CN105226233A - A kind of negative pole of alkaline dry battery and application thereof - Google Patents
A kind of negative pole of alkaline dry battery and application thereof Download PDFInfo
- Publication number
- CN105226233A CN105226233A CN201510684992.9A CN201510684992A CN105226233A CN 105226233 A CN105226233 A CN 105226233A CN 201510684992 A CN201510684992 A CN 201510684992A CN 105226233 A CN105226233 A CN 105226233A
- Authority
- CN
- China
- Prior art keywords
- particle diameter
- negative pole
- dry battery
- alkaline dry
- paa
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/06—Electrodes for primary cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
- H01M4/621—Binders
- H01M4/622—Binders being polymers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/04—Cells with aqueous electrolyte
- H01M6/06—Dry cells, i.e. cells wherein the electrolyte is rendered non-fluid
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Primary Cells (AREA)
Abstract
The present invention relates to a kind of negative pole and application thereof of alkaline dry battery, this negative pole comprises Zinc alloy powder, PAA, PA and electrolyte, and the ratio of weight and number of Zinc alloy powder, PAA, PA and electrolyte is 100:(0.9-1.2): (0.06-0.2): (51-56); Wherein, particle diameter≤300 μm of PAA.Use PAA and PA as anode binder in the present invention, collocation is simple, reduce additive types in negative pole, reduce bringing into of impurity element, and the present invention goes back the domain size distribution of conservative control PAA and PA simultaneously, make PAA ensure mobility and the electric conductivity of negative pole as large skeleton, PA ensures the stickiness of negative pole, be beneficial to the stability of zinc powder dispersion, prevent negative pole layering and sedimentation, thus ensure that cell discharge performance promotes the leak resistance of battery while stable.When this negative pole is applied to alkaline dry battery, make that the discharge performance of alkaline dry battery is more stable, leak resistance is better.
Description
Technical field
The present invention relates to a kind of alkaline dry battery, particularly relate to a kind of negative pole and application thereof of alkaline dry battery, belong to cell art.
In the present invention, the meaning of following expression formula is:
PAA: polyacrylic acid sodium salt
PA: polyacrylic acid powder
Background technology
Alkaline battery is the most successful high capacity type dry cell, is also one of battery of current most cost performance.Alkaline battery take manganese dioxide as positive pole, and zinc is negative pole, and negative pole zinc is also changed over granular by sheet, increase the response area of negative pole, and potassium hydroxide is electrolyte.So electrical property is greatly improved, the alkaline battery of general equal model be the capacity of common batteries and the 3-7 of discharge time doubly, both cryogenic properties gap is larger.Alkaline battery is more suitable for big current continuous discharge and requires the electricity consumption occasion of high operating voltage, is specially adapted to camera, photoflash lamp, shaver, electronic toy, CD player, high-power remote controller, wireless mouse, keyboard etc.
But easily layering such as the active material zinc powder of the negative pole of alkaline dry battery of the prior art and electrolyte, other additives etc., sedimentation, affect the carrying out of negative reaction, thus affect the discharge performance of alkaline dry battery.
In addition, easily there is the phenomenon of leakage in alkaline dry battery in adverse circumstances or under long term storage, because electrolyte is the mordant alkaline matter potassium hydroxide of band, has spread effect to eyes, respiratory tract and skin.And, electrolyte also can attack metal, destroy electronic component, the electrolyte that therefore battery spills also can destroy and use the product, particularly electronic product of this battery.
About solution negative electrode of alkaline dry cell active material zinc powder and electrolyte, the easily layering such as other additives, the problem of sedimentation, have been reported in prior art, as Chinese invention patent (publication number: CN102760894A) discloses a kind of alkaline dry battery and alkaline dry battery anode mixture pellet, the negative pole simultaneously also disclosing this alkaline dry battery comprises Zinc alloy powder and alkaline electrolyte, relative to the Zinc alloy powder of 100 weight portions, in alkaline electrolyte, the parts by weight of each component are: cross-linking type polyacrylic acid: 1.25 weight portions, cross linked sodium polyacrylate: 0.2 weight portion, indium oxide: 0.04 weight portion, electrolyte liquid: 53 weight portions, pure water: 3 weight portions.Wherein, cross-linking type polyacrylic acid in alkaline electrolyte and cross linked sodium polyacrylate all play gelatification, the two makes alkaline electrolyte be gel jointly, although the phenomenon of zinc powder and electrolyte, other additive hierarchical, sedimentation can be alleviated, but, not clearly, still have greatly improved effect space; And this patent fails to improve the leak resistance of alkaline dry battery, and due to cathode additive agent kind more, also can bring impurity element into, affect the performance of alkaline dry battery.
