CN105199627A - Environmental-friendly plant glue and preparation method thereof - Google Patents
Environmental-friendly plant glue and preparation method thereof Download PDFInfo
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- CN105199627A CN105199627A CN201510739974.6A CN201510739974A CN105199627A CN 105199627 A CN105199627 A CN 105199627A CN 201510739974 A CN201510739974 A CN 201510739974A CN 105199627 A CN105199627 A CN 105199627A
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Abstract
The invention provides environmental-friendly plant glue. The environmental-friendly plant glue comprises components as follows: chayote juice fermentation broth, starch pasting content, 8-10 parts by weight of seaweed meal and 80-100 parts by weight of water, wherein the chayote juice fermentation broth is prepared through fermentation of 350-450 parts by weight of chayote juice or diluted chayote juice containing 350-450 parts by weight of chayote juice and smaller than 500 parts by weight of water, and the chayote juice is prepared from chayote through grinding and filtering; the starch pasting content is prepared from 8-12 parts by weight of starch through pasting. The prepared environmental-friendly plant glue has the advantages of environment protection, non-toxicity and high bonding force, and can be used as wallpaper glue and putty glue.
Description
Technical field
The present invention relates to sizing agent field, be specifically related to a kind of environment protecting plant glue, can be used as wallpaper or wallpaper glue and putty glue.
Background technology
Current wallpaper environmental protection binding agent is mostly liquid starch glue or glutinous rice glue or powder, but traditional glutinous rice glue exists following defect: 1, be generally translucent shape colloid, and adhesive property is poor, and outward appearance is also poor; 2, solubization is poor, usually needs point to be watered for three or four times, easily lumps, and is unfavorable for construction; 3, due to the molecular structure of most of starch, make it not possess freezing tolerance, cannot store at low ambient temperatures; 4, additive is too much, is unfavorable for environmental protection.
And the sizing agent environmental-protecting performance that can be used for putty glue is at present poor, therefore need a kind ofly can be applied to wallpaper or wallpaper glue and putty glue and the strong glue of the feature of environmental protection.
Summary of the invention
For this reason, the invention provides a kind of environment protecting plant glue, there is environmental protection, the advantage that nontoxic and bounding force is strong, can be used as wallpaper or wallpaper glue and putty glue.
In one aspect, the invention provides a kind of environment protecting plant glue, its composition comprises: the seaweed powder of fruit of Christophine juice fermented liquid, starch paste compound, 8-10 weight part and the water of 80-100 weight part, wherein, described fruit of Christophine juice fermented liquid is the fruit of Christophine juice of 350-450 weight part or contains 350-450 weight part fruit of Christophine juice and the dilution fruit of Christophine juice fermentation gained being less than 500 weight parts waters, and described fruit of Christophine juice is filtration gained juice after fruit of Christophine is pulverized; Described starch paste compound is starch gained after gelatinization of 8-12 weight part.
Optionally, described fruit of Christophine juice fermented liquid be to 300-500 weight part fruit of Christophine juice or to containing 350-450 weight part fruit of Christophine juice and be less than 500 weight parts waters dilution fruit of Christophine juice in add the distiller's yeast of 0.4-0.5 weight part, at fermentation initial temperature is 10-30 DEG C, ferments and obtain for 10-30 days.
Optionally, described fruit of Christophine juice fermentation also comprises the volume fraction adding 0.1-0.15 weight part to it before starting is the medical alcohol of 70%.
Optionally, described starch is one or more in the edible starch such as sweet potato powder, Cornstarch, Tapioca Starch, kudzuvine root starch, W-Gum.
Optionally, wherein said starch paste compound be by add in described starch containing 0.8-1.2 weight part alkali alkali aqueous solution or heat described starch starch pasting obtained.
Optionally, wherein said alkali is one or more in sodium hydroxide, potassium hydroxide and sodium carbonate.
