CN105176638A - Chain lubricating oil composite agent and preparation method thereof - Google Patents
Chain lubricating oil composite agent and preparation method thereof Download PDFInfo
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Abstract
The invention relates to a chain lubricating oil composite agent and a preparation method thereof. The chain lubricating oil composite agent is characterized in that it comprises the following components by mass percentage: 40-60 mass% of softening oil; 10-20 mass% of an amine antioxidant; 8-20 mass% of a phenolic antioxidant; 8-20 mass% of an antiwear agent; 1-10 mass% of a friction improver; and 1-10 mass% of an ashless antirust agent. The high temperature chain lubricating oil prepared from the composite agent provided by the invention has superstrong oxidation resistance, wear resistance and corrosion resistance, so that the high temperature chain can acquire lower friction coefficient in work, safer and more reliable machine operation is ensured, the comprehensive performance is more excellent, and the antirust capability of the chain metal is further enhanced.
Description
Technical field
The application relates to a kind of chain greasisng oil recombiner, and more definite is a kind ofly has superpower high-temperature oxidation resistant stability and the chain greasisng of antifriction energy-saving oil recombiner.
Background technology
Chain is chain link or the annulation of metal, as mechanical transmission or traction.Along with the fast development of industry, machinery equipment is maked rapid progress, and operating mode service temperature is more and more high.Because high-temperature chain has special high temperature resistant property, be widely used under more occasion.Therefore the trend of the high-temperature chain lubricating oil development of a new generation has more excellent oxidation stability and heat-resistant quality energy, to guarantee or to extend the drain period of oil product, meanwhile, also needs to possess the features such as excellent resistance to abrasion, antifriction energy-saving and low carbon distribution proneness.
The extreme pressure agent of common middle low temperature amine, phenolic antioxidant and sulfur-bearing, phosphorus has certain antioxidant property and abrasion resistance, but regenerate along with equipment is constantly updated, operation working condition requirement is more and more harsher, and traditional high-temperature chain lubricating oil can not meet the normal operation of equipment.Compared with common lubricant, high-temperature chain lubricating oil requires more harsh, to ensure abrasion resistance and anti-oxidant dual property to the compatibility synergistic effect of oxidation inhibitor.Domestic and international in order to enable high-temperature chain lubricating oil life-time service under worst hot case at present, usually liquid amine and phenolic antioxidant is added, but these oxidation inhibitor flash-points are lower, generally can normally use at about 200 DEG C, thermolysis state has been in 230 DEG C time, namely lose resistance of oxidation, can not meet the operating mode of most of high-temperature chain more than 260 DEG C (as printing and dyeing mill's heat setting machine, tenter machine, the dry stove production line in paper mill, artificial board product line etc. are in the chain operating mode of more than 250 DEG C high bakes).
For the high-temperature chain lubricating oil composition (recombiner) that can use under higher than the high temperature of more than 260 DEG C, need to guarantee that high-temperature chain lubricating oil provides lubrication and anti-wear protection function in this worst hot case.Now high-temperature chain lubricating oil just with the addition of corresponding antioxygen, wear preventive additive to ensure this performance of high-temperature chain lubricating oil both at home and abroad, as Chinese invention patent application number be 201310349956.8 synthesizing high temperature chain greasisng oil, Chinese invention patent application number be 200910236609.8 high-temperature chain lubricating oil composition, all adopting common anti-wear agent, not mentioning for being reduced in the frictional coefficient played a key effect in the work of chain.Therefore exploitation has superpower resistance of oxidation, abrasion resistance and the lower high-temperature chain lubricating oil Promoter technique of frictional coefficient have become those skilled in the art Research Challenges and focus.