Summary of the invention
The object of the invention is for the above-mentioned problems in the prior art, propose and a kind ofly can ensure that cell discharge performance is stablized and promotes the negative pole of the alkaline dry battery of the leak resistance of battery.
Object of the present invention realizes by following technical proposal: a kind of negative pole of alkaline dry battery, comprise Zinc alloy powder, PAA, PA and electrolyte, the ratio of weight and number of Zinc alloy powder, PAA, PA and electrolyte is 100:(0.9-1.2): (0.06-0.2): (51-56); Wherein, particle diameter≤300 μm of PAA.
In the present invention, PAA and PA is as anode binder, mainly act on the dispersion distribution of zinc powder, keep mobility and the stickiness of negative pole, prevent layering and the sedimentation of negative electrode active material zinc powder and electrolyte, other additives etc., simultaneously, as conducting matrix grain after absorption electrolyte liquid, ensure that negative reaction steadily carries out.
These two kinds of anode binders of the present invention solve in current alkaline battery needs multiple gel to keep the not stratified problem with sedimentation of negative pole, collocation is simple, reduce additive types in negative pole, reduce the bringing into of impurity element simultaneously, thus ensure that cell discharge performance promotes the leak resistance of battery while stable.
As preferably, in the present invention, Zinc alloy powder and electrolyte are Zinc alloy powder conventional in alkaline dry battery and electrolyte.
In the negative pole of above-mentioned a kind of alkaline dry battery, the domain size distribution of PAA is (by percentage to the quality): particle diameter≤75 μm: 12-18%, 75 < particle diameter≤105 μm: 62-75%, 105 < particle diameter≤150 μm: 6-20%, 150 < particle diameter≤300 μm: 1-8%.The present invention is drawn by orthogonal experiment, and the particle diameter of PAA is by above-mentioned distribution, and electrolyte retention promotes about 2%, and during the electric discharge of load same resistance, its initial voltage improves 0.3%, and high section discharge performance promotes about 5.3%.
In the negative pole of above-mentioned a kind of alkaline dry battery, the proportion of PAA is 0.4-0.8g/cm
3, water content≤3.5wt%.
In the negative pole of above-mentioned a kind of alkaline dry battery, the pH of PAA is 5-7.
In the negative pole of above-mentioned a kind of alkaline dry battery, particle diameter≤150 μm of PA.
In the negative pole of above-mentioned a kind of alkaline dry battery, the domain size distribution of PA is (by percentage to the quality): particle diameter≤75 μm: >=85%, 75 < particle diameter≤105 μm: 7-12%, 105 < particle diameter≤150 μm: 3-8%.The present invention is drawn by orthogonal experiment, and the particle diameter of PA is by above-mentioned distribution, and electrolyte stratification oozes out ratio and reduces about 60%, and oozes out equal in quality electrolyte required time and add 230%.Meanwhile, in high-temperature storage situation, electrolyte oozes out ratio and reduces about 65%, embodies good high-temperature stability.
In the negative pole of above-mentioned a kind of alkaline dry battery, the proportion of PA is 0.15-0.50g/cm
3, water content≤3.5wt%.
In the negative pole of above-mentioned a kind of alkaline dry battery, the pH of PA is 2-4.
In the present invention, PAA is polyacrylic acid sodium salt, and Particle Phase is thick to PA, and in negative pole, Main Function is for supporting zinc powder, ensures mobility and the electric conductivity of negative pole as large skeleton; And PA is the polyacrylic acid powder that alkaline battery uses, for hard and crisp white powder, particle is less, meet water easily swelling and softening, after swelling in the electrolytic solution, viscosity is larger, ensure the stickiness of negative pole, be beneficial to the stability of zinc powder dispersion, prevent negative pole layering and sedimentation, thus ensure the electric performance stablity of battery.
In the present invention, the ratio weight average of two kinds of gels is determined by its size distribution profile, and the chemical property that pH scope is its main component determines.Therefore, the index such as proportion, water content, pH value of two kinds of gels all needs to control in certain limit.Because if any relatively large deviation, can affect the proterties of negative pole: as water content is higher, its active constituent content reduces, and the negative pole stability made in same recipe situation just has certain influence, also can produce corresponding impact to battery performance simultaneously.
