CN105199564A - Thermoset electromagnetic shielding powder coating - Google Patents
Thermoset electromagnetic shielding powder coating Download PDFInfo
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- CN105199564A CN105199564A CN201510738122.5A CN201510738122A CN105199564A CN 105199564 A CN105199564 A CN 105199564A CN 201510738122 A CN201510738122 A CN 201510738122A CN 105199564 A CN105199564 A CN 105199564A
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Abstract
The invention discloses a thermoset electromagnetic shielding powder coating. The thermoset electromagnetic shielding powder coating comprises raw materials in parts by mass as follows: 0.15-1.6 parts of a curing agent, 15-30 parts of mixed resin, 5-20 parts of silver-coated copper powder, 10-40 parts of nickel powder, 1-5.5 parts of a leveling agent, 1-2.5 parts of a titanate coupling agent, 20-45 parts of a mixed solvent, 0.1-0.6 parts of a dispersing and sinking resisting agent and 0.001-0.005 parts of an antioxidant. Nickel powder is adopted to replace copper-coated silver powder and micro-scale silver-coated copper powder is adopted to replace nano-scale silver-coated copper powder commonly used in existing electromagnetic shielding coatings, and the cost of raw materials is greatly reduced.
Description
Technical field
The invention belongs to electromagnetic screen coating technical field, be specifically related to a kind of powder thermosetting electromagnetic screen coating.
Background technology
Along with the high speed development of electronics, electrical equipment industry, various commercialization and domestic electronic appliances quantity sharply increase, and one, electromagnetic interference and electromagnetic compatibility effect formed a kind of new social effects of pollution to human body; Two, between electronic apparatus, signal disturbs the key issue also becoming Product Safety reliability and will pay close attention to mutually.Due to the microminiaturization of electronic circuit and element, integrated, lightweight and digitizing, the electric current used is weak current, it controls the power of signal and the power of external electromagnetic wave noise is close, and therefore easily causes and can not identify the useful signal even erroneous judgement etc. of useful signal; On the other hand, these electronic products itself also outwards launch the hertzian wave of different frequency, cause interference can to the robot calculator of contiguous operation and other communication, electrical equipment etc.Because the case material of the electronic product used at present instead of original metal or other effective shielding material by a large amount of plastics or similar macromolecular material, and common high molecular materials is isolator, hertzian wave almost can not be absorbed and reflect, do not possess function of shielding, in order to address this problem, research and development have the coating of electro-magnetic screen function, and being coated on electronic apparatus corresponding site shield electromagnetic interference, is a kind of effective method.
Though at present existing a small amount of scientific research and Lab Products are reported, can practical application to have the stay-in-grade industrialization product of good electrical Magnetic Shielding Effectiveness rare.
Worldwide, current silver system shielding coating product is comparatively ripe, and it is expensive, and general use is difficult to bear great number cost, and silver system product itself exists the defect of essence: product easily produces precipitation after joining glue, and occurs with transport phenomena.Though Recent study gets along with, have no industrialization matured product in a large number for the production of putting into practice (Zhao Bin etc., the application of super fine silver powder in electrically conducting coating, coating technology, 2000, (1): 40); Nickel system shielding coating existing market has a certain amount of sale, but not good at the low frequency range shield effectiveness lower than 30MHz, then due to its poor electric conductivity, shielding efficiency is lower, but is current shielding coating leading product; Copper system shielding coating shielding efficiency is high, and has price advantage, and also there is not silver migration affects coating performance problem, and therefore copper system product is developed gradually and increased, but due to the copper easily oxidized subject matter making unstable properties become practical application; Carbon system and composite coating research at the early-stagely do not have industrialization product.Moreover current existing the said products is also only formed for base-material with acrylic resin or fluorine resin, limits its scope of application.
Summary of the invention
For the deficiencies in the prior art, the object of the present invention is to provide a kind of powder thermosetting electromagnetic screen coating, it is applicable to the operable whole occasion of thermosetting powder coating(s), can have electro-magnetic screen function by use object.