Optionally, its composition also comprises the essence of 0.8-1.2 weight part.
Optionally, wherein said essence is spearmint oil.
Optionally, its composition also comprises the polyvinyl alcohol of 35-45 weight part.
On the other hand, the invention provides a kind of preparation method of environment protecting plant glue, comprising:
1) fruit of Christophine juice fermented liquid is prepared: pulverized by fruit of Christophine, filter to obtain 350-450 weight part fruit of Christophine juice or containing 350-450 fruit of Christophine juice be less than the dilution fruit of Christophine juice of 500 weight parts waters, in described fruit of Christophine juice or dilution fruit of Christophine juice, add distiller's yeast to ferment to obtain fruit of Christophine juice fermented liquid;
2) starch paste compound is prepared: the gelatinization of 8-12 weight starch is obtained starch paste compound;
3) the seaweed powder aqueous solution is prepared: be dissolved in by the seaweed powder of 8-10 weight part in the water of 80-100 weight part and obtain the seaweed powder aqueous solution;
4) mix: obtain environment protecting plant glue by even to described fruit of Christophine juice fermented liquid, described starch paste compound and described seaweed powder aqueous solution.
Beneficial effect of the present invention is: obtained environment protecting plant glue, raw material mainly adopts the fermented liquid of the fruit juice of natural phant fruit of Christophine, coordinate the starch paste compound of enhancing adhesive strength and water-holding agent seaweed powder and obtain, there is bond strength greatly, nontoxic, environmental protection, the feature that formaldehyde content is low.
Accompanying drawing explanation
By reading hereafter detailed description of the preferred embodiment, various other advantage and benefit will become cheer and bright for those of ordinary skill in the art.Accompanying drawing only for illustrating the object of preferred implementation, and does not think limitation of the present invention.In the accompanying drawings:
Figure 1 shows that the preparation flow of environment protecting plant glue of the present invention.
Embodiment
The invention provides many applicable creative concepts, this creative concept can be reflected in a large number of in concrete context.The specific embodiment described in following embodiments of the present invention only as the exemplary illustration of specific implementation of the present invention, and does not form limitation of the scope of the invention.
The embodiment of the present invention provides a kind of plant glue, its composition comprises: the seaweed powder of fruit of Christophine juice fermented liquid, starch paste compound, 8-10 weight part and the water of 80-100 weight part, wherein, described fruit of Christophine juice fermented liquid is the fruit of Christophine juice of 350-450 weight part or contains 350-450 weight part fruit of Christophine juice and the dilution fruit of Christophine juice fermentation gained being less than 500 weight parts waters, and described fruit of Christophine juice is filtration gained juice after fruit of Christophine is pulverized; Described starch paste compound is starch gained after gelatinization of 8-12 weight part.
Fruit of Christophine (formal name used at school: Sechiumedule), having another name called falcon people melon, Annan's melon, longevity melon, good harvest melon, foreign melon etc., is a kind of Curcurbitaceae fruit of Christophine platymiscium.The juice of fruit of Christophine described in the embodiment of the present invention is that the fruit of fruit of Christophine plant is called for short the juice filtering gained after fruit of Christophine is pulverized, described fruit of Christophine juice can choose the juice filtering gained after ripe or immature fruit of Christophine is pulverized, preferred maturity fruit of Christophine is pulverized and is filtered the juice obtained afterwards, in order to not make the effective constituent in fruit of Christophine run off when filtering, fruit of Christophine solidliquid mixture after pulverizing can be carried out adding water filtration, the fruit of Christophine juice of 350-450 weight part preferably adds the amount of water for being less than 500 weight parts, most preferably be 250-350 weight parts water, fruit of Christophine juice must be diluted after filtration, certainly, also can directly filter fruit of Christophine solidliquid mixture and not add water, what obtain like this is exactly fruit of Christophine juice, in fruit of Christophine juice, add water must dilute fruit of Christophine juice.