Another object of the present invention is to provide a kind of alkaline dry battery applying the negative pole of above-mentioned alkaline dry battery.
The negative pole of alkaline dry battery of the present invention is applied in alkaline dry battery, make the discharge performance of alkaline dry battery more stable, and leak resistance is better.
Compared with prior art, the present invention has following advantage:
1. use PAA and PA as anode binder in the present invention, collocation is simple, reduces additive types in negative pole, reduces bringing into of impurity element simultaneously, thus ensures that cell discharge performance promotes the leak resistance of battery while stable.
2. the domain size distribution of conservative control PAA and PA in the present invention, make PAA ensure mobility and the electric conductivity of negative pole as large skeleton, PA ensures the stickiness of negative pole, is beneficial to the stability of zinc powder dispersion, prevent negative pole layering and sedimentation, thus ensure that the discharge performance of battery is stablized.
3., in the present invention, proportion, water content, the pH value of conservative control two kinds of gels, ensure the stable of battery performance.
4. the negative pole of alkaline dry battery of the present invention is applied in alkaline dry battery and can obtains that discharge performance is stable, the better alkaline dry battery of leak resistance.
Embodiment
Be below specific embodiments of the invention, technical scheme of the present invention is further described, but the present invention is not limited to these embodiments.
Table 1: the constituent of the negative pole of embodiment of the present invention 1-5 alkaline dry battery and ratio of weight and number thereof
Embodiment 1:
By the raw material that constituent and the ratio of weight and number thereof of the negative pole of embodiment in table 11 alkaline dry battery take.
Wherein, in raw material, Zinc alloy powder and electrolyte are Zinc alloy powder conventional in alkaline dry battery and potassium hydroxide electrolyte.
In raw material, the proportion of PAA is 0.6g/cm
3, water content is 3wt%, pH is 6.Domain size distribution is (by percentage to the quality): particle diameter≤75 μm: 15%, 75 < particle diameter≤105 μm: 70%, 105 < particle diameter≤150 μm: 10%, 150 < particle diameter≤300 μm: 5%.
In raw material, the proportion of PA is 0.3g/cm
3, water content is 3wt%, pH is 3.Domain size distribution is (by percentage to the quality): particle diameter≤75 μm: 85%, 75 < particle diameter≤105 μm: 10%, 105 < particle diameter≤150 μm: 5%.
Then by the preparation method of the alkaline dry battery of prior art, Zinc alloy powder, PAA and PA are scattered in obtained negative pole in electrolyte.
Embodiment 2:
By the raw material that constituent and the ratio of weight and number thereof of the negative pole of embodiment in table 12 alkaline dry battery take.
Wherein, in raw material, Zinc alloy powder and electrolyte are Zinc alloy powder conventional in alkaline dry battery and potassium hydroxide electrolyte.
In raw material, the proportion of PAA is 0.8g/cm
3, water content is 3.5wt%, pH is 6.Domain size distribution is (by percentage to the quality): particle diameter≤75 μm: 15%, 75 < particle diameter≤105 μm: 70%, 105 < particle diameter≤150 μm: 10%, 150 < particle diameter≤300 μm: 5%.
In raw material, the proportion of PA is 0.5g/cm
3, water content is 3.5wt%, pH is 4.Domain size distribution is (by percentage to the quality): particle diameter≤75 μm: 85%, 75 < particle diameter≤105 μm: 10%, 105 < particle diameter≤150 μm: 5%.
Then by the preparation method of the alkaline dry battery of prior art, Zinc alloy powder, PAA and PA are scattered in obtained negative pole in electrolyte.
Embodiment 3:
By the raw material that constituent and the ratio of weight and number thereof of the negative pole of embodiment in table 13 alkaline dry battery take.
Wherein, in raw material, Zinc alloy powder and electrolyte are Zinc alloy powder conventional in alkaline dry battery and potassium hydroxide electrolyte.
In raw material, the proportion of PAA is 0.6g/cm
3, water content is 3wt%, pH is 6.Domain size distribution is (by percentage to the quality): particle diameter≤75 μm: 15%, 75 < particle diameter≤105 μm: 70%, 105 < particle diameter≤150 μm: 10%, 150 < particle diameter≤300 μm: 5%.
