CN105200435A - Antirust agent and preparation method thereof - Google Patents

Antirust agent and preparation method thereof Download PDF

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Publication number
CN105200435A
CN105200435A CN201510767992.5A CN201510767992A CN105200435A CN 105200435 A CN105200435 A CN 105200435A CN 201510767992 A CN201510767992 A CN 201510767992A CN 105200435 A CN105200435 A CN 105200435A
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antirust
stir
acid
raw material
rust
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CN201510767992.5A
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CN105200435B (en
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施德望
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Nantong Yongyu Antirust Material Co Ltd
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  • Preventing Corrosion Or Incrustation Of Metals (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Cosmetics (AREA)

Abstract

The invention discloses an antirust agent and a preparation method thereof. The antirust agent is mainly prepared from ammonium gluconate, dodecenylsuccinic acid, sodium nitrite, carrageenin, petroleum calcium sulfonate, ammonium molybdate, acetic acid, hydroxypropyl methyl cellulose, urea, glutamic acid, oxidized petrolatum barium soap, poloxamer, terpinyl acetate, nano titanium dioxide, China wood oil and a modified auxiliary agent. The antirust agent disclosed by the invention adopting ammonium gluconate and terpinyl acetate as main components is good in antirust effect, and also has the effects of resisting sun and sterilizing by matching with nano titanium dioxide, and the modified auxiliary agent improves the overall performance of the antirust performance, so that the antirust agent can achieve an antirust effect normally under the influence of moisture and temperature, and is long in antirust time and small in environmental pollution.

