nature, reducing and occupying space, often needing to carry out reduction processing to it.The thinning of such as mobile phone screen is exactly to obtain flatscreen, reduces space, allows colour seem nature.
The thining method of traditional chilled glass is by carrying out chemical reduction (such as, HF chemical reduction) after the antiacid protective membrane of chilled glass surface coverage.But due to antiacid protective membrane is attached to large-size (being greater than 10 cun) chilled glass surface time easily there is bubble, thus cause when carrying out chemical reduction produce circuit corrosion.Therefore, usually need the chilled glass of sheet to cut into small pieces, then carry out chemical reduction by the mode covering antiacid protective membrane.
The thining method complex operation of traditional chilled glass, the operation that large stretch of chilled glass cuts into small pieces also makes working (machining) efficiency low, thus causes tooling cost higher.
Summary of the invention
Based on this, be necessary to provide the thining method of the chilled glass that a kind of tooling cost is lower.
A thining method for chilled glass, comprises the steps:
Pending chilled glass is provided;
At a surface printing acid-proof ink of described chilled glass;
The described chilled glass that effects on surface is printed with acid-proof ink is heat-treated, and described acid-proof ink is solidify to form be attached to the acid proof coating that of described chilled glass surperficial; And
It is acid thinning that the described chilled glass that effects on surface is attached with acid proof coating carries out chemistry; after completing, employing scavenging solution washes away the acid proof coating of described chilled glass surface attachment; and described chilled glass is cleaned, dry, complete the thinning of described chilled glass.
In one embodiment, described in the operation of a surface printing acid-proof ink of described chilled glass, described printing is silk screen printing.
In one embodiment, described acid-proof ink comprises the [CH of 60 parts ~ 70 parts according to massfraction 2cHCl] n, the CH of 35 parts ~ 45 parts 2the C of=CHCOOH and 1.5 part ~ 2 parts 32h 16cuN 8.
In one embodiment, in the operation that the described chilled glass that described effects on surface is printed with acid-proof ink is heat-treated, described heat treated temperature is 140 DEG C ~ 160 DEG C, and the described heat treated time is 55min ~ 65min.
In one embodiment, the thickness of described acid proof coating is 30 μm ~ 50 μm.
In one embodiment; the described chilled glass that described effects on surface is attached with acid proof coating carries out acid thinning being operating as of chemistry: the described chilled glass adopting acid etching solution effects on surface to be attached with acid proof coating carries out etch processes, and described acid etching solution comprises HF and the 3% ~ 8%HCl of 10% ~ 30% according to mass percent.
In one embodiment, described scavenging solution to be mass percentage be 2% ~ 3% basic solution, the solute of described basic solution is KOH or NaOH solution.
In one embodiment, described described chilled glass to be cleaned, dry operation is specially: adopt deionized water to clean rear employing ionic air knife to described chilled glass and dry up.
The thining method of this chilled glass can directly operate the chilled glass of sheet, does not need the operation large stretch of chilled glass being cut into small pieces.Relative to the thining method of traditional chilled glass, the thining method of this chilled glass is simple to operate, and working (machining) efficiency is higher, thus tooling cost is lower.
Accompanying drawing explanation
Fig. 1 is the schema of the thining method of the chilled glass of an embodiment.
Embodiment
Mainly by reference to the accompanying drawings the thining method of chilled glass is described in further detail below.
The thining method of the chilled glass of an embodiment as shown in Figure 1, comprises the steps:
S10, provide pending chilled glass.
Pending chilled glass can be Asahi Glass chilled glass, imperial mark chilled glass or healthy and free from worry chilled glass.
The size of pending chilled glass can be 370mm × 470mm, 400mm × 500mm or 450mm × 550mm.
S20, the surface printing acid-proof ink of chilled glass obtained at S10.
In present embodiment, print for silk screen printing.
Acid-proof ink comprises the [CH of 60 parts ~ 70 parts according to massfraction 2cHCl] n, the CH of 35 parts ~ 45 parts 2the C of=CHCOOH and 1.5 part ~ 2 parts 32h 16cuN 8.
S30, there is the chilled glass of acid-proof ink to heat-treat to the surface printing that S20 obtains, acid-proof ink is solidify to form be attached to the acid proof coating that of chilled glass surperficial.
In present embodiment, heat treated temperature is 140 DEG C ~ 160 DEG C, and the heat treated time is 55min ~ 65min.
The thickness of the acid proof coating formed after thermal treatment is 30 μm ~ 50 μm.
It is acid thinning that S40, the surface attachment obtained S30 have the chilled glass of acid proof coating to carry out chemistry, and after completing, employing scavenging solution washes away the acid proof coating of chilled glass surface attachment.
The chilled glass that effects on surface is attached with acid proof coating carries out acid thinning being operating as of chemistry: the chilled glass adopting acid etching solution effects on surface to be attached with acid proof coating carries out etch processes, and acid etching solution comprises HF and the 3% ~ 8%HCl of 10% ~ 30% according to mass percent.。
In present embodiment, scavenging solution to be mass percentage be 2% ~ 3% inorganic alkali solution, the solute of inorganic alkali solution is NaOH or KOH.
S50, the chilled glass obtained S40 clean, dry, complete the thinning of chilled glass.
