CN105216389A - A kind of fabric, Its Preparation Method And Use - Google Patents
A kind of fabric, Its Preparation Method And Use Download PDFInfo
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- CN105216389A CN105216389A CN201510527497.7A CN201510527497A CN105216389A CN 105216389 A CN105216389 A CN 105216389A CN 201510527497 A CN201510527497 A CN 201510527497A CN 105216389 A CN105216389 A CN 105216389A
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- Prior art keywords
- fabric
- titanium
- composite material
- nano composite
- carbon
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
- B32B9/005—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising one layer of ceramic material, e.g. porcelain, ceramic tile
- B32B9/007—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising one layer of ceramic material, e.g. porcelain, ceramic tile comprising carbon, e.g. graphite, composite carbon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
- B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
- B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B9/048—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material made of particles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/20—Properties of the layers or laminate having particular electrical or magnetic properties, e.g. piezoelectric
- B32B2307/21—Anti-static
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/20—Properties of the layers or laminate having particular electrical or magnetic properties, e.g. piezoelectric
- B32B2307/212—Electromagnetic interference shielding
Landscapes
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The present invention relates to a kind of fabric, Its Preparation Method And Use.Described fabric contains the nano composite material coating of nano particle/titanium oxide/carbon; In described fabric, using textile material as base material, prepare fabric by covering described nano composite material as coating.The nano composite material specific area of the nano particle/titanium oxide/carbon in the present invention is large, structurally ordered, make the preparation-obtained fabric of the present invention have the features such as electromagnetic shielding rate is high, antibiotic property good, color fastness is good, mechanical property is good, electric conductivity is strong, there is permanently antistatic effect.
Description
Technical field
The present invention relates to textile material technical field, in particular, the present invention relates to a kind of fabric, Its Preparation Method And Use.
Background technology
The wide range of electromagnetic radiation, comprise neutron ray, X-ray, gamma-radiation, α-ray, the protection of tens kinds of rays such as ultraviolet, infrared ray, electromagnetic wave, cosmic ray, laser, microwave, these rays bring Gospel to the mankind, also bring injury simultaneously, bring the harm of electromagnetic radiation pollution.
For protecting personal safety and the health of labourer, in " labour protection articles for use outfit standard (trying) " that 2000 in China is made and issued, radiation proof articles for use are classified as the indispensable protective articles of part work post.Electromagnetic radiation colorless and odorless, can penetrate the many kinds of substance comprising human body.As long as the electrical installations such as various household electrical appliance, electronic equipment, business automation equipment, mobile communication equipment are in operation using state, electromagnetic radiation will be there is around it, if under human body is chronically exposed to and exceedes safe dose of radiation, human body cell will be killed and wounded by large area or kill.Old man, children, pregnant woman belong to the sensitive group to electromagnetic radiation, and heart, eyes and reproductive system then belong to the responsive organ of human body to electromagnetic radiation.It should be noted that the infringement of electromagnetic radiation to human body is long term accumulation and produces, it shows five aspects such as heartbeat oligemia, the reduction of man's sperm quality.In view of this, Chinese Consumers' Association warns, and the electrical equipment such as TV, computer should not be concentrated and be placed in bedroom, appeals that manufacturing enterprise actively develops, promotes effective Radiation proof dress.
Often touch for most people and endanger larger shortwave, ultrashortly involve microwave frequency band, adopt specific principle and method to develop and there is good electromagnetic wave proof effect and the various characteristics being suitable for clothes basic demand, as to the microwave defense material of human body without physics and chemistry excitant, natural gas permeability, flexibility, durability, wearability and resistance to ag(e)ing etc., have great importance.
The rinsing but existing exposure suit will be tried one's best when being contained in washing, does not firmly rub, rubs with the hands, twists, when depositing after drying, try not to fold, because its fabric contains metal ingredient, be afraid of wash-out, fearness fractures, and reduces shielding properties and the service life of anti-electromagnetic radiation.Metallic fiber blended yarn weaved fabric in exposure suit, half silver medal fiber blended fabric, complete silver-colored fiber knitted fabric and polyion fabric can wash, and after washing, shield effectiveness obviously reduces.Coating technology is a kind of process technology that in spinning post-finishing, new development is got up, mainly be coated with the film-forming macromolecular compound of last layer equably at fabric face, because it can give fabric various function, fabric can be given again with the style feel of uniqueness and outer existing form, and value-added content of product can be improved widely, its effect is also that general printing and dyeing arrangement institute is unapproachable.
