CN105200844A - Preparing method for antibacterial disinfecting tissue paper - Google Patents
Preparing method for antibacterial disinfecting tissue paper Download PDFInfo
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- CN105200844A CN105200844A CN201510520391.4A CN201510520391A CN105200844A CN 105200844 A CN105200844 A CN 105200844A CN 201510520391 A CN201510520391 A CN 201510520391A CN 105200844 A CN105200844 A CN 105200844A
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- tissue paper
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- sterilizing
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Abstract
The invention discloses a preparing method for antibacterial disinfecting tissue paper. The preparing method for the antibacterial disinfecting tissue paper includes the steps that an organic silicon quaternary phosphonium salt antibacterial disinfecting agent is dissolved in absolute ethyl alcohol to prepare a solution with the concentration of 0.2-2.0wt%; a certain quantity of paper pulp fibers are added and mixed evenly, the solvent is removed through volatilization at the temperature of 80 DEG C, and the fibers are washed with water and filtered to remove the unreacted antibacterial agent. The antibacterial disinfecting tissue paper has efficient and broad-spectrum antibacterial disinfecting effects; the antibacterial agent is fixed with chemical bonds, the problem that the micromolecular antibacterial agent dissolves out can be avoided, environment and human health are effectively protected, and safety, stability and the long-term effect of the antibacterial disinfecting performance of the paper are guaranteed. In addition, the preparing method for the antibacterial disinfecting tissue paper is simple in technological operation and suitable for large-scale production and has low requirements for production equipment and environment conditions.
Description
Technical field
The invention belongs to technical field of living goods, particularly relate to a kind of preparation method of antibiotic and sterilizing tissue paper.
Background technology
Along with the raising of social development and living standards of the people, people more and more pay attention to own health, also improve constantly the requirement of living environment.But, in recent years large-scale outbreak propagate by invasive organism the infectious disease caused, as the acute intestinal disorders etc. that the Middle East respiration syndrome (MERS) of Korea S, the Ebola hemorrhagic fever in Africa, the bird flu in Southeast Asia, the SARS in Asia, the EHEC antibiotic-resistant bacterium of Germany cause, health in serious threat, causes great economic loss.Therefore, the various materials with anti-bacteria and anti-virus function arise at the historic moment, and the closely-related research and development with the daily necessities of anti-bacteria and anti-virus performance of particularly living with people come into one's own day by day.Always and everywhere all can use the life tissue papers such as face tissue, roll web, paper for kitchen as people, become the important route of transmission of pathogenic microorganisms due to the dependence of people's life.Such as, a cold patients seals mouth with face tissue and sneezes or after wiping nasal mucus, face tissue thrown into dustbin conveniently, and the flu germ of now face tissue being infected with and virus will be propagated widely by air.And a little aspect of this to be face tissue can become pathogenic microorganisms route of transmission, all kinds of paper usings in fact in people's life are important routes of transmission of multiple malignant bacteria and virus.Therefore, the development & application tool of anti-bacteria and anti-virus function paper for daily use is of great significance.Current antibacterial tissue paper is mainly undertaken producing by inner or top sizing, surface coating or the method for spraying antiseptic.Antiseptic used is mainly inorganic antibacterial metal ion as silver, copper, zinc etc., and organic antibacterial agent is as organic acid, quaternary ammonium salt, phenolic etc.Inorganic antiseptic has security, heat resistance, but price is higher, and easily makes paper variable color; And organic antibacterial agent sterilizing power is strong, wide material sources, but there is certain volatility and easily separate out.The antibacterial paper that the mode of adding antiseptic by physics is produced, due to the stripping of antiseptic in storage and use procedure, easily causes the decline of its anti-microbial property.And Small molecular antiseptic, easily in human skin's enrichment, has certain excitant and toxicity.In addition, the loss of antiseptic also can cause environmental pollution.
Existing antibacterial tissue paper exist price higher, easily make paper variable color, anti-microbial property not high, there is excitant and toxicity, easily cause environmental pollution.
Summary of the invention
The object of the present invention is to provide a kind of preparation method of antibiotic and sterilizing tissue paper, be intended to solve existing antibacterial tissue paper exist price higher, easily make paper variable color, anti-microbial property not high, there is excitant and toxicity, easily cause the problem of environmental pollution.