Described fruit of Christophine juice fermented liquid can be in the fruit of Christophine juice of 350-450 weight part or to containing 350-450 weight part fruit of Christophine juice and be less than 500 weight parts waters dilution fruit of Christophine juice in add 0.4-0.5 weight part distiller's yeast fermentation obtain, the fermentation initial temperature of described fermentation is 10-30 DEG C, fermentation number of days is 10-30 days, and fruit of Christophine juice can be made fully to ferment.The fruit of Christophine juice distiller's yeast used that ferments is common all distiller's yeasts that can be used for fermenting, the initial temperature of its fermentation is lower, fermentation number of days is more mainly with guarantee fully fermentation, when initial temperature of such as fermenting is 10 DEG C, fermentation number of days can be 30 days, when fermentation initial temperature is 20 DEG C, fermentation number of days can be 20 days, and when fermentation initial temperature is 30 DEG C, fermentation number of days can be 15 days.In order to accelerate fermentation to reduce fermentation number of days, the volume fraction that can add 0.1-0.15 weight part before fermentation is the medical alcohol of 70%, and after adding alcohol, when initial temperature of fermenting is 10 DEG C, fermentation number of days can foreshorten to 10-15 days.
The composition of the plant glue of the embodiment of the present invention is mainly fruit of Christophine juice fermented liquid, in order to strengthen the bond strength of plant glue, described fruit of Christophine juice fermented liquid is mixed with starch paste compound, wherein said starch paste compound is sweet potato powder, Cornstarch, Tapioca Starch, the gelatinization thing of the edible such as kudzuvine root starch or W-Gum starch after gelatinization, starch pasting is known technology, those skilled in the art are easy to obtain multiple method and make starch pasting, such as: high temperature, add alkali, the combination of enzyme hydrolysis method or these methods, these methods all can use, but consider cost, preferably in the starch of 8-12 weight part, adding the alkali aqueous solution containing 0.8-1.2 weight part alkali in the embodiment of the present invention or heating described starch makes starch pasting obtain.When selecting the described starch of heating to make its gelatinization, should note choosing suitable container and regulate the temperature of heating too not high in case starch is stained with on wall of container, choose the method adding alkali when making starch pasting, the alkali added can be sodium hydroxide, one or more in potassium hydroxide and sodium carbonate, its concentration of aqueous solution can be multiple, the amount adding water is without the need to too much, as long as can alkali dissolution be made and make it add in starch make starch pasting, water then can affect the bond strength of product glue too much, the alkali of 0.8-1.2 weight part preferably adds in the water of 4-6 weight part and dissolves, alkali as 0.8 weight part adds the water of 4 weight parts, the alkali of water or 1.2 weight parts that the alkali of 1.0 weight parts adds 5 weight parts adds in the water of 6 weight parts.
Seaweed powder described in the embodiment of the present invention is used as water-holding agent in this composition, use seaweed powder and do not use other water-holding agent to be in order to environmental protection and safety, when preparing described plant glue, first the seaweed powder of 8-10 weight part is dissolved in the water of 80-100 weight part and forms solution, to mix with other compositions.
Water described in the embodiment of the present invention can be tap water, drinkable water etc., considers cost, is preferably tap water.
Plant glue described in the embodiment of the present invention, its composition can also comprise the essence of 0.8-1.2 weight part, object is the smell in order to regulate product, described essence can be the essence that this area is commonly used, preferred natural essence is as lemon oil, tangerine oil, peppermint wet goods, most preferably spearmint oil, the volatility of essence is conducive to volatile organic removing being harmful to or having other bad smells.
Plant glue described in the embodiment of the present invention, its composition can also comprise the polyvinyl alcohol of 30-50 weight part, to increase the binding property of product further and to improve water tolerance and the freeze-thaw resistance of glue, meets the purposes demand that binding property is strong.
