CN105199614A - Green environment-friendly adhesive sticker for printing and preparation method thereof - Google Patents
Green environment-friendly adhesive sticker for printing and preparation method thereof Download PDFInfo
- Publication number
- CN105199614A CN105199614A CN201510652235.3A CN201510652235A CN105199614A CN 105199614 A CN105199614 A CN 105199614A CN 201510652235 A CN201510652235 A CN 201510652235A CN 105199614 A CN105199614 A CN 105199614A
- Authority
- CN
- China
- Prior art keywords
- parts
- environmental protection
- ethyl acetate
- setting adhesive
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a green environment-friendly adhesive sticker for printing and a preparation method thereof. The green environment-friendly adhesive sticker for printing is composed of the following components in parts by weight: 100 parts of polystyrene, 30-50 parts of acrylic resin, 5-8 parts of polyacrylamide, 2-4 parts of ethyl acetate, 3-6 parts of vinyl acetate, 2-6 parts of dimethylbenzene, 1-3 parts of benzoperoxide, 4-8 parts of ethyl acetate, 10-20 parts of glycerol, 15-25 parts of acetamide, 0.5-1.5 parts of polyoxyethylene fatty acid and 0.1-0.4 part of sorbic acid. The adhesive sticker is prepared from low-toxicity raw materials, is green and environment-friendly, and has the advantages of wide raw material sources, aging resistance, corrosion resistance and favorable antimicrobial effect. The preparation method is simple, and has wide application range.
Description
Technical field
The invention belongs to printing material technical field, relate to a kind of non-setting adhesive, specifically a kind of environmental protection printing non-setting adhesive and preparation method thereof.
Background technology
Non-setting adhesive is also self-adhesive label material, is that the back side scribbles tackiness agent with paper, film or special material for fabric, to be coated with a kind of matrix material that silicon protection sheet is base stock.Because coating technique has multiple, adhesive material is caused to be formed with different class, current developing direction is to high pressure cast coat future development by traditional print roll coating, scraper for coating, to ensure the even perception be coated with to greatest extent, avoid the generation of bubble and pinprick, ensure coating quality, and curtain coating cloth is coated on domestic technique also prematurity, domestic main employing be conventional roller-type coating.
Summary of the invention
The object of the present invention is to provide a kind of environmental protection printing non-setting adhesive and preparation method thereof.
Object of the present invention can be achieved through the following technical solutions:
A kind of environmental protection printing non-setting adhesive, by weight, composed of the following components: polystyrene 100 parts, acrylic resin 30-50 part, polyacrylamide 5-8 part, ethyl acetate 2-4 part, vinyl acetate 3-6 part, dimethylbenzene 2-6 part, benzoyl peroxide 1-3 part, vinyl acetic monomer 4-8 part, glycerol 10-20 part, ethanamide 15-25 part, polyoxyethylene fatty acid 0.5-1.5 part, Sorbic Acid 0.1-0.4 part.
As preferred further, a kind of environmental protection printing non-setting adhesive, by weight, composed of the following components: polystyrene 100 parts, acrylic resin 40 parts, polyacrylamide 6.5 parts, ethyl acetate 3 parts, vinyl acetate 4.5 parts, dimethylbenzene 4 parts, benzoyl peroxide 2 parts, vinyl acetic monomer 6 parts, glycerol 15 parts, ethanamide 20 parts, polyoxyethylene fatty acid 1 part, Sorbic Acid 0.25 part.
The present invention also provides a kind of a kind of method preparing environmental protection printing non-setting adhesive, comprise the following steps: successively polystyrene, acrylic resin, polyacrylamide, ethyl acetate, vinyl acetate, dimethylbenzene, benzoyl peroxide, vinyl acetic monomer, glycerol, ethanamide are added in reactor, raised temperature to 78 DEG C, stir 5h, then 25 DEG C are cooled to, add polyoxyethylene fatty acid, Sorbic Acid again, stir 20min, obtain environmental protection non-setting adhesive.
Beneficial effect of the present invention: the starting material that non-setting adhesive of the present invention selects toxicity little, environmental protection, raw material sources is extensive, ageing-resistant, anticorrosion, good anti-bacterial effect; Non-setting adhesive preparation method provided by the invention is simple, of many uses.
Embodiment
For the ease of it will be appreciated by those skilled in the art that the present invention is further illustrated below in conjunction with embodiment.
Embodiment 1
Environmental protection printing non-setting adhesive, by weight, composed of the following components: polystyrene 100 parts, acrylic resin 40 parts, polyacrylamide 6.5 parts, ethyl acetate 3 parts, vinyl acetate 4.5 parts, dimethylbenzene 4 parts, benzoyl peroxide 2 parts, vinyl acetic monomer 6 parts, glycerol 15 parts, ethanamide 20 parts, polyoxyethylene fatty acid 1 part, Sorbic Acid 0.25 part.
