CN105188996A - CVI bonded and coated PCBN to WC tool body - Google Patents

CVI bonded and coated PCBN to WC tool body Download PDF

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Publication number
CN105188996A
CN105188996A CN201480009571.XA CN201480009571A CN105188996A CN 105188996 A CN105188996 A CN 105188996A CN 201480009571 A CN201480009571 A CN 201480009571A CN 105188996 A CN105188996 A CN 105188996A
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CN
China
Prior art keywords
cutting tool
coating
cutter hub
super hard
hard abrasive
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CN201480009571.XA
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Chinese (zh)
Inventor
威廉·拉赛尔
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Diamond Innovations Inc
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Diamond Innovations Inc
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Publication of CN105188996A publication Critical patent/CN105188996A/en
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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F7/00Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression
    • B22F7/06Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression of composite workpieces or articles from parts, e.g. to form tipped tools
    • B22F7/062Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression of composite workpieces or articles from parts, e.g. to form tipped tools involving the connection or repairing of preformed parts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24DTOOLS FOR GRINDING, BUFFING OR SHARPENING
    • B24D3/00Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents
    • B24D3/02Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent
    • B24D3/04Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent and being essentially inorganic
    • B24D3/14Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent and being essentially inorganic ceramic, i.e. vitrified bondings
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23BTURNING; BORING
    • B23B27/00Tools for turning or boring machines; Tools of a similar kind in general; Accessories therefor
    • B23B27/14Cutting tools of which the bits or tips or cutting inserts are of special material
    • B23B27/141Specially shaped plate-like cutting inserts, i.e. length greater or equal to width, width greater than or equal to thickness
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24DTOOLS FOR GRINDING, BUFFING OR SHARPENING
    • B24D18/00Manufacture of grinding tools or other grinding devices, e.g. wheels, not otherwise provided for
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B37/00Joining burned ceramic articles with other burned ceramic articles or other articles by heating
    • C04B37/02Joining burned ceramic articles with other burned ceramic articles or other articles by heating with metallic articles
    • C04B37/023Joining burned ceramic articles with other burned ceramic articles or other articles by heating with metallic articles characterised by the interlayer used
    • C04B37/025Joining burned ceramic articles with other burned ceramic articles or other articles by heating with metallic articles characterised by the interlayer used consisting of glass or ceramic material
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C26/00Alloys containing diamond or cubic or wurtzitic boron nitride, fullerenes or carbon nanotubes
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/04Coating on selected surface areas, e.g. using masks
    • C23C16/045Coating cavities or hollow spaces, e.g. interior of tubes; Infiltration of porous substrates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F5/00Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product
    • B22F2005/001Cutting tools, earth boring or grinding tool other than table ware
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23BTURNING; BORING
    • B23B2226/00Materials of tools or workpieces not comprising a metal
    • B23B2226/12Boron nitride
    • B23B2226/125Boron nitride cubic [CBN]
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23BTURNING; BORING
    • B23B2226/00Materials of tools or workpieces not comprising a metal
    • B23B2226/31Diamond
    • B23B2226/315Diamond polycrystalline [PCD]
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23BTURNING; BORING
    • B23B2228/00Properties of materials of tools or workpieces, materials of tools or workpieces applied in a specific manner
    • B23B2228/04Properties of materials of tools or workpieces, materials of tools or workpieces applied in a specific manner applied by chemical vapour deposition [CVD]
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2237/00Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
    • C04B2237/02Aspects relating to interlayers, e.g. used to join ceramic articles with other articles by heating
    • C04B2237/04Ceramic interlayers
    • C04B2237/06Oxidic interlayers
    • C04B2237/062Oxidic interlayers based on silica or silicates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2237/00Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
    • C04B2237/02Aspects relating to interlayers, e.g. used to join ceramic articles with other articles by heating
    • C04B2237/04Ceramic interlayers
    • C04B2237/08Non-oxidic interlayers
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2237/00Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
    • C04B2237/02Aspects relating to interlayers, e.g. used to join ceramic articles with other articles by heating
    • C04B2237/04Ceramic interlayers
    • C04B2237/08Non-oxidic interlayers
    • C04B2237/086Carbon interlayers
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2237/00Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
    • C04B2237/30Composition of layers of ceramic laminates or of ceramic or metallic articles to be joined by heating, e.g. Si substrates
    • C04B2237/32Ceramic
    • C04B2237/34Oxidic
    • C04B2237/343Alumina or aluminates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2237/00Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
    • C04B2237/30Composition of layers of ceramic laminates or of ceramic or metallic articles to be joined by heating, e.g. Si substrates
    • C04B2237/32Ceramic
    • C04B2237/36Non-oxidic
    • C04B2237/361Boron nitride
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2237/00Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
    • C04B2237/30Composition of layers of ceramic laminates or of ceramic or metallic articles to be joined by heating, e.g. Si substrates
    • C04B2237/32Ceramic
    • C04B2237/36Non-oxidic
    • C04B2237/363Carbon
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2237/00Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
    • C04B2237/30Composition of layers of ceramic laminates or of ceramic or metallic articles to be joined by heating, e.g. Si substrates
    • C04B2237/40Metallic
    • C04B2237/401Cermets
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2237/00Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
    • C04B2237/50Processing aspects relating to ceramic laminates or to the joining of ceramic articles with other articles by heating
    • C04B2237/72Forming laminates or joined articles comprising at least two interlayers directly next to each other
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2237/00Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
    • C04B2237/50Processing aspects relating to ceramic laminates or to the joining of ceramic articles with other articles by heating
    • C04B2237/84Joining of a first substrate with a second substrate at least partially inside the first substrate, where the bonding area is at the inside of the first substrate, e.g. one tube inside another tube