Description

A kind of rust-preventive agent and preparation method thereof
Technical field
The present invention relates to chemical technology field, is more particularly a kind of rust-preventive agent and preparation method thereof.
Background technology
Metal processing piece, in the process of process for processing and transport, is easy to get rusty, and this just needs to use slushing oil to form thin film in metallic surface, prevents the chemical of corrosion of metal.So-called rust is that iron rust is red, and patina is green, and the rust of aluminum and zinc claims white rust because oxygen and water act on the mixture that metallic surface generates oxide compound and oxyhydroxide.Machinery is difficult to not contact with the oxygen in air, moisture or other corrosive medium in operation with storage, and generation galvanic corrosion is got rusty in metallic surface by these materials, prevent corrosion from must stop above material and metallic contact.Rust-preventive agent belongs to the one of antirust product, slushing oil, the anti-tarnish paper etc. in addition of other type.
The subject matter that antirust product exists at home is that between preservation period, the effect against corrosion of rust-preventive agent is undesirable in steel product.
Summary of the invention
The object of the invention is, in order to make up the deficiencies in the prior art, to provide a kind of rust-preventive agent and preparation method thereof.
The object of the invention is to be achieved through the following technical solutions:
A kind of rust-preventive agent, is made up of following raw material: ammonium gluconate 1-3, dodecenylsuccinic acid 2-4, Sodium Nitrite 3-5, carrageenin 1-3, calcium mahogany sulfonate 0.5-1, ammonium molybdate 1-2, acetic acid 2-4, Vltra tears 3-5, urea 1-2, L-glutamic acid 1-2, oxidized petrolatum barium soap 2-4, poloxamer 0.5-1, terpinyl acetate 2-4, nano titanium oxide 2-4, tung oil 1-2, modified additive 5-7; Wherein modified additive is made up of following raw material: rosin 1-3, lipid acid potassium 3-5, Oleum Cinnamomi 1-2, polyvinylpyrrolidone 0.5-1, sodium wolframate 3-5, tin protochloride 2-4, polyvinyl alcohol 3-5, benzotriazole 1-2, lanolin 1-3, zinc powder 1-2; Preparation method is: it is in the distilled water of 60-70 DEG C that rosin, lipid acid potassium, Oleum Cinnamomi, polyvinylpyrrolidone, sodium wolframate, tin protochloride, polyvinyl alcohol, benzotriazole, lanolin, zinc powder are all joined temperature, then whipping appts is started, 30 revs/min, stir 20 minutes, form solution and get final product.
A preparation method for rust-preventive agent, is made up of following steps:
(1) each raw material is taken by weight;
(2) stir after terpinyl acetate and tung oil mixing, add ammonium gluconate, dodecenylsuccinic acid, oxidized petrolatum barium soap, poloxamer again, 40-45 DEG C, 500-600r/min stirs 8-15min, finally add Sodium Nitrite, carrageenin, calcium mahogany sulfonate, ammonium molybdate, urea, L-glutamic acid and appropriate water, stir 0.5-1 hour under similarity condition, obtain component A;
(3) by the mixing of the raw material such as Vltra tears, acetic acid, nano titanium oxide, 70-80 DEG C, 900-1000r/min stirs 0.5-1 hour, obtains B component;
(4) by component A and B component mixing, stir 10-20 minute under 500-600r/min, then add modified additive ultrasonic disperse 5-10 minute and get final product.
The invention has the advantages that:
Rust-preventive agent of the present invention adopts ammonium gluconate, terpinyl acetate is main component, favorable rust preventing effect, nano titanium oxide is coordinated to use together, also there is the effect of anti-solarization, sterilization, modified additive then improves the overall performance of rust-preventive agent, under moist and temperature affect, can play rust inhibition normally, antirust time is long and environmental pollution is little.
Embodiment
Embodiment 1, a kind of rust-preventive agent, is made up of following weight (kg) raw material: ammonium gluconate 1, dodecenylsuccinic acid 2, Sodium Nitrite 3, carrageenin 1, calcium mahogany sulfonate 0.5, ammonium molybdate 1, acetic acid 2, Vltra tears 3, urea 1, L-glutamic acid 1, oxidized petrolatum barium soap 2, poloxamer 0.5, terpinyl acetate 2, nano titanium oxide 2, tung oil 1, modified additive 5; Wherein modified additive is made up of following raw material: rosin 1, lipid acid potassium 3, Oleum Cinnamomi 1, polyvinylpyrrolidone 0.5, sodium wolframate 3, tin protochloride 2, polyvinyl alcohol 3, benzotriazole 1, lanolin 1, zinc powder 1; Preparation method is: it is in the distilled water of 60 DEG C that rosin, lipid acid potassium, Oleum Cinnamomi, polyvinylpyrrolidone, sodium wolframate, tin protochloride, polyvinyl alcohol, benzotriazole, lanolin, zinc powder are all joined temperature, then whipping appts is started, 30 revs/min, stir 20 minutes, form solution and get final product.
