CN105198414B - A kind of 3D printing ceramic material and preparation method thereof - Google Patents
A kind of 3D printing ceramic material and preparation method thereof Download PDFInfo
- Publication number
- CN105198414B CN105198414B CN201510588763.7A CN201510588763A CN105198414B CN 105198414 B CN105198414 B CN 105198414B CN 201510588763 A CN201510588763 A CN 201510588763A CN 105198414 B CN105198414 B CN 105198414B
- Authority
- CN
- China
- Prior art keywords
- ceramic material
- weight
- parts
- zirconium oxide
- printing ceramic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000010146 3D printing Methods 0.000 title claims abstract description 33
- 229910010293 ceramic material Inorganic materials 0.000 title claims abstract description 31
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- 239000000843 powder Substances 0.000 claims abstract description 38
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims abstract description 33
- 229910001928 zirconium oxide Inorganic materials 0.000 claims abstract description 33
- 229910052594 sapphire Inorganic materials 0.000 claims abstract description 22
- 239000010980 sapphire Substances 0.000 claims abstract description 22
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 17
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000003381 stabilizer Substances 0.000 claims abstract description 6
- 238000003756 stirring Methods 0.000 claims description 22
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 12
- 238000010438 heat treatment Methods 0.000 claims description 11
- 238000006243 chemical reaction Methods 0.000 claims description 7
- 239000011812 mixed powder Substances 0.000 claims description 7
- 238000002604 ultrasonography Methods 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 6
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical group [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 claims description 6
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 6
- 235000019818 tetrasodium diphosphate Nutrition 0.000 claims description 6
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 claims description 5
- 239000008367 deionised water Substances 0.000 claims description 5
- 229910021641 deionized water Inorganic materials 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 229920005749 polyurethane resin Polymers 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000003822 epoxy resin Substances 0.000 claims description 4
- 235000006408 oxalic acid Nutrition 0.000 claims description 4
- 229920000647 polyepoxide Polymers 0.000 claims description 4
- 229940048086 sodium pyrophosphate Drugs 0.000 claims description 4
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims description 4
- 230000008859 change Effects 0.000 claims description 3
- 239000002994 raw material Substances 0.000 claims description 3
- 239000004925 Acrylic resin Substances 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims description 2
- FIXNOXLJNSSSLJ-UHFFFAOYSA-N ytterbium(III) oxide Inorganic materials O=[Yb]O[Yb]=O FIXNOXLJNSSSLJ-UHFFFAOYSA-N 0.000 claims description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- 238000005452 bending Methods 0.000 abstract description 5
- 239000000919 ceramic Substances 0.000 abstract description 5
- 230000003068 static effect Effects 0.000 abstract description 3
- 239000000463 material Substances 0.000 description 10
- 238000004519 manufacturing process Methods 0.000 description 7
- 238000005516 engineering process Methods 0.000 description 6
- 239000002253 acid Substances 0.000 description 5
- 150000002148 esters Chemical class 0.000 description 5
- 235000019441 ethanol Nutrition 0.000 description 5
- 125000005909 ethyl alcohol group Chemical group 0.000 description 5
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 5
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 5
- 238000012216 screening Methods 0.000 description 5
- 230000008901 benefit Effects 0.000 description 4
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000003643 water by type Substances 0.000 description 4
- 238000000465 moulding Methods 0.000 description 3
- 239000013078 crystal Substances 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000000110 selective laser sintering Methods 0.000 description 2
- 238000007493 shaping process Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 230000009471 action Effects 0.000 description 1
- 239000011157 advanced composite material Substances 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 238000000149 argon plasma sintering Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
Abstract
The present invention provides a kind of 3D printing ceramic material and preparation method thereof, including following component by weight：50 ~ 150 parts by weight of Zirconium oxide powder；10 ~ 30 parts by weight of Zirconium oxide powder inorganic agent；100 ~ 500 parts by weight of decentralized medium；1 ~ 10 parts by weight of monocrystalline sapphire whisker；1 ~ 10 parts by weight of stabilizer；5 ~ 50 parts by weight of light curing agent.After the present invention in zirconia ceramics by adding in monocrystalline sapphire whisker, the modulus of elasticity in static bending, the tensile strength of product can be significantly improved, is used to prepare high-strength, the fine engineering ceramics of high-ductility.
Description
Technical field
The invention belongs to field of compound material, and in particular to a kind of preparation method of 3D printing ceramic material.