In raw material, the proportion of PA is 0.3g/cm
3, water content is 3wt%, pH is 3.Domain size distribution is (by percentage to the quality): particle diameter≤75 μm: 85%, 75 < particle diameter≤105 μm: 10%, 105 < particle diameter≤150 μm: 5%.
Then by the preparation method of the alkaline dry battery of prior art, Zinc alloy powder, PAA and PA are scattered in obtained negative pole in electrolyte.
Embodiment 4:
By the raw material that constituent and the ratio of weight and number thereof of the negative pole of embodiment in table 14 alkaline dry battery take.
Wherein, in raw material, Zinc alloy powder and electrolyte are Zinc alloy powder conventional in alkaline dry battery and potassium hydroxide electrolyte.
In raw material, the proportion of PAA is 0.6g/cm
3, water content is 3wt%, pH is 6.Domain size distribution is (by percentage to the quality): particle diameter≤75 μm: 15%, 75 < particle diameter≤105 μm: 70%, 105 < particle diameter≤150 μm: 10%, 150 < particle diameter≤300 μm: 5%.
In raw material, the proportion of PA is 0.3g/cm
3, water content is 3wt%, pH is 3.Domain size distribution is (by percentage to the quality): particle diameter≤75 μm: 85%, 75 < particle diameter≤105 μm: 10%, 105 < particle diameter≤150 μm: 5%.
Then by the preparation method of the alkaline dry battery of prior art, Zinc alloy powder, PAA and PA are scattered in obtained negative pole in electrolyte.
Embodiment 5:
By the raw material that constituent and the ratio of weight and number thereof of the negative pole of embodiment in table 15 alkaline dry battery take.
Wherein, in raw material, Zinc alloy powder and electrolyte are Zinc alloy powder conventional in alkaline dry battery and potassium hydroxide electrolyte.
In raw material, the proportion of PAA is 0.6g/cm
3, water content is 3wt%, pH is 6.Domain size distribution is (by percentage to the quality): particle diameter≤75 μm: 15%, 75 < particle diameter≤105 μm: 70%, 105 < particle diameter≤150 μm: 10%, 150 < particle diameter≤300 μm: 5%.
In raw material, the proportion of PA is 0.3g/cm
3, water content is 3wt%, pH is 3.Domain size distribution is (by percentage to the quality): particle diameter≤75 μm: 85%, 75 < particle diameter≤105 μm: 10%, 105 < particle diameter≤150 μm: 5%.
Then by the preparation method of the alkaline dry battery of prior art, Zinc alloy powder, PAA and PA are scattered in obtained negative pole in electrolyte.
In the embodiment and alternative thereof of the negative pole of above-mentioned alkaline dry battery, relative to the Zinc alloy powder of 100 weight portions, the weight portion of PAA can also be: 0.95,1.05,1.15.
In the embodiment and alternative thereof of the negative pole of above-mentioned alkaline dry battery, relative to the Zinc alloy powder of 100 weight portions, the weight portion of PA can also be: 0.065,0.07,0.075,0.085,0.09,0.095,0.105,0.11,0.115,0.12,0.125,0.13,0.135,0.14,0.145,0.155,0.16,0.165,0.17,0.175,0.18,0.185,0.19,0.195.
In the embodiment and alternative thereof of the negative pole of above-mentioned alkaline dry battery, relative to the Zinc alloy powder of 100 weight portions, the weight portion of electrolyte can also be: 51.5,52.5,53.5,54,54.5,55.5.
In the embodiment and alternative thereof of the negative pole of above-mentioned alkaline dry battery, the proportion of PAA can also be 0.4g/cm
3, 0.45g/cm
3, 0.5g/cm
3, 0.55g/cm
3, 0.65g/cm
3, 0.7g/cm
3, 0.75g/cm
3.
In the embodiment and alternative thereof of the negative pole of above-mentioned alkaline dry battery, the moisture content of PAA can also be 0.1wt%, 0.5wt%, 1wt%, 1.5wt%, 2wt%, 2.5wt%.
In the embodiment and alternative thereof of the negative pole of above-mentioned alkaline dry battery, the pH of PAA can also be 5,5.1,5.2,5.3,5.4,5.5,5.6,5.7,5.8,5.9,6.1,6.2,6.3,6.4,6.5,6.6,6.7,6.8,6.9,7.