A preparation method for rust-preventive agent, is made up of following steps:
(1) each raw material is taken by weight;
(2) stir after terpinyl acetate and tung oil mixing, add ammonium gluconate, dodecenylsuccinic acid, oxidized petrolatum barium soap, poloxamer again, 40 DEG C, 500r/min stirs 8min, finally add Sodium Nitrite, carrageenin, calcium mahogany sulfonate, ammonium molybdate, urea, L-glutamic acid and appropriate water, stir 0.5 hour under similarity condition, obtain component A;
(3) by the mixing of the raw material such as Vltra tears, acetic acid, nano titanium oxide, 70 DEG C, 900r/min stirs 0.5 hour, obtains B component;
(4) by component A and B component mixing, stir 10 minutes under 500r/min, then add modified additive ultrasonic disperse 5 minutes and get final product.
Embodiment 2, a kind of rust-preventive agent, is made up of following weight (kg) raw material: ammonium gluconate 2, dodecenylsuccinic acid 3, Sodium Nitrite 4, carrageenin 2, calcium mahogany sulfonate 0.8, ammonium molybdate 1, acetic acid 3, Vltra tears 4, urea 1, L-glutamic acid 2, oxidized petrolatum barium soap 3, poloxamer 0.7, terpinyl acetate 3, nano titanium oxide 3, tung oil 1, modified additive 6; Wherein modified additive is made up of following raw material: rosin 2, lipid acid potassium 4, Oleum Cinnamomi 1, polyvinylpyrrolidone 0.8, sodium wolframate 4, tin protochloride 3, polyvinyl alcohol 4, benzotriazole 1, lanolin 2, zinc powder 2; Preparation method is: it is in the distilled water of 65 DEG C that rosin, lipid acid potassium, Oleum Cinnamomi, polyvinylpyrrolidone, sodium wolframate, tin protochloride, polyvinyl alcohol, benzotriazole, lanolin, zinc powder are all joined temperature, then whipping appts is started, 30 revs/min, stir 20 minutes, form solution and get final product.
A preparation method for rust-preventive agent, is made up of following steps:
(1) each raw material is taken by weight;
(2) stir after terpinyl acetate and tung oil mixing, add ammonium gluconate, dodecenylsuccinic acid, oxidized petrolatum barium soap, poloxamer again, 43 DEG C, 550r/min stirs 12min, finally add Sodium Nitrite, carrageenin, calcium mahogany sulfonate, ammonium molybdate, urea, L-glutamic acid and appropriate water, stir 0.8 hour under similarity condition, obtain component A;
(3) by the mixing of the raw material such as Vltra tears, acetic acid, nano titanium oxide, 75 DEG C, 950r/min stirs 0.8 hour, obtains B component;
(4) by component A and B component mixing, stir 15 minutes under 550r/min, then add modified additive ultrasonic disperse 8 minutes and get final product.
Embodiment 3, a kind of rust-preventive agent, is made up of following weight (kg) raw material: ammonium gluconate 3, dodecenylsuccinic acid 4, Sodium Nitrite 5, carrageenin 3, calcium mahogany sulfonate 1, ammonium molybdate 2, acetic acid 4, Vltra tears 5, urea 2, L-glutamic acid 2, oxidized petrolatum barium soap 4, poloxamer 1, terpinyl acetate 4, nano titanium oxide 4, tung oil 2, modified additive 7; Wherein modified additive is made up of following raw material: rosin 3, lipid acid potassium 5, Oleum Cinnamomi 2, polyvinylpyrrolidone 1, sodium wolframate 5, tin protochloride 4, polyvinyl alcohol 5, benzotriazole 2, lanolin 3, zinc powder 2; Preparation method is: it is in the distilled water of 70 DEG C that rosin, lipid acid potassium, Oleum Cinnamomi, polyvinylpyrrolidone, sodium wolframate, tin protochloride, polyvinyl alcohol, benzotriazole, lanolin, zinc powder are all joined temperature, then whipping appts is started, 30 revs/min, stir 20 minutes, form solution and get final product.
A preparation method for rust-preventive agent, is made up of following steps:
(1) each raw material is taken by weight;
(2) stir after terpinyl acetate and tung oil mixing, add ammonium gluconate, dodecenylsuccinic acid, oxidized petrolatum barium soap, poloxamer again, 45 DEG C, 600r/min stirs 15min, finally add Sodium Nitrite, carrageenin, calcium mahogany sulfonate, ammonium molybdate, urea, L-glutamic acid and appropriate water, stir 1 hour under similarity condition, obtain component A;
(3) by the mixing of the raw material such as Vltra tears, acetic acid, nano titanium oxide, 80 DEG C, 1000r/min stirs 1 hour, obtains B component;
(4) by component A and B component mixing, stir 20 minutes under 600r/min, then add modified additive ultrasonic disperse 10 minutes and get final product.
The salient features detected result of the rust-preventive agent that above-described embodiment 1-3 obtains is as shown in the table:
The salient features detected result of the rust-preventive agent that table 1 embodiment 1-3 obtains
Viscosity Set time (min) Water tolerance Antirust time (moon)
Embodiment 1 760 22 Excellent 22
Embodiment 2 740 24 Excellent 20
Embodiment 3 760 23 Excellent 18

