CN105226137A - A kind of photovoltaic glass assembly and manufacture method thereof - Google Patents

A kind of photovoltaic glass assembly and manufacture method thereof Download PDF

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Publication number
CN105226137A
CN105226137A CN201510675476.XA CN201510675476A CN105226137A CN 105226137 A CN105226137 A CN 105226137A CN 201510675476 A CN201510675476 A CN 201510675476A CN 105226137 A CN105226137 A CN 105226137A
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China
Prior art keywords
glass substrate
manufacture method
photovoltaic glass
glass assembly
assembly
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Application number
CN201510675476.XA
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Chinese (zh)
Inventor
刘祥志
徐鹏程
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BAZHONG HUASHENG GLASS Co Ltd
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BAZHONG HUASHENG GLASS Co Ltd
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Priority to CN201510675476.XA priority Critical patent/CN105226137A/en
Publication of CN105226137A publication Critical patent/CN105226137A/en
Pending legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/18Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
    • H01L31/1804Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof comprising only elements of Group IV of the Periodic Table
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/042PV modules or arrays of single PV cells
    • H01L31/048Encapsulation of modules
    • H01L31/0488Double glass encapsulation, e.g. photovoltaic cells arranged between front and rear glass sheets
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy
    • Y02E10/547Monocrystalline silicon PV cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Electromagnetism (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Hybrid Cells (AREA)

Abstract

The invention discloses a kind of photovoltaic glass assembly and manufacture method thereof, comprise and selecting materials, stacked, Bao Mian, vacuumize, hot pressing, clean and coated with nano photocatalyst material step, the present invention is provided with parcel high temperature cotton, vacuum seal and heat-press step, reduce in conventional photovoltaic glass assembly and occur the phenomenon such as impurity, bubble in glass sandwich, production efficiency is high, and technique is simple, improves the quality of photovoltaic glass assembly.