In the embodiment and alternative thereof of the negative pole of above-mentioned alkaline dry battery, the domain size distribution of PAA can also be (by percentage to the quality): particle diameter≤75 μm: 12%, 75 < particle diameter≤105 μm: 74%, 105 < particle diameter≤150 μm: 6%, 150 < particle diameter≤300 μm: 8%; Particle diameter≤75 μm: 13%, 75 < particle diameter≤105 μm: 66%, 105 < particle diameter≤150 μm: 20%, 150 < particle diameter≤300 μm: 1%; Particle diameter≤75 μm: 14%, 75 < particle diameter≤105 μm: 62%, 105 < particle diameter≤150 μm: 18%, 150 < particle diameter≤300 μm: 6%; Particle diameter≤75 μm: 16%, 75 < particle diameter≤105 μm: 75%, 105 < particle diameter≤150 μm: 7%, 150 < particle diameter≤300 μm: 2%; Particle diameter≤75 μm: 17%, 75 < particle diameter≤105 μm: 65%, 105 < particle diameter≤150 μm: 15%, 150 < particle diameter≤300 μm: 3%; Particle diameter≤75 μm: 18%, 75 < particle diameter≤105 μm: 68%, 105 < particle diameter≤150 μm: 8%, 150 < particle diameter≤300 μm: 6%.
In the embodiment and alternative thereof of the negative pole of above-mentioned alkaline dry battery, the proportion of PA can also be 0.15g/cm
3, 0.2g/cm
3, 0.25g/cm
3, 0.35g/cm
3, 0.4g/cm
3, 0.45g/cm
3.
In the embodiment and alternative thereof of the negative pole of above-mentioned alkaline dry battery, the moisture content of PA can also be 0.1wt%, 0.5wt%, 1wt%, 1.5wt%, 2wt%, 2.5wt%.
In the embodiment and alternative thereof of the negative pole of above-mentioned alkaline dry battery, the pH of PA can also be 2,2.1,2.2,2.3,2.4,2.5,2.6,2.7,2.8,2.9,3.1,3.2,3.3,3.4,3.5,3.6,3.7,3.8,3.9,4.
In the embodiment and alternative thereof of the negative pole of above-mentioned alkaline dry battery, the domain size distribution of PA can also be (by percentage to the quality): particle diameter≤75 μm: 90%, 75 < particle diameter≤105 μm: 7%, 105 < particle diameter≤150 μm: 3%; Particle diameter≤75 μm: 89%, 75 < particle diameter≤105 μm: 7%, 105 < particle diameter≤150 μm: 4%; Particle diameter≤75 μm: 88%, 75 < particle diameter≤105 μm: 7%, 105 < particle diameter≤150 μm: 5%; Particle diameter≤75 μm: 87%, 75 < particle diameter≤105 μm: 7%, 105 < particle diameter≤150 μm: 6%; Particle diameter≤75 μm: 86%, 75 < particle diameter≤105 μm: 7%, 105 < particle diameter≤150 μm: 7%; Particle diameter≤75 μm: 85%, 75 < particle diameter≤105 μm: 7%, 105 < particle diameter≤150 μm: 8%;
Particle diameter≤75 μm: 89%, 75 < particle diameter≤105 μm: 8%, 105 < particle diameter≤150 μm: 3%; Particle diameter≤75 μm: 88%, 75 < particle diameter≤105 μm: 8%, 105 < particle diameter≤150 μm: 4%; Particle diameter≤75 μm: 87%, 75 < particle diameter≤105 μm: 8%, 105 < particle diameter≤150 μm: 5%; Particle diameter≤75 μm: 86%, 75 < particle diameter≤105 μm: 8%, 105 < particle diameter≤150 μm: 6%; Particle diameter≤75 μm: 85%, 75 < particle diameter≤105 μm: 8%, 105 < particle diameter≤150 μm: 7%;
Particle diameter≤75 μm: 88%, 75 < particle diameter≤105 μm: 9%, 105 < particle diameter≤150 μm: 3%; Particle diameter≤75 μm: 87%, 75 < particle diameter≤105 μm: 9%, 105 < particle diameter≤150 μm: 4%; Particle diameter≤75 μm: 86%, 75 < particle diameter≤105 μm: 9%, 105 < particle diameter≤150 μm: 5%; Particle diameter≤75 μm: 85%, 75 < particle diameter≤105 μm: 9%, 105 < particle diameter≤150 μm: 6%;
Particle diameter≤75 μm: 87%, 75 < particle diameter≤105 μm: 10%, 105 < particle diameter≤150 μm: 3%; Particle diameter≤75 μm: 86%, 75 < particle diameter≤105 μm: 10%, 105 < particle diameter≤150 μm: 4%;
Particle diameter≤75 μm: 86%, 75 < particle diameter≤105 μm: 11%, 105 < particle diameter≤150 μm: 3%; Particle diameter≤75 μm: 85%, 75 < particle diameter≤105 μm: 11%, 105 < particle diameter≤150 μm: 4%;
Particle diameter≤75 μm: 85%, 75 < particle diameter≤105 μm: 12%, 105 < particle diameter≤150 μm: 3%.