The present invention realizes like this, a preparation method for antibiotic and sterilizing tissue paper, the preparation method of described antibiotic and sterilizing tissue paper is hydroxyl generation chemical reaction and functional group is incorporated into paper pulp fiber in the mode of chemical bonding gets on silicone coupling agents by being connected to antibiotic and sterilizing season phosphonium salt and fiber; Specifically comprise and organosilicon season phosphonium salt antibiosis and sterilization agent is dissolved in absolute ethyl alcohol the concentration being mixed with 0.2 ~ 2.0wt%; Then add paper pulp fiber to mix, on antiseptic and fiber, the mol ratio of hydroxyl is 1:1 ~ 5:1, solvent evaporates is removed at 80 DEG C, washes fiber with water and filters to remove unreacted antiseptic.
Further, need to be dried by modified fibre at 100 ~ 120 DEG C copy paper after the unreacted antiseptic of described removing or by modified fibre and paper pulp fiber according to copy paper after the mixed in molar ratio of 1:4.
Further, the preparation method of described antibiotic and sterilizing tissue paper specifically comprises and is dissolved in absolute ethyl alcohol by organosilicon season phosphonium salt antibiosis and sterilization agent, be mixed with the concentration of 0.2 ~ 1.0wt%, then the paper pulp fiber added mixes, the mol ratio of hydroxyl on antiseptic and fiber is made to be 1:1 ~ 5:1, at 80 DEG C, solvent evaporates is removed, wash fiber with water and filter to remove unreacted antiseptic, at last 100 ~ 120 DEG C, modified fibre is dried copy paper, both must have the tissue paper of antibiotic and sterilizing function.
Further, the preparation method of described antibiotic and sterilizing tissue paper specifically comprises and is dissolved in absolute ethyl alcohol by organosilicon season phosphonium salt antibiosis and sterilization agent, be mixed with the concentration of 2.0wt%, then add 20g paper pulp fiber to mix, at 80 DEG C, solvent evaporates is removed, wash fiber with water and filter to remove unreacted antiseptic, at 100 ~ 120 DEG C, drying copy paper after modified fibre and 60g paper pulp fiber being mixed, the tissue paper of antibiotic and sterilizing function must be had.
The preparation method of antibiotic and sterilizing tissue paper provided by the invention, compared with prior art, tool has the following advantages and beneficial effect:
1) the present invention using season phosphonium salt as the antibiotic and sterilizing function body of tissue paper, there is the anti-microbial property higher than isostructural quaternary ammonium salt, and season phosphonium salt to part enveloped virus as common cold virus and the inactivation of virus performance as certain in adenovirus etc. has of nonenveloped virus.Therefore, antibiotic and sterilizing tissue paper provided by the present invention possess efficiently, the antibiotic and sterilizing effect of wide spectrum.
2) antibiotic and sterilizing tissue paper provided by the present invention is the hydroxyl generation chemical reaction on silicone coupling agents by being connected to season phosphonium salt and fiber, and antibiosis and sterilization agent is incorporated in the mode of chemical bonding paper pulp fiber gets on; The stripping problem of Small molecular antiseptic can be avoided with chemical bond set antiseptic, available protecting environmental and human health impacts, ensure that the security of paper antibiotic and sterilizing performance, stability and long-lasting simultaneously.
3) preparation method of the antibiotic and sterilizing tissue paper provided in the present invention, technological operation is simple, to production equipment and requirement for environmental conditions not high, be applicable to large-scale production.
Accompanying drawing explanation
Fig. 1 is preparation method's flow chart of the antibiotic and sterilizing tissue paper that the embodiment of the present invention provides.
Detailed description of the invention
In order to make object of the present invention, technical scheme and advantage clearly understand, below in conjunction with embodiment, the present invention is further elaborated.Should be appreciated that specific embodiment described herein only in order to explain the present invention, be not intended to limit the present invention.
That what the present invention was obtained by chemical bonding antiseptic have is efficient, wide spectrum, stable, safety, long acting antibiotic antiseptic property tissue paper.
Below in conjunction with accompanying drawing, application principle of the present invention is explained in detail.
As shown in Figure 1, the preparation method of the antibiotic and sterilizing tissue paper of the embodiment of the present invention comprises the following steps:
S101: organosilicon season phosphonium salt antibiosis and sterilization agent is dissolved in absolute ethyl alcohol, is mixed with the concentration of 0.2 ~ 2.0wt%;
S102: then add a certain amount of paper pulp fiber and mix, removes solvent evaporates at 80 DEG C, also filters to remove unreacted antiseptic with a large amount of water washing fibers;
At S103:100 ~ 120 DEG C, modified fibre is dried copy paper or modified fibre is mixed rear copy paper according to a certain percentage with paper pulp fiber.