Abstract

A cutting tool (10) and a method of making a cutting tool are provided. The cutting tool (10) comprises a sintered superabrasive tip (12) with a plurality of superhard particles of polycrystalline boron nitride, a tool body (14) and a non-brazing material (24). The non- brazing material (24) fills a gap (15, 16) between the superabrasive tip (12) and the tool body (14). The method of making a cutting tool comprises steps of providing a superabrasive tip (12); providing a tool body (14); filling a gap (15, 16) between the superabrasive tip (12) and the tool body (14) with a non-brazing material (24); and depositing a first coating (22) to the non-brazing material (24).

Description

CVI bonding and coating PCBN to WC cutter hub
Technical field
This application claims the priority that the name submitted on February 28th, 2013 is called the U.S. Provisional Patent Application 61/770419 of " CVI bonding and coating PCBN to WC cutter hub ".
Background technology
The present invention relates to a kind of for the mach cutting tool of metal, described cutting tool comprises: at least one contains the cutter hub of polycrystal cubic boron nitride (PCBN), and its tool is with or without cemented carbide substrate (backing); With the hard and wear-resisting refractory coating on described cutter hub surface, more specifically, the method using chemical vapor infiltration (CVI) or chemical vapour deposition (CVD) (CVD) to utilize porous or the gap between fine grained Filled Dielectrics PCBN point of a knife (tooltip) and WC cutter hub (toolbody) is related to.
Polycrystal cubic boron nitride (PCBN), polycrystalline diamond and polycrystalline diamond stone composite material are generally used for providing those as used in metal machine processing of the superhard cutting edge of cutting tool.
The cutting tool with the cutting edge formed as cubic boron nitride (CBN) sill by super hard abrasive is manufactured by PM technique and is mainly used in the machined of cast iron and hardened steel.The CBN cutting tool of several types is known, and majority is made up of the PCBN point of a knife be soldered on carbide chip.Other makes PCBN direct sintering to the cemented carbide substrate of adequate thickness to manufacture blade, and also has other to be made up of the cutter hub containing PCBN without any cemented carbide substrate.
Make the PCBN cutter hub of the sintering temperature stood more than 1000 DEG C that the undesirable structure in material may be caused to change.In addition, when the blade of soldering, soldered fitting will be destroyed.
Therefore, can find out that demand is existed for the cutting tool between PcBN point of a knife and cutter hub (WC/Co) with high temperature bond.
Summary of the invention
In one embodiment, cutting tool can comprise the super hard abrasive point (superabrasivetip) of the sintering with multiple ultra-hard particles; Keep the cutter hub of described super hard abrasive point; And fill the non brazing material in the gap between described super hard abrasive point and described cutter hub.
In another embodiment, method can comprise the steps: the super hard abrasive point providing sintering; Cutter hub is provided; The gap between described super hard abrasive point and described cutter hub is filled with non brazing material; Be deposited to non brazing material with being coated with first, wherein said first coating is impregnant coating point, cutter hub and non brazing material are bonded to one another.
In another embodiment, cutter can comprise the super hard abrasive point of the sintering with multiple ultra-hard particles; Keep the cutter hub of described super hard abrasive point; Impregnant bonding coat between described super hard abrasive point and described cutter hub; With the high temperature coating of the super hard abrasive point and described cutter hub that are attached to described sintering.
Accompanying drawing explanation
When understanding by reference to the accompanying drawings, will be better understood aforesaid summary and following detailed description of the invention.The embodiment should understanding description is not limited to the accurate layout that illustrates and instrument.
Fig. 1 is the perspective view being attached at the super hard abrasive point of cutter hub according to illustrative embodiments;