The coating at present with radiation proof function is widely used, but, the electromagnetic shielding rate of general radiation proof material is still lower, and, usually not there is sterilizing function, color fastness and poor mechanical property, the defects such as electric conductivity is not strong, therefore research and develop one and there is permanently antistatic effect, and the fabric with excellent physical property is current problem demanding prompt solution.
Summary of the invention
For the deficiencies in the prior art, the invention provides a kind of fabric, Its Preparation Method And Use, particularly a kind ofly may be used for antistatic, fabric, Its Preparation Method And Use that electromagnetic shielding rate is high.
For reaching this goal of the invention, the present invention by the following technical solutions:
First aspect, the invention provides a kind of fabric, and it comprises the nano composite material coating of nano particle/titanium oxide/carbon.
In the present invention, the nano composite material of described nano particle/titanium oxide/carbon comprises nano-particle layer, TiO
2layer and CMK-5 mesoporous carbon.
Preferably, described TiO
2layer be evenly distributed on CMK-5 mesoporous carbon outer surface and inner surface on, described nano particle is evenly distributed on TiO
2the outer surface of layer.
The mesoporous carbon of CMK-5 described in the present invention is be masterplate with molecular sieve SBA-15, selects pyridine or sucrose to be the duct that carbon source fills SBA-15, the nanotube of the two dimension six side ordered structure obtained.
In the present invention, antistatic, the high effect of electromagnetic shielding rate effectively can be realized by adopting above-mentioned nano composite material coating, and, nano-particle layer in nano composite material coating of the present invention, titanium oxide layer and carbon-coating three have played synergy, compare the combination adopting wherein any one or two kinds, its effect all will be got well.
In the present invention, described fabric covers described nano composite material coating on textile material base material.
Preferably, the thickness that textile material base material covers described nano composite material is 15-50nm, such as, can be 15nm, 18nm, 20nm, 22nm, 25nm, 30nm, 32nm, 35nm, 40nm, 45nm, 50nm, is preferably 20-32nm.
Second aspect, present invention also offers a kind of preparation method of fabric as described in relation to the first aspect, it comprises:
(1) in the solution of titanium source, disperse CMK-5 mesoporous carbon, removal of impurities, obtain the nano composite material presoma of titanium oxide/carbon, calcining, then mixes it with nano particle, obtains the nano composite material of nano particle/titanium oxide/carbon;
(2) cover the nano composite material coating of step (1) at textile material substrate surface, obtain described fabric.
In step of the present invention (1), described titanium source is the combination of in isopropyl titanate, titanyl sulfate, titanium tetrachloride, titanium sulfate or Titanium Nitrate a kind or at least 2 kinds; 1 kind preferably in titanyl sulfate, titanium tetrachloride or titanium sulfate or the combination of at least 2 kinds.
Preferably, described titanium source solution solvent is the combination of in acetone, oxolane, benzene,toluene,xylene or dimethyl formamide a kind or at least 2 kinds.
In step of the present invention (1), described in be separated into ultrasonic disperse.
Preferably, described jitter time is 0.5-3h, is preferably 30-45min.
Preferably, described calcining is carried out under reducing atmosphere; Described calcining heat is 700-900 DEG C; Described calcination time is 35-60min.
Preferably, described removal of impurities is washing, dry.
Preferably, described drying is for drying.
In step of the present invention (2), described coating layer thickness is 15-50nm, is preferably 20-32nm.
Preferably, after described coating, at 90-110 DEG C of preliminary drying 1-5min, 100-150 DEG C of solidification 10-15min, places after 24-48h and get final product.