Summary of the invention
the problem that invention will solve
The object of the application is to provide a kind of chain greasisng oil recombiner being suitable for using under ultrahigh-temperature and preparation method thereof, the high-temperature chain lubricating oil prepared by the recombiner of the application has superpower oxidation-resistance, resistance to abrasion and Corrosion Protection, add friction improver simultaneously, for high-temperature chain obtains lower frictional coefficient at work, guarantee machine operation safety and reliability, over-all properties is more excellent; Add novel antirust agent in this application, improve the antirust ability to chain strip metal further.In addition the recombiner that the application provides is produced, it is convenient to add, and preparation is simple, and cost is low, applied range, is extremely beneficial to commercial introduction application.
for the scheme of dealing with problems
The application provides a kind of chain greasisng oil recombiner, is characterised in that, in each component total mass of described recombiner for 100%, comprises following component:
Chain greasisng oil recombiner according to the application, be characterised in that, in each component total mass of described recombiner for 100%, the content of softening oil is 40-50 quality %, the content of amine antioxidants is 10-15 quality %, and the content of phenolic antioxidant is 10-15 quality %, and the content of anti-wear agent is 10-15 quality %, the content of friction improver is 2-8 quality %, and the content of ashless anti-rusting additive is 2-8 quality %.
Chain greasisng oil recombiner according to the application, be characterised in that, described softening oil be the refining base oil of dewaxing, polyalphaolefin, pentaerythritol ester, bis(pentaerythritolester), trimellitate, bis adipate, tricarboxymethyl propane oleate, two different tridecanol dibasic acid esters, bis phthalate, multiple ester, polyoxyethylene glycol, silicone oil one or more.
Chain greasisng oil recombiner according to the application, be characterised in that, described amine antioxidants is right, one or more of p octtttyl diphenylamine, octyl group-butyl pentanoic, alkylation phenyl-a-naphthylamine.
Chain greasisng oil recombiner according to the application, be characterised in that, described phenolic antioxidant is that sulfur-bearing ether phenol, metal organic disulfide are for phosphoric acid salt, containing ester group phenol, containing ester group hindered phenol, 2,6-ditertbutylparacresol, 2, one or more of 6-di-t-butyl mixed ester, 2,6-di-t-butyls-alpha, alpha-dimethyl nitrogen base p-cresol.
Chain greasisng oil recombiner according to the application, be characterised in that, described anti-wear agent is antimony dialkyl-dithiocarbamate, methylene-bis Keywords dibutyl dithiocarbamate, phosphamide compounds, three potassium borate neutral oil dispersion liquids, chlorodiphenyl, acid phosphoric acid ester, acidic phosphite, sulfide fat oil, acid dibutyl phosphite, sulphur phosphoric acid nitrogen containing derivative, tritolyl phosphate, thiophosphoric acid amine salt, isooctyl acid phosphoric acid ester stearylamine salt, tri o cresyl thiophosphate alizarinic acid, sulfide isobutene, dibenzyldisulfide, aminothio ester, lead naphthenate, dibutyl dithiocaarbamate molybdenum, dibutyl dithiocaarbamate antimony, dibutyl dithiocaarbamate is plumbous, borate, boronation oleylamide, A-type organocopper compound, tricresyl phosphate (2, 3-propylene dichloride) one or more of ester.
Chain greasisng oil recombiner according to the application, be characterised in that, described friction improver be polyester type friction improver, oleic acid epoxy ester, tricarbimide trimeric cyanamide, organic boron low friction compound, sulphur molybdenum phosphate, phosphoric acid ester, the metal-salt of sulfuration and many sulfurorganics, organic aliphatic acid, organophosphorus one or more.
Chain greasisng oil recombiner according to the application, be characterised in that, described ashless anti-rusting additive is ammonium phosphate type compound, synthesis barium sulfonate, heavy alkylbenzene sulfonic acid barium, petroleum sodium sulfonate, synthetic sodium sulfonate, sodium heavy alkyl benzene sulfonate, 17 alkenyl imidazoline alkenyl succinates, zinc naphthenate, barium dinonyl napthalene sulphonate, benzotriazole, synthesis sulfonic acid magnesium, alkylphosphonic acid carboxylic acid imidazoline salt, oxidized petrolatum barium soap, alkenyl succinic acid ester, lanolin magnesium soap, dehydrating sorbitol monooleate, triethanolamine oleate ester, sulfonated castor oil, ricinoleic ester potassium, three ancient butylamine, lanolin, metal organic disulfide is for phosphoric acid salt, one or more of metal alkylide sulfonate.