For achieving the above object, the present invention adopts following technical scheme:
A kind of powder thermosetting electromagnetic screen coating, its raw material and mass parts are: solidifying agent 0.15-1.6 part, hybrid resin 15-30 part, silver-coated copper powder 5-20 part, nickel powder 10-40 part, flow agent 1-5.5 part, titanate coupling agent 1-2.5 part, mixed solvent 20-45 part, the anti-heavy agent 0.1-0.6 part of dispersion, antioxidant 0.001-0.005 part;
Described nickel powder quality accounts for the 60-70% of the quality sum of whole metal-powder and nickel powder and silver-coated copper powder, and more preferably 67%;
In described silver-coated copper powder, the volumn concentration of silver is 5-30%, particle diameter 38-53 μm;
Described nickel powder particle diameter is 38-53 μm;
Described solidifying agent be selected from glyoxal ethyline, 2-benzylimidazoline one or both;
Described hybrid resin is the mixture of vibrin and epoxy resin, and the mass ratio of vibrin and epoxy resin is 1:1-4:1, preferred polyester resin: the mass ratio of epoxy resin is 1:1,3:2,7:3,4:1;
Described mixed solvent is the mixture of water, polyethoxye octylphenol ether, ethyl carbitol, and the mass ratio of water, polyethoxye octylphenol ether, ethyl carbitol is 1:1:1;
Described antioxidant be selected from three (2,4-di-t-butyl) phenyl-phosphite, two (2,4-di-tert-butyl-phenyl) pentaerythritol diphosphites one or both;
A preparation method for powder thermosetting electromagnetic screen coating, step comprises:
A, the silver-coated copper powder cleaned up and nickel powder are mixed after, add titanate coupling agent and the Virahol with titanate coupling agent equivalent, be uniformly mixed;
B, half amount mixed solvent, 1/4th amount flow agents to be added in the obtained compound of steps A, be uniformly mixed;
C, the hybrid resin powder of 1/2nd amounts and the flow agent of 1/4th amounts and remaining mixed solvent to be added in the obtained compound of step B, be uniformly mixed;
D, compound obtained for step C is carried out drying treatment after, carry out fine grinding and arrive more than 300 orders, sieve;
E, the compound obtained by step D add remaining hybrid resin powder and flow agent, then add the anti-heavy agent of dispersion and antioxidant, put into high-speed stirring mixer stirring and make mixing of materials even, then add solidifying agent, continue to be uniformly mixed;
F, compound obtained for step e is carried out melt extruding combination treatment, extruded stock is cooled, broken, then extruded stock is carried out pulverization process to 300 orders.
Silver-coated copper powder overcomes the oxidizable defect of copper powder, has conductive good, the good characteristics such as chemical stability is high, not oxidizable, price is low.
Under normal circumstances, the shielding efficiency of nickel powder in powder thermosetting electromagnetic screen coating is not as copper powder and silver powder, substitute silver-coated copper powder shielding properties with the nickel powder of equal parts will reduce, but contriver finds in proportioning raw materials of the present invention, when nickel powder content accounts for the 60-70% of quality sum of nickel powder and silver-coated copper powder, the shield effectiveness of coating reaches more than 90dB, improves unexpectedly, particularly nickel powder account for whole metal-powder reach the consumption of 67% time, cover efficiency and reach 95dB.Owing to adopting nickel powder to replace copper-clad silver powder, and the micron order copper-clad silver powder adopted replaces nano level silver-coated copper powder conventional in existing electromagnetic screen coating, also greatly reduces raw materials cost.