As the preferred technical scheme of the present invention, the preparation method of described fabric, it comprises the following steps:
(1) using 1 in isopropyl titanate, titanyl sulfate, titanium tetrachloride, titanium sulfate or Titanium Nitrate kind or the combination of at least 2 kinds as titanium source, CMK-5 mesoporous carbon 0.5-3h is disperseed in the solution of described titanium source, removal of impurities, obtain the nano composite material presoma of titanium oxide/carbon, calcine under reducing atmosphere, described calcining heat is 700-900 DEG C; Described calcination time is 35-60min; Then it is mixed with nano particle, obtain the nano composite material of nano particle/titanium oxide/carbon;
(2) carry out the coating of nano composite material at textile material substrate surface, coating layer thickness is 15-50nm; Then at 90-110 DEG C of preliminary drying 1-5min, 100-150 DEG C of solidification 10-15min, places after 24-48h and get final product.
The third aspect, present invention also offers the application of fabric in antistatic dress ornament as described in relation to the first aspect.
Compared with prior art, the present invention at least has following beneficial effect:
(1) the preparation-obtained fabric of the present invention has the effect of electromagnetic shielding rate height and permanently antistatic, and its shielding rate reaches more than 99.99%, more than shield effectiveness 59dB; Use 5 months or after washing 60 times, shielding rate is still more than 99.9%, and more than shield effectiveness 52dB, namely used after a period of time, and the durability of described fabric and anti-electromagnetic radiation effect are still good;
(2) the preparation-obtained fabric of the present invention also has moisture absorption, ventilative, comfortable feature, especially has the features such as antibiotic property is good, color fastness is good, mechanical property is good;
(3) fabric preparation method of the present invention is simple, and cost is low, is beneficial to suitability for industrialized production.
Detailed description of the invention
For ease of understanding the present invention, it is as follows that the present invention enumerates embodiment.Those skilled in the art should understand, described embodiment is only help to understand the present invention, should not be considered as concrete restriction of the present invention.
(the LeiZB such as CMK-5 mesoporous carbon LeiZB, BaiSY, XiaoYetal.CMK-5MesoporousCarbonSynthesizedviaChemicalVap orDepositionofFerroceneasCatalystSupportforMethanolOxida tion.J.Phys.Chem.C, 2008,112 (3): 722-731.) method described in is prepared, gained CMK-5 aperture 3.3nm and 5nm, specific area is about 2400m
2/ g, pore volume is 2.20cm
3/ g.A kind of two-dimentional six side's ordered mesoporous material with carbon elements.CMK-5, before the use first through the activation of 5.5M salpeter solution, strengthens to make its dispersiveness.
Embodiment 1
(1) take 8mL isopropyl titanate, 2g concentrated hydrochloric acid is slowly added with for subsequent use in isopropyl titanate under ceaselessly stirring, claim 0.4gCMK-5 ultrasonic disperse simultaneously in 28mL toluene.The isopropyl titanate handled well is slowly added in CMK-5 toluene mixture liquid, uninterrupted stirring 48 hours.Then mixed liquor washing, oven dry are obtained powders A, 700 DEG C of Heat preservation 35min under nitrogen atmosphere protection, then mix it with nano particle, obtain nano particle/TiO
2/ C nano composite.
(2) nano composite material step (1) obtained is in flexible fiber fabric face coating, and THICKNESS CONTROL is at 15nm, and at 110 DEG C of preliminary drying 2min, 130 DEG C of solidification 12min, place after 24h and get final product.
Method with reference to national standard GB/T 26383-2011 " anti-electromagnetic-radiation combing worsted spinning " measures anti-electromagnetic radiation performance, and after tested, the fabric of embodiment 1 can shield electromagnetic wave, and shielding rate reaches 99.99%, shield effectiveness 59dB; After washing 60 times, shielding rate is 99.93%, shield effectiveness 53dB.
Embodiment 2
(1) take 8mL titanium sulfate, 5g concentrated hydrochloric acid is slowly added with for subsequent use in titanium sulfate under ceaselessly stirring, claim 0.9gCMK-5 ultrasonic disperse simultaneously in 28mL dimethylbenzene.The titanium sulfate handled well is slowly added in CMK-5 dimethylbenzene mixed liquor, uninterrupted stirring 36 hours.Then mixed liquor washing, oven dry are obtained powders A, 800 DEG C of Heat preservation 40min under nitrogen atmosphere protection, then mix it with nano particle, obtain nano particle/TiO
2/ C nano composite.