The application also provides a kind of preparation method of the chain greasisng oil recombiner according to the application, is characterised in that, comprises the step of each component mixing of described recombiner.
Method according to the application, is characterised in that, comprises the following steps:
(1) softening oil is added container;
(2) amine antioxidants, phenolic antioxidant is added, stirring and dissolving;
(3) add anti-wear agent, friction improver, ashless anti-rusting additive, stir, obtain described recombiner.
the effect of invention
The high-temperature chain lubricating oil of ultrahigh-temperature chain greasisng oil prepared by recombiner provided by the application, has excellent ultrahigh-temperature antioxidant property, inhibits oil product rapid oxidation under worst hot case to go bad.Because oxidation inhibitor preferred in the application is two kinds of polymeric powder shape ultrahigh-temperature oxidation inhibitor, its decomposition temperature is up to more than 320 DEG C, far away higher than ordinary liquid amine, 230 DEG C of phenolic antioxidant, ensure that the normal use of high-temperature chain lubricating oil temperature case more than 260 DEG C.Wherein with the addition of the ashless polyester type friction improver etc. of world-leading technology especially, greatly reduce chain frictional coefficient in the course of the work, effectively extend work-ing life and the secure persistent running of chain.
In addition, add Ashless type anti-wear agent and can be the abrasion resistance that high-temperature chain lubricating oil provides excellence, can work in coordination with antioxidant the antioxidant property improving high-temperature chain lubricating oil further adding of Ashless type anti-wear agent simultaneously, and possess certain antirust ability.The application also adopts ashless anti-rusting additive, and it is without any high-temperature residual, matches in this application with Ashless type anti-wear agent, can provide a more preferably rustless property for high-temperature chain.
Embodiment
The application provides a kind of chain greasisng oil recombiner, is characterised in that, in each component total mass of described recombiner for 100%, comprises following component:
The chain greasisng oil recombiner of the application, wherein softening oil be the refining base oil of dewaxing, polyalphaolefin, pentaerythritol ester, bis(pentaerythritolester), trimellitate, bis adipate, tricarboxymethyl propane oleate, two different tridecanol dibasic acid esters, bis phthalate, multiple ester, polyoxyethylene glycol, silicone oil one or more.
Be 100% calculating with each component total mass of recombiner, the addition of softening oil is 40-60 quality %, preferred 40-50 quality %, preferably, each component can effectively merge collaborative by the softening oil of addition described in the application, prevents from cannot dissolving each other the problem such as the disabler caused or the recombiner turbid appearance occurred because of each component.If the addition of softening oil is less than the addition described in the application, then cause recombiner cannot be fused to best miscible state, if the addition of softening oil is greater than the addition described in the application, then softening oil accounting is too high, cannot provide a best antioxygen, the performance such as wear-resistant for high-temperature chain lubricating oil.
The chain greasisng oil recombiner of the application, wherein said amine antioxidants is right, one or more of p octtttyl diphenylamine, octyl group-butyl pentanoic, alkylation phenyl-a-naphthylamine.
Be 100% calculating with each component total mass of recombiner, the addition of amine antioxidants is 10-20 quality %, preferred 10-15 quality %, preferably, the amine antioxidants of addition described in the application can be high-temperature chain lubricating oil under worst hot case, provides a best resistance of oxidation.Amine antioxidants described in the application, its heat decomposition temperature, more than 320 DEG C, can be applicable to working temperature up in the chain greasisng oil of 300 DEG C, the rapid oxidation of lubricant base under worst hot case effectively can be suppressed to go bad, cause lubrication failure.If the addition of amine antioxidants is less than the addition described in the application, amine antioxidants contained in lubricating oil is in high temperature environments too small, cannot effectively suppress the Quick Oxidation of lubricant base to go bad.If the addition of amine antioxidants is greater than the addition described in the application, the high-temperature oxidation resistance of lubricating oil also cannot promote again, and can form increase and the waste of cost.
