CN105199174A - Red smoke tire and preparation method thereof - Google Patents
Red smoke tire and preparation method thereof Download PDFInfo
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- CN105199174A CN105199174A CN201510746745.7A CN201510746745A CN105199174A CN 105199174 A CN105199174 A CN 105199174A CN 201510746745 A CN201510746745 A CN 201510746745A CN 105199174 A CN105199174 A CN 105199174A
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Abstract
The invention relates to a tire for drift show in a racing track, and in particular discloses a red smoke tire and a preparation method thereof. The red smoke tire is prepared from the following raw materials: solution polymerized styrene-butadiene rubber, cis-polybutadiene rubber, carbon black, aromatic hydrocarbon oil, stearic acid, styrene resin, white carbon black, a silane coupling agent, zinc oxide, an anti-aging agent 4020, microcrystalline wax, a red smoke agent, sulfur, an accelerant DZ and an accelerate TMTD-80. The red smoke tire provided by the invention has the following beneficial effects: 1-(N-methylamino)-9,10-anthraquinone with a relatively low sublimating point is selected as a dye of the red smoke agent to ensure that the tire also can release red smoke when the friction temperature for the tire to rub with a road surface is low; in the whole preparation process, a variety of mixing modes including internal mixer constant-temperature mixing adopted in the first stage of a mixing process, internal mixer variable rotating speed mixing adopted at the first and second stages of the mixing process, mixing mill complementary mixing and the like are used together to ensure that the smoke is generated more uniformly and densely, thereby enabling the tire to have a better smoke effect in use.
Description
(1) technical field
The present invention relates to drift performance tire in a kind of racing track, particularly red smog tire of one and preparation method thereof.
(2) background technology
Red smog tire is drift performance tire in a racing track, when tire is run at high speed, tread surface reaches sublimation temperature, add red smog dyestuff in tire tread to and pavement friction will produce red smog, this is mainly realized by the automobile of rear wheel drive.When tire low-speed running, the red smog had in a small amount at the groove periphery of tire produces, and when tire runs up, when meeting or exceeding the sublimation temperature of red smog dyestuff, red smog can shroud whole vehicle.The generation of the colored smoke of fireworks is because smog dyestuff obtains distillation under close to the high temperature of 400 DEG C, dyestuff is sublimate into colored steam by solid particulate, dyestuff is condensed into colored smoke in an atmosphere, the amount of smog and the addition of dyestuff and produce temperature and be directly proportional, but the abrasion adding dyestuff rear tyre can decline, and tire is when running up, with the temperature produced during pavement friction far below the temperature reached required for dye sublimation, therefore find a kind of sublimation point low and the red smog dyestuff enabling tire play excellent properties can be melted in tire composition well, it is the large difficult point in current Tire production industry, moreover after adding red smog dyestuff, the subject matter faced also has the earth-grasping force of tire, tread wear, rolling resistance, handling, anti-cutting chunking resistance energy, mixing difficulty, curing time and production cost etc., and these all govern the development of red smog tire.
(3) summary of the invention
The present invention is in order to make up the deficiencies in the prior art, provide and a kind ofly can ensure that tire is when the temperature with pavement friction is not high, also can discharge red smog, and can be melted into well in tire composition enable tire play excellent properties, have better haze effect, make that tire traction improves, earth-grasping force promotes, improve tread wear, rolling resistance, handling and anti-cutting chunking resistance energy, reduce mixing difficulty, shorten curing time, the red smog tire decreasing production cost and preparation method thereof.
The present invention is achieved through the following technical solutions:
A kind of red smog tire, be made up of the raw material of following parts by weight:
Solution polymerized butadiene styrene rubber 120-135 part, cis-1,4-polybutadiene rubber 10-20 part, carbon black 85-95 part, aromatic hydrocarbon oil 40-45 part, stearic acid 1-2 part, styrene resin 10-20 part, white carbon black 15-25 part, silane coupling agent 3-5 part, zinc oxide 2-4 part, antioxidant 4020 0.5-1.5 part, Microcrystalline Wax 0.5-1.5 part, red smoke substance 15-25 part, sulphur 2-2.5 part, accelerator DZ 1-3 part, Vulcanization accelerator TMTD-800.5-1 part.