The embodiment of the present invention also provides a kind of preparation method of plant glue, comprising:
1) fruit of Christophine juice fermented liquid is prepared: pulverized by fruit of Christophine, filter 350-450 weight part fruit of Christophine juice or containing 350-450 fruit of Christophine juice be less than the dilution fruit of Christophine juice of 500 weight parts waters, in described fruit of Christophine juice or dilution fruit of Christophine juice, add distiller's yeast to ferment to obtain fruit of Christophine juice fermented liquid;
2) starch paste compound is prepared: the gelatinization of 8-12 weight starch is obtained starch paste compound;
3) the seaweed powder aqueous solution is prepared: be dissolved in by the seaweed powder of 8-10 weight part in the water of 80-100 weight part and obtain the seaweed powder aqueous solution;
4) mix: obtain environment protecting plant glue by even to described fruit of Christophine juice fermented liquid, described starch paste compound and described seaweed powder aqueous solution.
In the preparation method of the embodiment of the present invention, described mixing can adopt conventional blending means, such as be uniformly mixed or rotate mixing, high speed rotating is selected to mix in the present embodiment, in described mixing step, preferably first described fruit of Christophine juice fermented liquid and described starch paste compound are mixed, again the seaweed powder aqueous solution is added and continue to mix, when the composition of plant glue comprises essence and polyvinyl alcohol, add after essence continues to mix while adding described starch paste compound, finally add polyvinyl alcohol and proceed mixing until mix.This is because essence volatile thus need add in the later stage fragrance keeping essence, and polyvinyl alcohol due to its bond strength as sizing agent larger, not easily with between other moietys mix, therefore need add after other compositions mix all and continue mixing, the vegetable jelly fishery products composition obtained like this is evenly.
The bond strength of the plant glue obtained by the present invention is large, and to porous material as timber, paper, cotton, leather, pottery etc. have very strong cohesive force, and initial viscosity is higher; Use temperature can not lower than 0 degree, seals the good plant glue quality guaranteed period can reach 18 months.
Below enumerate several specific embodiment to describe in detail:
Embodiment 1
A kind of environment protecting plant glue, its composition comprises: 350 weight part fruit of Christophine juice are through fermentation gained fruit of Christophine juice fermented liquid, 8-12 the parts by weight Corn starch seaweed powder of gained corn starch paste compound, 8-10 weight part and tap water of 80-100 weight part after gelatinization process.
Its preparation method comprises: 1) smashed by the fruit of Christophine of 1000 weight parts and filter to obtain the fruit of Christophine juice of 350 weight parts, the distiller's yeast adding 0.4 weight part to described fruit of Christophine juice temperature be 10 DEG C of bottom fermentations 30 days fruit of Christophine juice fermented liquid; 2) W-Gum heating 8 weight parts makes its gelatinization obtain corn starch paste compound; 3) seaweed powder of 8 weight parts is dissolved in the tap water of 80 weight parts, obtains the seaweed powder aqueous solution; 4) described fruit of Christophine juice fermented liquid and described corn starch pasting thing high speed rotating are mixed; Add the described seaweed powder aqueous solution more wherein and continue high speed rotating to mix to obtain vegetable jelly fishery products.
Embodiment 2
A kind of environment protecting plant glue, its composition comprises: containing the dilution fruit of Christophine juice of 400 weight part fruit of Christophine juice and 300 weight part tap water through the spearmint oil of the sweet potato starch of the gained fruit of Christophine juice fermented liquid that ferments, 10 weight parts gained sweet potato starch gelatinization thing, the seaweed powder of 9 weight parts, the tap water of 90 weight parts and 1 weight part after gelatinization process.
