CN105199560A - Separation device of lead block of waste storage battery - Google Patents
Separation device of lead block of waste storage battery Download PDFInfo
- Publication number
- CN105199560A CN105199560A CN201510691047.1A CN201510691047A CN105199560A CN 105199560 A CN105199560 A CN 105199560A CN 201510691047 A CN201510691047 A CN 201510691047A CN 105199560 A CN105199560 A CN 105199560A
- Authority
- CN
- China
- Prior art keywords
- storage battery
- old storage
- collection box
- plumbous
- section
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/62—Plastics recycling; Rubber recycling
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/84—Recycling of batteries or fuel cells
Abstract
The invention discloses a separation device of a lead block of a waste storage battery. The separation device comprises a rack, a waste storage battery feeding mechanism fixed above the rack, a waste storage battery notching mechanism connected with the waste storage battery feeding mechanism, a vibration lead removing mechanism connected with the waste storage battery notching mechanism, and a slice collection box, a lead block collection box and a plastic box collection box which are located under the vibration lead removing mechanism. According to the separation device of the lead block of the waste storage battery, a lead block in a plastic shell of the storage battery can be separated from the plastic shell through high-frequency vibration and the separated lead block is put into the lead block collection box and the plastic shell is put into the plastic box collection box, so that manual detachment of the waste storage battery is replaced, the labor cost is reduced and the detachment efficiency of the waste storage battery is improved; the work of manually classifying the lead block and the plastic shell is saved, and furthermore, the recycling efficiency of the lead block of the waste storage battery is improved.
Description
Technical field
The present invention relates to metal recovery field, particularly about a kind of tripping device of old storage battery lead.
Background technology
As the core drive parts of electromobile, storage battery can have powerful power for electromobile provides; But the restricted lifetime of storage battery, the mode of classification recovery is deferred in the recovery of discarded storage battery, namely removes plastic casing, respectively plastics, lead is carried out to classification and reclaims.Due to the close structure of storage battery, the dismounting of old storage battery is comparatively difficult, and adopt the mode of workman's hand disassembly at present more, cost of labor is too high, inefficiency, and comparatively large owing to dismantling difficulty, workman is the as easy as rolling off a log accident that meets accident in actually operating, cause personal injury, strengthen cost of labor further.
Summary of the invention
In view of this, the present invention, for solving the problems of the technologies described above, provides a kind of tripping device of old storage battery lead, for the old storage battery of alternative workman's hand disassembly, reduces cost of labor, improves the removal efficiency of old storage battery.
Object of the present invention is achieved through the following technical solutions:
A tripping device for old storage battery lead, comprises frame, is fixed on the old storage battery feed mechanism above frame, the old storage battery notching mechanism be connected with old storage battery feed mechanism, the vibrations Tuo Qian mechanism be connected with old storage battery notching mechanism, is positioned at the section collection box, lead collection box and the plastics casing collection box that shake below Tuo Qian mechanism, described old storage battery feed mechanism comprises belt motion-work wheel, belt slave wheel, be sleeved on the transmission belt on belt motion-work wheel and belt slave wheel, be positioned at two belt guide plates above transmission belt, two belt guide plate composition belt tapered channels, the terminal end width size of belt tapered channels is equal with the length scale of the most minor face of old storage battery, transmission belt right is also provided with the oblique rail of blanking, the oblique rail of blanking comprises two side levers be obliquely installed, the cross bar be connected with two side levers and two the oblique rail guide plates be positioned at above side lever, guide plate is fixedly connected with side lever, two oblique rail guide plates form the straight passage of oblique rail, the width size of oblique rail is straight passage equals the terminal end width size of belt tapered channels, cross bar is rotatably connected on side lever, the oblique rail of blanking is connected with lower track lowering, the cross section of lower track lowering is equal with the smallest cross-sectional of old storage battery, described old storage battery notching mechanism comprises and is positioned at bottom lower track lowering, and the section storehouse that volume is equal with old storage battery volume, the right side wall in section storehouse is provided with hole and right side wall lower opening on right side wall, on right side wall, hole is provided with the pusher dish running through hole on right side wall, described pusher dish is fixed on the push rod of cylinder one, cylinder one is fixedly connected with frame, right side wall lower opening is provided with the cutting knife running through right side wall lower opening, cutting knife is fixed on the push rod of cylinder two, cylinder two is fixedly connected with frame, section bottom, storehouse is provided with section storehouse and windows, section storehouse is windowed as rectangle, the length windowed in section storehouse is less than the length of old storage battery smallest cross-sectional, the length difference of the length windowed in section storehouse and old storage battery smallest cross-sectional is 1-5mm, the width windowed in section storehouse is less than the width of old storage battery smallest cross-sectional, the width differential of the width windowed in section storehouse and old storage battery smallest cross-sectional is 1-5mm, section is provided with buffer channel on the left of storehouse, buffer channel top is provided with hole on passage, buffer channel bottom is provided with groove under passage lower opening and passage, on passage, hole is provided with the baffle plate one in hole on penetrating via, baffle plate one is fixed on the push rod of cylinder three, cylinder three is fixedly connected with frame, under passage, the cross section of groove is equal with cross section, hole on passage, passage lower opening is provided with the baffle plate two of penetrating via lower opening, baffle plate two is fixed on the push rod of cylinder four, cylinder four is fixedly connected with frame, described vibrations Tuo Qian mechanism comprises the de-plumbous passage being arranged on buffer channel left part, de-plumbous clamping plate are provided with in de-plumbous passage, the buffering being distributed in de-plumbous clamping plate periphery is cotton, de-plumbous clamping plate are cotton and de-plumbous expanding channels by buffering, de-plumbous clamping plate are fixedly connected with drive block, drive block is fixedly connected with high-frequency vibration motor, drive block is connected with frame by bumper ring, de-plumbous beneath galleries is provided with windows greatly, buffering cotton is provided with equal with large window size, identical buffering cotton is windowed in position, de-plumbous clamping plate are provided with equal with cushioning cotton window size, the identical clamping plate in position are windowed, section collection box is positioned at below section storehouse, and section collection box is windowed by storehouse of cutting into slices and to be communicated with storehouse of cutting into slices, lead collection box is positioned at below de-plumbous passage, the section collection box left side, and lead collection box by windowing greatly, cushioning, window, clamping plate are windowed and de-plumbous channel connection by cotton, and lead collection box is completely isolated with section collection box, plastics casing collection box is positioned on the left of lead collection box, plastics casing collection box and lead collection box completely isolated, de-plumbous channel end is uncovered, and this uncovered area is enough to guarantee that old storage battery passes through, plastics casing collection box top is provided with opening.