Description

A kind of photovoltaic glass assembly and manufacture method thereof
Technical field
The present invention relates to photovoltaic glass and make field, particularly a kind of photovoltaic glass assembly and manufacture method thereof.
Background technology
Along with the quickening of China's modernization rhythm, social economy's rapid development and the improvement of people's living environment, driven modern architecture industry also high speed development thereupon, while also driven the fast development of glass manufacture industry.Country promotes new forms of energy at present, and solar energy is as existing optimal regenerative resource, inexhaustible, and it and the perfect adaptation of modern architecture industry, facilitate the integrative development of photovoltaic building.
Current photovoltaic glass assembly is generally the structure of pressing from both sides battery membranes in two glass substrates, but the method for routine, easily produce bubble between two glass substrates and battery membranes, affect the quality of whole photovoltaic glass assembly.Meanwhile, the selection of glass substrate is also the key of whole photovoltaic glass assembly.
Summary of the invention
Based on this, for the problems referred to above, be necessary to propose a kind of photovoltaic glass assembly and manufacture method thereof, be provided with parcel high temperature cotton, vacuum seal and heat-press step, reduce in conventional photovoltaic glass assembly and occur the phenomenon such as impurity, bubble in glass sandwich, production efficiency is high, and technique is simple, improves the quality of photovoltaic glass assembly.
Technical scheme of the present invention is: a kind of manufacture method of photovoltaic glass assembly, comprises the following steps:
A, by after cleaning glass substrate, put one piece of glass substrate on mould;
B, by stretching for PVB glued membrane tiling on the glass substrate;
C, on PVB glued membrane, place one deck monocrystalline silicon battery membranes, both positive and negative polarity is carried out to monocrystalline silicon battery membranes and puts and spacing location, and by extraction two lead-out wires;
D, above monocrystalline silicon battery membranes, repave lid layer PVB glued membrane, the PVB glued membrane before and after bedding keeps totally pollution-free;
E, put plastic ring at module edge pad, plastic ring can not be pressed onto the edge of monocrystalline silicon battery membranes, covers another layer of glass substrate, and the position alignment of upper lower glass substrate, without folded difference, namely removes plastic ring;
F, with cutter, PVB glued membrane unnecessary for module edge to be cut away;
G, one deck nylon cloth and two-layer high temperature cotton to be superimposed, and to be stretchingly wrapped in module edge, then with high temperature gummed tape, nylon cloth and high temperature cotton are fixed on glass;
H, cut the vacuum diaphragm of pre-set dimension, more cotton for the bag assembly completed is put in vacuum diaphragm, be positioned on high temperature cotton with vacuum nozzle through vacuum diaphragm;
Whether the bonding of i, inspection high-temperature seal adhesive and suction nozzle and vacuum diaphragm is firm, with or without air vent hole, and the reduction of unnecessary vacuum diaphragm fallen, transfers in autoclave and carry out hot pressing;
After j, hot pressing, take out assembly, and dirty, the cull on cleaning assemblies surface;
After the cooling of k, assembly, apply one deck nano photocatalyst catalytic material at assembly surface.
Traditional photovoltaic glass assembly be manufactured on sealing time easily because compacting does not tightly leak air, air infiltrates from module edge and produces bubble, and Another reason is then because the PVB glue in glass assembly is lepthymenia, and air fails to discharge the bubble produced in time.There is the assembly of bubble in use, PVB glued membrane easily and glass substrate, the delamination of monocrystalline silicon battery membranes, have a strong impact on assembly outward appearance, battery performance and life-span.The present invention adopts vacuum bag molding, and photovoltaic glass assembly is placed in vacuum bag, then by the air in vacuum nozzle pick-up component, can discharge inner bubble in time.
Preferably, in step f, during cutting, the angle α of cutter and glass substrate is 45 °, and this angle is convenient to cutter fly-cutting PVB glued membrane.
Preferably, in step e, the folded difference of maximum permission of upper lower glass substrate is: length folded difference a≤1mm, width folded difference b≤1mm.
Preferably, step I uses autoclave to carry out in the process of hot pressing, first heating up makes autoclave temp reach 45 DEG C, the temperature-pressure while of again, programming rate controls at 5 DEG C/min, and pressing speed controls at 0.06Mpa/min, treats that temperature reaches 120 DEG C ~ 140 DEG C, when pressure reaches 1.0Mpa ~ 1.5Mpa, heat-insulation pressure keeping 30min ~ 60min.
Preferably, described nano photocatalyst catalytic material is titanium dioxide.
Preferably, described glass substrate is prepared from by the raw material of following weight portion: quartz sand 60-100 part, aluminium oxide 12-15 part, calcite 6-8 part, saltcake 6-8 part, sodium oxide molybdena 4-6 part, kaolin 2-4 part, barium monoxide 0.5-2 part, yittrium oxide 0.2-0.3 part, lanthana 0.2-0.3 part.
Preferably, the manufacture method of described glass substrate comprises the following steps:
S1, take each raw material for standby by weight;
S2, become particle diameter to be less than the powder of 150um raw material grinding mill, and material powder is mixed;
S3, crucible is warming up to 1200 DEG C with the speed of 20 DEG C/min, adds raw material, after insulation reaction 30min, be warming up to 1500 DEG C, insulation 40min;