The chain greasisng oil recombiner of the application, wherein said phenolic antioxidant be sulfur-bearing ether phenol (such as: Sulfide-containing Hindered based high molecular amount phenol, trade mark IRGANOXL115), metal organic disulfide for phosphoric acid salt, containing ester group phenol (such as: containing ester group high molecular phenol, trade mark IRGANOXL135 etc.), containing ester group hindered phenol (such as: trade mark Naugalube531 etc.), 2,6-ditertbutylparacresol, 2, one or more of 6-di-t-butyl mixed ester, 2,6-di-t-butyls-alpha, alpha-dimethyl nitrogen base p-cresol.
Be 100% calculating with each component total mass of recombiner, the addition of phenolic antioxidant is 8-20 quality %, preferred 10-15 quality %, preferably, the phenolic antioxidant of addition described in the application can effectively and amine antioxidants work in coordination with the antioxidant property promoting high-temperature chain lubricating oil, phenolic antioxidant also has and suppresses high-temperature chain lubricating oil under worst hot case to form the usefulness of greasy filth carbon distribution because of high temperature oxidation, for prevent because of high temperature oxidation cause high-temperature chain oil ageing rotten, form greasy filth carbon distribution and cause that chain is stuck plays key effect.If the addition of phenolic antioxidant is less than the addition described in the application, then cannot effectively and amine antioxidants coordinated promote the antioxidant property of high-temperature chain oil, and enough suppression greasy filth carbon distribution performances cannot be provided.If the addition of phenolic antioxidant is greater than the addition described in the application, without obviously promoting on antioxidant property is collaborative, and too high accounting can cause the addition of lubricant base to reduce, and the lubrication protection of chain is also meaningless.
The chain greasisng oil recombiner of the application, wherein said friction improver is that polyester type friction improver is (only containing C, H and O, phosphoric acid salt, sulfonate, can not produce any coke and remain after high temperature), oleic acid epoxy ester, tricarbimide trimeric cyanamide, organic boron low friction compound, sulphur molybdenum phosphate, phosphoric acid ester, the metal-salt of sulfuration and many sulfurorganics, organic aliphatic acid, organophosphorus one or more.
Be 100% calculating with each component total mass of recombiner, the addition of friction improver is 1-10 quality %, preferred 2-8 quality %, preferably, the friction improver of addition described in the application, frictional coefficient can be reduced for the chain under continuous high temperature operation operating mode, avoid chain because of working accuracy not high, excessive and the phenomenon in shortening chains life-span of the frictional coefficient that surface irregularity brings, due to the reduction of chain friction coefficient, required for chain gear, kinetic energy also decreases, this effectively can reduce the kinetic energy needed for chain drive, thus low-energy consumption is fallen, directly show that the energy that propulsion source consumes reduces, reduce running cost.If the addition of friction improver is less than the addition described in the application, then cannot provide minimum frictional coefficient for high-temperature chain lubricating oil, will the performance in designed energy-saving and cost-reducing prolongation chain work-ing life do not realized.If the addition of friction improver is greater than the addition described in the application, realize reducing intermetallic frictional coefficient because friction improver is adsorbed in metallic surface formation protective filmy layer, add too much friction improver and also cannot form better protective benefits to metallic surface again.