This red smog tire, preferred version is: be made up of the raw material of following parts by weight:
Solution polymerized butadiene styrene rubber 127.5 parts, cis-1,4-polybutadiene rubber 15 parts, carbon black 90 parts, aromatic hydrocarbon oil 42.5 parts, stearic acid 1.5 parts, styrene resin 15 parts, white carbon black 20 parts, silane coupling agent 4 parts, 3 parts, zinc oxide, antioxidant 4020 1 part, Microcrystalline Wax 1 part, red smoke substance 20 parts, 2.2 parts, sulphur, accelerator DZ 2 parts, Vulcanization accelerator TMTD-800.8 parts.
Described red smoke substance is 1-methylamino-anthraquinone.
Described red smoke substance is 1-(N-methylamino-)-9,10-anthraquinones.
Described solution polymerized butadiene styrene rubber is solution polymerized butadiene styrene rubber SSBR4850, and described cis-1,4-polybutadiene rubber is cis-1,4-polybutadiene rubber BR9000, and described carbon black is carbon black N110, and described silane coupling agent is silane coupling agent Si-69.
The preparation method of this red smog tire, comprises the steps:
(1) banburying operation: the solution polymerized butadiene styrene rubber of above-mentioned parts by weight, cis-1,4-polybutadiene rubber, carbon black, aromatic hydrocarbon oil, stearic acid, styrene resin, white carbon black, silane coupling agent are added in Banbury mixer calendering process one section, mixing time is 3-5 minute, obtains one section of mixing rubber master batch; Then add in Banbury mixer by zinc oxide, antioxidant 4020, Microcrystalline Wax, red smoke substance calendering process two sections, mixing time is 2.5-4 minute, obtains two-stage mixing rubber master batch; Finally added in Banbury mixer by sulphur, accelerator DZ and Vulcanization accelerator TMTD-80, mixing time is 2-3 minute, then supplements mixing on a mill until, obtained final sizing material;
(2) roll: using final sizing material obtained for cord two sides adhering step (1) as carcass ply, framework material become can operate, fit, shaping elastomerics;
(3) shaping: by the work in-process of cover tire all parts, comprise tread components, sidewall component, air retaining wall parts, belt component, carcass parts are assembled into green tire on forming machine, be transported to subsequent processing;
(4) sulfuration: installed to by green tire on vulcanizer, obtains finished tire at mould back warp over cure, finally by namely obtaining this red smog tire after the assay was approved.
The beneficial effect of the red smog tire of the present invention and preparation method thereof is: the 1-(N-methylamino-)-9 selecting sublimation point lower, 10-anthraquinone is as red smoke substance dyestuff, ensure that tire is when the temperature with pavement friction is not high, also red smog can be discharged, and can be melted into well in tire composition and enable tire play excellent properties, add 1-(N-methylamino-)-9, the tire that 10-anthraquinone is prepared, initial appearance color is still black, both ensure that the attractive in appearance of tire, be also convenient to the inspection of tire; Red smoke substance 1-(N-methylamino-)-9,10-anthraquinone adds calendering process two sections, in whole preparation process calendering process one section take Banbury mixer constant temperature mixing, mixing at calendering process one section, two sections of Banbury mixer variable speeds, add that mill supplements the multiple mixing mode such as mixing and uses, sizing material, carbon black and red smoke substance 1-(N-methylamino-)-9 can be made, 10-anthraquinone is dispersed in sizing material, make smog produce ground more all even dense, thus make tire in use have better haze effect; By increasing the consumption of cis-1,4-polybutadiene rubber, the consumption reducing solution polymerized butadiene styrene rubber eliminates the loss of tire wear, make tire traction raising, earth-grasping force lifting, improve tread wear, rolling resistance, handling and anti-cutting chunking resistance energy, reduce mixing difficulty, shorten curing time, decrease production cost, make the red smog tire prepared be particularly suitable for performing the place drift match of class.