Described lower track lowering right side wall top is provided with scarp, and the cross-sectional length size of described buffer channel equals the height after old storage battery otch; The angle of inclination on described scarp is 1-10 °.
The principle of work of the retrieving arrangement of described old storage battery lead is: during use, old storage battery is erected on transmission belt, entirely fit with transmission belt and contact in the surface that now on old storage battery, area is minimum, old storage battery moves right along with moving of belt, under the constraint of belt tapered channels, along belt guide plate adjustment position, eventually through belt tapered channels; Because the terminal end width size of belt tapered channels is equal with the length scale of the most minor face of old storage battery, the oblique rail of blanking is arrived exactly by belt tapered channels end old storage battery out, the old storage battery entering the oblique rail of blanking accelerates to fall into lower track lowering under gravity, nationality, by the constraint of lower track lowering right side wall, is avoided old storage battery to fall and lower track lowering; Old storage battery falls in section storehouse in lower track lowering, cylinder three in buffer channel on the left of section storehouse is inflated with cylinder four, cylinder three is released with the push rod of cylinder four simultaneously, baffle plate one moves down under the promotion of cylinder three push rod until the end of baffle plate one contacts with groove under passage, and baffle plate two moves up under the promotion of cylinder four push rod until the end of baffle plate two and buffer channel upper contact; Now, old storage battery is completely fixed in section storehouse, and cylinder two is inflated, and cylinder two push rod promotes cutting knife and is moved to the left, and cutting knife cuts out opening in the bottom of old storage battery; After cutting knife cuts opening, there is old storage battery and cutting knife in section storehouse simultaneously, makes to be in shrink-fit in section storehouse, and the plastic sheet that cutting knife is cut is windowed via section storehouse and extruded section storehouse and fall to section collection box under the extruding of cutting knife; After cutting plastic sheet, cylinder two, cylinder three, cylinder four are exitted, and cutting knife, baffle plate one, baffle plate two are regained; Cylinder one is inflated, and the push rod of cylinder one promotes pusher dish and is moved to the left, and pusher dish promotes old storage battery in section storehouse and moves to left, and enters buffer channel, and is positioned on the left of baffle plate one; Next Geju City storage battery is according to above-mentioned steps, and finally enter buffer channel, promote last Geju City storage battery and be moved to the left, after abundant old storage battery enters buffer channel, former Geju City storage battery arrives de-plumbous passage, and is shaken off by the plastics casing of opening by lead under the vibrations of high-frequency electric machines; After lead shakes off, window, clamping plate are windowed by windowing greatly, cushioning lead drop to lead collection box by cotton, and plastics casing drops to plastics casing collection box by taking off plumbous channel end.
The surface of de-plumbous clamping plate, de-plumbous passage, bumper ring, drive block and buffer channel is coated with refractory layer, and described refractory layer comprises heat-resistant inks, and heat-resistant inks is made up of the component of following parts by weight:
End group is the linear polyester 15 ~ 30 parts of carboxyl; Hyperbranched resin 10 ~ 25 parts; Reactive thinner 5 ~ 20 parts; Mineral filler 10 ~ 35 parts; Pigment 0 ~ 15 part; Functional agent 0 ~ 8 part; Solvent 0 ~ 20 part; 1 ~ 3 part, solidifying agent; Described hyperbranched resin synthesizes in accordance with the following steps:
(1) in the protection of inert atmosphere with under stirring, in molar ratio, by the 3-methylpentane-2 of 1 part, 3 of 4-glycol and 1 part, 5-bis-(methylol) phenylformic acid is added in encloses container, then add the vitriol oil as catalyzer, at 160 ~ 180 DEG C, stir the matrix G1 obtaining hyperbranched resin after there is condensation reaction in 1 ~ 2 hour;
(2) then continue to add 1 part 3,5-bis-(methylol) phenylformic acid and the vitriol oil at the matrix G1 of above-mentioned hyperbranched resin, stir 1 ~ 2 hour at 160 ~ 180 DEG C, then this step is repeated 6 times, obtain the matrix G7 of hyperbranched resin;
(3) then the temperature of reaction of step (2) is down to 80 DEG C, adds excessive epoxy chloropropane and aqueous sodium hydroxide solution, react washing, suction filtration after 3 hours, obtain described hyperbranched resin.
Further, the matrix G7 of the hyperbranched resin obtained in described hyperbranched resin synthesis step (2) contains 100 ~ 118 terminal hydroxy group.
Further, described end group is the hydroxyl value of the linear polyester of carboxyl is 120 ~ 180mgKOH/g, and weight-average molecular weight is 10000 ~ 30000.
Further, described reactive thinner is the mixture of ethylene glycol diglycidylether, polypropylene glycol diglycidyl ether and isocyanuric acid three-glycidyl ester.
Further, described mineral filler is at least one in calcium carbonate, aluminium hydroxide, barium sulfate, titanium dioxide.
Further, described functional agent is at least one in defoamer, flow agent, antioxidant.The present invention's functional agent used is that the commercial product of the art all can realize the present invention.