Embodiment
Embodiment 1
A kind of powder thermosetting electromagnetic screen coating, its raw material and mass parts are: glyoxal ethyline, each 0.13 part of 2-benzylimidazoline, hybrid resin (vibrin: epoxy resin ratio 1:1, Anhui Shenjian New Material Co., Ltd., mixed type curable epoxide vibrin, SJ3A) 18.97 parts, silver-coated copper powder (Li Hongjin Science and Technology Ltd. of Shenzhen, Li-0103) 16.42 parts, nickel powder (Beijing Xin Rongyuan Science and Technology Ltd., 300 height of eye pure nickel powders) 37.25 parts, flow agent (ModaflowPowderIII, U.S. SOLUTIA, N-(1, 3-DIMETHYLBUTYL)-N'-PHENYL-P-PHENYLENEDIAMINE) 1.68 parts, titanate coupling agent (Nanjing You Pu Chemical Co., Ltd., three iso stearate isopropyl titanates, UP-130) 1.32 parts, by water, polyethoxye octylphenol ether, the mixed solvent 30.34 parts that ethyl carbitol forms with mass ratio 1:1:1, anti-heavy agent (the Qing Hong auxiliary chemicals factory of Linan City of dispersion, the anti-heavy agent of CP-88.118 solvent based coating) 0.6 part, three (2, 4-di-t-butyl) phenyl-phosphite 0.003 part.
The preparation method of powder thermosetting electromagnetic screen coating is as follows:
Get silver-coated copper powder, in glass cylinder body, do surface cleaning processing with organic solvent-acetone, guarantee that surface is without oil pollution.In kind process nickel powder.Then acetone solvent is evaporated clean by the two in low-temperature bake oven at 60 DEG C;
Adopt V-arrangement metal-powder mixer, mix, first low speed (100 turns/min) stirs 5min, rear high speed (1000 turns/min) stirs 10min, again low speed (100 turns/min) and stir 5min, make it mix;
Add whole amount coupling agent, add the Virahol with titanate coupling agent equivalent, low speed (120 turns/min) stirs 20min, for subsequent use;
The mixed solvent of half amount is joined in above-mentioned mixed powder, adds the flow agent of 1/4th amounts, carry out being uniformly mixed 20min in solid-liquid mixing and blending machine;
By the hybrid resin powder of half amount and the flow agent of 1/4th amounts, and remaining mixed solvent, add the compound that previous step is obtained, in blender, mix (1200 turns/min) 10min;
After mixed material is carried out drying treatment 3h in loft drier, carry out fine grinding 20min at ultra-fine micropowder machine, when arriving more than 300 orders, sieve;
Add remaining polyester resin powder and flow agent in material obtained in previous step, add the anti-heavy agent of dispersion, antioxidant, put into high-speed stirring type mixing machine, rotating speed 2800 turns/min, process 3min, then adds solidifying agent, continue to stir 2min, mix.
Adopt thermosetting powder coating(s) production line to carry out coating and melt extrude mixing manufacture, wherein master operation is: become the reverse twin screw extruder of screw thread and melt extrude combination treatment (district's temperature 90 DEG C to material obtained in previous step, two district's temperature 110 DEG C, three district's temperature: 100 DEG C; Double-screw extruder screw rotating speed is controlled by mair motor, mair motor rotating speed 3000r/min), the material extruded, through cooling, after fragmentation, enters ball mill and supper micron mill twice technique processes, and makes end product granularity reach 300 orders, for subsequent use.
Use the powder thermosetting electromagnetic screen coating of preparation to carry out shielding efficiency test, the shielding efficiency detecting coating is 90dB.
Concrete detection method is implemented according to GB/T30142-2013 " plane electromagnetic shielding material effectiveness of shielding measuring method ".