(4) embodiment
Below in conjunction with embodiment, the invention will be further described, but the present invention is not limited thereto, and the preparation method in embodiment is customary preparation methods, no longer describes in detail.
Embodiment 1:
This red smog tire, be made up of the raw material of following weight:
Solution polymerized butadiene styrene rubber SSBR4850127.5 kilogram, cis-1,4-polybutadiene rubber BR900015 kilogram, carbon black N11090 kilogram, aromatic hydrocarbon oil 42.5 kilograms, stearic acid 1.5 kilograms, styrene resin 15 kilograms, white carbon black 20 kilograms, silane coupling agent Si-694 kilogram, 3 kilograms, zinc oxide, antioxidant 4020 1 kilogram, Microcrystalline Wax 1 kilogram, red smoke substance 1-(N-methylamino-)-9,10-anthraquinone 20 kilograms, 2.2 kilograms, sulphur, accelerator DZ 2 kilograms, Vulcanization accelerator TMTD-800.8 kilograms;
The preparation method of this red smog tire, adopts following steps:
(1) banburying operation: the solution polymerized butadiene styrene rubber SSBR4850 of above-mentioned weight, cis-1,4-polybutadiene rubber BR9000, carbon black N110, aromatic hydrocarbon oil, stearic acid, styrene resin, white carbon black, silane coupling agent Si-69 are added in Banbury mixer calendering process one section, mixing time is 3-5 minute, obtains one section of mixing rubber master batch; Then add in Banbury mixer by zinc oxide, antioxidant 4020, Microcrystalline Wax, red smoke substance 1-(N-methylamino-)-9,10-anthraquinones calendering process two sections, mixing time is 2.5-4 minute, obtains two-stage mixing rubber master batch; Finally added in Banbury mixer by sulphur, accelerator DZ and Vulcanization accelerator TMTD-80, mixing time is 2-3 minute, then supplements mixing on a mill until, obtained final sizing material;
(2) roll: using final sizing material obtained for cord two sides adhering step (1) as carcass ply, framework material become can operate, fit, shaping elastomerics;
(3) shaping: by the work in-process of cover tire all parts, comprise the parts such as tread components, sidewall component, air retaining wall parts, belt component, carcass parts on forming machine, be assembled into green tire, be transported to subsequent processing;
(4) sulfuration: installed to by green tire on vulcanizer, obtains finished tire at mould back warp over cure, finally by namely obtaining this red smog tire after the assay was approved.
In above-mentioned preparation method, sizing material concrete mixed refining process technique compares with traditional sizing material complete processing, has very big-difference: raw material segmentation is added; In whole preparation process calendering process one section take Banbury mixer constant temperature mixing, mixing at calendering process one section, two sections of Banbury mixer variable speeds, add that mill supplements the multiple mixing mode such as mixing and uses; Difference according to plant capacity carries out different production, and concrete technology is as follows:
Red smog tire tread glue one section of mixing milling maternal rubber technique
Red smog tire tread glue two-stage mixing milling maternal rubber technique
Red smog tire tread glue adds sulphur glue calendering process
Embodiment 2:
This red smog tire, be made up of the raw material of following weight:
Solution polymerized butadiene styrene rubber SSBR4850120 kilogram, cis-1,4-polybutadiene rubber BR900010 kilogram, carbon black N11085 kilogram, aromatic hydrocarbon oil 40 kilograms, stearic acid 1 kilogram, styrene resin 10 kilograms, white carbon black 15 kilograms, silane coupling agent Si-693 kilogram, 2 kilograms, zinc oxide, antioxidant 4020 0.5 kilogram, Microcrystalline Wax 0.5 kilogram, red smoke substance 1-(N-methylamino-)-9,10-anthraquinone 15 kilograms, 2 kilograms, sulphur, accelerator DZ 1 kilogram, Vulcanization accelerator TMTD-800.5 kilograms;
The preparation method of red smog tire is with embodiment 1.