Fig. 2 is the optical imagery being attached at the cross-sectional view of the super hard abrasive point of cutter hub according to another illustrative embodiments;
Fig. 3 is the optical imagery that the part of the cross-sectional view of the super hard abrasive point being attached at cutter hub is as shown in Figure 2 amplified; With
Fig. 4 illustrates the flow chart being attached at the method for the super hard abrasive point of cutter hub manufactured according to illustrative embodiments.
Detailed description of the invention
Term as used in this article " point " refers to the main body for grinding or cutting workpiece, and it is made by the manufacturing process of the step comprising mixing super hard abrasive particle and binding agent.
Term as used in this article " cutter hub " refers to such rigid body, and point is firmly held in appropriate location and makes it may be used for turning, milling, boring, cutting or drilling application by it.
In an illustrative embodiments, point can be made up of the super hard abrasive particle being attached at suitable cutter hub metal as hard in carbide alloy.This illustrative embodiments uses chemical vapor infiltration (CVI) or chemical vapour deposition (CVD) (CVD) to utilize porous or fine grained medium to fill the gap between super hard abrasive point and cutter hub.Porous or fine grained medium can be bonded to one another and be bonded to point and cutter hub by the deposition of CVI or CVD.High-temperaure coating or a series of laminated coating can be coated with subsequently as Al as a part for same process 2o 3, to provide the wearability of enhancing.
More specifically, the porous of use or fine grained medium can be survived in CVI or CVD technique.Or fine grained such as diamond or cubic boron nitride can by processes expend.Can deposit high-temperaure coating or a series of laminated coating to provide extra wearability to cutting tool during machined, this does not affect (soldering being different from metal) for the adhesion strength formed.
As shown in FIG. 1, cutting tool 10 comprises the super hard abrasive point 12 of sintering and contains the cutter hub 14 of porose 19.Cutter hub 14 can be made up of the many materials comprising tungsten-cobalt hard alloy.Cutter hub 14 can be designed to keep super hard abrasive point 12.The super hard abrasive point 12 of sintering can have multiple ultra-hard particles, and described ultra-hard particles can be selected from cubic boron nitride, diamond, diamond composites and ceramic material.Seam or gap such as gap 15, bottom and sidewall gap 16 can be there is between super hard abrasive point and cutter hub.Super hard abrasive point 12 can have or not have substrate supports thing.Substrate supports thing can be that hard metal support is as tungsten carbide supported thing.
As shown in FIG. 2, cutter 10 can comprise the super hard abrasive point 12 with tungsten carbide supported thing 20.Super hard abrasive point 12 can have polycrystal cubic boron nitride (PcBN) particle.Cutting tool 10 also can comprise the cutter hub 14 keeping super hard abrasive point 12.The non brazing material 24 of the fusing point can with at least 1000 DEG C can be deposited with filled sidewall gap 16 and gap, bottom 15.Non brazing material 24 can be at least one in such as zeolite, pottery, cubic boron nitride and diamond.Cutting tool 10 also can comprise coating, such as, impregnant bonding coat 22 on the non brazing material 24 between super hard abrasive point 24 and cutter hub.Impregnant bonding coat 22 can cover the super hard abrasive point 12 of sintering, substrate supports 20 and cutter hub 14.Impregnant bonding coat can comprise at least one of the IVB compounds of group containing C, N, O, B, such as TiN, TiC and TiCN, ZrN, ZrC, ZrCN, HfN, HfC, HfCN.
The amplification optical imagery shown in Fig. 3 illustrates, coating 22 is whole cubic boron nitride crystal 24 as TiN may cover.Coating 22 can also provide non brazing material as cBN, diamond or zeolite, the bonding between super hard abrasive point 20 and cutter hub 14.
Because non brazing material has the fusing point of at least 1000 DEG C, so can by high-temperaure coating as Al 2o 3the non brazing material that (not shown) deposited or was applied to the super hard abrasive point 12 of sintering, cutter hub 14 and is arranged between super hard abrasive point 12 and cutter hub 24.