Background technology
The principle of 3D printing technique is layered manufacturing, successively increases material to generate the technology of 3D solid, so quilt again
Referred to as increases material manufacturing technology.In recent years, increases material manufacturing technology is quickly grown, huge on manufacture field influence, each by the world
The very big concern of state is known as overturning the industrial revolution again of traditional manufacture, is put into China's strategic emerging industries.
3D printing mainstream forming technique includes selective laser sintering（SLS）, melting precipitation molding（FDM）, cubic light it is solid
Change（SLA）Deng.Selective laser sintering was ground by the C.R. Dechard of Texas ,Usa university Austin in 1989
Work(is made.The energy is made using infrared laser, the Modeling Material used is mostly dusty material.During processing, powder is preheated first
To the temperature for being slightly less than its fusing point, then powder is paved under the action of rod is struck off；Laser beam root under the control of the computer
It is selectively sintered according to layering cross section information, carries out next layer of sintering after the completion of one layer again, remove after being all sintered more
Remaining powder then can be obtained by the part sintered.Such forming method has that manufacturing process is simple, and degree of flexibility is high, material
Range of choice is wide, material price is cheap, it is at low cost, stock utilization is high, and shaping speed is fast the features such as, 2014, GE companies ground
20 parts have been made a part by the aircraft engine machine nozzle of hair, and material cost is greatly reduced, and also save fuel oil 15%.
3D printing currently on the market is of less types with laser sintered ceramic material, relies primarily on import.
Monocrystalline sapphire whisker (Single crystal sapphire Whisker, also known as monocrystalline sapphire fiber) is
A kind of signle crystal alumina whisker with certain draw ratio is small, anti-oxidant, high with superior mechanical intensity, heat shock resistance, proportion
The excellent physical property such as wear-resisting amount and highly corrosion resistant.Monocrystalline sapphire whisker is suitable as ceramics, metal, plastics and rubber
Reinforcing component.Therefore, monocrystalline sapphire whisker becomes the optimal selection of third generation advanced composite material.
Invention content
The purpose of the present invention is to provide a kind of 3D printing ceramic materials and preparation method thereof, add in zirconia ceramics
After entering monocrystalline sapphire whisker, the modulus of elasticity in static bending, the tensile strength of product can be significantly improved, is used to prepare high-strength, high-ductility
Fine engineering ceramics.
In order to achieve the above object, the technical scheme is that：
A kind of 3D printing ceramic material, including following component by weight：
50 ~ 150 parts by weight of Zirconium oxide powder
10 ~ 30 parts by weight of Zirconium oxide powder inorganic agent
100 ~ 500 parts by weight of decentralized medium
1 ~ 10 parts by weight of monocrystalline sapphire whisker
1 ~ 10 parts by weight of stabilizer
5 ~ 50 parts by weight of light curing agent.
The 3D printing ceramic material, each component preferred weight number are as follows：
80 ~ 120 parts by weight of Zirconium oxide powder
20 ~ 30 parts by weight of Zirconium oxide powder inorganic agent
100 ~ 500 parts by weight of decentralized medium
1 ~ 10 parts by weight of monocrystalline sapphire whisker
1 ~ 10 parts by weight of stabilizer
5 ~ 30 parts by weight of light curing agent.
The Zirconium oxide powder be 50 ~ 500nm of grain size, purity（wt%）>90% commercially available monoclinic zirconia；The zirconium oxide
Powder-processed agent is sodium pyrophosphate, sodium tripolyphosphate and oxalic acid any and more than；The decentralized medium for deionized water and
Any and two kinds of mixing of absolute ethyl alcohol.
The monocrystalline sapphire whisker is 0.1 ~ 1 micron of diameter, and length is 5 ~ 100 microns, density 4g/cm3, purity
（wt%）Monocrystalline sapphire whisker for 90-99.9%.
Mixture of the stabilizer for any one of Yb2O3, CeO2 or both；The light curing agent is acrylate
One of with the mixture of polyurethane resin, acrylate and epoxy resin.