Its preparation method comprises: 1) smashed by the fruit of Christophine of 1000 weight parts, add the fruit of Christophine juice that water filtration obtains 400 weight parts, add 300 weight parts waters and must dilute fruit of Christophine juice, the distiller's yeast adding 0.45 weight part to described dilution fruit of Christophine juice is that 20 DEG C of bottom fermentations obtain fruit of Christophine juice fermented liquid in 20 days in temperature; 2) in the sweet potato starch of 10 weight parts, add the alkali aqueous solution containing 1 weight part caustic soda and 5 weight parts waters, make sweet potato starch gelatinization obtain sweet potato starch gelatinization thing; 3) seaweed powder of 9 weight parts is dissolved in the tap water of 90 weight parts, obtains the seaweed powder aqueous solution; 4) described fruit of Christophine juice fermented liquid and described sweet potato starch gelatinization thing high speed rotating are mixed; The spearmint oil adding the described seaweed powder aqueous solution and 1 weight part more wherein continues high speed rotating to mix to obtain vegetable jelly fishery products.
Embodiment 3
A kind of environment protecting plant glue, the difference of itself and embodiment 2 is: the composition of this plant glue also comprises the polyvinyl alcohol of 40 weight parts, therefore, step 4 in its preparation method) in, continue high speed rotating with after mixing at the spearmint oil adding the described seaweed powder aqueous solution and 1 weight part, then add the polyvinyl alcohol of 40 weight parts and mix to obtain product.
Embodiment 4
A kind of environment protecting plant glue, its composition comprises: containing the dilution fruit of Christophine juice of 450 weight part fruit of Christophine juice and 400 weight part tap water through the polyvinyl alcohol of the seaweed powder of W-Gum gained corn starch paste compound, 10 weight parts after gelatinization process of the gained fruit of Christophine juice fermented liquid that ferments, 12 weight parts, the tap water of 100 weight parts, the spearmint oil of 1.2 weight parts and 30 weight parts.Its preparation process is in the same manner as in Example 3.
Embodiment 5
A kind of environment protecting plant glue, its composition comprises: containing the dilution fruit of Christophine juice of 450 weight part fruit of Christophine juice and 500 weight parts waters through the polyvinyl alcohol of the seaweed powder of W-Gum gained corn starch paste compound, 10 weight parts after gelatinization process of the gained fruit of Christophine juice fermented liquid that ferments, 12 weight parts, the water of 100 weight parts, the spearmint oil of 0.8 weight part and 50 weight parts.Its preparation process is in the same manner as in Example 3.
Embodiment 6
A kind of environment protecting plant glue, its composition comprises: the polyvinyl alcohol of ferment through distiller's yeast containing the dilution fruit of Christophine juice of 350 weight part fruit of Christophine juice and 200 weight parts waters gained fruit of Christophine juice fermented liquid, the seaweed powder of W-Gum gained corn starch paste compound, 8.5 weight parts after gelatinization process of 9 weight parts, the water of 85 weight parts, the spearmint oil of 1.2 weight parts and 35 weight parts.The difference of its preparation process and embodiment 3 is: the volume fraction of distiller's yeast and 0.1-0.15 weight part that described dilution fruit of Christophine juice adds 0.4 weight part is the medical alcohol of 70%, within 10 days, obtains fruit of Christophine juice fermented liquid at 20 DEG C of fermentation initial temperature bottom fermentations.
Above embodiment gained environment protecting plant glue product composition is uniform and stable, and bond strength is large, can be used as wallpaper or wallpaper glue and putty glue, environment-protecting asepsis simultaneously.