The chain greasisng oil recombiner of the application, wherein said anti-wear agent is antimony dialkyl-dithiocarbamate, methylene-bis Keywords dibutyl dithiocarbamate, phosphamide compounds, three potassium borate neutral oil dispersion liquids, chlorodiphenyl, acid phosphoric acid ester, acidic phosphite, sulfide fat oil, acid dibutyl phosphite, sulphur phosphoric acid nitrogen containing derivative, tritolyl phosphate, thiophosphoric acid amine salt, isooctyl acid phosphoric acid ester stearylamine salt, tri o cresyl thiophosphate alizarinic acid, sulfide isobutene, dibenzyldisulfide, aminothio ester, lead naphthenate, dibutyl dithiocaarbamate molybdenum, dibutyl dithiocaarbamate antimony, dibutyl dithiocaarbamate is plumbous, borate, boronation oleylamide, A-type organocopper compound, tricresyl phosphate (2, 3-propylene dichloride) one or more of ester.
Be 100% calculating with each component total mass of recombiner, the addition of anti-wear agent is 8-20 quality %, preferred 10-15 quality %, preferably, the anti-wear agent of addition described in the application, the chain damage that can effectively prevent chain in operation process because load or intermetallic wearing and tearing cause, extends the work-ing life of chain greatly, the replacing of element part reduces, and also directly shows the reduction of production cost.If the addition of anti-wear agent is less than the addition described in the application, then high-temperature chain lubricating oil cannot realize the intermetallic wearing and tearing minimum value under best extreme pressure operating mode, excellent extreme pressure and antiwear behavior can not be provided, the safe and reliable operation of chain under heavy loading operating mode cannot be realized.If the addition of anti-wear agent is greater than the addition described in the application, then exceed extreme pressure anti-wear additives the best in high-temperature chain lubricating oil and add proportioning, will there is lubrication failure in shared base oil proportioning space, reduce the phenomenon of lubrication usefulness.
The chain greasisng oil recombiner of the application, wherein said ashless anti-rusting additive is ammonium phosphate type compound, synthesis barium sulfonate, heavy alkylbenzene sulfonic acid barium, petroleum sodium sulfonate, synthetic sodium sulfonate, sodium heavy alkyl benzene sulfonate, 17 alkenyl imidazoline alkenyl succinates, zinc naphthenate, barium dinonyl napthalene sulphonate, benzotriazole, synthesis sulfonic acid magnesium, alkylphosphonic acid carboxylic acid imidazoline salt, oxidized petrolatum barium soap, alkenyl succinic acid ester, lanolin magnesium soap, dehydrating sorbitol monooleate, triethanolamine oleate ester, sulfonated castor oil, ricinoleic ester potassium, three ancient butylamine, lanolin, metal organic disulfide is for phosphoric acid salt, one or more of metal alkylide sulfonate.
Be 100% calculating with each component total mass of recombiner, the addition of ashless anti-rusting additive is 1-10 quality %, preferred 2-8 quality %, preferably,, chemical reaction can be there is in chain metallic surface and form one deck chemical films, effectively prevent metal from contacting with the direct of moisture with oxygen in the ashless anti-rusting additive of addition described in the application, thus prevent the corrosion of metal, ensure that the normal use of chain.If the addition of ashless anti-rusting additive is less than the addition described in the application, then rust-preventive agent cannot be implemented in metallic surface and form chemical films fully, cannot realize effective rust protection protection of metallic surface.If the addition of ashless anti-rusting additive is greater than the addition described in the application; the antirust ability of metal cannot be promoted further; because ashless anti-rusting additive forms layer of metal protective membrane to realize antirust function at metal surface generation chemical reaction; too much rust-preventive agent material participates in the chemical reaction with metal; then can form a destruction to metal surface; under the performance not realizing metal rust preventing, also can cause the infringement of chain metallic surface.
In addition to the components described above, the recombiner of the application can also comprise other conventional binder components.
The application also provides a kind of preparation method of described chain oils recombiner, is characterised in that, comprises the step of each component mixing of described recombiner.
Preferably, said method comprising the steps of:
(1) softening oil is added container;
(2) amine antioxidants, phenolic antioxidant is added, stirring and dissolving;
(3) add anti-wear agent, friction improver, ashless anti-rusting additive, stir, obtain described recombiner.