A kind of preparation method of 3D printing ceramic material, a, in heating unit add in deionized water according to formula ratio
With Zirconium oxide powder inorganic agent, stirring and dissolving is until Zirconium oxide powder inorganic agent is completely dissolved obtained solution；B is made to step a
Solution in add in Zirconium oxide powder, stir 1 ~ 4h at a constant temperature, fully after reaction, cool down, filter, it is dry, after being handled
Zirconium oxide powder；C, stabilizer, light curing agent and monocrystalline sapphire whisker are added to according to formula ratio in absolute ethyl alcohol,
2 ~ 6h is quickly stirred under room temperature, mixed liquor is made；D, mixed liquor made from step c is shaken into 30 ~ 90min under ultrasound；Then plus
Enter step b treated Zirconium oxide powder, stir 3 ~ 15h；E, above-mentioned mixed-powder is dried, 3D printing use can be obtained after sieve
Ceramic material.
Heating temperature described in the step a is 50 ~ 80 DEG C, and mixing speed is 350 ~ 550r/min.
Heating temperature is 80 ± 5 DEG C in the step b, and mixing speed is 350 ~ 750r/min.
Step c, mixing speed is 500 ~ 750r/min in d.
Drying temperature is 80 ~ 120 DEG C in step e.
Using 400 model 3D printers of EOS M, using powder sintered molding（Selected Laser Sintering,
Abbreviation SLS）Technology carries out powder sintered molding using laser to dusty material.The monocrystalline sapphire whisker is by Dongguan
Prepared by the research and development of monocrystalline sapphire whisker team of Shenzhen Research Institute of Tsinghua University innovation center, select 0.1 ~ 5 micron of diameter, and length is
5 ~ 100 microns of monocrystalline sapphire whisker.Selected monocrystalline sapphire whisker density be 4g/cm3, purity（wt%）About 99%.
The beneficial effects of the invention are as follows：
Advantageous effect：
（1）A kind of 3D printing of the present invention has the higher modulus of elasticity in static bending, tensile strength with ceramic material；
（2）A kind of 3D printing of the present invention is small with powder granule with ceramic material, and particle diameter distribution is narrow, and mobility is preferable,
It is preferable with 3D printer shaping speed matching；Product property is stablized, and precision is high.
（3）A kind of 3D printing of the present invention is simple with ceramic material process, is easy to industrialized production；
（4）A kind of 3D printing of the present invention is extensive with ceramic material raw material sources, at low cost, and with good environment
Benefit and economic benefit.
Description of the drawings
Attached drawing 1 shows the preparation flow figure of 3D printing ceramic material.
Specific embodiment
The present invention is described in further detail by embodiment.
Embodiment 1
（1）In 50 ~ 80 DEG C of heating unit, 20 parts by weight sodium pyrophosphates are added in 100 deionized waters, 350 ~
Stirring under 750r/min speed is until sodium pyrophosphate fully dissolves.
（2）80 parts by weight Zirconium oxide powders are added in into above-mentioned solution, 350 ~ 750r/min at being 80 ± 5 DEG C in constant temperature
1h is stirred, fully after reaction, cools down, filters, dry, the Zirconium oxide powder that obtains that treated.
（3）By 2 parts by weight Y2O3, 5 parts by weight propylene acid esters and polyurethane resin（1:1）With 1 parts by weight monocrystalline sapphire crystalline substance
It must be added to according to formula ratio in 200 parts by weight absolute ethyl alcohols, quickly stir 2 ~ 6 h with 500 ~ 750r/min at normal temperatures.（4）
Above-mentioned mixed liquor is shaken into 30 ~ 90min under ultrasound.
（5）By treated, Zirconium oxide powder is added in above-mentioned mixed liquor, and 500 ~ 750r/min stirs 3 ~ 15h.
（6）Will be dry at above-mentioned 80 ~ 120 DEG C of mixed-powder, 3D printing ceramic material can be obtained after screening.
Embodiment 2
（1）In 50 ~ 80 DEG C of heating unit, 20 parts by weight sodium tripolyphosphates are added in 200 parts by weight of deionized water,
Stirring under 350 ~ 750r/min speed is until sodium tripolyphosphate fully dissolves.
（2）90 parts by weight Zirconium oxide powders are added in into above-mentioned solution, 350 ~ 750r/min at being 80 ± 5 DEG C in constant temperature
2h is stirred, fully after reaction, cools down, filters, dry, the Zirconium oxide powder that obtains that treated.
（3）By 1 parts by weight Y2O3, 3 parts by weight propylene acid esters and polyurethane resin（1:1）With 3 parts by weight monocrystalline sapphires crystalline substance
It must be added to according to formula ratio in 200 parts by weight absolute ethyl alcohols, quickly stir 2 ~ 6 h with 500 ~ 750r/min at normal temperatures.