Embodiment 2
A kind of powder thermosetting electromagnetic screen coating, its raw material and mass parts are: glyoxal ethyline 1.16 parts, hybrid resin (vibrin: epoxy resin ratio 3:2, Anhui Shenjian New Material Co., Ltd., mixed type curable epoxide vibrin, SJ5A) 22.83 parts, silver-coated copper powder 17.75 parts, nickel powder 27.45 parts (60.7%), flow agent 1.33 parts, titanate coupling agent 1.9 parts, by water, polyethoxye octylphenol ether, the mixed solvent 33.13 parts that ethyl carbitol forms with mass ratio 1:1:1, the anti-heavy agent 0.42 part of dispersion, three (2, 4-di-t-butyl) phenyl-phosphite 0.003 part,
The preparation method of powder thermosetting electromagnetic screen coating is as follows:
Get silver-coated copper powder, in glass cylinder body, do surface cleaning processing with organic solvent-acetone, guarantee that surface is without oil pollution.In kind process nickel powder.Then acetone solvent is evaporated clean by the two in low-temperature bake oven at 60 DEG C;
Adopt V-arrangement metal-powder mixer, mix, first low speed (100 turns/min) stirs 5min, rear high speed (1000 turns/min) stirs 10min, again low speed (100 turns/min) and stir 5min, make it mix;
Add whole amount coupling agent, add the Virahol with titanate coupling agent equivalent, low speed (120 turns/min) stirs 20min, for subsequent use;
The mixed solvent of half amount is joined in above-mentioned mixed powder, adds the flow agent of 1/4th amounts, carry out being uniformly mixed 20min in solid-liquid mixing and blending machine;
By the hybrid resin powder of half amount and the flow agent of 1/4th amounts, and remaining mixed solvent, add the compound that previous step is obtained, in blender, mix (1200 turns/min) 10min;
After mixed material is carried out drying treatment 5h in loft drier, carry out fine grinding 20min at ultra-fine micropowder machine, when arriving more than 300 orders, sieve;
Add remaining polyester resin powder and flow agent in material obtained in previous step, add the anti-heavy agent of dispersion, antioxidant, put into high-speed stirring type mixing machine, rotating speed 2800 turns/min, process 5min, then adds solidifying agent, continue to stir 1min, mix.
Adopt thermosetting powder coating(s) production line to carry out coating and melt extrude mixing manufacture, master operation: become screw thread reverse twin screw extruder and combination treatment (district's temperature 95 DEG C is melt extruded to material obtained in previous step, two district's temperature 115 DEG C, three district's temperature: 110 DEG C; Double-screw extruder screw rotating speed is controlled by mair motor, mair motor rotating speed 2500r/min), the material extruded, through cooling, after fragmentation, enters ball mill and supper micron mill twice technique processes, and makes end product granularity reach 300 orders, for subsequent use.
The shielding efficiency detecting coating is 92dB.
Embodiment 3
A kind of powder thermosetting electromagnetic screen coating, its raw material and mass parts are: glyoxal ethyline 1.5 parts, hybrid resin (vibrin: epoxy resin ratio 7:3, Anhui Shenjian New Material Co., Ltd., mixed type curable epoxide vibrin, SJ6A) 22.83 parts, silver-coated copper powder 20.32 parts, nickel powder 40.50 parts (66.6%), flow agent 5 parts, titanate coupling agent 2.03 parts, by water, polyethoxye octylphenol ether, the mixed solvent 40.72 parts that ethyl carbitol forms with mass ratio 1:1:1, the anti-heavy agent 0.5 part of dispersion, three (2, 4-di-t-butyl) phenyl-phosphite 0.002 part,
The preparation method of powder thermosetting electromagnetic screen coating is as follows:
Get silver-coated copper powder, in glass cylinder body, do surface cleaning processing with organic solvent-acetone, guarantee that surface is without oil pollution.In kind process nickel powder.Then acetone solvent is evaporated clean by the two in low-temperature bake oven at 60 DEG C;
Adopt V-arrangement metal-powder mixer, mix, first low speed (100 turns/min) stirs 5min, rear high speed (1000 turns/min) stirs 10min, again low speed (100 turns/min) and stir 5min, make it mix;
Add whole amount coupling agent, add the Virahol with titanate coupling agent equivalent, low speed (120 turns/min) stirs 20min, for subsequent use;
The mixed solvent of half amount is joined in above-mentioned mixed powder, adds the flow agent of 1/4th amounts, carry out being uniformly mixed 20min in solid-liquid mixing and blending machine;
By the hybrid resin powder of half amount and the flow agent of 1/4th amounts, and remaining mixed solvent, add the compound that previous step is obtained, in blender, mix (1200 turns/min) 10min;
After mixed material is carried out drying treatment 5h in loft drier, carry out fine grinding 20min at ultra-fine micropowder machine, when arriving more than 300 orders, sieve;
Add remaining polyester resin powder and flow agent in material obtained in previous step, add the anti-heavy agent of dispersion, antioxidant, put into high-speed stirring type mixing machine, rotating speed 2800 turns/min, process 4min, then adds solidifying agent, continue to stir 2min, mix.