More preferably, said method comprising the steps of:
(1) softening oil is squeezed into stainless steel mediation still, be heated to 85-95 DEG C;
(2) amine antioxidants, phenolic antioxidant is added, stirring and dissolving under 85-95 DEG C of constant temperature;
(3) be cooled to 40-60 DEG C, add anti-wear agent, friction improver, ashless anti-rusting additive, stir, filter the recombiner namely obtaining finished product.
Below provide the embodiment of the application, it only for explaining and illustration purpose, does not limit the application.In an embodiment, " part " refers to " mass parts ".
Embodiment 1
By softening oil bis(pentaerythritolester) (U.S. HATCOL, trade mark HATCOL3165, lower with) 50 parts squeeze into clean stainless steel and be in harmonious proportion still, be heated to 90 DEG C, add amine antioxidants pair, p octtttyl diphenylamine (BASF Aktiengesellschaft, trade mark IRGANOXL01, lower with) 15 parts, add phenolic antioxidant sulfur-bearing ether phenol (BASF Aktiengesellschaft, IRGANOXL115, lower with) 11 parts, uniform stirring 40 minutes at 90 DEG C of temperature; Be cooled to 55 DEG C, add polyester type friction improver (standing grain major company of Britain, trade mark Perfad3000, lower with) 8 parts, add Ashless type anti-wear agent antimony dialkyl-dithiocarbamate (Tiarco company of the U.S., trade mark OctopolPTB, lower with) 11 parts, ashless anti-rusting additive ammonium phosphate type compound (Vanderbilt company of the U.S., trade mark Vanlube9123,5 parts down together), uniform stirring 30 minutes, filters and namely obtains finished product recombiner I.
Embodiment 2
Softening oil bis(pentaerythritolester) 50 parts is squeezed into clean stainless steel mediation still, be heated to 90 DEG C, add amine antioxidants pair, p octtttyl diphenylamine 11 parts, add 15 parts, phenolic antioxidant sulfur-bearing ether phenol, uniform stirring 40 minutes at 90 DEG C of temperature; Be cooled to 55 DEG C, add polyester type friction improver 4 parts, add Ashless type anti-wear agent antimony dialkyl-dithiocarbamate 15 parts, ashless anti-rusting additive ammonium phosphate type compound 5 parts, uniform stirring 30 minutes, filter and namely obtain finished product recombiner II.
Embodiment 3
Softening oil bis(pentaerythritolester) 50 parts is squeezed into clean stainless steel mediation still, be heated to 90 DEG C, add amine antioxidants pair, p octtttyl diphenylamine 15 parts, add 11 parts, phenolic antioxidant sulfur-bearing ether phenol, uniform stirring 40 minutes at 90 DEG C of temperature; Be cooled to 55 DEG C, add friction improver phosphoric acid ester (Hongze Zhong Peng petroleum additive company limited, trade mark T451) 8 parts, add Ashless type anti-wear agent antimony dialkyl-dithiocarbamate 11 parts, ashless anti-rusting additive ammonium phosphate type compound 5 parts, uniform stirring 30 minutes, filters and namely obtains finished product recombiner III.
Comparative example 1
Softening oil bis(pentaerythritolester) 50 parts is squeezed into clean stainless steel mediation still, be heated to 90 DEG C, add amine antioxidants pair, p octtttyl diphenylamine 15 parts, add 15 parts, phenolic antioxidant sulfur-bearing ether phenol, uniform stirring 40 minutes at 90 DEG C of temperature; Be cooled to 55 DEG C, add Ashless type anti-wear agent antimony dialkyl-dithiocarbamate 15 parts, ashless anti-rusting additive ammonium phosphate type compound 5 parts, uniform stirring 30 minutes, filter and namely obtain finished product recombiner IV.