S4, pour in mould by glass metal, shaping rear feeding annealing furnace, annealing temperature is 600 DEG C ~ 650 DEG C;
S5, to cool.
The invention has the beneficial effects as follows: the present invention is provided with parcel high temperature cotton, vacuum seal and heat-press step, reduce in conventional photovoltaic glass assembly and occur the phenomenon such as impurity, bubble in glass sandwich, production efficiency is high, and technique is simple, improves the quality of photovoltaic glass assembly.
Accompanying drawing explanation
Fig. 1 is the structural representation of the embodiment of the present invention;
In figure, 10-glass substrate, 20-PVB glued membrane, 30-monocrystalline silicon battery membranes.
Embodiment
Below in conjunction with accompanying drawing, embodiments of the invention are described in detail.
Embodiment:
A kind of photovoltaic glass assembly, as shown in Figure 1, cover monocrystalline silicon battery membranes by upper and lower layer glass substrate folder and form, comprise PVB glued membrane between glass substrate and monocrystalline silicon battery membranes, described PVB glued membrane also can replace by EVA adhesive film, and its manufacture method comprises the following steps:
A, glass substrate 10 is cleaned after, put one piece of glass substrate 10 on mould;
B, by stretching for PVB glued membrane 20 tiling on the glass substrate 10;
C, on PVB glued membrane 20, place one deck monocrystalline silicon battery membranes 30, both positive and negative polarity is carried out to monocrystalline silicon battery membranes 30 and puts and spacing location, and by extraction two lead-out wires;
D, above monocrystalline silicon battery membranes 30, repave lid layer PVB glued membrane 20, the PVB glued membrane 20 before and after bedding keeps totally pollution-free;
E, put plastic ring at module edge pad, plastic ring can not be pressed onto the edge of monocrystalline silicon battery membranes 30, covers another layer of glass substrate 10, and the position alignment of upper lower glass substrate, without folded difference, namely removes plastic ring;
F, with cutter, PVB glued membrane 20 unnecessary for module edge to be cut away;
G, one deck nylon cloth and two-layer high temperature cotton to be superimposed, and to be stretchingly wrapped in module edge, then with high temperature gummed tape, nylon cloth and high temperature cotton are fixed on glass;
H, cut the vacuum diaphragm of pre-set dimension, more cotton for the bag assembly completed is put in vacuum diaphragm, be positioned on high temperature cotton with vacuum nozzle through vacuum diaphragm;
Whether the bonding of i, inspection high-temperature seal adhesive and suction nozzle and vacuum diaphragm is firm, with or without air vent hole, and the reduction of unnecessary vacuum diaphragm fallen, transfers in autoclave and carry out hot pressing;
After j, hot pressing, take out assembly, and dirty, the cull on cleaning assemblies surface;
After the cooling of k, assembly, apply one deck nano photocatalyst catalytic material at assembly surface.
Traditional photovoltaic glass assembly be manufactured on sealing time easily because compacting does not tightly leak air, air infiltrates from module edge and produces bubble, and Another reason is then because the PVB glue in glass assembly is lepthymenia, and air fails to discharge the bubble produced in time.There is the assembly of bubble in use, PVB glued membrane easily and glass substrate, the delamination of monocrystalline silicon battery membranes, have a strong impact on assembly outward appearance, battery performance and life-span.The present invention adopts vacuum bag molding, and photovoltaic glass assembly is placed in vacuum bag, then by the air in vacuum nozzle pick-up component, can discharge inner bubble in time.
Preferably, in step f, during cutting, the angle α of cutter and glass substrate 10 is 45 °, and this angle is convenient to cutter fly-cutting PVB glued membrane.
Preferably, in step e, the folded difference of maximum permission of upper lower glass substrate 10 is: length folded difference a≤1mm, width folded difference b≤1mm.
Preferably, step I uses autoclave to carry out in the process of hot pressing, first heating up makes autoclave temp reach 45 DEG C, the temperature-pressure while of again, programming rate controls at 5 DEG C/min, and pressing speed controls at 0.06Mpa/min, treats that temperature reaches 120 DEG C ~ 140 DEG C, when pressure reaches 1.0Mpa ~ 1.5Mpa, heat-insulation pressure keeping 30min ~ 60min.
Preferably, described nano photocatalyst catalytic material is titanium dioxide.
Preferably, described glass substrate 10 is prepared from by the raw material of following weight portion: quartz sand 60-100 part, aluminium oxide 12-15 part, calcite 6-8 part, saltcake 6-8 part, sodium oxide molybdena 4-6 part, kaolin 2-4 part, barium monoxide 0.5-2 part, yittrium oxide 0.2-0.3 part, lanthana 0.2-0.3 part.
Preferably, the manufacture method of described glass substrate 10 comprises the following steps:
S1, take each raw material for standby by weight;
S2, become particle diameter to be less than the powder of 150um raw material grinding mill, and material powder is mixed;
S3, crucible is warming up to 1200 DEG C with the speed of 20 DEG C/min, adds raw material, after insulation reaction 30min, be warming up to 1500 DEG C, insulation 40min;
S4, pour in mould by glass metal, shaping rear feeding annealing furnace, annealing temperature is 600 DEG C ~ 650 DEG C;
S5, to cool.
The above embodiment only have expressed the specific embodiment of the present invention, and it describes comparatively concrete and detailed, but therefore can not be interpreted as the restriction to the scope of the claims of the present invention.It should be pointed out that for the person of ordinary skill of the art, without departing from the inventive concept of the premise, can also make some distortion and improvement, these all belong to protection scope of the present invention.