Further, described solvent is at least one in alcoholic solvent, esters solvent, ketones solvent, solvent of ether ester type.The present invention's solvent used is that the conventional solvent of the art all can realize the present invention, as organic solvents such as ethylene glycol ethyl ether, acetone, 1-Methoxy-2-propyl acetates.
Further, described solidifying agent is amine curing agent.The present invention adopts the conventional amine curing agent of the art all can realize the present invention, as materials such as triethylamine, four ethene triamines.
Further, described heat-resistant inks is made up of the component of following parts by weight:
End group is the linear polyester 15 ~ 30 parts of carboxyl; Hyperbranched resin 10 ~ 25 parts; Ethylene glycol diglycidylether 1 ~ 5 part; Polypropylene glycol diglycidyl ether 2 ~ 4 parts; Isocyanuric acid three-glycidyl ester 3 ~ 7 parts; Mineral filler 10 ~ 35 parts; Pigment 0 ~ 15 part; Functional agent 0 ~ 8 part; Solvent 0 ~ 20 part; 1 ~ 3 part, solidifying agent.
The present invention compared to the beneficial effect of prior art is:
The present invention utilizes cutting knife on storage battery plastic casing, cut out an otch, and the storage battery cutting out otch is entered de-plumbous passage, the buffering directly contacted with de-plumbous passage is provided with cotton in de-plumbous passage, by cushioning the de-plumbous clamping plate of cotton and de-plumbous passage indirect contact, high-frequency electric machines is connected with de-plumbous Boards wall, storage battery in de-plumbous clamping plate shakes along with the vibrations of high-frequency electric machines, by high-frequency vibration, the lead in storage battery plastic casing is separated with plastic casing, lead after separation is from windowing greatly, buffering cotton is windowed and falls to lead collection box, plastic casing falls into plastics casing collection box via de-plumbous channel end, the old storage battery of workman's hand disassembly is substituted by aforementioned mechanical arrangement, cost of labor can be reduced, effective raising removal efficiency, greatly reduce the generation of the old storage battery mishap of dismounting, eliminate the work of lead and plastic casing manual sort simultaneously, improve the efficiency that old storage battery lead reclaims further.
In addition, the present invention is by the specific asymmetric hyperbranched resin of synthesis, then coordinate specific linear polyester as matrix resin, make matrix resin of the present invention not only have good curing performance, solidification value is low, and has excellent sticking power to most of ground, but also there is extremely strong thermotolerance, excellent weathering resistance, this resin can also form fine and close polymeric film simultaneously, and its coating formed has excellent weathering resistance, high thermal resistance and splendid resistance to acids and bases.Further in order to solve the problem of asymmetric hyperbranched resin and specific linear polyester consistency, the present invention is by selecting ethylene glycol diglycidylether, the mixture of polypropylene glycol diglycidyl ether and isocyanuric acid three-glycidyl ester is as reactive thinner, can the bad problem of solution consistency cleverly, reduce the solidification value of resin further.Heat-resistant inks provided by the invention, compared with traditional heat-resistant inks of domestic production, heat-resistant inks prepared by the present invention has low solidification value, the excellent feature such as thermotolerance, soldering resistance, yellowing resistance.
Accompanying drawing explanation
The invention will be further described to utilize accompanying drawing, but the embodiment in accompanying drawing does not form any limitation of the invention.
Fig. 1 is the one-piece construction figure of the retrieving arrangement of old storage battery lead of the present invention.
Embodiment
Below in conjunction with embodiment, the present invention will be described in detail, and embodiment is only the preferred embodiment of the present invention, is not limitation of the invention.
A tripping device for old storage battery lead, comprises frame 18, is fixed on the old storage battery feed mechanism above frame 18, the old storage battery notching mechanism be connected with old storage battery feed mechanism, the vibrations Tuo Qian mechanism be connected with old storage battery notching mechanism, is positioned at the section collection box 25, lead collection box 30 and the plastics casing collection box 31 that shake below Tuo Qian mechanism, old storage battery feed mechanism comprises belt motion-work wheel 7, belt slave wheel, be sleeved on the transmission belt 8 on belt motion-work wheel 7 and belt slave wheel, be positioned at two belt guide plates 9 above transmission belt 8, two belt guide plates 9 form belt tapered channels, the terminal end width size of belt tapered channels is equal with the length scale of the most minor face of old storage battery, transmission belt 8 right is also provided with the oblique rail of blanking, the oblique rail of blanking comprises two side levers 10 be obliquely installed, the cross bar 12 be connected with two side levers 10 and two the oblique rail guide plates 11 be positioned at above side lever 10, guide plate 9 is fixedly connected with side lever 10, two oblique rail guide plates 11 form the straight passage of oblique rail, the width size of oblique rail is straight passage equals the terminal end width size of belt tapered channels, cross bar 12 is rotatably connected on side lever 10, the oblique rail of blanking is connected with lower track lowering 14, the cross section of lower track lowering 14 is equal with the smallest cross-sectional of old storage battery, old storage battery notching mechanism comprises and is positioned at bottom lower track lowering 14, and the section storehouse that volume is equal with old storage battery volume, the right side wall in section storehouse is provided with hole and right side wall lower opening on right side wall, on right side wall, hole is provided with the pusher dish 17 running through hole on right side wall, pusher dish 17 is fixed on the push rod of cylinder 1, cylinder 1 is fixedly connected with frame 18, right side wall lower opening is provided with the cutting knife 21 running through right side wall lower opening, cutting knife 21 is fixed on the push rod of cylinder 2 20, cylinder 2 20 is fixedly connected with frame 18, section bottom, storehouse is provided with section storehouse and windows 22, section storehouse windows 22 for rectangle, the length windowed in section storehouse is less than the length of old storage battery smallest cross-sectional, the length difference of the length windowed in section storehouse and old storage battery smallest cross-sectional is 1-5mm, the width windowed in section storehouse is less than the width of old storage battery smallest cross-sectional, the width differential of the width windowed in section storehouse and old storage