In order to test the content of formaldehyde in embodiment of the present invention gained vegetable jelly fishery products, embodiment 1-6 products obtained therefrom is sent to building material product quality supervision and test institute of Guizhou Province to test, test basis GB18583-2008 " in indoor decorating and refurnishing materials sizing agent limits of harmful substances ", assay shows below:
| Sample number | Sample size | Interventions Requested | I measures unit | Technical requirements | Assay | Individual event conclusion |
| Embodiment 1 | 500ML | Free formaldehyde | g/kg | ≤0.50 | 0.10 | Meet the requirements |
| Embodiment 2 | 500ML | Free formaldehyde | g/kg | ≤0.50 | 0.11 | Meet the requirements |
| Embodiment 3 | 500ML | Free formaldehyde | g/kg | ≤0.50 | 0.11 | Meet the requirements |
| Embodiment 4 | 500ML | Free formaldehyde | g/kg | ≤0.50 | 0.11 | Meet the requirements |
| Embodiment 5 | 500ML | Free formaldehyde | g/kg | ≤0.50 | 0.12 | Meet the requirements |
| Embodiment 6 | 500ML | Free formaldehyde | g/kg | ≤0.50 | 0.10 | Meet the requirements |
As can be seen from the above results, embodiment 1-6 products obtained therefrom all meets the requirements, and the normal content comparing technical requirements is low many.
Although describe the present invention with reference to some embodiments, should be appreciated that, the present invention is not limited to disclosed embodiment.The present invention is intended to contain the interior included various amendment of spirit and scope and the equivalent arrangements of claims.The scope of claims meets the most wide in range explanation, thus comprises all such amendments and equivalent structure and function.
Claims (10)
1. an environment protecting plant glue, its composition comprises: the seaweed powder of fruit of Christophine juice fermented liquid, starch paste compound, 8-10 weight part and the water of 80-100 weight part, wherein, described fruit of Christophine juice fermented liquid is the fruit of Christophine juice of 350-450 weight part or contains 350-450 weight part fruit of Christophine juice and the dilution fruit of Christophine juice fermentation gained being less than 500 weight parts waters, and described fruit of Christophine juice is filtration gained juice after fruit of Christophine is pulverized; Described starch paste compound is starch gained after gelatinization of 8-12 weight part.
2. environment protecting plant glue according to claim 1, wherein, described fruit of Christophine juice fermented liquid be to 300-500 weight part fruit of Christophine juice or to containing 350-450 weight part fruit of Christophine juice and be less than 500 weight parts waters dilution fruit of Christophine juice in add the distiller's yeast of 0.4-0.5 weight part, at fermentation initial temperature is 10-30 DEG C, ferments and obtain for 10-30 days.
3. environment protecting plant glue according to claim 2, also comprising the volume fraction adding 0.1-0.15 weight part to it before wherein said fruit of Christophine juice fermentation starts is the medical alcohol of 70%.
4. environment protecting plant glue according to claim 1, wherein said starch is one or more in the edible starch such as sweet potato powder, Cornstarch, Tapioca Starch, kudzuvine root starch, W-Gum.
5. environment protecting plant glue according to claim 1, wherein said starch paste compound be by add in described starch containing 0.8-1.2 weight part alkali alkali aqueous solution or heat described starch starch pasting obtained.
6. environment protecting plant glue according to claim 4, wherein said alkali is one or more in sodium hydroxide, potassium hydroxide and sodium carbonate.
7. environment protecting plant glue according to claim 1, its composition also comprises the essence of 0.8-1.2 weight part.
8., according to the environment protecting plant glue described in claim 6, wherein said essence is spearmint oil.
9. environment protecting plant glue according to claim 1, its composition also comprises the polyvinyl alcohol of 35-45 weight part.
10. a preparation method for environment protecting plant glue, comprising:
1) fruit of Christophine juice fermented liquid is prepared: pulverized by fruit of Christophine, filter 350-450 weight part fruit of Christophine juice or containing 350-450 fruit of Christophine juice be less than the dilution fruit of Christophine juice of 500 weight parts waters, in described fruit of Christophine juice or dilution fruit of Christophine juice, add distiller's yeast to ferment to obtain fruit of Christophine juice fermented liquid;
2) starch paste compound is prepared: the gelatinization of 8-12 weight starch is obtained starch paste compound;
3) the seaweed powder aqueous solution is prepared: be dissolved in by the seaweed powder of 8-10 weight part in the water of 80-100 weight part and obtain the seaweed powder aqueous solution;
4) mix: obtain environment protecting plant glue by even to described fruit of Christophine juice fermented liquid, described starch paste compound and described seaweed powder aqueous solution.