Claims (7)

1. a manufacture method for photovoltaic glass assembly, is characterized in that, comprises the following steps:
A, by after cleaning glass substrate, put one piece of glass substrate on mould;
B, by stretching for PVB glued membrane tiling on the glass substrate;
C, on PVB glued membrane, place one deck monocrystalline silicon battery membranes, both positive and negative polarity is carried out to monocrystalline silicon battery membranes and puts and spacing location, and by extraction two lead-out wires;
D, above monocrystalline silicon battery membranes, repave lid layer PVB glued membrane, the PVB glued membrane before and after bedding keeps totally pollution-free;
E, put plastic ring at module edge pad, plastic ring can not be pressed onto the edge of monocrystalline silicon battery membranes, covers another layer of glass substrate, and the position alignment of upper lower glass substrate, without folded difference, namely removes plastic ring;
F, with cutter, PVB glued membrane unnecessary for module edge to be cut away;
G, one deck nylon cloth and two-layer high temperature cotton to be superimposed, and to be stretchingly wrapped in module edge, then with high temperature gummed tape, nylon cloth and high temperature cotton are fixed on glass;
H, cut the vacuum diaphragm of pre-set dimension, more cotton for the bag assembly completed is put in vacuum diaphragm, be positioned on high temperature cotton with vacuum nozzle through vacuum diaphragm;
Whether the bonding of i, inspection high-temperature seal adhesive and suction nozzle and vacuum diaphragm is firm, with or without air vent hole, and the reduction of unnecessary vacuum diaphragm fallen, transfers in autoclave and carry out hot pressing;
After j, hot pressing, take out assembly, and dirty, the cull on cleaning assemblies surface;
After the cooling of k, assembly, apply one deck nano photocatalyst catalytic material at assembly surface.
2. the manufacture method of a kind of photovoltaic glass assembly according to claim 1, it is characterized in that, in step f, during cutting, the angle α of cutter and glass substrate is 45 °.
3. the manufacture method of a kind of photovoltaic glass assembly according to claim 1, is characterized in that, in step e, the folded difference of maximum permission of upper lower glass substrate is: length folded difference a≤1mm, the folded poor b≤1mm of width.
4. the manufacture method of a kind of photovoltaic glass assembly according to claim 1, it is characterized in that, step I uses autoclave to carry out in the process of hot pressing, first heating up makes autoclave temp reach 45 DEG C, more simultaneously temperature-pressure, and programming rate controls at 5 DEG C/min, pressing speed controls at 0.06Mpa/min, treat that temperature reaches 120 DEG C ~ 140 DEG C, when pressure reaches 1.0Mpa ~ 1.5Mpa, heat-insulation pressure keeping 30min ~ 60min.
5. the manufacture method of a kind of photovoltaic glass assembly according to claim 1, it is characterized in that, described nano photocatalyst catalytic material is titanium dioxide.
6. the manufacture method of a kind of photovoltaic glass assembly according to claim 1, it is characterized in that, described glass substrate is prepared from by the raw material of following weight portion:
Quartz sand 60-100 part, aluminium oxide 12-15 part, calcite 6-8 part, saltcake 6-8 part, sodium oxide molybdena 4-6 part, kaolin 2-4 part, barium monoxide 0.5-2 part, yittrium oxide 0.2-0.3 part, lanthana 0.2-0.3 part.
7. a kind of manufacture method of photovoltaic glass assembly according to claim 1 or 6, it is characterized in that, the manufacture method of described glass substrate comprises the following steps:
S1, take each raw material for standby by weight;
S2, become particle diameter to be less than the powder of 150um raw material grinding mill, and material powder is mixed;
S3, crucible is warming up to 1200 DEG C with the speed of 20 DEG C/min, adds raw material, after insulation reaction 30min, be warming up to 1500 DEG C, insulation 40min;
S4, pour in mould by glass metal, shaping rear feeding annealing furnace, annealing temperature is 600 DEG C ~ 650 DEG C;
S5, to cool.
CN201510675476.XA 2015-10-16 2015-10-16 A kind of photovoltaic glass assembly and manufacture method thereof Pending CN105226137A (en)

Priority Applications (1)

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Publication Number Publication Date
CN105226137A true CN105226137A (en) 2016-01-06

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111162135A (en) * 2019-12-20 2020-05-15 中建材浚鑫科技有限公司 Manufacturing process of glass with frame and double-glass product

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101162742A (en) * 2007-11-27 2008-04-16 上海耀华皮尔金顿玻璃股份有限公司 Solar photovoltaic interlining curtain wall glass manufacturing process
CN101997046A (en) * 2010-10-15 2011-03-30 河南新能光伏有限公司 Encapsulating method of solar photovoltaic laminated glass component
CN104529158A (en) * 2014-12-19 2015-04-22 江门市江海区金达玻璃文化有限公司 Photovoltaic glass production process

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101162742A (en) * 2007-11-27 2008-04-16 上海耀华皮尔金顿玻璃股份有限公司 Solar photovoltaic interlining curtain wall glass manufacturing process
CN101997046A (en) * 2010-10-15 2011-03-30 河南新能光伏有限公司 Encapsulating method of solar photovoltaic laminated glass component
CN104529158A (en) * 2014-12-19 2015-04-22 江门市江海区金达玻璃文化有限公司 Photovoltaic glass production process

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111162135A (en) * 2019-12-20 2020-05-15 中建材浚鑫科技有限公司 Manufacturing process of glass with frame and double-glass product
CN111162135B (en) * 2019-12-20 2023-08-18 中建材浚鑫科技有限公司 Glass manufacturing process for framed double-glass product

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