CN105199232A - Polyolefin resin composition - Google Patents

Polyolefin resin composition Download PDF

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Publication number
CN105199232A
CN105199232A CN201510727116.XA CN201510727116A CN105199232A CN 105199232 A CN105199232 A CN 105199232A CN 201510727116 A CN201510727116 A CN 201510727116A CN 105199232 A CN105199232 A CN 105199232A
Authority
CN
China
Prior art keywords
resin composition
parts
polyolefin resin
polyolefine resin
graft polymer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510727116.XA
Other languages
Chinese (zh)
Inventor
刘姝
王晓宁
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Liaoning Shihua University
Original Assignee
Liaoning Shihua University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Liaoning Shihua University filed Critical Liaoning Shihua University
Priority to CN201510727116.XA priority Critical patent/CN105199232A/en
Publication of CN105199232A publication Critical patent/CN105199232A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/12Polypropene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/08Copolymers of ethene
    • C08L23/0807Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
    • C08L23/0815Copolymers of ethene with aliphatic 1-olefins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16Fibres; Fibrils

Abstract

The invention provides polyolefin resin composition. The polyolefin resin composition comprises raw materials in parts by weight as follows: 100 parts of polyolefin resin, 15-30 parts of graft polymer resin, 1-10 parts of wholly aromatic polyester fiber and 1-5 parts of lignocellulose fiber, wherein the graft polymer resin is obtained by grafting unsaturated carboxylic compounds to an olefin homopolymer or two different olefin copolymers. The polyolefin resin composition has the benefits as follows: the polyolefin resin composition has excellent mechanical strength and is green and environment-friendly, woods can be recycled and waste recycling is promoted.

Description

A kind of polyolefine resin composition
Technical field
The invention belongs to chemical material technical field, especially relate to a kind of polyolefine resin composition.
Background technology
Polyolefine has that relative density is little, chemical proofing, water-tolerant; The features such as good physical strength, electrical insulating property.Can be used for film, tubing, sheet material, various moulded products, electric wire etc.At agricultural, packaging, electronics, electrically, have been widely used in automobile, machinery, daily use Sundry goods etc.Meanwhile, due to abundant raw material, cheap, easy machine-shaping, therefore high comprehensive performance is that a class output is maximum, application macromolecular material very widely.Wherein important with polyethylene, polypropylene.
China's polyolefin plastics output is large, and purposes is wide, occupies very consequence.Can change more polyolefinic performances by adding auxiliary agent, expansive approach scope, improves processibility, and a kind of physical strength is excellent, and the polyolefine resin composition of environmental protection awaits further research and development.
Summary of the invention
The object of this invention is to provide a kind of polyolefine resin composition, particularly a kind of impact resistance and the excellent polyolefine resin composition of resistance to tension.
Technical scheme of the present invention is: a kind of polyolefine resin composition of the present invention, comprises the raw material of following weight part:
Polyolefin resin 100 parts
Graft polymer resin 15-30 part that grafting unsaturated carboxylic acid compounds obtains on olefin homo or two kinds of different olefin copolymers
Full aromatic polyester fiber 1-10 part
Lignocellulose fiber 1-5 part
Preferably, also additive can be added in described polyolefine resin composition.
Preferably, described additive is one or more in antioxidant, UV light absorber, photostabilizer, fire retardant, compatilizer.
The advantage that the present invention has and positively effect are:
1, the adding of synthon and natural fiber, make polyolefine resin composition physical strength of the present invention excellent, especially resistance to impact shock and tensile strength excellent.
2, natural fiber can extract from recovery timber, promotes refuse reclamation, environmental protection.
3, the adding of various additive, workability and the physicals of self of composition can be improved.
Embodiment
Embodiment 1:
A kind of polyolefine resin composition of the present embodiment, comprises following effective constituent:
Acrylic resin 100 parts
The graft polymer resin 15 parts that graft acrylic acid obtains on polypropylene
Full aromatic polyester fiber 10 parts
Lignocellulose fiber 3 parts.
The present embodiment also can add in antioxidant, UV light absorber, photostabilizer, fire retardant, compatilizer one or more.
Embodiment 2:
A kind of polyolefine resin composition of the present embodiment, comprises following effective constituent:
Polyvinyl resin 100 parts
The graft polymer resin 30 parts that obtains of grafted maleic on the polyethylene
Full aromatic polyester fiber 5 parts
Lignocellulose fiber 3 parts.
The present embodiment also can add in antioxidant, UV light absorber, photostabilizer, fire retardant, compatilizer one or more.
Embodiment 3:
A kind of polyolefine resin composition of the present embodiment, comprises following effective constituent:
Alpha-olefin-random copolymer of propylene 100 parts
The graft polymer resin 20 parts that obtains of grafted maleic on the polyethylene
Full aromatic polyester fiber 8 parts
Lignocellulose fiber 2 parts.
The present embodiment also can add in antioxidant, UV light absorber, photostabilizer, fire retardant, compatilizer one or more.
Embodiment 4:
A kind of polyolefine resin composition of the present embodiment, comprises following effective constituent:
Second hydrocarbon-random copolymer of propylene 100 parts
The graft polymer resin 30 parts that obtains of graft acrylic acid on the polyethylene
Full aromatic polyester fiber 10 parts
Lignocellulose fiber 2 parts.
The present embodiment also can add in antioxidant, UV light absorber, photostabilizer, fire retardant, compatilizer one or more.
Above four embodiments of the present invention have been described in detail, but described content being only preferred embodiment of the present invention, can not being considered to for limiting practical range of the present invention.All equalizations done according to the present patent application scope change and improve, and all should still belong within patent covering scope of the present invention.

