CN103467799A - Solution-polymerized styrene-butadiene tread rubber and mixing process thereof - Google Patents
Solution-polymerized styrene-butadiene tread rubber and mixing process thereof Download PDFInfo
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- CN103467799A CN103467799A CN2013103332894A CN201310333289A CN103467799A CN 103467799 A CN103467799 A CN 103467799A CN 2013103332894 A CN2013103332894 A CN 2013103332894A CN 201310333289 A CN201310333289 A CN 201310333289A CN 103467799 A CN103467799 A CN 103467799A
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- carbon black
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- 229920001971 elastomer Polymers 0.000 title claims abstract description 71
- 239000005060 rubber Substances 0.000 title claims abstract description 71
- 238000002156 mixing Methods 0.000 title claims abstract description 56
- 238000000034 method Methods 0.000 title claims abstract description 30
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 title claims abstract description 25
- 229920003048 styrene butadiene rubber Polymers 0.000 title abstract 3
- 239000002174 Styrene-butadiene Substances 0.000 title abstract 2
- 239000011115 styrene butadiene Substances 0.000 title abstract 2
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 90
- 239000006229 carbon black Substances 0.000 claims abstract description 82
- 230000003712 anti-aging effect Effects 0.000 claims abstract description 49
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 38
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 32
- 244000043261 Hevea brasiliensis Species 0.000 claims abstract description 31
- 229920003052 natural elastomer Polymers 0.000 claims abstract description 31
- 229920001194 natural rubber Polymers 0.000 claims abstract description 31
- 239000000843 powder Substances 0.000 claims abstract description 25
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 21
- 235000021355 Stearic acid Nutrition 0.000 claims abstract description 19
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims abstract description 19
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims abstract description 19
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000008117 stearic acid Substances 0.000 claims abstract description 19
- 239000011787 zinc oxide Substances 0.000 claims abstract description 19
- OCKPCBLVNKHBMX-UHFFFAOYSA-N butylbenzene Chemical compound CCCCC1=CC=CC=C1 OCKPCBLVNKHBMX-UHFFFAOYSA-N 0.000 claims description 52
- 238000002844 melting Methods 0.000 claims description 24
- 230000008018 melting Effects 0.000 claims description 24
- 239000004594 Masterbatch (MB) Substances 0.000 claims description 20
- 229910052717 sulfur Inorganic materials 0.000 claims description 20
- 239000011593 sulfur Substances 0.000 claims description 20
- 235000013312 flour Nutrition 0.000 claims description 18
- 238000003490 calendering Methods 0.000 claims description 17
- 239000003208 petroleum Substances 0.000 claims description 17
- 239000011347 resin Substances 0.000 claims description 17
- 229920005989 resin Polymers 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 12
- AFZSMODLJJCVPP-UHFFFAOYSA-N dibenzothiazol-2-yl disulfide Chemical compound C1=CC=C2SC(SSC=3SC4=CC=CC=C4N=3)=NC2=C1 AFZSMODLJJCVPP-UHFFFAOYSA-N 0.000 claims description 10
- 235000019808 microcrystalline wax Nutrition 0.000 claims description 10
- 239000004200 microcrystalline wax Substances 0.000 claims description 10
- 229920000297 Rayon Polymers 0.000 claims description 8
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 7
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 7
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 7
- ZZMVLMVFYMGSMY-UHFFFAOYSA-N 4-n-(4-methylpentan-2-yl)-1-n-phenylbenzene-1,4-diamine Chemical compound C1=CC(NC(C)CC(C)C)=CC=C1NC1=CC=CC=C1 ZZMVLMVFYMGSMY-UHFFFAOYSA-N 0.000 claims description 3
- 239000005864 Sulphur Substances 0.000 abstract 1
- 239000007767 bonding agent Substances 0.000 abstract 1
- 239000001794 pinus palustris tar oil Substances 0.000 abstract 1
- 235000019241 carbon black Nutrition 0.000 description 67
- 230000032683 aging Effects 0.000 description 11
- 239000000463 material Substances 0.000 description 10
- 239000003963 antioxidant agent Substances 0.000 description 9
- 230000003078 antioxidant effect Effects 0.000 description 9