Adopt thermosetting powder coating(s) production line to carry out coating and melt extrude mixing manufacture, master operation: become screw thread reverse twin screw extruder and combination treatment (district's temperature 100 DEG C is melt extruded to material obtained in previous step, two district's temperature 120 DEG C, three district's temperature: 115 DEG C; Double-screw extruder screw rotating speed is controlled by mair motor, mair motor rotating speed 3500r/min), the material extruded, through cooling, after fragmentation, enters ball mill and supper micron mill twice technique processes, and makes end product granularity reach 300 orders, for subsequent use.
The shielding efficiency detecting coating is 95dB.
Embodiment 4
A kind of powder thermosetting electromagnetic screen coating, its raw material and mass parts are: glyoxal ethyline, each 0.6 part of 2-benzylimidazoline, hybrid resin (vibrin: epoxy resin ratio 4:1, Anhui Shenjian New Material Co., Ltd., mixed type curable epoxide vibrin, SJ6BDT) 26.05 parts, silver-coated copper powder 8.5 parts, nickel powder 19 parts (69%), flow agent 3 parts, titanate coupling agent 1.46 parts, by water, polyethoxye octylphenol ether, the mixed solvent 35 parts that ethyl carbitol forms with mass ratio 1:1:1, the anti-heavy agent 0.2 part of dispersion, two (2, 4-di-tert-butyl-phenyl) pentaerythritol diphosphites 0.004 part,
The preparation method of powder thermosetting electromagnetic screen coating is as follows:
Get silver-coated copper powder, in glass cylinder body, do surface cleaning processing with organic solvent-acetone, guarantee that surface is without oil pollution.In kind process nickel powder.Then acetone solvent is evaporated clean by the two in low-temperature bake oven at 60 DEG C;
Adopt V-arrangement metal-powder mixer, mix, first low speed (100 turns/min) stirs 5min, rear high speed (1000 turns/min) stirs 10min, again low speed (100 turns/min) and stir 5min, make it mix;
Add whole amount coupling agent, add the Virahol with titanate coupling agent equivalent, low speed (120 turns/min) stirs 20min, for subsequent use;
The mixed solvent of half amount is joined in above-mentioned mixed powder, adds the flow agent of 1/4th amounts, carry out being uniformly mixed 20min in solid-liquid mixing and blending machine;
By the hybrid resin powder of half amount and the flow agent of 1/4th amounts, and remaining mixed solvent, add the compound that previous step is obtained, in blender, mix (1200 turns/min) 10min;
After mixed material is carried out drying treatment 3h in loft drier, carry out fine grinding 20min at ultra-fine micropowder machine, when arriving more than 300 orders, sieve;
Add remaining polyester resin powder and flow agent in material obtained in previous step, add the anti-heavy agent of dispersion, antioxidant, put into high-speed stirring type mixing machine, rotating speed 2800 turns/min, process 4min, then adds solidifying agent, continue to stir 2min, mix.
Adopt thermosetting powder coating(s) production line to carry out coating and melt extrude mixing manufacture, master operation: become screw thread reverse twin screw extruder and combination treatment (district's temperature 90 DEG C is melt extruded to material obtained in previous step, two district's temperature 110 DEG C, three district's temperature: 100 DEG C; Double-screw extruder screw rotating speed is controlled by mair motor, mair motor rotating speed 4000r/min), the material extruded, through cooling, after fragmentation, enters ball mill and supper micron mill twice technique processes, and makes end product granularity reach 300 orders, for subsequent use.