Claims (2)

1. a rust-preventive agent, is characterized in that: be made up of following raw material: ammonium gluconate 1-3, dodecenylsuccinic acid 2-4, Sodium Nitrite 3-5, carrageenin 1-3, calcium mahogany sulfonate 0.5-1, ammonium molybdate 1-2, acetic acid 2-4, Vltra tears 3-5, urea 1-2, L-glutamic acid 1-2, oxidized petrolatum barium soap 2-4, poloxamer 0.5-1, terpinyl acetate 2-4, nano titanium oxide 2-4, tung oil 1-2, modified additive 5-7; Wherein modified additive is made up of following raw material: rosin 1-3, lipid acid potassium 3-5, Oleum Cinnamomi 1-2, polyvinylpyrrolidone 0.5-1, sodium wolframate 3-5, tin protochloride 2-4, polyvinyl alcohol 3-5, benzotriazole 1-2, lanolin 1-3, zinc powder 1-2; Preparation method is: it is in the distilled water of 60-70 DEG C that rosin, lipid acid potassium, Oleum Cinnamomi, polyvinylpyrrolidone, sodium wolframate, tin protochloride, polyvinyl alcohol, benzotriazole, lanolin, zinc powder are all joined temperature, then whipping appts is started, 30 revs/min, stir 20 minutes, form solution and get final product.
2. the preparation method of a kind of rust-preventive agent according to claim 1, is characterized in that: be made up of following steps:
(1) each raw material is taken by weight;
(2) stir after terpinyl acetate and tung oil mixing, add ammonium gluconate, dodecenylsuccinic acid, oxidized petrolatum barium soap, poloxamer again, 40-45 DEG C, 500-600r/min stirs 8-15min, finally add Sodium Nitrite, carrageenin, calcium mahogany sulfonate, ammonium molybdate, urea, L-glutamic acid and appropriate water, stir 0.5-1 hour under similarity condition, obtain component A;
(3) by the mixing of the raw material such as Vltra tears, acetic acid, nano titanium oxide, 70-80 DEG C, 900-1000r/min stirs 0.5-1 hour, obtains B component;
(4) by component A and B component mixing, stir 10-20 minute under 500-600r/min, then add modified additive ultrasonic disperse 5-10 minute and get final product.
CN201510767992.5A 2015-11-12 2015-11-12 A kind of antirust agent and preparation method thereof Active CN105200435B (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106634126A (en) * 2016-12-16 2017-05-10 常州市鼎日环保科技有限公司 Preparation method for environment-friendly water-based antirust agent
CN106978016A (en) * 2017-04-06 2017-07-25 天长市润达金属防锈助剂有限公司 A kind of metal antirusting agent with excellent damping performance
CN108047879A (en) * 2017-12-06 2018-05-18 季雅佩 A kind of antirust waterborne epoxy coatings and preparation method thereof
CN108149256A (en) * 2017-12-27 2018-06-12 洛阳神佳窑业有限公司 A kind of corrosion inhibiter with protective film
CN115291483A (en) * 2022-09-02 2022-11-04 昆山晶科微电子材料有限公司 Semiconductor stripping liquid and preparation method thereof

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106634126A (en) * 2016-12-16 2017-05-10 常州市鼎日环保科技有限公司 Preparation method for environment-friendly water-based antirust agent
CN106978016A (en) * 2017-04-06 2017-07-25 天长市润达金属防锈助剂有限公司 A kind of metal antirusting agent with excellent damping performance
CN108047879A (en) * 2017-12-06 2018-05-18 季雅佩 A kind of antirust waterborne epoxy coatings and preparation method thereof
CN108149256A (en) * 2017-12-27 2018-06-12 洛阳神佳窑业有限公司 A kind of corrosion inhibiter with protective film
CN115291483A (en) * 2022-09-02 2022-11-04 昆山晶科微电子材料有限公司 Semiconductor stripping liquid and preparation method thereof
CN115291483B (en) * 2022-09-02 2023-08-29 昆山晶科微电子材料有限公司 Semiconductor stripping liquid and preparation method thereof

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Effective date of registration: 20200103

Address after: 226600 Haian Town Industrial Park, Nantong City, Jiangsu Province (Group 15, Pingqiao Village)

Patentee after: Nantong Yongyu Antirust Material Co., Ltd.

Address before: 302, room 1, unit 1, Lane 330, Ankang Road, Anyang street, Ruian, Zhejiang, Wenzhou, 325000

Patentee before: Shi Dewang

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