（4）Above-mentioned mixed liquor is shaken into 30 ~ 90min under ultrasound.
（5）By treated, Zirconium oxide powder is added in above-mentioned mixed liquor, and 500 ~ 750r/min stirs 3 ~ 15h.
（6）Will be dry at above-mentioned 80 ~ 120 DEG C of mixed-powder, 3D printing ceramic material can be obtained after screening.
Embodiment 3
（1）In 50 ~ 80 DEG C of heating unit, 25 parts by weight oxalic acid are added in 300 deionized waters, 350 ~ 750r/min
Stirring under speed is until oxalic acid fully dissolves.
（2）100 parts by weight Zirconium oxide powders are added in into above-mentioned solution, 350 ~ 750r/min at being 80 ± 5 DEG C in constant temperature
2h is stirred, fully after reaction, cools down, filters, dry, the Zirconium oxide powder that obtains that treated.
（3）By 5 parts by weight CeO2, 5 parts by weight propylene acid esters and polyurethane resin（2:3）With 7 parts by weight monocrystalline sapphires
Whisker is added to according to formula ratio in 500 parts by weight absolute ethyl alcohols, quickly stirs 2 ~ 6 h with 500 ~ 750r/min at normal temperatures.
（4）Above-mentioned mixed liquor is shaken into 30 ~ 90min under ultrasound.
（5）By treated, Zirconium oxide powder is added in above-mentioned mixed liquor, and 500 ~ 750r/min stirs 3 ~ 15h.
（6）Will be dry at above-mentioned 80 ~ 120 DEG C of mixed-powder, 3D printing ceramic material can be obtained after screening.
Embodiment 4
（1）In 50 ~ 80 DEG C of heating unit, 30 parts by weight sodium tripolyphosphates are added in 500 deionized waters, 350 ~
Stirring under 750r/min speed is until sodium tripolyphosphate fully dissolves.
（2）100 parts by weight Zirconium oxide powders are added in into above-mentioned solution, 350 ~ 750r/min at being 80 ± 5 DEG C in constant temperature
2h is stirred, fully after reaction, cools down, filters, dry, the Zirconium oxide powder that obtains that treated.
（3）By 5 parts by weight CeO2, 10 parts by weight propylene acid esters and epoxy resin（2:3）With 10 parts by weight monocrystalline sapphires
Whisker is added to according to formula ratio in 500 parts by weight absolute ethyl alcohols, quickly stirs 2 ~ 6 h with 500 ~ 750r/min at normal temperatures.
（4）Above-mentioned mixed liquor is shaken into 30 ~ 90min under ultrasound.
（5）By treated, Zirconium oxide powder is added in above-mentioned mixed liquor, and 500 ~ 750r/min stirs 3 ~ 15h.
（6）Will be dry at above-mentioned 80 ~ 120 DEG C of mixed-powder, 3D printing ceramic material can be obtained after screening.
Embodiment 5
（1）In 50 ~ 80 DEG C of heating unit, 30 parts by weight sodium pyrophosphates are added in 500 deionized waters, 350 ~
Stirring under 750r/min speed is until sodium pyrophosphate fully dissolves.
（2）120 parts by weight Zirconium oxide powders are added in into above-mentioned solution, 350 ~ 750r/min at being 80 ± 5 DEG C in constant temperature
2h is stirred, fully after reaction, cools down, filters, dry, the Zirconium oxide powder that obtains that treated.
（3）By 10 parts by weight Y2O3：CeO2（2:3）, 5 parts by weight propylene acid esters and epoxy resin（2:3）With 8 parts by weight lists
Brilliant sapphire whisker is added to according to formula ratio in 500 parts by weight absolute ethyl alcohols, is quickly stirred with 500 ~ 750r/min at normal temperatures
Mix 2 ~ 6 h.
（4）Above-mentioned mixed liquor is shaken into 30 ~ 90min under ultrasound.
（5）By treated, Zirconium oxide powder is added in above-mentioned mixed liquor, and 500 ~ 750r/min stirs 3 ~ 15h.
（6）Will be dry at above-mentioned 80 ~ 120 DEG C of mixed-powder, 3D printing ceramic material can be obtained after screening.