Chilled glass is cleaned, dry operation is specially: adopt deionized water to clean rear employing ionic air knife to chilled glass and dry up.
The thining method of this chilled glass can directly operate the chilled glass of sheet, does not need the operation large stretch of chilled glass being cut into small pieces.Relative to the thining method of traditional chilled glass, the thining method of this chilled glass is simple to operate, and working (machining) efficiency is higher, thus tooling cost is lower.
In addition, the thining method of this chilled glass forms acid proof coating by printing acid-proof ink after fixing, relative to the method for the antiacid protective membrane of traditional attaching, can not produce bubble, produce yield and raise, thus reduce further cost.Meanwhile, acid proof coating can directly be washed away by scavenging solution, simple to operate.
Be specific embodiment part below.
Embodiment 1
There is provided pending Asahi Glass chilled glass, at a surface screen-printed acid-proof ink of Asahi Glass chilled glass.In the present embodiment, acid-proof ink comprises the [CH of 65 parts according to massfraction 2cHCl] n, the CH of 40 parts 2the C of=CHCOOH and 1.5 part 32h 16cuN 8.
The chilled glass that effects on surface is printed with acid-proof ink is heat-treated, and acid-proof ink is solidify to form be attached to the acid proof coating that of chilled glass surperficial.Heat treated temperature is 150 DEG C, and the heat treated time is 60min.In the present embodiment, the thickness of the acid proof coating formed after thermal treatment is 38nm.
It is 0.125mm that the chilled glass that effects on surface is attached with acid proof coating carries out the thickness that chemical acidity is thinned to chilled glass, and after completing, employing scavenging solution washes away the acid proof coating of chilled glass surface attachment.In the present embodiment, chemical acid reduction processing is specially: the chilled glass adopting acid etching solution effects on surface to be attached with acid proof coating carries out etch processes, and acid etching solution comprises HF and 5%HCl of 20% according to mass percent.In the present embodiment, scavenging solution to be mass percentage be 2% NaOH solution.
After adopting washed with de-ionized water chilled glass, ionic air knife dries up, and completes the thinning of chilled glass.
Embodiment 2
There is provided pending imperial mark chilled glass, at a surface screen-printed acid-proof ink of imperial mark chilled glass.In the present embodiment, acid-proof ink comprises the [CH of 70 parts according to massfraction 2cHCl] n, the CH of 45 parts 2the C of=CHCOOH and 2 part 32h 16cuN 8.
The chilled glass that effects on surface is printed with acid-proof ink is heat-treated, and acid-proof ink is solidify to form be attached to the acid proof coating that of chilled glass surperficial.Heat treated temperature is 140 DEG C, and the heat treated time is 65min.In the present embodiment, the thickness of the acid proof coating formed after thermal treatment is 42nm.
It is 0.116mm that the chilled glass that effects on surface is attached with acid proof coating carries out the thickness that chemical acidity is thinned to chilled glass, and after completing, employing scavenging solution washes away the acid proof coating of chilled glass surface attachment.In the present embodiment, chemical acid reduction processing is specially: the chilled glass adopting acid etching solution effects on surface to be attached with acid proof coating carries out etch processes, and acid etching solution comprises HF and 8%HCl of 10% according to mass percent.In the present embodiment, scavenging solution to be mass percentage be 3% KOH solution.
After adopting washed with de-ionized water chilled glass, ionic air knife dries up, and completes the thinning of chilled glass.
Embodiment 3
There is provided pending healthy and free from worry chilled glass, at a surface screen-printed acid-proof ink of healthy and free from worry chilled glass.In the present embodiment, acid-proof ink comprises the [CH of 60 parts according to massfraction 2cHCl] n, the CH of 30 parts 2the C of=CHCOOH and 1.5 part 32h 16cuN 8.
The chilled glass that effects on surface is printed with acid-proof ink is heat-treated, and acid-proof ink is solidify to form be attached to the acid proof coating that of chilled glass surperficial.Heat treated temperature is 160 DEG C, and the heat treated time is 55min.In the present embodiment, the thickness of the acid proof coating formed after thermal treatment is 40nm.
It is 0.121mm that the chilled glass that effects on surface is attached with acid proof coating carries out the thickness that chemical acidity is thinned to chilled glass, and after completing, employing scavenging solution washes away the acid proof coating of chilled glass surface attachment.In the present embodiment, chemical acid reduction processing is specially: the chilled glass adopting acid etching solution effects on surface to be attached with acid proof coating carries out etch processes, and acid etching solution comprises HF and 3%HCl of 30% according to mass percent.In the present embodiment, scavenging solution to be mass percentage be 2% KOH solution.
After adopting washed with de-ionized water chilled glass, ionic air knife dries up, and completes the thinning of chilled glass.
The above embodiment only have expressed several embodiment of the present invention, and it describes comparatively concrete and detailed, but therefore can not be interpreted as the restriction to the scope of the claims of the present invention.It should be pointed out that for the person of ordinary skill of the art, without departing from the inventive concept of the premise, can also make some distortion and improvement, these all belong to protection scope of the present invention.Therefore, the protection domain of patent of the present invention should be as the criterion with claims.