(2) nano composite material step (1) obtained is in flexible fiber fabric face coating, and THICKNESS CONTROL is at 50nm, and at 100 DEG C of preliminary drying 2min, 110 DEG C of solidification 13min, place after 28h and get final product.
Method with reference to national standard GB/T 26383-2011 " anti-electromagnetic-radiation combing worsted spinning " measures anti-electromagnetic radiation performance, and after tested, the fabric of embodiment 1 can shield electromagnetic wave, and shielding rate reaches 99.992%, shield effectiveness 60dB; After washing 60 times, shielding rate is 99.91%, shield effectiveness 54dB.
Embodiment 3
(1) take 5mL titanium tetrachloride, 1.5g concentrated hydrochloric acid is slowly added with for subsequent use in titanium tetrachloride under ceaselessly stirring, claim 0.4gCMK-ultrasonic disperse simultaneously in 25mL acetone.The titanium tetrachloride handled well is slowly added in CMK-5 acetone mixture, uninterrupted stirring 30 hours.Then washed by mixed liquor, dry and obtain powders A, under nitrogen atmosphere protection, 890 DEG C of Heat preservations 1 hour, then mix it with nano particle, obtain nano particle/TiO
2/ C nano composite.
(2) nano composite material step (1) obtained is in flexible fiber fabric face coating, and THICKNESS CONTROL is at 25nm, and at 90 DEG C of preliminary drying 2min, 150 DEG C of solidification 15min, place after 48h and get final product.
Method with reference to national standard GB/T 26383-2011 " anti-electromagnetic-radiation combing worsted spinning " measures anti-electromagnetic radiation performance, and after tested, the fabric of embodiment 1 can shield electromagnetic wave, and shielding rate reaches 99.999%, shield effectiveness 62dB; After washing 60 times, shielding rate is 99.92%, shield effectiveness 55dB.
Comparative example 1
(1) take 5mL titanium tetrachloride, 1.5g concentrated hydrochloric acid is slowly added with for subsequent use in titanium tetrachloride under ceaselessly stirring, claim 0.4gCMK-ultrasonic disperse simultaneously in 25mL acetone.The titanium tetrachloride handled well is slowly added in CMK-5 acetone mixture, uninterrupted stirring 30 hours.Then mixed liquor washing, oven dry are obtained powders A, under nitrogen atmosphere protection, 890 DEG C of Heat preservations obtain TiO in 1 hour
2/ C nano composite.
(2) nano composite material step (1) obtained is in flexible fiber fabric face coating, and THICKNESS CONTROL is at 25nm, and at 90 DEG C of preliminary drying 2min, 150 DEG C of solidification 15min, place after 48h and get final product.
Method with reference to national standard GB/T 26383-2011 " anti-electromagnetic-radiation combing worsted spinning " measures anti-electromagnetic radiation performance, and after tested, the fabric of embodiment 1 can shield electromagnetic wave, and shielding rate reaches 99.6%, shield effectiveness 45dB; After washing 60 times, shielding rate is 99.1%, shield effectiveness 40dB.
Comparative example 2
(1) take 5mL titanium tetrachloride, 1.5g concentrated hydrochloric acid is slowly added with for subsequent use in titanium tetrachloride under ceaselessly stirring, claim 0.4gCMK-ultrasonic disperse simultaneously in 25mL acetone.The titanium tetrachloride handled well is slowly added in CMK-5 acetone mixture, uninterrupted stirring 30 hours.Then washed by mixed liquor, dry and obtain powders A, under nitrogen atmosphere protection, 890 DEG C of Heat preservations 1 hour, then mix it with nano particle, obtain nano particle/TiO
2/ C nano composite.
(2) nano composite material step (1) obtained is in flexible fiber fabric face coating, and THICKNESS CONTROL is at 10nm, and at 90 DEG C of preliminary drying 2min, 150 DEG C of solidification 15min, place after 48h and get final product.