Embodiment 3:
This red smog tire, be made up of the raw material of following weight:
Solution polymerized butadiene styrene rubber SSBR4850135 kilogram, cis-1,4-polybutadiene rubber BR900020 kilogram, carbon black N11095 kilogram, aromatic hydrocarbon oil 45 kilograms, stearic acid 2 kilograms, styrene resin 20 kilograms, white carbon black 25 kilograms, silane coupling agent Si-695 kilogram, 4 kilograms, zinc oxide, antioxidant 4020 1.5 kilograms, Microcrystalline Wax 1.5 kilograms, red smoke substance 1-(N-methylamino-)-9,10-anthraquinone 25 kilograms, 2.5 kilograms, sulphur, accelerator DZ 3 kilograms, Vulcanization accelerator TMTD-801 kilograms;
The preparation method of red smog tire is with embodiment 1.
Raw materials usedly in embodiment 1-3 be commercially available prod, no longer describe in detail; In embodiment 1-3 preparation method in detail part is not described in detail, is the known technology of those skilled in the art of the present technique.
Above-mentioned embodiment can not as limiting the scope of the invention, and for those skilled in the art, any alternate modification make embodiment of the present invention or conversion all drop in protection scope of the present invention.
The present invention does not describe part in detail, is the known technology of those skilled in the art of the present technique.
Claims (6)
1. a red smog tire, is characterized in that: be made up of the raw material of following parts by weight:
Solution polymerized butadiene styrene rubber 120-135 part, cis-1,4-polybutadiene rubber 10-20 part, carbon black 85-95 part, aromatic hydrocarbon oil 40-45 part, stearic acid 1-2 part, styrene resin 10-20 part, white carbon black 15-25 part, silane coupling agent 3-5 part, zinc oxide 2-4 part, antioxidant 4020 0.5-1.5 part, Microcrystalline Wax 0.5-1.5 part, red smoke substance 15-25 part, sulphur 2-2.5 part, accelerator DZ 1-3 part, Vulcanization accelerator TMTD-800.5-1 part.
2. the red smog tire of one according to claim 1, is characterized in that: be made up of the raw material of following parts by weight:
Solution polymerized butadiene styrene rubber 127.5 parts, cis-1,4-polybutadiene rubber 15 parts, carbon black 90 parts, aromatic hydrocarbon oil 42.5 parts, stearic acid 1.5 parts, styrene resin 15 parts, white carbon black 20 parts, silane coupling agent 4 parts, 3 parts, zinc oxide, antioxidant 4020 1 part, Microcrystalline Wax 1 part, red smoke substance 20 parts, 2.2 parts, sulphur, accelerator DZ 2 parts, Vulcanization accelerator TMTD-800.8 parts.
3. the red smog tire of one according to claim 1 and 2, is characterized in that: described red smoke substance is 1-methylamino-anthraquinone.
4. the red smog tire of one according to claim 3, is characterized in that: described red smoke substance is 1-(N-methylamino-)-9,10-anthraquinones.
5. the red smog tire of one according to claim 1 and 2, it is characterized in that: described solution polymerized butadiene styrene rubber is solution polymerized butadiene styrene rubber SSBR4850, described cis-1,4-polybutadiene rubber is cis-1,4-polybutadiene rubber BR9000, and described carbon black is carbon black N110, and described silane coupling agent is silane coupling agent Si-69.