The shielding efficiency detecting coating is 91dB.
Comparative example:
Coating raw material proportioning and preparation method are substantially with embodiment 3, difference is in the compound replacing silver-coated copper powder and nickel powder in the silver-coated copper powder and nickel powder of using equivalent respectively, namely use merely silver-coated copper powder, nickel powder as shielded metal, then detect the shielding efficiency of obtained shielding coating, the simple silver-coated copper powder that uses is 96dB as the shielding efficiency of the coating of shielded metal; Simple use nickel powder is 75dB as the shielding efficiency of the coating of shielded metal.
Claims (8)
1. a powder thermosetting electromagnetic screen coating, its raw material and mass parts are: solidifying agent 0.15-1.6 part, hybrid resin 15-30 part, silver-coated copper powder 5-20 part, nickel powder 10-40 part, flow agent 1-5.5 part, titanate coupling agent 1-2.5 part, mixed solvent 20-45 part, the anti-heavy agent 0.1-0.6 part of dispersion, antioxidant 0.001-0.005 part.
2. electromagnetic screen coating as claimed in claim 1, is characterized in that: described nickel powder quality accounts for the 60-70% of the quality sum of whole metal-powder and nickel powder and silver-coated copper powder, more preferably 67%.
3. electromagnetic screen coating as claimed in claim 1, is characterized in that: in described silver-coated copper powder, the volumn concentration of silver is 5-30%, particle diameter 38-53 μm; Described nickel powder particle diameter is 38-53 μm.
4. electromagnetic screen coating as claimed in claim 1, is characterized in that: described solidifying agent be selected from glyoxal ethyline, 2-benzylimidazoline one or both.
5. electromagnetic screen coating as claimed in claim 1, it is characterized in that: described hybrid resin is the mixture of vibrin and epoxy resin, the mass ratio of vibrin and epoxy resin is 1:1-4:1, preferred polyester resin: the mass ratio of epoxy resin is 1:1,3:2,7:3,4:1.
6. electromagnetic screen coating as claimed in claim 1, it is characterized in that: described mixed solvent is the mixture of water, polyethoxye octylphenol ether, ethyl carbitol, the mass ratio of water, polyethoxye octylphenol ether, ethyl carbitol is 1:1:1.
7. electromagnetic screen coating as claimed in claim 1, it is characterized in that: described antioxidant is selected from three (2,4-di-t-butyl) phenyl-phosphite, one or both in two (2,4-di-tert-butyl-phenyl) pentaerythritol diphosphites.