Method with reference to national standard GB/T 26383-2011 " anti-electromagnetic-radiation combing worsted spinning " measures anti-electromagnetic radiation performance, and after tested, the fabric of embodiment 1 can shield electromagnetic wave, and shielding rate reaches 99.1%, shield effectiveness 42dB; After washing 60 times, shielding rate is 98.3%, shield effectiveness 41dB.
Comparative example 3
(1) take 5mL titanium tetrachloride, 1.5g concentrated hydrochloric acid is slowly added with for subsequent use in titanium tetrachloride under ceaselessly stirring, claim 0.4gCMK-ultrasonic disperse simultaneously in 25mL acetone.The titanium tetrachloride handled well is slowly added in CMK-5 acetone mixture, uninterrupted stirring 30 hours.Then washed by mixed liquor, dry and obtain powders A, under nitrogen atmosphere protection, 890 DEG C of Heat preservations 1 hour, then mix it with nano particle, obtain nano particle/TiO
2/ C nano composite.
(2) nano composite material step (1) obtained is in flexible fiber fabric face coating, and THICKNESS CONTROL is at 52nm, and at 90 DEG C of preliminary drying 2min, 150 DEG C of solidification 15min, place after 48h and get final product.
Method with reference to national standard GB/T 26383-2011 " anti-electromagnetic-radiation combing worsted spinning " measures anti-electromagnetic radiation performance, and after tested, the fabric of embodiment 1 can shield electromagnetic wave, and shielding rate reaches 99.16%, shield effectiveness 40dB; After washing 60 times, shielding rate is 98.0%, shield effectiveness 38dB.
By by embodiment 3 compared with comparative example 1, can find out, embodiment 3 has higher electromagnetic shielding rate and the effect of permanently antistatic, illustrates that the present invention adopts nano particle/TiO
2/ C nano composite coating compares TiO
2/ C nano composite has more excellent performance.
By by embodiment 3 compared with comparative example 2-3, can find out, embodiment 3 has higher electromagnetic shielding rate and the effect of permanently antistatic equally, illustrates that the present invention adopts the nano particle/TiO covering 15-50nm thickness
2during/C nano composite coating, it has more excellent performance than the nano composite material coating covering below 15nm or more than 50nm.
Therefore, used in fabric of the present invention nano particle/TiO
2between three kinds of components of/C nano composite, there is synergy, and the coating layer thickness of described nano composite material also can have influence on electromagnetic shielding and the antistatic performance of whole fabric, and anti-microbial property is good, security high to make fabric have, and has use value widely.
Applicant states, the present invention illustrates detailed process equipment and process flow process of the present invention by above-described embodiment, but the present invention is not limited to above-mentioned detailed process equipment and process flow process, namely do not mean that the present invention must rely on above-mentioned detailed process equipment and process flow process and could implement.Person of ordinary skill in the field should understand, any improvement in the present invention, to equivalence replacement and the interpolation of auxiliary element, the concrete way choice etc. of each raw material of product of the present invention, all drops within protection scope of the present invention and open scope.
Claims (10)
1. a fabric, is characterized in that, described fabric comprises the nano composite material coating of nano particle/titanium oxide/carbon.
2. fabric as claimed in claim 1, it is characterized in that, the nano composite material of described nano particle/titanium oxide/carbon comprises nano-particle layer, TiO
2layer and CMK-5 mesoporous carbon;
Preferably, described TiO
2layer be evenly distributed on CMK-5 mesoporous carbon outer surface and inner surface on, described nano particle is evenly distributed on TiO
2the outer surface of layer.
3. fabric as claimed in claim 2, is characterized in that, described CMK-5 mesoporous carbon be masterplate with molecular sieve SBA-15, selects pyridine or sucrose to be the duct of carbon source filling SBA-15, the nanotube of the two dimension six side ordered structure obtained.
4. the fabric as described in any one of claim 1-3, is characterized in that, described fabric covers described nano composite material coating on textile material base material;
Preferably, the thickness that textile material base material covers described nano composite material coating is 15-50nm, is preferably 20-32nm.