3D printing prepared by embodiment 1-5 with ceramic material in mechanical performance is tested, as a result see the table below：
The mechanical performance of 1 3D printing ceramic material of subordinate list
| Bending strength (MPa) | Tensile strength (MPa) | Density (g/cm3) | |
| Embodiment 1 | 753 | 450 | 6.25 |
| Embodiment 2 | 749 | 463 | 6.13 |
| Embodiment 3 | 758 | 448 | 6.32 |
| Embodiment 4 | 776 | 469 | 6.25 |
| Embodiment 5 | 768 | 465 | 6.18 |
Show that the embodiment of the present invention bending strength and tensile strength are very high by data above, it is with the obvious advantage.
Basic principle, main feature and the advantages of the present invention of the present invention has been shown and described above.The technology of the industry
Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the above embodiments and description only describe this
The principle of invention, various changes and improvements may be made to the invention without departing from the spirit and scope of the present invention, these changes
Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its
Equivalent defines.
Claims (8)
1. a kind of 3D printing ceramic material includes the raw material of following parts by weight：
The Zirconium oxide powder be 50~500nm of grain size, purity (wt%)>90% commercially available monoclinic zirconia；The zirconium oxide
Powder-processed agent is sodium pyrophosphate, sodium tripolyphosphate and oxalic acid any and more than；The decentralized medium for deionized water and
Absolute ethyl alcohol；Preparation method is：A, in heating unit, deionized water and Zirconium oxide powder inorganic agent are added according to formula ratio,
Stirring and dissolving is until Zirconium oxide powder inorganic agent is completely dissolved obtained solution；B adds in zirconia powder into solution made from step a
End stirs 1~4h, fully after reaction, cools down, filter at a constant temperature, dry, the Zirconium oxide powder that obtains that treated；It c, will be steady
Determine agent, light curing agent and monocrystalline sapphire whisker to be added in absolute ethyl alcohol according to formula ratio, quickly stir 2~6h at normal temperatures
Mixed liquor is made；D, mixed liquor made from step c is shaken into 30~90min under ultrasound；Then step b is added in treated oxygen
Change zirconium powder, stir 3~15h；E, above-mentioned mixed-powder is dried, 3D printing ceramic material can be obtained after sieve.
2. 3D printing ceramic material according to claim 1, each raw material weight number is as follows：
3. 3D printing ceramic material according to claim 1, the monocrystalline sapphire whisker is 0.1~1 micron of diameter,
Length is 5~100 microns, density 4g/cm3, purity (wt%) is the monocrystalline sapphire whisker of 90-99.9%.
4. 3D printing ceramic material according to claim 1, the stabilizer is Yb2O3、CeO2Any one of or two
The mixture of person；The light curing agent is one of acrylate and the mixture of polyurethane resin, acrylate and epoxy resin.
5. 3D printing ceramic material according to claim 1, heating temperature described in the step a is 50~80 DEG C,
Mixing speed is 350~550r/min.
6. 3D printing ceramic material according to claim 1, heating temperature is 80 ± 5 DEG C in the step b, stirring speed
It spends for 350~750r/min.
7. 3D printing ceramic material according to claim 1, step c, mixing speed is 500~750r/min in d.