The preparation method of described antibiotic and sterilizing tissue paper is hydroxyl generation chemical reaction and functional group is incorporated into paper pulp fiber in the mode of chemical bonding gets on silicone coupling agents by being connected to antibiotic and sterilizing season phosphonium salt and fiber; Specifically comprise and organosilicon season phosphonium salt antibiosis and sterilization agent is dissolved in absolute ethyl alcohol the concentration being mixed with 0.2 ~ 2.0wt%; Then add paper pulp fiber to mix, on antiseptic and fiber, the mol ratio of hydroxyl is 1:1 ~ 5:1, solvent evaporates is removed at 80 DEG C, washes fiber with water and filters to remove unreacted antiseptic.
Further, need to be dried by modified fibre at 100 ~ 120 DEG C copy paper after the unreacted antiseptic of described removing or by modified fibre and paper pulp fiber according to copy paper after the mixed in molar ratio of 1:4.
Below in conjunction with specific embodiment, application principle of the present invention is further described:
Embodiment 1
Organosilicon season phosphonium salt antibiosis and sterilization agent is dissolved in absolute ethyl alcohol, be mixed with the concentration of 0.2 ~ 1.0wt%, then add a certain amount of paper pulp fiber to mix, the mol ratio of hydroxyl on antiseptic and fiber is made to be 1:1 ~ 5:1, at 80 DEG C, solvent evaporates is removed, also filter to remove unreacted antiseptic with a large amount of water washing fibers, at last 100 ~ 120 DEG C, modified fibre is dried copy paper, both must have the tissue paper of antibiotic and sterilizing function.
Embodiment 2
Organosilicon season phosphonium salt antibiosis and sterilization agent is dissolved in absolute ethyl alcohol, be mixed with the concentration of 2.0wt%, then add 20g paper pulp fiber to mix, at 80 DEG C, solvent evaporates is removed, also filter to remove unreacted antiseptic with a large amount of water washing fibers, at 100 ~ 120 DEG C, dry copy paper after modified fibre and 60g paper pulp fiber being mixed, both must have the tissue paper of antibiotic and sterilizing function.
The foregoing is only preferred embodiment of the present invention, not in order to limit the present invention, all any amendments done within the spirit and principles in the present invention, equivalent replacement and improvement etc., all should be included within protection scope of the present invention.
Claims (4)
1. the preparation method of an antibiotic and sterilizing tissue paper, it is characterized in that, the preparation method of described antibiotic and sterilizing tissue paper is hydroxyl generation chemical reaction and functional group is incorporated into paper pulp fiber in the mode of chemical bonding gets on silicone coupling agents by being connected to antibiotic and sterilizing season phosphonium salt and fiber; Specifically comprise and organosilicon season phosphonium salt antibiosis and sterilization agent is dissolved in absolute ethyl alcohol the concentration being mixed with 0.2 ~ 2.0wt%; Then add paper pulp fiber to mix, on antiseptic and fiber, the mol ratio of hydroxyl is 1:1 ~ 5:1, solvent evaporates is removed at 80 DEG C, washes fiber with water and filters to remove unreacted antiseptic.
2. the preparation method of antibiotic and sterilizing tissue paper as claimed in claim 1, it is characterized in that, need to be dried by modified fibre copy paper after the unreacted antiseptic of described removing at 100 ~ 120 DEG C or by modified fibre and paper pulp fiber according to copy paper after the mixed in molar ratio of 1:4.
3. the preparation method of antibiotic and sterilizing tissue paper as claimed in claim 1, it is characterized in that, the preparation method of described antibiotic and sterilizing tissue paper specifically comprises and is dissolved in absolute ethyl alcohol by organosilicon season phosphonium salt antibiosis and sterilization agent, be mixed with the concentration of 0.2 ~ 1.0wt%, then the paper pulp fiber added mixes, the mol ratio of hydroxyl on antiseptic and fiber is made to be 1:1 ~ 5:1, at 80 DEG C, solvent evaporates is removed, wash fiber with water and filter to remove unreacted antiseptic, at last 100 ~ 120 DEG C, modified fibre is dried copy paper, both the tissue paper of antibiotic and sterilizing function must have been had.