battery smallest cross-sectional is 1-5mm, section is provided with buffer channel on the left of storehouse, buffer channel 26 top is provided with hole on passage, buffer channel bottom is provided with groove 16 under passage lower opening and passage, on passage, hole is provided with the baffle plate 1 in hole on penetrating via, baffle plate 1 is fixed on the push rod of cylinder 3 13, cylinder 3 13 is fixedly connected with frame 18, under passage, the cross section of groove 16 is equal with cross section, hole on passage, passage lower opening is provided with the baffle plate 2 23 of penetrating via lower opening, baffle plate 2 23 is fixed on the push rod of cylinder 4 24, cylinder 4 24 is fixedly connected with frame 18, vibrations Tuo Qian mechanism comprises the de-plumbous passage 3 being arranged on buffer channel 26 left part, de-plumbous clamping plate 1 are provided with in de-plumbous passage 3, be distributed in the buffering cotton 2 of de-plumbous clamping plate 1 periphery, de-plumbous clamping plate 1 are connected with de-plumbous passage 3 by buffering cotton 2, de-plumbous clamping plate 1 are fixedly connected with drive block 5, drive block 5 is fixedly connected with high-frequency vibration motor 6, drive block 5 is connected with frame 18 by bumper ring 4, de-plumbous passage 3 bottom is provided with windows greatly 29, buffering cotton 2 is provided with equal with 29 sizes of windowing greatly, identical buffering cotton windows 28 in position, de-plumbous clamping plate 1 are provided with equal with cushioning cotton 28 sizes of windowing, the identical clamping plate in position window 27, section collection box 25 be positioned at section storehouse below, section collection box 25 by section storehouse window 22 with cut into slices storehouse be communicated with, lead collection box 30 is positioned at below de-plumbous passage 3, section collection box 25 left side, lead collection box 30 by windowing greatly 29, buffering cotton windows 28, clamping plate are windowed 27 is communicated with de-plumbous passage 3, lead collection box 30 and collection box 25 of cutting into slices completely isolated, plastics casing collection box 31 is positioned on the left of lead collection box 30, and plastics casing collection box 31 is completely isolated with lead collection box 31, and de-plumbous passage 3 end is uncovered, and this uncovered area is enough to guarantee that old storage battery passes through, plastics casing collection box 31 top is provided with opening.Lower track lowering 14 right side wall top is provided with scarp 13, and the cross-sectional length size of buffer channel 26 equals the height after old storage battery otch; The angle of inclination on described scarp is 10 °.
The principle of work of the retrieving arrangement of this old storage battery lead is: during use, old storage battery is erected on transmission belt, entirely fit with transmission belt and contact in the surface that now on old storage battery, area is minimum, old storage battery moves right along with moving of belt, under the constraint of belt tapered channels, along belt guide plate adjustment position, eventually through belt tapered channels; Because the terminal end width size of belt tapered channels is equal with the length scale of the most minor face of old storage battery, the oblique rail of blanking is arrived exactly by belt tapered channels end old storage battery out, the old storage battery entering the oblique rail of blanking accelerates to fall into lower track lowering under gravity, nationality, by the constraint of lower track lowering right side wall, is avoided old storage battery to fall and lower track lowering; Old storage battery falls in section storehouse in lower track lowering, cylinder three in buffer channel on the left of section storehouse is inflated with cylinder four, cylinder three is released with the push rod of cylinder four simultaneously, baffle plate one moves down under the promotion of cylinder three push rod until the end of baffle plate one contacts with groove under passage, and baffle plate two moves up under the promotion of cylinder four push rod until the end of baffle plate two and buffer channel upper contact; Now, old storage battery is completely fixed in section storehouse, and cylinder two is inflated, and cylinder two push rod promotes cutting knife and is moved to the left, and cutting knife cuts out opening in the bottom of old storage battery; After cutting knife cuts opening, there is old storage battery and cutting knife in section storehouse simultaneously, makes to be in shrink-fit in section storehouse, and the plastic sheet that cutting knife is cut is windowed via section storehouse and extruded section storehouse and fall to section collection box under the extruding of cutting knife; After cutting plastic sheet, cylinder two, cylinder three, cylinder four are exitted, and cutting knife, baffle plate one, baffle plate two are regained; Cylinder one is inflated, and the push rod of cylinder one promotes pusher dish and is moved to the left, and pusher dish promotes old storage battery in section storehouse and moves to left, and enters buffer channel, and is positioned on the left of baffle plate one; Next Geju City storage battery is according to above-mentioned steps, and finally enter buffer channel, promote last Geju City storage battery and be moved to the left, after abundant old storage battery enters buffer channel, former Geju City storage battery arrives de-plumbous passage, and is shaken off by the plastics casing of opening by lead under the vibrations of high-frequency electric machines; After lead shakes off, window, clamping plate are windowed by windowing greatly, cushioning lead drop to lead collection box by cotton, and plastics casing drops to plastics casing collection box by taking off plumbous channel end.
Utilize cutting knife on storage battery plastic casing, cut out an otch, and the storage battery cutting out otch is entered de-plumbous passage, the buffering directly contacted with de-plumbous passage is provided with cotton in de-plumbous passage, by cushioning the de-plumbous clamping plate of cotton and de-plumbous passage indirect contact, high-frequency electric machines is connected with de-plumbous Boards wall, storage battery in de-plumbous clamping plate shakes along with the vibrations of high-frequency electric machines, by high-frequency vibration, the lead in storage battery plastic casing is separated with plastic casing, lead after separation is from windowing greatly, buffering cotton is windowed and falls to lead collection box, plastic casing falls into plastics casing collection box via de-plumbous channel end, the old storage battery of workman's hand disassembly is substituted by aforementioned mechanical arrangement, cost of labor can be reduced, effective raising removal efficiency, greatly reduce the generation of the old storage battery mishap of dismounting, eliminate the work of lead and plastic casing manual sort simultaneously, improve the efficiency that old storage battery lead reclaims further.