Claims (8)

1. a thining method for chilled glass, is characterized in that, comprises the steps:
Pending chilled glass is provided;
At a surface printing acid-proof ink of described chilled glass;
The described chilled glass that effects on surface is printed with acid-proof ink is heat-treated, and described acid-proof ink is solidify to form be attached to the acid proof coating that of described chilled glass surperficial; And
It is acid thinning that the described chilled glass that effects on surface is attached with acid proof coating carries out chemistry; after completing, employing scavenging solution washes away the acid proof coating of described chilled glass surface attachment; and described chilled glass is cleaned, dry, complete the thinning of described chilled glass.
2. the thining method of chilled glass according to claim 1, is characterized in that, described in the operation of a surface printing acid-proof ink of described chilled glass, described printing is silk screen printing.
3. the thining method of chilled glass according to claim 1 and 2, is characterized in that, described acid-proof ink comprises the [CH of 60 parts ~ 70 parts according to massfraction 2cHCl] n, the CH of 35 parts ~ 45 parts 2the C of=CHCOOH and 1.5 part ~ 2 parts 32h 16cuN 8.
4. the thining method of chilled glass according to claim 1, it is characterized in that, in the operation that the described chilled glass that described effects on surface is printed with acid-proof ink is heat-treated, described heat treated temperature is 140 DEG C ~ 160 DEG C, and the described heat treated time is 55min ~ 65min.
5. the thining method of chilled glass according to claim 1, is characterized in that, the thickness of described acid proof coating is 30 μm ~ 50 μm.
6. the thining method of chilled glass according to claim 1; it is characterized in that; the described chilled glass that described effects on surface is attached with acid proof coating carries out acid thinning being operating as of chemistry: the described chilled glass adopting acid etching solution effects on surface to be attached with acid proof coating carries out etch processes, and described acid etching solution comprises HF and the 3% ~ 8%HCl of 10% ~ 30% according to mass percent.
7. the thining method of chilled glass according to claim 1, is characterized in that, described scavenging solution to be mass percentage be 2% ~ 3% basic solution, the solute of described basic solution is KOH or NaOH solution.
8. the thining method of chilled glass according to claim 1, is characterized in that, describedly to clean described chilled glass, dry operation is specially: adopt deionized water to clean rear employing ionic air knife to described chilled glass and dry up.
CN201510532333.3A 2015-08-26 2015-08-26 Tempered glass thinning method Pending CN105236755A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107601914A (en) * 2017-11-03 2018-01-19 太仓经济开发区坚毅工艺美术品工作室 The thining method of strengthened glass
CN109133660A (en) * 2018-07-26 2019-01-04 信利光电股份有限公司 A kind of processing method of the tempered glass of bending deformation

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0663411A1 (en) * 1994-01-17 1995-07-19 Nippon Kayaku Kabushiki Kaisha Photo-imaging resist ink and cured product thereof
CN101017325A (en) * 2007-02-06 2007-08-15 上海中大科技发展有限公司 Liquid photosensitive etching resisting ink
CN101372397A (en) * 2007-08-24 2009-02-25 吴海生 Production method of concave glass
CN101781092A (en) * 2009-01-16 2010-07-21 中国南玻集团股份有限公司 Method for manufacturing transparent conductive film glass

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0663411A1 (en) * 1994-01-17 1995-07-19 Nippon Kayaku Kabushiki Kaisha Photo-imaging resist ink and cured product thereof
CN101017325A (en) * 2007-02-06 2007-08-15 上海中大科技发展有限公司 Liquid photosensitive etching resisting ink
CN101372397A (en) * 2007-08-24 2009-02-25 吴海生 Production method of concave glass
CN101781092A (en) * 2009-01-16 2010-07-21 中国南玻集团股份有限公司 Method for manufacturing transparent conductive film glass

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107601914A (en) * 2017-11-03 2018-01-19 太仓经济开发区坚毅工艺美术品工作室 The thining method of strengthened glass
CN109133660A (en) * 2018-07-26 2019-01-04 信利光电股份有限公司 A kind of processing method of the tempered glass of bending deformation

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Effective date of registration: 20160127

Address after: 443005 No. 38, Dalian Road, Yichang, Hubei

Applicant after: YICHANG NANBO DISPLAY DEVICES CO., LTD.

Address before: 518000 Guangdong Province, Shenzhen high tech Zone of Nanshan District City, No. three North Road, CSG Electronics Building

Applicant before: Shenzhen Nanbo Welllight Conductive Coating Co., Ltd.

RJ01 Rejection of invention patent application after publication

Application publication date: 20160113

RJ01 Rejection of invention patent application after publication