Fig. 4 shows the illustrative methods 400 of the technique manufacturing cutting tool.Described technique comprises the steps: to provide super hard abrasive point in step 401; There is provided cutter hub in step 402; The gap between super hard abrasive point and cutter hub is filled in step 403 with non brazing material; Be coated with first in step 404 and be deposited to non brazing material.
The super hard abrasive point of sintering can be attached to cutter hub by certain methods.Then cutting tool can be placed in CVD (chemical vapour deposition (CVD)) reaction vessel, wherein remove air and replaced by the gas comprising inertia and reactive species.Metal deposition can adopt and comprise metal carbonyl or metal acetal acetonate as the gas of iron pentacarbonyl.Pottery precursors to deposit can refer to the compound containing N, C and O, its cracking at lower than the temperature of 1000 DEG C.In some illustrative embodiments, ceramic precursors to deposit can comprise such as TiCl 4, NH 3, CH 4, AlCl 3, (Me) 3al, N 2, CH 3cN, H 2, CO, CO 2or its mixture.Gas by diffusing and penetrate in gap, seam, contact gap, and be deposited on outside or inside in a device can close to the heat solid of gas on the surface.From the teeth outwards during condensation, condensation phase chemistry ground reacts thus forms the new solid-phase as the first coating.First coating can be by super hard abrasive point, the impregnant coating of cutter hub together with non brazing material binding.Such as, TiCl 4+ CH 4→ TiC solid+gas phase 4HCl.This solid-phase depends on that chemical affinity is adhesively bonded to the surface of solids.The quality (crystal perfection, density) of solid-phase depends on temperature and the affinity to the surface of solids, and they are condensate on the described surface of solids.As long as temperature is enough high and there is reactant, then forms the infiltration of new solid-phase, the technique of condensation and reaction continues to carry out.Once hole is filled, super hard abrasive point and cutter keep material surface just there will be direct coating.
Gas accessibility is spread by gas and determines, it depends on temperature and pressure.Lower pressure allows reactant gas to be more in depth diffused in seam in tool assembly and gap.Must be controlled the gas aggradation of formation solid, reaction and curing degree thus prevent from too early " obstruction " occurring in narrow gap and seam, being reduced film contact area and strength of joint thus.This needs to reduce temperature usually, or regulates the gaseous phase partial pressure of reactant.Finally, the quality of the film of formation, its degree of crystallinity and crystal orientation depend on temperature and time.If film is too fast formed and quenches, it may be of poor quality and break in film or at film-point or film-tool interface place.
Importantly, no matter the orientation in reactor, vapor precursor and the surface of solids indistinguishably react.So-called " sight line " depositing operation, may be effective unlike vapor precursor as physical vapour deposition (PVD) (PVD), and the impermeable gap of possibility and seam, significantly reduce adhered area and adhesion strength thus.
In addition, non-line-of-sight CVD coating does not need turning tool and repeatedly processes to form uniform coating.In a stove cycle, CVD is coated with the come-at-able surface of whole gas.
The gas-phase reaction that also can be regarded as CVD comprises any gas solids reaction, such as oxidation, hydration or carburizing.Solid constituent can first be adsorbed on the surface, then reaction and crystallization, or can be formed on surface before reaction and crystallization and be deposited by solid surface tension.
After can carrying out ,-CVD process is if annealing is with the quality or the film-point/film-cutter adhesiveness that improve film.
When not deviating from the scope of present disclosure, for each step in abovementioned steps 401-404, one or more step can be inserted therebetween or replace.
Although made reference to detailed description of the invention, it is evident that, when not deviating from its purport and scope, those skilled in the art can design other embodiment and variant.Be intended to appended claims to be interpreted as and comprise whole this embodiment and equivalent variations.