The present invention's hyperbranched resin used synthesizes in accordance with the following steps:
(1) in the protection of inert atmosphere with under stirring, in molar ratio, by the 3-methylpentane-2 of 1 part, 3 of 4-glycol and 1 part, 5-bis-(methylol) phenylformic acid is added in encloses container, then add the vitriol oil as catalyzer, at 170 DEG C, stir the matrix G1 obtaining hyperbranched resin after there is condensation reaction in 2 hours;
(2) then continue to add 1 part 3,5-bis-(methylol) phenylformic acid and the vitriol oil at the matrix G1 of above-mentioned hyperbranched resin, stir 2 hours at 170 DEG C, then this step is repeated 6 times, obtain the matrix G7 of hyperbranched resin;
(3) then the temperature of reaction of step (2) is down to 80 DEG C, adds excessive epoxy chloropropane and aqueous sodium hydroxide solution, react washing, suction filtration after 3 hours, obtain described hyperbranched resin.
The present invention's end group used is the hydroxyl value of the linear polyester of carboxyl is 120 ~ 180mgKOH/g, and weight-average molecular weight is 10000 ~ 30000.
The preparation method of heat-resistant inks of the present invention is the common method in ink manufacturing technology field, is not described in detail at this.
embodiment 1
A kind of heat-resistant inks, is made up of the component of following parts by weight:
End group is the linear polyester 18 parts of carboxyl; Hyperbranched resin 20 parts; Ethylene glycol diglycidylether 3 parts; Polypropylene glycol diglycidyl ether 3 parts; Isocyanuric acid three-glycidyl ester 4 parts; 12 parts, calcium carbonate; 15 parts, aluminium hydroxide; Carbon black 10 parts; Defoamer 1 part; Flow agent 1 part; Antioxidant 1 part; 13 parts, acetone; Triethylene tetramine 2 parts.
Through testing the solidification value of known the present embodiment at 90 DEG C.
During use, in 90-100 DEG C, quick-drying solidifies 2 minutes.Build controls at 25-30 μm.Then 100 DEG C of slakings 60 minutes in convection oven.
Performance test methods and result as follows:
Prebake conditions (75 DEG C): 25 minutes.After prebake conditions, ink is tack-free.
Rear baking (180 DEG C): 60 minutes.After rear baking, ink non yellowing.
Sticking power (GB/T9286-1998): 1 grade.
Hardness (GB/T6739-2006): 6H.
Glossiness (GB/T1743-1979): 79.
Welding resistance performance (288 DEG C of solder furnace dipping 10s, three times): ink without xanthochromia, without explosion, without coming off, non-soldering tin enters phenomenon.
Through thermogravimetric test, the heat resisting temperature of the solder mask of the present embodiment is greater than 400 DEG C.
embodiment 2
A kind of heat-resistant inks, is made up of the component of following parts by weight:
End group is the linear polyester 28 parts of carboxyl; Hyperbranched resin 12 parts; Ethylene glycol diglycidylether 2 parts; Polypropylene glycol diglycidyl ether 4 parts; Isocyanuric acid three-glycidyl ester 6 parts; 20 parts, barium sulfate; 10 parts, aluminium hydroxide; Carbon black 13 parts; Defoamer 1 part; Flow agent 1 part; Antioxidant 1 part; 1-Methoxy-2-propyl acetate 18 parts; Triethylene tetramine 3 parts.
Through testing the solidification value of known the present embodiment at 90 DEG C.
During use, in 90-100 DEG C, quick-drying solidifies 2 minutes.Build controls at 25-30 μm.Then 100 DEG C of slakings 60 minutes in convection oven.
Performance test methods and result as follows:
Prebake conditions (75 DEG C): 25 minutes.After prebake conditions, ink is tack-free.
Rear baking (180 DEG C): 60 minutes.After rear baking, ink non yellowing.
Sticking power (GB/T9286-1998): 1 grade.
Hardness (GB/T6739-2006): 6H.
Glossiness (GB/T1743-1979): 77.
Welding resistance performance (288 DEG C of solder furnace dipping 10s, three times): ink without xanthochromia, without explosion, without coming off, non-soldering tin enters phenomenon.
Through thermogravimetric test, the heat resisting temperature of the solder mask of the present embodiment is greater than 400 DEG C.
embodiment 3
A kind of heat-resistant inks, is made up of the component of following parts by weight:
End group is the linear polyester 16 parts of carboxyl; Hyperbranched resin 23 parts; Ethylene glycol diglycidylether 4 parts; Polypropylene glycol diglycidyl ether 2 parts; Isocyanuric acid three-glycidyl ester 3 parts; 15 parts, barium sulfate; 15 parts, calcium carbonate; Carbon black 13 parts; Defoamer 1 part; Flow agent 1 part; Antioxidant 1 part; Ethylene glycol ethyl ether 2 parts; Triethylene tetramine 1 part.
Through testing the solidification value of known the present embodiment at 90 DEG C.
During use, in 90-100 DEG C, quick-drying solidifies 2 minutes.Build controls at 25-30 μm.Then 100 DEG C of slakings 60 minutes in convection oven.
Performance test methods and result as follows:
Prebake conditions (75 DEG C): 25 minutes.After prebake conditions, ink is tack-free.
Rear baking (180 DEG C): 60 minutes.After rear baking, ink non yellowing.
Sticking power (GB/T9286-1998): 1 grade.
Hardness (GB/T6739-2006): 6H.
Glossiness (GB/T1743-1979): 81.
Welding resistance performance (288 DEG C of solder furnace dipping 10s, three times): ink without xanthochromia, without explosion, without coming off, non-soldering tin enters phenomenon.