Claims (3)

1. a polyolefine resin composition, is characterized in that: the raw material comprising following weight part:
Polyolefin resin 100 parts
Graft polymer resin 15-30 part that grafting unsaturated carboxylic acid compounds obtains on olefin homo or two kinds of different olefin copolymers
Full aromatic polyester fiber 1-10 part
Lignocellulose fiber 1-5 part.
2. a kind of polyolefine resin composition according to claim 1, is characterized in that: also can add additive in described polyolefine resin composition.
3. a kind of polyolefine resin composition according to claim 2, is characterized in that: described additive is one or more in antioxidant, UV light absorber, photostabilizer, fire retardant, compatilizer.
CN201510727116.XA 2015-10-28 2015-10-28 Polyolefin resin composition Pending CN105199232A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510727116.XA CN105199232A (en) 2015-10-28 2015-10-28 Polyolefin resin composition

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510727116.XA CN105199232A (en) 2015-10-28 2015-10-28 Polyolefin resin composition

Publications (1)

Publication Number Publication Date
CN105199232A true CN105199232A (en) 2015-12-30

Family

ID=54947210

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201510727116.XA Pending CN105199232A (en) 2015-10-28 2015-10-28 Polyolefin resin composition

Country Status (1)

Country Link
CN (1) CN105199232A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107523083A (en) * 2017-10-11 2017-12-29 安徽顺彤包装材料有限公司 A kind of fire-retardant packaging material and preparation method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1026197A1 (en) * 1998-07-17 2000-08-09 Namba Press Works Co., Ltd. Ligneous fibrous filler/olefinic plastic composite sheet for bonding
CA2407880A1 (en) * 2002-10-26 2004-04-26 Mohini M. Sain Process to manufacture high impact natural composites
CN1847296A (en) * 2005-03-14 2006-10-18 住友化学株式会社 Polyolefin resin composition
CN102164989A (en) * 2008-09-30 2011-08-24 三井化学株式会社 Fiber-reinforced resin composition and molded object thereof
CN103571213A (en) * 2013-10-24 2014-02-12 合肥会通新材料有限公司 Polypropylene composite material filled and strengthened by wood fiber for automotive upholstery and preparation method thereof
CN103788488A (en) * 2014-01-24 2014-05-14 南通红石科技发展有限公司 Polypropylene composite material and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1026197A1 (en) * 1998-07-17 2000-08-09 Namba Press Works Co., Ltd. Ligneous fibrous filler/olefinic plastic composite sheet for bonding
CA2407880A1 (en) * 2002-10-26 2004-04-26 Mohini M. Sain Process to manufacture high impact natural composites
CN1847296A (en) * 2005-03-14 2006-10-18 住友化学株式会社 Polyolefin resin composition
CN102164989A (en) * 2008-09-30 2011-08-24 三井化学株式会社 Fiber-reinforced resin composition and molded object thereof
CN103571213A (en) * 2013-10-24 2014-02-12 合肥会通新材料有限公司 Polypropylene composite material filled and strengthened by wood fiber for automotive upholstery and preparation method thereof
CN103788488A (en) * 2014-01-24 2014-05-14 南通红石科技发展有限公司 Polypropylene composite material and preparation method thereof

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
徐晓虹等: "《材料概论》", 31 May 2006 *
杨鸣波等: "《高分子材料手册 上》", 31 July 2009 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107523083A (en) * 2017-10-11 2017-12-29 安徽顺彤包装材料有限公司 A kind of fire-retardant packaging material and preparation method thereof

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Application publication date: 20151230

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