4. the preparation method of antibiotic and sterilizing tissue paper as claimed in claim 1, it is characterized in that, the preparation method of described antibiotic and sterilizing tissue paper specifically comprises and is dissolved in absolute ethyl alcohol by organosilicon season phosphonium salt antibiosis and sterilization agent, be mixed with the concentration of 2.0wt%, then add 20g paper pulp fiber to mix, at 80 DEG C, solvent evaporates is removed, wash fiber with water and filter to remove unreacted antiseptic, at 100 ~ 120 DEG C, dry copy paper after modified fibre and 60g paper pulp fiber being mixed, the tissue paper of antibiotic and sterilizing function must be had.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201510520391.4A CN105200844A (en) | 2015-08-21 | 2015-08-21 | Preparing method for antibacterial disinfecting tissue paper |
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| CN201510520391.4A CN105200844A (en) | 2015-08-21 | 2015-08-21 | Preparing method for antibacterial disinfecting tissue paper |
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| CN105200844A true CN105200844A (en) | 2015-12-30 |
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| CN201510520391.4A Pending CN105200844A (en) | 2015-08-21 | 2015-08-21 | Preparing method for antibacterial disinfecting tissue paper |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110055759A (en) * | 2019-05-24 | 2019-07-26 | 刘群英 | Comfortable protective garment of antibacterial and preparation method thereof |
| CN110506736A (en) * | 2019-09-30 | 2019-11-29 | 定西市农业科学研究院 | A kind of Radix Angelicae Sinensis is guaranteed the quality storage method |
| CN113799514A (en) * | 2021-09-24 | 2021-12-17 | 广州松源实业有限公司 | Environment-friendly paper file box with mould-proof and insect-proof functions |
Citations (5)
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| CN1372039A (en) * | 2001-02-22 | 2002-10-02 | 永丰馀造纸股份有限公司 | Domestic paper with antibiosis and making method thereof |
| JP2006137462A (en) * | 2004-11-12 | 2006-06-01 | Nippon Sanmou Senshoku Kk | Paperboard for storage case having deodorizing and antibacterial function, and manufacturing method for the same |
| US20060283567A1 (en) * | 2003-04-04 | 2006-12-21 | Reiner Buettner | Cellulosed molded article having a functional effect and method for producing the same |
| CN101845771A (en) * | 2010-06-08 | 2010-09-29 | 福建省晋江优兰发纸业有限公司 | Production method of antimicrobial and disinfectant paper towel |
| CN102619121A (en) * | 2012-04-09 | 2012-08-01 | 天津科技大学 | Method for producing antibacterial paper from wood fibers treated by laccase/phenols substances |
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2015
- 2015-08-21 CN CN201510520391.4A patent/CN105200844A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1372039A (en) * | 2001-02-22 | 2002-10-02 | 永丰馀造纸股份有限公司 | Domestic paper with antibiosis and making method thereof |
| US20060283567A1 (en) * | 2003-04-04 | 2006-12-21 | Reiner Buettner | Cellulosed molded article having a functional effect and method for producing the same |
| JP2006137462A (en) * | 2004-11-12 | 2006-06-01 | Nippon Sanmou Senshoku Kk | Paperboard for storage case having deodorizing and antibacterial function, and manufacturing method for the same |
| CN101845771A (en) * | 2010-06-08 | 2010-09-29 | 福建省晋江优兰发纸业有限公司 | Production method of antimicrobial and disinfectant paper towel |
| CN102619121A (en) * | 2012-04-09 | 2012-08-01 | 天津科技大学 | Method for producing antibacterial paper from wood fibers treated by laccase/phenols substances |
Non-Patent Citations (2)
| Title |
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| 王萌等: "新型有机硅季鏻盐抗菌剂的合成及应用研究", 《印染助剂》 * |
| 王鲁燕等: "纳米二氧化钛复合纤维织物的抗光降解及耐久抗菌研究进展", 《材料导报》 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110055759A (en) * | 2019-05-24 | 2019-07-26 | 刘群英 | Comfortable protective garment of antibacterial and preparation method thereof |
| CN110506736A (en) * | 2019-09-30 | 2019-11-29 | 定西市农业科学研究院 | A kind of Radix Angelicae Sinensis is guaranteed the quality storage method |
| CN113799514A (en) * | 2021-09-24 | 2021-12-17 | 广州松源实业有限公司 | Environment-friendly paper file box with mould-proof and insect-proof functions |
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Application publication date: 20151230 |