Through thermogravimetric test, the heat resisting temperature of the solder mask of the present embodiment is greater than 400 DEG C.
comparative example 1
A kind of heat-resistant inks, is made up of the component of following parts by weight:
End group is the linear polyester 18 parts of carboxyl; Ethylene glycol diglycidylether 3 parts; Polypropylene glycol diglycidyl ether 3 parts; Isocyanuric acid three-glycidyl ester 4 parts; 12 parts, calcium carbonate; 15 parts, aluminium hydroxide; Carbon black 10 parts; Defoamer 1 part; Flow agent 1 part; Antioxidant 1 part; 13 parts, acetone; Triethylene tetramine 2 parts.
Through testing the solidification value of known the present embodiment at 130 DEG C.
During use, in 130-150 DEG C, quick-drying solidifies 2 minutes.Build controls at 25-30 μm.Then 140 DEG C of slakings 60 minutes in convection oven.
Performance test methods and result as follows:
Prebake conditions (75 DEG C): 25 minutes.After prebake conditions, ink is tack-free.
Rear baking (180 DEG C): 60 minutes.After rear baking, ink starts xanthochromia.
Sticking power (GB/T9286-1998): 3 grades.
Hardness (GB/T6739-2006): 4H.
Glossiness (GB/T1743-1979): 68.
Welding resistance performance (288 DEG C of solder furnace dipping 10s, three times): start to come off, find that scolding tin enters phenomenon.
Through thermogravimetric test, the heat resisting temperature of the solder mask of the present embodiment is 270 DEG C.
comparative example 2
A kind of heat-resistant inks, is made up of the component of following parts by weight:
Hyperbranched resin 20 parts; Ethylene glycol diglycidylether 3 parts; Polypropylene glycol diglycidyl ether 3 parts; Isocyanuric acid three-glycidyl ester 4 parts; 12 parts, calcium carbonate; 15 parts, aluminium hydroxide; Carbon black 10 parts; Defoamer 1 part; Flow agent 1 part; Antioxidant 1 part; 13 parts, acetone; Triethylene tetramine 2 parts.
Through testing the solidification value of known the present embodiment at 110 DEG C.
During use, in 110-130 DEG C, quick-drying solidifies 2 minutes.Build controls at 25-30 μm.Then 120 DEG C of slakings 60 minutes in convection oven.
Performance test methods and result as follows:
Prebake conditions (75 DEG C): 25 minutes.After prebake conditions, ink is tack-free.
Rear baking (180 DEG C): 60 minutes.After rear baking, ink non yellowing.
Sticking power (GB/T9286-1998): 2 grades.
Hardness (GB/T6739-2006): 5H.
Glossiness (GB/T1743-1979): 45.
Welding resistance performance (288 DEG C of solder furnace dipping 10s, three times): start to come off, find that scolding tin enters phenomenon.
Through thermogravimetric test, the heat resisting temperature of the solder mask of the present embodiment is 300 DEG C.
comparative example 3
A kind of heat-resistant inks, is made up of the component of following parts by weight:
End group is the linear polyester 18 parts of carboxyl; Hyperbranched resin 20 parts; Ethylene glycol diglycidylether 3 parts; 12 parts, calcium carbonate; 15 parts, aluminium hydroxide; Carbon black 10 parts; Defoamer 1 part; Flow agent 1 part; Antioxidant 1 part; 13 parts, acetone; Triethylene tetramine 2 parts.
Through testing the solidification value of known the present embodiment at 150 DEG C.
During use, in 150-170 DEG C, quick-drying solidifies 2 minutes.Build controls at 25-30 μm.Then 160 DEG C of slakings 60 minutes in convection oven.
Performance test methods and result as follows:
Prebake conditions (75 DEG C): 25 minutes.After prebake conditions, ink is tack-free.
Rear baking (180 DEG C): 60 minutes.After rear baking, ink non yellowing.
Sticking power (GB/T9286-1998): 4 grades.
Hardness (GB/T6739-2006): 5H.
Glossiness (GB/T1743-1979): 50.
Welding resistance performance (288 DEG C of solder furnace dipping 10s, three times): start to come off, find that scolding tin enters phenomenon.
Through thermogravimetric test, the heat resisting temperature of the solder mask of the present embodiment is 350 DEG C.
Known by the test data of above-described embodiment and comparative example, heat-resistant inks of the present invention become refractory layer to have the excellent feature such as thermotolerance, soldering resistance, yellowing resistance; So, the de-plumbous clamping plate covered by this refractory layer, de-plumbous passage, bumper ring, drive block and buffering passage capable of being adapt to the comparatively rough operating mode of tripping device enough completely, the high hot temperature degree produced under can bearing rough operating mode, ensure that tripping device can long time running sustainedly and stably, improve stability and the reliability of tripping device.
Finally should be noted that; above embodiment illustrates technical scheme of the present invention; but not limiting the scope of the invention; although done to explain to the present invention with reference to preferred embodiment; those of ordinary skill in the art is to be understood that; can modify to technical scheme of the present invention or equivalent replacement, and not depart from essence and the scope of technical solution of the present invention.