Its preparation method is: add in reactor by polystyrene 100 parts, acrylic resin 40 parts, polyacrylamide 6.5 parts, ethyl acetate 3 parts, vinyl acetate 4.5 parts, dimethylbenzene 4 parts, benzoyl peroxide 2 parts, vinyl acetic monomer 6 parts, glycerol 15 parts, ethanamide 20 parts successively, raised temperature to 78 DEG C, stir 5h, then 25 DEG C are cooled to, add polyoxyethylene fatty acid 1 part, Sorbic Acid 0.25 part again, stir 20min, obtain environmental protection non-setting adhesive.
Embodiment 2
Environmental protection printing non-setting adhesive, by weight, composed of the following components: polystyrene 100 parts, acrylic resin 30 parts, polyacrylamide 5 parts, ethyl acetate 2 parts, vinyl acetate 3 parts, dimethylbenzene 2 parts, benzoyl peroxide 1 part, vinyl acetic monomer 4 parts, glycerol 10 parts, ethanamide 15 parts, polyoxyethylene fatty acid 0.5 part, Sorbic Acid 0.1 part.
Its preparation method is: add in reactor by polystyrene 100 parts, acrylic resin 30 parts, polyacrylamide 5 parts, ethyl acetate 2 parts, vinyl acetate 3 parts, dimethylbenzene 2 parts, benzoyl peroxide 1 part, vinyl acetic monomer 4 parts, glycerol 10 parts, ethanamide successively, raised temperature to 78 DEG C, stir 5h, then 25 DEG C are cooled to, add polyoxyethylene fatty acid 0.5 part, Sorbic Acid 0.1 part again, stir 20min, obtain environmental protection non-setting adhesive.
Embodiment 3
Environmental protection printing non-setting adhesive, by weight, composed of the following components: polystyrene 100 parts, acrylic resin 50 parts, polyacrylamide 8 parts, ethyl acetate 4 parts, vinyl acetate 6 parts, dimethylbenzene 6 parts, benzoyl peroxide 3 parts, vinyl acetic monomer 8 parts, glycerol 20 parts, ethanamide 25 parts, polyoxyethylene fatty acid 1.5 parts, Sorbic Acid 0.4 part.
Its preparation method is: add in reactor by polystyrene 100 parts, acrylic resin 50 parts, polyacrylamide 8 parts, ethyl acetate 4 parts, vinyl acetate 6 parts, dimethylbenzene 6 parts, benzoyl peroxide 3 parts, vinyl acetic monomer 8 parts, glycerol 20 parts, ethanamide 25 parts successively, raised temperature to 78 DEG C, stir 5h, then 25 DEG C are cooled to, add polyoxyethylene fatty acid 1.5 parts, Sorbic Acid 0.4 part again, stir 20min, obtain environmental protection non-setting adhesive.
Above content is only citing made for the present invention and explanation; affiliated those skilled in the art make various amendment to described specific embodiment or supplement or adopt similar mode to substitute; only otherwise depart from the structure of invention or surmount this scope as defined in the claims, protection scope of the present invention all should be belonged to.
Claims (3)
1. an environmental protection printing non-setting adhesive, it is characterized in that, by weight, composed of the following components: polystyrene 100 parts, acrylic resin 30-50 part, polyacrylamide 5-8 part, ethyl acetate 2-4 part, vinyl acetate 3-6 part, dimethylbenzene 2-6 part, benzoyl peroxide 1-3 part, vinyl acetic monomer 4-8 part, glycerol 10-20 part, ethanamide 15-25 part, polyoxyethylene fatty acid 0.5-1.5 part, Sorbic Acid 0.1-0.4 part.
2. a kind of environmental protection printing non-setting adhesive according to claim 1, it is characterized in that, by weight, composed of the following components: polystyrene 100 parts, acrylic resin 40 parts, polyacrylamide 6.5 parts, ethyl acetate 3 parts, vinyl acetate 4.5 parts, dimethylbenzene 4 parts, benzoyl peroxide 2 parts, vinyl acetic monomer 6 parts, glycerol 15 parts, ethanamide 20 parts, polyoxyethylene fatty acid 1 part, Sorbic Acid 0.25 part.