Application Example 1-5:
The negative pole of the alkaline dry battery obtained by embodiment of the present invention 1-5 respectively replaces the negative pole of LR20 battery in prior art, prepares new alkaline dry battery.
Comparative example: commercially available LR20 battery.
The alkaline dry battery prepared by Application Example 1-5 and the alkaline dry battery of comparative example carry out discharge performance and leak resistance test, and test result is as shown in table 2.
Table 2: test result
In addition, after testing, apply the interior gas amount of the alkaline dry battery of the negative pole of alkaline dry battery of the present invention all at 3.2-4.8mL, and the interior gas amount of the commercially available LR20 battery of comparative example is all at 4.6-6.5mL.
Therefore known, discharge performance and the leak resistance of applying the alkaline dry battery of the negative pole of alkaline dry battery of the present invention are all greatly improved.
Specific embodiment described herein is only to the explanation for example of the present invention's spirit.Those skilled in the art can make various amendment or supplement or adopt similar mode to substitute to described specific embodiment, but can't depart from spirit of the present invention or surmount the scope that appended claims defines.
Although made a detailed description the present invention and quoted some specific embodiments as proof, to those skilled in the art, only otherwise it is obvious for leaving that the spirit and scope of the present invention can make various changes or revise.
Claims (9)
1. the negative pole of an alkaline dry battery, it is characterized in that, described negative pole comprises Zinc alloy powder, PAA, PA and electrolyte, and the ratio of weight and number of described Zinc alloy powder, PAA, PA and electrolyte is 100:(0.9-1.2): (0.06-0.2): (51-56); Wherein, particle diameter≤300 μm of described PAA.
2. the negative pole of a kind of alkaline dry battery according to claim 1, it is characterized in that, the domain size distribution of described PAA is (by percentage to the quality): particle diameter≤75 μm: 12-18%, 75 < particle diameter≤105 μm: 62-75%, 105 < particle diameter≤150 μm: 6-20%, 150 < particle diameter≤300 μm: 1-8%.
3. the negative pole of a kind of alkaline dry battery according to claim 1 and 2, is characterized in that, the proportion of described PAA is 0.4-0.8g/cm
3, water content≤3.5wt%.
4. the negative pole of a kind of alkaline dry battery according to claim 3, is characterized in that, the pH of described PAA is 5-7.
5. the negative pole of a kind of alkaline dry battery according to claim 1, is characterized in that, particle diameter≤150 μm of described PA.
6. the negative pole of a kind of alkaline dry battery according to claim 5, it is characterized in that, the domain size distribution of described PA is (by percentage to the quality): particle diameter≤75 μm: >=85%, 75 < particle diameter≤105 μm: 7-12%, 105 < particle diameter≤150 μm: 3-8%.
7. the negative pole of a kind of alkaline dry battery according to claim 1 or 5 or 6, is characterized in that, the proportion of described PA is 0.15-0.50g/cm
3, water content≤3.5wt%.
8. the negative pole of a kind of alkaline dry battery according to claim 7, is characterized in that, the pH of described PA is 2-4.