Claims (10)
1. the tripping device of an old storage battery lead, it is characterized in that, comprise frame, be fixed on the old storage battery feed mechanism above frame, the old storage battery notching mechanism be connected with old storage battery feed mechanism, the vibrations Tuo Qian mechanism be connected with old storage battery notching mechanism, be positioned at the section collection box, lead collection box and the plastics casing collection box that shake below Tuo Qian mechanism;
Described old storage battery feed mechanism comprises belt motion-work wheel, belt slave wheel, be sleeved on the transmission belt on belt motion-work wheel and belt slave wheel, be positioned at two belt guide plates above transmission belt, two belt guide plate composition belt tapered channels, the terminal end width size of belt tapered channels is equal with the length scale of the most minor face of old storage battery, transmission belt right is also provided with the oblique rail of blanking, the oblique rail of blanking comprises two side levers be obliquely installed, the cross bar be connected with two side levers and two the oblique rail guide plates be positioned at above side lever, guide plate is fixedly connected with side lever, two oblique rail guide plates form the straight passage of oblique rail, the width size of oblique rail is straight passage equals the terminal end width size of belt tapered channels, cross bar is rotatably connected on side lever, the oblique rail of blanking is connected with lower track lowering, the cross section of lower track lowering is equal with the smallest cross-sectional of old storage battery,
Described old storage battery notching mechanism comprises and is positioned at bottom lower track lowering, and the section storehouse that volume is equal with old storage battery volume, the right side wall in section storehouse is provided with hole and right side wall lower opening on right side wall, on right side wall, hole is provided with the pusher dish running through hole on right side wall, described pusher dish is fixed on the push rod of cylinder one, cylinder one is fixedly connected with frame, right side wall lower opening is provided with the cutting knife running through right side wall lower opening, cutting knife is fixed on the push rod of cylinder two, cylinder two is fixedly connected with frame, section bottom, storehouse is provided with section storehouse and windows, section storehouse is windowed as rectangle, the length windowed in section storehouse is less than the length of old storage battery smallest cross-sectional, the length difference of the length windowed in section storehouse and old storage battery smallest cross-sectional is 1-5mm, the width windowed in section storehouse is less than the width of old storage battery smallest cross-sectional, the width differential of the width windowed in section storehouse and old storage battery smallest cross-sectional is 1-5mm, section is provided with buffer channel on the left of storehouse, buffer channel top is provided with hole on passage, buffer channel bottom is provided with groove under passage lower opening and passage, on passage, hole is provided with the baffle plate one in hole on penetrating via, baffle plate one is fixed on the push rod of cylinder three, cylinder three is fixedly connected with frame, under passage, the cross section of groove is equal with cross section, hole on passage, passage lower opening is provided with the baffle plate two of penetrating via lower opening, baffle plate two is fixed on the push rod of cylinder four, cylinder four is fixedly connected with frame,
Described vibrations Tuo Qian mechanism comprises the de-plumbous passage being arranged on buffer channel left part, de-plumbous clamping plate are provided with in de-plumbous passage, the buffering being distributed in de-plumbous clamping plate periphery is cotton, de-plumbous clamping plate are cotton and de-plumbous expanding channels by buffering, de-plumbous clamping plate are fixedly connected with drive block, drive block is fixedly connected with high-frequency vibration motor, drive block is connected with frame by bumper ring, de-plumbous beneath galleries is provided with windows greatly, buffering cotton is provided with equal with large window size, identical buffering cotton is windowed in position, de-plumbous clamping plate are provided with equal with cushioning cotton window size, the identical clamping plate in position are windowed,
Section collection box is positioned at below section storehouse, and section collection box is windowed by storehouse of cutting into slices and to be communicated with storehouse of cutting into slices;
Lead collection box is positioned at below de-plumbous passage, the section collection box left side, and lead collection box by windowing greatly, cushioning, window, clamping plate are windowed and de-plumbous channel connection by cotton, and lead collection box is completely isolated with section collection box;
Plastics casing collection box is positioned on the left of lead collection box, plastics casing collection box and lead collection box completely isolated, de-plumbous channel end is uncovered, and this uncovered area is enough to guarantee that old storage battery passes through; Plastics casing collection box top is provided with opening;
The surface of de-plumbous clamping plate, de-plumbous passage, bumper ring, drive block and buffer channel is coated with refractory layer, and described refractory layer comprises heat-resistant inks, and heat-resistant inks is made up of the component of following parts by weight:
End group is the linear polyester 15 ~ 30 parts of carboxyl; Hyperbranched resin 10 ~ 25 parts; Reactive thinner 5 ~ 20 parts; Mineral filler 10 ~ 35 parts; Pigment 0 ~ 15 part; Functional agent 0 ~ 8 part; Solvent 0 ~ 20 part; 1 ~ 3 part, solidifying agent; Described hyperbranched resin synthesizes in accordance with the following steps:
(1) in the protection of inert atmosphere with under stirring, in molar ratio, by the 3-methylpentane-2 of 1 part, 3 of 4-glycol and 1 part, 5-bis-(methylol) phenylformic acid is added in encloses container, then add the vitriol oil as catalyzer, at 160 ~ 180 DEG C, stir the matrix G1 obtaining hyperbranched resin after there is condensation reaction in 1 ~ 2 hour;
(2) then continue to add 1 part 3,5-bis-(methylol) phenylformic acid and the vitriol oil at the matrix G1 of above-mentioned hyperbranched resin, stir 1 ~ 2 hour at 160 ~ 180 DEG C, then this step is repeated 6 times, obtain the matrix G7 of hyperbranched resin;
(3) then the temperature of reaction of step (2) is down to 80 DEG C, adds excessive epoxy chloropropane and aqueous sodium hydroxide solution, react washing, suction filtration after 3 hours, obtain described hyperbranched resin.
2. the retrieving arrangement of old storage battery lead according to claim 1, is characterized in that, described lower track lowering right side wall top is provided with scarp; The cross-sectional length size of described buffer channel equals the height after old storage battery otch.
3. the retrieving arrangement of old storage battery lead according to claim 1, is characterized in that, the angle of inclination on described scarp is 1-10 °.
4. the retrieving arrangement of old storage battery lead according to claim 1, is characterized in that, the matrix G7 of the hyperbranched resin obtained in described hyperbranched resin synthesis step (2) contains 100 ~ 118 terminal hydroxy group.
5. the retrieving arrangement of old storage battery lead according to claim 1, is characterized in that, end group is the hydroxyl value of the linear polyester of carboxyl is 120 ~ 180mgKOH/g, and weight-average molecular weight is 10000 ~ 30000.