Claims (28)

1. a cutting tool, described cutting tool comprises:
The super hard abrasive point of sintering, it has multiple ultra-hard particles;
Cutter hub, it keeps described super hard abrasive point; With
Non brazing material, it fills the gap between described super hard abrasive point and described cutter hub.
2. the cutting tool of claim 1, wherein said ultra-hard particles is selected from cubic boron nitride, diamond, diamond composites, and ceramic material.
3. the cutting tool of claim 1, wherein said non brazing material is at least one in zeolite, cubic boron nitride, diamond and pottery.
4. the cutting tool of claim 1, is also included in the coating on described non brazing material.
5. the cutting tool of claim 1, wherein said non brazing material has the fusing point of at least 1000 DEG C.
6. the cutting tool of claim 4, wherein said coating comprises at least one in the IVB compounds of group containing C, N, O, B.
7. the cutting tool of claim 1, wherein said cutter hub is made up of at least one in tungsten carbide, pottery or cermet.
8. the cutting tool of claim 4, wherein said coating covers the super hard abrasive point of described sintering and described cutter hub.
9. a method, described method comprises:
Super hard abrasive point is provided;
Cutter hub is provided;
The gap between described super hard abrasive point and described cutter hub is filled with non brazing material; With
Be coated with first and be deposited on described non brazing material.
10. the method for claim 9, also comprises deposition first coating, and described first coating is by described super hard abrasive point, the impregnant coating of described cutter hub together with described non brazing material binding.
The method of 11. claims 10, wherein said first coating comprises at least one of the IVB compounds of group containing C, N, O, B.
The method of 12. claims 9, also comprises the super hard abrasive point the second coating or a series of laminated coating being deposited to described sintering, described cutter hub and described non brazing material.
The method of 13. claims 12, wherein said second coating or a series of laminated coating comprise at least one deck refractory oxide coating.
The method of 14. claims 12, wherein said refractory oxide coating is aluminum oxide coating layer.
The method of 15. claims 11, also comprise bonding described non brazing material, sintering super hard abrasive point and described cutter hub.
The method of 16. claims 9, the deposition of wherein said first coating is undertaken by chemical vapour deposition (CVD).
The method of 17. claims 9, the deposition of wherein said first coating is undertaken by chemical vapor infiltration.
18. 1 kinds of cutting tools, described cutting tool comprises:
The super hard abrasive point of sintering, it has multiple ultra-hard particles;
Cutter hub, it keeps described super hard abrasive point;
Impregnant bonding coat, it is between described super hard abrasive point and described cutter hub; With
High-temperaure coating, its be deposited on described sintering super hard abrasive point and described cutter hub on.
The cutting tool of 19. claims 18, also comprises the non brazing material be arranged between described super hard abrasive point and described cutter hub.
The cutting tool of 20. claims 18, wherein said high-temperaure coating is aluminium oxide.
The cutting tool of 21. claims 19, wherein said non brazing material binding is to described super hard abrasive point and described cutter hub.
The cutting tool of 22. claims 18, wherein said super hard abrasive point has ultra-hard particles, and wherein said super hard abrasive particle is selected from cubic boron nitride, diamond, diamond composites and ceramic material.
The cutting tool of 23. claims 19, wherein said non brazing material comprises at least one in zeolite, cubic boron nitride, diamond and ceramic material.
The cutting tool of 24. claims 23, wherein said non brazing material is bondd by one or more high temperature coating.
The cutting tool of 25. claims 18, wherein said high temperature coating is selected from least one of the IVB compounds of group containing C, N, O, B.
The cutting tool of 26. claims 18, the super hard abrasive point of wherein said sintering has substrate supports thing.
The cutting tool of 27. claims 26, wherein said substrate supports thing is hard metal support.
The cutting tool of 28. claims 27, wherein said hard metal support is tungsten carbide.
CN201480009571.XA 2013-02-28 2014-02-27 CVI bonded and coated PCBN to WC tool body Pending CN105188996A (en)

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