6. a preparation method for red smog tire as claimed in claim 1, is characterized in that: comprise the steps:
(1) banburying operation: the solution polymerized butadiene styrene rubber of above-mentioned parts by weight, cis-1,4-polybutadiene rubber, carbon black, aromatic hydrocarbon oil, stearic acid, styrene resin, white carbon black, silane coupling agent are added in Banbury mixer calendering process one section, mixing time is 3-5 minute, obtains one section of mixing rubber master batch; Then add in Banbury mixer by zinc oxide, antioxidant 4020, Microcrystalline Wax, red smoke substance calendering process two sections, mixing time is 2.5-4 minute, obtains two-stage mixing rubber master batch; Finally added in Banbury mixer by sulphur, accelerator DZ and Vulcanization accelerator TMTD-80, mixing time is 2-3 minute, then supplements mixing on a mill until, obtained final sizing material;
(2) roll: using final sizing material obtained for cord two sides adhering step (1) as carcass ply, framework material become can operate, fit, shaping elastomerics;
(3) shaping: by the work in-process of cover tire all parts, comprise tread components, sidewall component, air retaining wall parts, belt component, carcass parts are assembled into green tire on forming machine, be transported to subsequent processing;
(4) sulfuration: installed to by green tire on vulcanizer, obtains finished tire at mould back warp over cure, finally by namely obtaining this red smog tire after the assay was approved.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201510746745.7A CN105199174A (en) | 2015-11-05 | 2015-11-05 | Red smoke tire and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510746745.7A CN105199174A (en) | 2015-11-05 | 2015-11-05 | Red smoke tire and preparation method thereof |
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| CN105199174A true CN105199174A (en) | 2015-12-30 |
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| CN201510746745.7A Pending CN105199174A (en) | 2015-11-05 | 2015-11-05 | Red smoke tire and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106519350A (en) * | 2016-08-24 | 2017-03-22 | 山东新大陆橡胶科技股份有限公司 | Colorful smoke drift tire crown rubber composition and preparation method thereof |
| CN108373556A (en) * | 2018-04-04 | 2018-08-07 | 青岛莱斯帝诺轮胎研发有限公司 | A kind of tread rubber composition of rally racing tire |
| CN108410044A (en) * | 2018-04-04 | 2018-08-17 | 青岛莱斯帝诺轮胎研发有限公司 | A kind of hair coloured silk cigarette tread rubber composition of racing-car tyre |
| CN114133640A (en) * | 2021-12-31 | 2022-03-04 | 四川远星橡胶有限责任公司 | Anti-sideslip fuming rubber material and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1700717A1 (en) * | 2005-03-08 | 2006-09-13 | Kumho Tire Co., Inc. | Tread rubber composition for color smoke tires, tire comprising the same, and method of manufacturing the same |
| CN101747546A (en) * | 2008-12-05 | 2010-06-23 | 韩国轮胎株式会社 | Rubber composition for tire tread |
-
2015
- 2015-11-05 CN CN201510746745.7A patent/CN105199174A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1700717A1 (en) * | 2005-03-08 | 2006-09-13 | Kumho Tire Co., Inc. | Tread rubber composition for color smoke tires, tire comprising the same, and method of manufacturing the same |
| CN101747546A (en) * | 2008-12-05 | 2010-06-23 | 韩国轮胎株式会社 | Rubber composition for tire tread |
Non-Patent Citations (1)
| Title |
|---|
| 辛梅 编译: "有色烟雾轮胎的发展", 《现代橡胶技术》 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106519350A (en) * | 2016-08-24 | 2017-03-22 | 山东新大陆橡胶科技股份有限公司 | Colorful smoke drift tire crown rubber composition and preparation method thereof |
| CN108373556A (en) * | 2018-04-04 | 2018-08-07 | 青岛莱斯帝诺轮胎研发有限公司 | A kind of tread rubber composition of rally racing tire |
| CN108410044A (en) * | 2018-04-04 | 2018-08-17 | 青岛莱斯帝诺轮胎研发有限公司 | A kind of hair coloured silk cigarette tread rubber composition of racing-car tyre |
| CN114133640A (en) * | 2021-12-31 | 2022-03-04 | 四川远星橡胶有限责任公司 | Anti-sideslip fuming rubber material and preparation method thereof |
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Application publication date: 20151230 |