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| CN106281051A (en) * | 2016-08-31 | 2017-01-04 | 桐乡嘉力丰实业股份有限公司 | Mildew-resistant flavouring wallpaper glue stick and preparation method thereof |
| CN107674266A (en) * | 2017-11-01 | 2018-02-09 | 安徽宝岛新能源发展有限公司 | A kind of anti-aging adhesive tape for wiper blade of electric automobile |
| CN109135436A (en) * | 2018-08-07 | 2019-01-04 | 东莞理工学院 | A kind of epipremnum aureum plant organic coating and preparation method thereof |
| CN110343471A (en) * | 2019-07-12 | 2019-10-18 | 杭州厚瑞科技有限公司 | A kind of medical instrument production line profession glue and preparation method thereof |
| CN110746886A (en) * | 2019-10-15 | 2020-02-04 | 程福清 | Ecological environment-friendly coating adopting rose juice and preparation method thereof |
| CN110760290A (en) * | 2019-11-15 | 2020-02-07 | 占剑华 | Environment-friendly adhesive for five-cereal grain picture and preparation method thereof |
| CN110903781A (en) * | 2019-11-27 | 2020-03-24 | 南京格润包装材料有限公司 | Environment-friendly glue and production process thereof |
| CN111718679A (en) * | 2020-07-03 | 2020-09-29 | 江西多冠建筑装饰工程有限公司 | Adhesive glue for formaldehyde-free flame-retardant sheet material and preparation method thereof |
| CN115287025A (en) * | 2022-09-05 | 2022-11-04 | 北京别丽美特装饰材料有限公司 | Glue for wallpaper and preparation method thereof |
| CN115418172A (en) * | 2022-10-17 | 2022-12-02 | 北京别丽美特装饰材料有限公司 | Environment-friendly glue and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106281051A (en) * | 2016-08-31 | 2017-01-04 | 桐乡嘉力丰实业股份有限公司 | Mildew-resistant flavouring wallpaper glue stick and preparation method thereof |
| CN107674266A (en) * | 2017-11-01 | 2018-02-09 | 安徽宝岛新能源发展有限公司 | A kind of anti-aging adhesive tape for wiper blade of electric automobile |
| CN109135436A (en) * | 2018-08-07 | 2019-01-04 | 东莞理工学院 | A kind of epipremnum aureum plant organic coating and preparation method thereof |
| CN110343471A (en) * | 2019-07-12 | 2019-10-18 | 杭州厚瑞科技有限公司 | A kind of medical instrument production line profession glue and preparation method thereof |
| CN110746886A (en) * | 2019-10-15 | 2020-02-04 | 程福清 | Ecological environment-friendly coating adopting rose juice and preparation method thereof |
| CN110760290A (en) * | 2019-11-15 | 2020-02-07 | 占剑华 | Environment-friendly adhesive for five-cereal grain picture and preparation method thereof |
| CN110903781A (en) * | 2019-11-27 | 2020-03-24 | 南京格润包装材料有限公司 | Environment-friendly glue and production process thereof |
| CN111718679A (en) * | 2020-07-03 | 2020-09-29 | 江西多冠建筑装饰工程有限公司 | Adhesive glue for formaldehyde-free flame-retardant sheet material and preparation method thereof |
| CN115287025A (en) * | 2022-09-05 | 2022-11-04 | 北京别丽美特装饰材料有限公司 | Glue for wallpaper and preparation method thereof |
| CN115418172A (en) * | 2022-10-17 | 2022-12-02 | 北京别丽美特装饰材料有限公司 | Environment-friendly glue and preparation method thereof |
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| CN105199627B (en) | 2018-08-28 |
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