8. 3D printing ceramic material according to claim 1, drying temperature is 80~120 DEG C in step e.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510588763.7A CN105198414B (en) | 2015-09-16 | 2015-09-16 | A kind of 3D printing ceramic material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510588763.7A CN105198414B (en) | 2015-09-16 | 2015-09-16 | A kind of 3D printing ceramic material and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105198414A CN105198414A (en) | 2015-12-30 |
| CN105198414B true CN105198414B (en) | 2018-06-15 |
Family
ID=54946442
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510588763.7A Active CN105198414B (en) | 2015-09-16 | 2015-09-16 | A kind of 3D printing ceramic material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105198414B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU2018204646A1 (en) * | 2018-05-16 | 2019-12-05 | Research Institute Of Tsinghua University In Shenzhen | Ceramic-based toughness-enhanced material based on single crystal sapphire fiber and preparation method therefor |
| CN109276816A (en) * | 2018-09-19 | 2019-01-29 | 张玉森 | It is a kind of to treat card and preparation method thereof |
| CN112374903A (en) * | 2020-12-21 | 2021-02-19 | 山东蓝合智能科技有限公司 | Preparation method for zirconia ceramic 3D printing material |
| CN114853493A (en) * | 2022-04-22 | 2022-08-05 | 华南理工大学 | Zirconia whisker reinforced zirconia ceramic and forming method thereof |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104291832B (en) * | 2014-09-10 | 2016-01-20 | 济南大学 | A kind of three D print the preparation method of rapid shaping nanometer titanium dioxide zirconia material |
| CN104529475A (en) * | 2014-12-01 | 2015-04-22 | 青岛麦特瑞欧新材料技术有限公司 | Zirconium-doped inorganic nano-grade composite material used in 3D printing, and preparation method thereof |
| CN104526838B (en) * | 2014-12-30 | 2017-01-11 | 宁波伏尔肯陶瓷科技有限公司 | Method for 3D ceramic printing forming |
| CN104649698B (en) * | 2014-12-31 | 2016-09-14 | 东莞深圳清华大学研究院创新中心 | A kind of monocrystalline sapphire fiber process for dispersing in Zirconium oxide ceramic composite material and a kind of composite |
| CN104788081B (en) * | 2015-03-23 | 2016-11-09 | 济南大学 | A kind of preparation method of alumina powder 3D printed material |
-
2015
- 2015-09-16 CN CN201510588763.7A patent/CN105198414B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN105198414A (en) | 2015-12-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105198414B (en) | A kind of 3D printing ceramic material and preparation method thereof | |
| CN108456457B (en) | 3D direct-writing zirconia ceramic ink | |
| CN106115805B (en) | The preparation method of the sour nickel/mos2 microsphere of nanometer hierarchy cobalt | |
| CN104575626B (en) | For the spike microballoon of pebble bed high temperature reactor | |
| CN105237022A (en) | Ceramic-base 3D printing material and preparation method thereof | |
| CN108046665A (en) | A kind of micro-nano composite hollow structure nano material modification high durability concrete material and preparation method thereof | |
| CN110240484A (en) | A kind of method of 3D printing high-specific surface area high efficiency catalysts-support system | |
| CN101024514A (en) | Novel process for preparing cubic-phase nano zirconium dioxide | |
| CN102584224A (en) | Preparation method of nanoscale zirconia ceramic powder for spraying | |
| CN106735174A (en) | A kind of 3D printing metal-base composites and preparation method thereof | |
| CN104788108A (en) | Zirconia fiber board and preparation method | |
| CN108516730A (en) | A kind of composition, preparation and its application for spraying 3D printing based on binder | |
| CN105384190A (en) | Method for preparing nano samarium zirconate powder used for additive manufacturing and feeding | |
| CN102503538A (en) | Continuously pore-forming silicon carbide ceramic material and preparation method for same | |
| CN103964874B (en) | Zirconium mullite sagger | |
| CN107760018A (en) | A kind of selective laser sintering 3D printing composite powders of PA 12 | |
| Cai et al. | Preparation of porous Al2O3 ceramic microspheres by a novel micro-droplet jetting rapid forming method | |
| CN106431458B (en) | The method that tailings in vanadium extraction prepares porous ceramics | |
| CN104451954A (en) | Preparation method of nano-alumina fibers | |
| Wang et al. | Preparation of ceria-stabilized zirconia microspheres by external gelation: size control | |
| Romanczuk-Ruszuk et al. | 3D printing ceramics—materials for direct extrusion process | |
| CN104387102B (en) | A kind of CNT ceramic composite and preparation method thereof | |
| CN106046755A (en) | Polyurethane composite material for 3D (three-dimensional) printing | |
| CN105499597A (en) | Preparation method for micron silver powder for silver clay, and preparation method for silver clay product | |
| CN107353711A (en) | A kind of preparation method of nano-particle reinforced resin lead for retractable pencil |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20231117 Address after: 523000 Building 1, No.1 Xuefu Road, Songshanhu Park, Dongguan City, Guangdong Province Patentee after: Guangdong Qingda Innovation Research Institute Co.,Ltd. Patentee after: DONGGUAN NIUKA NEW MATERIAL SCIENCE & TECHNOLOGY Co.,Ltd. Address before: 523000 Innovation Science Park, Songshan Lake High-tech Industrial Development Zone, Dongguan City, Guangdong Province, 8 Tsinghua Dongguan Innovation Center Patentee before: TSINGHUA INNOVATION CENTER IN DONGGUAN Patentee before: DONGGUAN NIUKA NEW MATERIAL SCIENCE & TECHNOLOGY Co.,Ltd. |