6. the retrieving arrangement of old storage battery lead according to claim 1, is characterized in that, described reactive thinner is the mixture of ethylene glycol diglycidylether, polypropylene glycol diglycidyl ether and isocyanuric acid three-glycidyl ester.
7. the retrieving arrangement of old storage battery lead according to claim 1, is characterized in that, described mineral filler is at least one in calcium carbonate, aluminium hydroxide, barium sulfate, titanium dioxide.
8. the retrieving arrangement of old storage battery lead according to claim 1, is characterized in that, described functional agent is at least one in defoamer, flow agent, antioxidant.
9. the retrieving arrangement of old storage battery lead according to claim 1, is characterized in that, described Solvents Solvent is at least one in alcoholic solvent, esters solvent, ketones solvent, solvent of ether ester type.
10. the retrieving arrangement of old storage battery lead according to claim 1, is characterized in that, described solidifying agent is amine curing agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510691047.1A CN105199560A (en) | 2015-10-23 | 2015-10-23 | Separation device of lead block of waste storage battery |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510691047.1A CN105199560A (en) | 2015-10-23 | 2015-10-23 | Separation device of lead block of waste storage battery |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105199560A true CN105199560A (en) | 2015-12-30 |
Family
ID=54947527
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510691047.1A Pending CN105199560A (en) | 2015-10-23 | 2015-10-23 | Separation device of lead block of waste storage battery |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105199560A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102585607A (en) * | 2012-03-28 | 2012-07-18 | 成都多吉昌新材料有限公司 | Solder mask ink composite and method for manufacturing solder mask layer of light-emitting diode (LED) circuit board |
| CN103030799A (en) * | 2013-01-05 | 2013-04-10 | 哈尔滨玻璃钢研究院 | Ternary core end epoxy hyperbranched polyester and preparation method thereof |
| CN203598916U (en) * | 2013-12-05 | 2014-05-21 | 魏兴虎 | Lead and plastic separating device and lead-acid battery fragmentized separation system comprising same |
| CN103881473A (en) * | 2014-04-01 | 2014-06-25 | 恒昌涂料（惠阳）有限公司 | Yellowing-resistant photosensitive solder resist ink and preparation method thereof |
| CN204685649U (en) * | 2015-05-29 | 2015-10-07 | 李志科 | A kind of waste and old accumulator jar disassemble machine |
-
2015
- 2015-10-23 CN CN201510691047.1A patent/CN105199560A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102585607A (en) * | 2012-03-28 | 2012-07-18 | 成都多吉昌新材料有限公司 | Solder mask ink composite and method for manufacturing solder mask layer of light-emitting diode (LED) circuit board |
| CN103030799A (en) * | 2013-01-05 | 2013-04-10 | 哈尔滨玻璃钢研究院 | Ternary core end epoxy hyperbranched polyester and preparation method thereof |
| CN203598916U (en) * | 2013-12-05 | 2014-05-21 | 魏兴虎 | Lead and plastic separating device and lead-acid battery fragmentized separation system comprising same |
| CN103881473A (en) * | 2014-04-01 | 2014-06-25 | 恒昌涂料（惠阳）有限公司 | Yellowing-resistant photosensitive solder resist ink and preparation method thereof |
| CN204685649U (en) * | 2015-05-29 | 2015-10-07 | 李志科 | A kind of waste and old accumulator jar disassemble machine |
Non-Patent Citations (3)
| Title |
|---|
| CCTV-10: "《我爱发明》", 18 August 2015 * |
| 李和平: "《胶黏剂》", 31 May 2005, 化学工业出版社 * |
| 李子东: "《胶黏剂助剂》", 30 June 2009, 化学工业出版社 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US11162040B2 (en) | Method for preparing low-sulfur biodiesel | |
| EP3348596A8 (en) | Method for economical producing of resin composition comprising polyalkylene carbonate with improved thermal stability and processability | |
| CN204997144U (en) | Novel high -efficient aluminum alloy stick saw cuts device | |
| CN108631017B (en) | Method for recovering electrolyte of waste lithium ion battery | |
| CN105199560A (en) | Separation device of lead block of waste storage battery | |
| CN217292481U (en) | Artificial leather cutting equipment | |
| CN105140587B (en) | A kind of retracting device for old storage battery lead | |
| CN202964236U (en) | Displacement device for processing lock core | |
| CN114012957A (en) | Pressing device for glass fiber board production and use method thereof | |
| CN105001388A (en) | Preparation method for vegetable oil modified rosin phenolic resin | |
| CN109352299A (en) | Discarded crystal silicon solar battery component aluminium frame automatic dismantling method and apparatus | |
| CN207272441U (en) | A kind of battery peeling seperator | |
| CN101591453A (en) | A kind of production method of environment-friendly rubber extending oil | |
| CN201030374Y (en) | Ring-pull can metal separating recovery machine | |
| CN210361449U (en) | Linear reciprocating type medicine cutting machine | |
| CN209532272U (en) | A kind of sawing structure being servo-actuated sawing machine for weather strip for automobile | |
| CN204148617U (en) | Chip recycling formula aluminum profile cutting machine | |
| CN207171053U (en) | A kind of aluminium base plate shearing machine | |
| CN206597970U (en) | The online saw cutting system of aluminium section bar | |
| CN112125780B (en) | Device for reducing water content of solid neopentyl glycol and dehydration method | |
| CN209288647U (en) | Discarded crystal silicon solar battery component aluminium frame automatic disassembling device | |
| CN103358348A (en) | Double-station full-automatic processing device for screw holes in junction box | |
| CN107234289A (en) | A kind of aluminium base plate shearing machine | |
| CN105058491A (en) | Carbon hollow bar machining device with waste collecting function | |
| CN220612073U (en) | Aluminum sheet punching press waste recycling collection device |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20151230 |