- 235000006708 antioxidants Nutrition 0.000 description 9
- 239000003292 glue Substances 0.000 description 9
- 235000014692 zinc oxide Nutrition 0.000 description 8
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 7
- 238000004513 sizing Methods 0.000 description 7
- 238000005096 rolling process Methods 0.000 description 6
- 238000012360 testing method Methods 0.000 description 5
- 238000004073 vulcanization Methods 0.000 description 5
- 229910000831 Steel Inorganic materials 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000005336 cracking Methods 0.000 description 3
- 235000012489 doughnuts Nutrition 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- 238000005987 sulfurization reaction Methods 0.000 description 3
- 230000003245 working effect Effects 0.000 description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- 239000000899 Gutta-Percha Substances 0.000 description 2
- 240000000342 Palaquium gutta Species 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 229920000588 gutta-percha Polymers 0.000 description 2
- 230000001939 inductive effect Effects 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- PIBIAJQNHWMGTD-UHFFFAOYSA-N 1-n,3-n-bis(4-methylphenyl)benzene-1,3-diamine Chemical compound C1=CC(C)=CC=C1NC1=CC=CC(NC=2C=CC(C)=CC=2)=C1 PIBIAJQNHWMGTD-UHFFFAOYSA-N 0.000 description 1
- LOVYCUYJRWLTSU-UHFFFAOYSA-N 2-(3,4-dichlorophenoxy)-n,n-diethylethanamine Chemical compound CCN(CC)CCOC1=CC=C(Cl)C(Cl)=C1 LOVYCUYJRWLTSU-UHFFFAOYSA-N 0.000 description 1
- 229920002943 EPDM rubber Polymers 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 241001495453 Parthenium argentatum Species 0.000 description 1
- 208000037656 Respiratory Sounds Diseases 0.000 description 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 210000000481 breast Anatomy 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 230000006355 external stress Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 210000003754 fetus Anatomy 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229920001206 natural gum Polymers 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- 238000007539 photo-oxidation reaction Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000000452 restraining effect Effects 0.000 description 1
- 238000013040 rubber vulcanization Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 229920002725 thermoplastic elastomer Polymers 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 239000004636 vulcanized rubber Substances 0.000 description 1
Classifications
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- Y02T10/862—
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- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
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CN201310333289.4A CN103467799B (en) | 2013-08-02 | 2013-08-02 | Solution-polymerized styrene-butadiene tread rubber and mixing process thereof |
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CN201310333289.4A CN103467799B (en) | 2013-08-02 | 2013-08-02 | Solution-polymerized styrene-butadiene tread rubber and mixing process thereof |
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CN103467799A true CN103467799A (en) | 2013-12-25 |
CN103467799B CN103467799B (en) | 2015-04-15 |
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Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103642084A (en) * | 2013-12-20 | 2014-03-19 | 北京彤程创展科技有限公司 | Rubber composition and tyre using same |
CN104262713A (en) * | 2014-10-13 | 2015-01-07 | 四川远星橡胶有限责任公司 | Motorcycle tire tread rubber material with skid and wear resistance and preparation method thereof |
CN104945819A (en) * | 2015-07-24 | 2015-09-30 | 广州丰力橡胶轮胎有限公司 | Application of wet process rubber compound to tyre, and application process of wet process rubber compound |
CN105348596A (en) * | 2014-08-19 | 2016-02-24 | 建大橡胶(中国)有限公司 | Ultra-high performance tire tread and synthesis method thereof |
CN105542261A (en) * | 2016-01-27 | 2016-05-04 | 北京化工大学 | Low rolling resistance boron carbide rubber composition and preparation process thereof |
CN105566702A (en) * | 2016-03-08 | 2016-05-11 | 徐州工业职业技术学院 | Agricultural tire crown compound of high filling tire reclaimed rubber |
CN105860158A (en) * | 2016-04-26 | 2016-08-17 | 安徽润康橡塑科技有限公司 | Oxidation resisting rubber for automobiles |