5. the preparation method of the fabric as described in any one of claim 1-4, is characterized in that, it comprises:
(1) in the solution of titanium source, disperse CMK-5 mesoporous carbon, removal of impurities, obtain the nano composite material presoma of titanium oxide/carbon, calcining, then mixes it with nano particle, obtains the nano composite material of nano particle/titanium oxide/carbon;
(2) cover the nano composite material coating of step (1) at textile material substrate surface, obtain described fabric.
6. method as claimed in claim 5, is characterized in that, in step (1), described titanium source is the combination of in isopropyl titanate, titanyl sulfate, titanium tetrachloride, titanium sulfate or Titanium Nitrate a kind or at least 2 kinds;
Preferably, described titanium source is the combination of in titanyl sulfate, titanium tetrachloride or titanium sulfate a kind or at least 2 kinds;
Preferably, described titanium source solution solvent is the combination of in acetone, oxolane, benzene,toluene,xylene or dimethyl formamide a kind or at least 2 kinds.
7. the method as described in claim 5 or 6, is characterized in that, in step (1), described in be separated into ultrasonic disperse;
Preferably, described jitter time is 0.5-3h, is preferably 30-45min;
Preferably, described calcining is carried out under inert atmosphere or reducing atmosphere; Described calcining heat is 700-900 DEG C; Described calcination time is 35-60min;
Preferably, described removal of impurities is washing, dry;
Preferably, described drying is for drying.
8. the method as described in any one of claim 5-7, is characterized in that, in step (2), described coating layer thickness is 15-50nm, is preferably 20-32nm;
Preferably, after described coating, at 90-110 DEG C of preliminary drying 1-5min, 100-150 DEG C of solidification 10-15min, places after 24-48h and get final product.
9. the method as described in any one of claim 5-8, is characterized in that, it comprises the following steps:
(1) using 1 in isopropyl titanate, titanyl sulfate, titanium tetrachloride, titanium sulfate or Titanium Nitrate kind or the combination of at least 2 kinds as titanium source, CMK-5 mesoporous carbon 0.5-3h is disperseed in the solution of described titanium source, removal of impurities, obtain the nano composite material presoma of titanium oxide/carbon, calcine under reducing atmosphere, described calcining heat is 700-900 DEG C; Described calcination time is 35-60min; Then it is mixed with nano particle, obtain the nano composite material of nano particle/titanium oxide/carbon;
(2) carry out the coating of nano composite material at textile material substrate surface, coating layer thickness is 15-50nm; Then at 90-110 DEG C of preliminary drying 1-5min, 100-150 DEG C of solidification 10-15min, places after 24-48h and get final product.
10. the application of the fabric as described in any one of claim 1-4 in antistatic dress ornament.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510527497.7A CN105216389A (en) | 2015-08-25 | 2015-08-25 | A kind of fabric, Its Preparation Method And Use |
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|---|---|---|---|
| CN201510527497.7A CN105216389A (en) | 2015-08-25 | 2015-08-25 | A kind of fabric, Its Preparation Method And Use |
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| Publication Number | Publication Date |
|---|---|
| CN105216389A true CN105216389A (en) | 2016-01-06 |
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| CN201510527497.7A Pending CN105216389A (en) | 2015-08-25 | 2015-08-25 | A kind of fabric, Its Preparation Method And Use |
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1795978A (en) * | 2004-12-29 | 2006-07-05 | 上海杰事杰新材料股份有限公司 | Nano hollow microsphere of composite titania / inorganic carbon, preparation method and application |
| CN102891289A (en) * | 2012-10-23 | 2013-01-23 | 中国科学院过程工程研究所 | Multi-dimensional LTO/C nano composite material, preparation method and application thereof |
-
2015
- 2015-08-25 CN CN201510527497.7A patent/CN105216389A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1795978A (en) * | 2004-12-29 | 2006-07-05 | 上海杰事杰新材料股份有限公司 | Nano hollow microsphere of composite titania / inorganic carbon, preparation method and application |
| CN102891289A (en) * | 2012-10-23 | 2013-01-23 | 中国科学院过程工程研究所 | Multi-dimensional LTO/C nano composite material, preparation method and application thereof |
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