8. the electromagnetic screen coating as described in any one of claim 1-7, is characterized in that: the step preparation by the following method of described electromagnetic screen coating:
A, the silver-coated copper powder cleaned up and nickel powder are mixed after, add titanate coupling agent and the Virahol with titanate coupling agent equivalent, be uniformly mixed;
B, half amount mixed solvent, 1/4th amount flow agents to be added in the obtained compound of steps A, be uniformly mixed;
C, the hybrid resin powder of 1/2nd amounts and the flow agent of 1/4th amounts and remaining mixed solvent to be added in the obtained compound of step B, be uniformly mixed;
D, compound obtained for step C is carried out drying treatment after, carry out fine grinding and arrive more than 300 orders, sieve;
E, the compound obtained by step D add remaining hybrid resin powder and flow agent, then add the anti-heavy agent of dispersion and antioxidant, put into high-speed stirring mixer stirring and make mixing of materials even, then add solidifying agent, continue to be uniformly mixed;
F, compound obtained for step e is carried out melt extruding combination treatment, extruded stock is cooled, broken, then extruded stock is carried out pulverization process to 300 orders.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106010155A (en) * | 2016-07-14 | 2016-10-12 | 夏嘉伟 | Composite electromagnetic shielding conductive coating |
| CN107163629A (en) * | 2017-06-07 | 2017-09-15 | 合肥励仙电力工程有限公司 | It is a kind of for magnetic field shielding coating of distribution transformer and preparation method thereof |
| CN111138956A (en) * | 2019-12-23 | 2020-05-12 | 江阴市玲珑高分子材料有限公司 | Thermosetting powder electromagnetic shielding coating |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS56118467A (en) * | 1980-02-25 | 1981-09-17 | Nippon Kokuen Kogyo Kk | Manufacture of conductive powder paint |
| JPH1180612A (en) * | 1997-09-03 | 1999-03-26 | Inter Metallics Kk | Powder coating and film forming method using it |
| CN101245201A (en) * | 2008-03-21 | 2008-08-20 | 杨建平 | Thermoplastic powder electrically-conducting paint/printing ink and manufacture method thereof |
| CN101275052A (en) * | 2008-05-14 | 2008-10-01 | 海洋化工研究院 | Corrosion-resistant electromagnetic screen coating and preparation thereof |
| CN102329560A (en) * | 2010-07-14 | 2012-01-25 | 中化化工科学技术研究总院 | Novel electromagnetic shielding paint for surface of silicone rubber |
| CN102408813A (en) * | 2011-09-28 | 2012-04-11 | 国润恒科（天津）防腐工程技术有限公司 | High-electric-conductivity heavy-anticorrosion wave-absorbing powder paint |
| CN102618145A (en) * | 2012-04-01 | 2012-08-01 | 昆明理工大学 | Electromagnetic shielding conductive coating and preparation method thereof |
-
2015
- 2015-10-31 CN CN201510738122.5A patent/CN105199564B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS56118467A (en) * | 1980-02-25 | 1981-09-17 | Nippon Kokuen Kogyo Kk | Manufacture of conductive powder paint |
| JPH1180612A (en) * | 1997-09-03 | 1999-03-26 | Inter Metallics Kk | Powder coating and film forming method using it |
| CN101245201A (en) * | 2008-03-21 | 2008-08-20 | 杨建平 | Thermoplastic powder electrically-conducting paint/printing ink and manufacture method thereof |
| CN101275052A (en) * | 2008-05-14 | 2008-10-01 | 海洋化工研究院 | Corrosion-resistant electromagnetic screen coating and preparation thereof |
| CN102329560A (en) * | 2010-07-14 | 2012-01-25 | 中化化工科学技术研究总院 | Novel electromagnetic shielding paint for surface of silicone rubber |
| CN102408813A (en) * | 2011-09-28 | 2012-04-11 | 国润恒科（天津）防腐工程技术有限公司 | High-electric-conductivity heavy-anticorrosion wave-absorbing powder paint |
| CN102618145A (en) * | 2012-04-01 | 2012-08-01 | 昆明理工大学 | Electromagnetic shielding conductive coating and preparation method thereof |
Non-Patent Citations (4)
| Title |
|---|
| 代少俊等: "《涂料与黏合剂》", 31 August 2014 * |
| 冯玉杰等: "《环境功能材料》", 30 April 2010 * |
| 刘嘉等: "《航空橡胶与密封材料》", 30 November 2011 * |
| 童忠良: "《新型功能复合材料制备新技术》", 31 October 2010 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106010155A (en) * | 2016-07-14 | 2016-10-12 | 夏嘉伟 | Composite electromagnetic shielding conductive coating |
| CN107163629A (en) * | 2017-06-07 | 2017-09-15 | 合肥励仙电力工程有限公司 | It is a kind of for magnetic field shielding coating of distribution transformer and preparation method thereof |
| CN111138956A (en) * | 2019-12-23 | 2020-05-12 | 江阴市玲珑高分子材料有限公司 | Thermosetting powder electromagnetic shielding coating |
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| CN105199564B (en) | 2018-03-20 |
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