CN106626982A (en) * | 2016-12-08 | 2017-05-10 | 淮安优迪亚橡胶有限公司 | Fiber compound rubber |
CN107418122A (en) * | 2017-06-29 | 2017-12-01 | 常州西夏墅东方工具有限公司 | A kind of tread rubber and preparation method thereof |
CN107488285A (en) * | 2017-09-15 | 2017-12-19 | 李克 | A kind of low rolling resistance tire tread glue and preparation method thereof |
CN108219347A (en) * | 2016-12-15 | 2018-06-29 | 东洋橡胶工业株式会社 | Rubber composition |
CN110128715A (en) * | 2019-06-06 | 2019-08-16 | 江苏通用科技股份有限公司 | A kind of low-heat-generation, low rolling hinder all steel radial tire for heavy truck tread rubber |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102040755A (en) * | 2011-01-18 | 2011-05-04 | 沈阳化工大学 | Ultra-fine full vulcanized powdered styrene-butadiene rubber (UFPSBR) and solution polymerized styrene-butadiene rubber (SSBR) blend tread rubber and manufacturing method thereof |
-
2013
- 2013-08-02 CN CN201310333289.4A patent/CN103467799B/en not_active Expired - Fee Related
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102040755A (en) * | 2011-01-18 | 2011-05-04 | 沈阳化工大学 | Ultra-fine full vulcanized powdered styrene-butadiene rubber (UFPSBR) and solution polymerized styrene-butadiene rubber (SSBR) blend tread rubber and manufacturing method thereof |
Non-Patent Citations (1)
Title |
---|
张萍等: "硫化胶粉的形态结构及其在胎面胶中的应用", 《轮胎工业》, vol. 18, no. 3, 13 March 1998 (1998-03-13), pages 152 - 159 * |
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103642084B (en) * | 2013-12-20 | 2015-12-09 | 北京彤程创展科技有限公司 | A kind of rubber combination and use its tire |
CN103642084A (en) * | 2013-12-20 | 2014-03-19 | 北京彤程创展科技有限公司 | Rubber composition and tyre using same |
CN105348596A (en) * | 2014-08-19 | 2016-02-24 | 建大橡胶(中国)有限公司 | Ultra-high performance tire tread and synthesis method thereof |
CN104262713A (en) * | 2014-10-13 | 2015-01-07 | 四川远星橡胶有限责任公司 | Motorcycle tire tread rubber material with skid and wear resistance and preparation method thereof |
CN104945819B (en) * | 2015-07-24 | 2018-06-26 | 万力轮胎股份有限公司 | Application and technique for applying of a kind of wet method rubber compound in tire |
CN104945819A (en) * | 2015-07-24 | 2015-09-30 | 广州丰力橡胶轮胎有限公司 | Application of wet process rubber compound to tyre, and application process of wet process rubber compound |
CN105542261A (en) * | 2016-01-27 | 2016-05-04 | 北京化工大学 | Low rolling resistance boron carbide rubber composition and preparation process thereof |
CN105566702A (en) * | 2016-03-08 | 2016-05-11 | 徐州工业职业技术学院 | Agricultural tire crown compound of high filling tire reclaimed rubber |
CN105860158A (en) * | 2016-04-26 | 2016-08-17 | 安徽润康橡塑科技有限公司 | Oxidation resisting rubber for automobiles |
CN106626982A (en) * | 2016-12-08 | 2017-05-10 | 淮安优迪亚橡胶有限公司 | Fiber compound rubber |
CN108219347A (en) * | 2016-12-15 | 2018-06-29 | 东洋橡胶工业株式会社 | Rubber composition |
CN107418122A (en) * | 2017-06-29 | 2017-12-01 | 常州西夏墅东方工具有限公司 | A kind of tread rubber and preparation method thereof |
CN107488285A (en) * | 2017-09-15 | 2017-12-19 | 李克 | A kind of low rolling resistance tire tread glue and preparation method thereof |
CN110128715A (en) * | 2019-06-06 | 2019-08-16 | 江苏通用科技股份有限公司 | A kind of low-heat-generation, low rolling hinder all steel radial tire for heavy truck tread rubber |
Also Published As
Publication number | Publication date |
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CN103467799B (en) | 2015-04-15 |
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GR01 | Patent grant | ||
C56 | Change in the name or address of the patentee |
Owner name: SHANDONG YONGTAI GROUP CO., LTD. Free format text: FORMER NAME: SHANDONG YONGTAI CHEMICAL ENGINEERING CO., LTD. |
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CP03 | Change of name, title or address |
Address after: 257335 No. 262, Tsing Yi Road, rubber industrial zone, Da Wang Town, Guangrao County, Shandong Patentee after: Yongtai, Shandong Group Co., Ltd Address before: 257335 Guangrao City, Dongying Province town of Rubber Industrial Park Patentee before: Shandong Yongtai Chemical Co., Ltd. |
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Effective date of registration: 20170216 Granted publication date: 20150415 |
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Date of cancellation: 20170816 Granted publication date: 20150415 |
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