3. prepare the method for environmental protection printing non-setting adhesive described in claim 1 or 2 for one kind, it is characterized in that, comprise the following steps: successively polystyrene, acrylic resin, polyacrylamide, ethyl acetate, vinyl acetate, dimethylbenzene, benzoyl peroxide, vinyl acetic monomer, glycerol, ethanamide are added in reactor, raised temperature to 78 DEG C, stir 5h, be then cooled to 25 DEG C, then add polyoxyethylene fatty acid, Sorbic Acid, stir 20min, obtain environmental protection non-setting adhesive.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510652235.3A CN105199614A (en) | 2015-10-08 | 2015-10-08 | Green environment-friendly adhesive sticker for printing and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510652235.3A CN105199614A (en) | 2015-10-08 | 2015-10-08 | Green environment-friendly adhesive sticker for printing and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105199614A true CN105199614A (en) | 2015-12-30 |
Family
ID=54947581
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510652235.3A Pending CN105199614A (en) | 2015-10-08 | 2015-10-08 | Green environment-friendly adhesive sticker for printing and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105199614A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107722845A (en) * | 2017-10-09 | 2018-02-23 | 安徽源美广告传媒有限公司 | A kind of advertising and printing adhesive sticker and preparation method thereof |
| CN108129997A (en) * | 2017-12-22 | 2018-06-08 | 上海金大塑胶有限公司 | A kind of preparation method of environment-friendly type adhesive material |
| CN108641693A (en) * | 2018-04-22 | 2018-10-12 | 陈琪峰 | A kind of oil field Wax removing agent |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1760302A (en) * | 2005-06-16 | 2006-04-19 | 湖北省化学研究院 | Modified adhesive of acrylic ester in low flow in use for multing layer flexible printed circuit, and preparation |
| CN102329573A (en) * | 2011-05-28 | 2012-01-25 | 王崇高 | Formula for production of non-setting adhesive and preparation method thereof |
| CN103740298A (en) * | 2012-04-06 | 2014-04-23 | 上海加富橡胶制品有限公司 | Method for attaching mark in rubber product and application of adhesive sticker to manufacturing tyre |
-
2015
- 2015-10-08 CN CN201510652235.3A patent/CN105199614A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1760302A (en) * | 2005-06-16 | 2006-04-19 | 湖北省化学研究院 | Modified adhesive of acrylic ester in low flow in use for multing layer flexible printed circuit, and preparation |
| CN102329573A (en) * | 2011-05-28 | 2012-01-25 | 王崇高 | Formula for production of non-setting adhesive and preparation method thereof |
| CN103740298A (en) * | 2012-04-06 | 2014-04-23 | 上海加富橡胶制品有限公司 | Method for attaching mark in rubber product and application of adhesive sticker to manufacturing tyre |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107722845A (en) * | 2017-10-09 | 2018-02-23 | 安徽源美广告传媒有限公司 | A kind of advertising and printing adhesive sticker and preparation method thereof |
| CN108129997A (en) * | 2017-12-22 | 2018-06-08 | 上海金大塑胶有限公司 | A kind of preparation method of environment-friendly type adhesive material |
| CN108641693A (en) * | 2018-04-22 | 2018-10-12 | 陈琪峰 | A kind of oil field Wax removing agent |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105199614A (en) | Green environment-friendly adhesive sticker for printing and preparation method thereof | |
| CN103333628B (en) | Special protective film for polymer lithium battery | |
| CN103555180A (en) | Water-based laser transfer coating for wine bottle glass baking paper, and preparation method thereof | |
| CN105017548B (en) | A kind of digital painting advertising base material and preparation method thereof | |
| CN101078491A (en) | Color spray lamp production method | |
| CN110093808A (en) | A kind of digital printing water-based paper coating material and preparation method thereof | |
| CN106626861B (en) | A kind of Medical film chip base and its application | |
| CN103146326A (en) | Emulsion type acrylic ester adhesive for anti-yellowing polishing membrane and preparation method thereof | |
| CN105348990A (en) | Material composition and preparation method of corrosion-resistant coating | |
| CN105365425B (en) | Gold stamping transfer membrane process | |
| CN208558689U (en) | Environment-friendly type, which is pasted, shifts straight calico paper | |
| CN103551762B (en) | A kind of hot air leveling-up scaling powder of non-volatility organic matter and preparation method thereof | |
| CN102040895A (en) | Temperature-sensing liquid wall paper | |
| CN100450786C (en) | Waterproof colored digital image spray-painting and printing medium | |
| CN102492380A (en) | Paper and plastic laminating adhesive | |
| CN215049847U (en) | Back cover adhesive sticker suitable for automatic machine seal | |
| CN103897540A (en) | Formula of high brightness performance coating capable of absorbing ECO-solvent ink | |
| CN104403590A (en) | Polytetrafluoroethylene adhesive tape, and preparation method and application thereof | |
| CN103319945A (en) | Green intaglio ink for wallpapers and preparation method thereof | |
| CN204125796U (en) | A kind of wallpaper based on non-woven paper | |
| CN109572262B (en) | Laser mother film for film pressure transfer film and preparation method and application method thereof | |
| CN208558690U (en) | Environment-friendly type, which is pasted, shifts straight calico paper complex printing paper membrane | |
| CN107488423A (en) | Paper adhesive sticker formula | |
| CN103172782A (en) | Vinyl acetate emulsion | |
| CN103507455A (en) | Stencil screen printing technology of tinplate round can |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20151230 |