9. the alkaline dry battery of the negative pole of an application alkaline dry battery as claimed in claim 1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510684992.9A CN105226233A (en) | 2015-10-21 | 2015-10-21 | A kind of negative pole of alkaline dry battery and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510684992.9A CN105226233A (en) | 2015-10-21 | 2015-10-21 | A kind of negative pole of alkaline dry battery and application thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105226233A true CN105226233A (en) | 2016-01-06 |
Family
ID=54995058
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510684992.9A Withdrawn CN105226233A (en) | 2015-10-21 | 2015-10-21 | A kind of negative pole of alkaline dry battery and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105226233A (en) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001006680A (en) * | 1999-06-18 | 2001-01-12 | Toshiba Battery Co Ltd | Zinc alkaline battery |
| JP2004259454A (en) * | 2003-02-24 | 2004-09-16 | Toshiba Battery Co Ltd | Cylindrical alkaline battery |
| JP2005038697A (en) * | 2003-07-14 | 2005-02-10 | Toshiba Battery Co Ltd | Cylinder alkaline battery |
| JP2006331767A (en) * | 2005-05-25 | 2006-12-07 | Hitachi Maxell Ltd | Alkaline cell |
| US20110294004A1 (en) * | 2010-05-28 | 2011-12-01 | Rovcal, Inc. | Alkaline cell with additive for improved discharge performance |
| CN103078119A (en) * | 2013-01-22 | 2013-05-01 | 中银（宁波）电池有限公司 | Mercury-free alkaline battery negative electrode material and preparation method thereof |
-
2015
- 2015-10-21 CN CN201510684992.9A patent/CN105226233A/en not_active Withdrawn
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001006680A (en) * | 1999-06-18 | 2001-01-12 | Toshiba Battery Co Ltd | Zinc alkaline battery |
| JP2004259454A (en) * | 2003-02-24 | 2004-09-16 | Toshiba Battery Co Ltd | Cylindrical alkaline battery |
| JP2005038697A (en) * | 2003-07-14 | 2005-02-10 | Toshiba Battery Co Ltd | Cylinder alkaline battery |
| JP2006331767A (en) * | 2005-05-25 | 2006-12-07 | Hitachi Maxell Ltd | Alkaline cell |
| US20110294004A1 (en) * | 2010-05-28 | 2011-12-01 | Rovcal, Inc. | Alkaline cell with additive for improved discharge performance |
| CN103078119A (en) * | 2013-01-22 | 2013-05-01 | 中银（宁波）电池有限公司 | Mercury-free alkaline battery negative electrode material and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101764253B (en) | Secondary aluminum battery and preparation method thereof | |
| Jiao et al. | A novel polar copolymer design as a multi-functional binder for strong affinity of polysulfides in lithium-sulfur batteries | |
| JP2016520969A (en) | Zinc ion secondary battery and manufacturing method thereof | |
| CN103700860A (en) | Lithium ion battery | |
| CN103700808A (en) | Lithium ion battery composite anode pole piece, preparation method and lithium ion battery | |
| CN107293733A (en) | A kind of Dual-ion cell | |
| CN104577130A (en) | Flexible-packaged high-power lithium iron phosphate power battery | |
| CN109148821B (en) | Preparation method of composite positive electrode of high-capacity lithium primary battery | |
| CN103346297A (en) | Preparation method for carbon coated composite metal oxide electrode material | |
| CN105047938A (en) | Preparation method for anode paste of lithium battery | |
| CN105633360A (en) | Amorphous state ferriferrous oxide/graphene aerogel composite material and preparation method and application thereof | |
| JP2024524314A (en) | Positive electrode for all-solid-state battery and all-solid-state battery including the same | |
| CN109524653A (en) | A method of lithium-ion capacitor specific capacity is promoted using conducting polymer | |
| CN106158413B (en) | Lithium is from electronic POD | |
| CN106129379A (en) | Large-current alkaline zinc-manganese battery using superfine alloy zinc powder | |
| WO2024125486A1 (en) | Sodium-ion battery and energy storage device | |
| CN109802135A (en) | A kind of lithium sulfur battery anode material, and its preparation method and application | |
| CN107068998A (en) | Battery electrode containing conducting polymer/graphene and its preparation method and application | |
| CN104201374A (en) | High-capacity lithium ion battery cathode material and preparation method thereof | |
| CN105470461A (en) | High-nickel base cathode paste for lithium-ion battery and preparation method of high-nickel base cathode paste | |
| CN103700848B (en) | A kind of anode material for lithium-ion batteries, positive pole and battery | |
| CN105374982A (en) | Electrode structure of lithium sulfur battery and processing technology therefor | |
| CN106848327A (en) | A kind of positive pole of lithium pyrite battery and the battery being made from it | |
| CN105185971A (en) | Cathode of alkaline dry battery and application thereof | |
| CN108242543A (en) | A kind of soft carbon makees the preparation method of the sodium Dual-ion cell of negative material |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20160106 |