Comparative example 2
Softening oil bis(pentaerythritolester) 50 parts is squeezed into clean stainless steel mediation still, be heated to 90 DEG C, add amine antioxidants pair, p octtttyl diphenylamine 15 parts, add 11 parts, phenolic antioxidant sulfur-bearing ether phenol, uniform stirring 40 minutes at 90 DEG C of temperature; Be cooled to 55 DEG C, add friction improver nanometer boron ceramic friction improving agent (how chemistry (mountain of mobilizing troop) company limited, trade mark KMK101) 8 parts, add Ashless type anti-wear agent antimony dialkyl-dithiocarbamate 11 parts, ashless anti-rusting additive ammonium phosphate type compound 5 parts, uniform stirring 30 minutes, filters and namely obtains finished product recombiner V.
Comparative example 3
Softening oil bis(pentaerythritolester) 20.5 parts is squeezed into clean stainless steel mediation still, be heated to 90 DEG C, add amine antioxidants pair, p octtttyl diphenylamine 22 parts, add 22 parts, phenolic antioxidant sulfur-bearing ether phenol, uniform stirring 40 minutes at 90 DEG C of temperature; Be cooled to 55 DEG C, add polyester type friction improver 0.5 part, add Ashless type anti-wear agent antimony dialkyl-dithiocarbamate 22 parts, ashless anti-rusting additive ammonium phosphate type compound 13 parts, uniform stirring 30 minutes, filter and namely obtain finished product recombiner VI.
With the quality of base oil for benchmark, recombiner I, II, III, IV, V, VI of obtaining in embodiment 1-3 and comparative example 1-3 are called in base oil respectively in the ratio of 9 quality %, described base oil consists of trimellitate (the standing grain major company of Britain of 56 quality %, trade mark Priolube1938), bis(pentaerythritolester) (HATCO Corp. of the U.S. of 20 quality %, trade mark HATCOL5150), multiple ester (the standing grain major company of Britain of 15 quality %, trade mark Priolube3986), four to form content sum be 100 quality %.After tested, the property indices of the high-temperature chain lubricating oil prepared by above-mentioned chain greasisng oil recombiner I, II, III, IV, V, VI is in table 1.
The performance index of high-temperature chain lubricating oil prepared by table 1 chain greasisng oil recombiner
Can draw from the indices of the embodiment 1 of table 1, embodiment 2 and embodiment 3; high-temperature chain oil after described high-temperature chain oil recombiner blending possesses lower frictional coefficient; and very little carbon residue and excellent abrasion resistance; the performance of every excellence shows, the high-temperature chain oil prepared by high-temperature chain oil recombiner of the present invention possesses the ability meeting chain and provide safety lubricating to protect under worst hot case.
Relative to embodiment 1, embodiment 2 with the high-temperature chain oil recombiner of comparative example 2, comparative example 1 does not add friction improver, the frictional coefficient reflecting high-temperature chain lubricating oil 4 in the frictional coefficient index of table 1 is relatively large, and this illustrates: friction improver effectively can reduce the frictional coefficient of chain in operation process in high-temperature chain lubricating oil.
The friction improver beyond scope described in the application is have selected in comparative example 2, as shown in Table 1, after the friction improver selected in comparative example 2 reconciles into high-temperature chain lubricating oil, the index of its Conradson carbon residue is very undesirable, after burning, residue is more, and be easily attached on chain, and then the generation of the stuck of chain and coking phenomenon may be caused; Also can see in frictional coefficient index, the performance of frictional coefficient is deteriorated along with the replacing of friction improver simultaneously.Along with the increase of frictional coefficient in chain operation process, the intermetallic abrasion of chain also can increase, and directly will have influence on the safe operation of chain.
In the chain greasisng oil recombiner of comparative example 3, component described in the application is not all in mass ratio described in the application, as can be seen from the performance index of the high-temperature chain oil 6 of table 1, rust-inhibiting additive add excessive after fail to reach the rust-proof effect of expection, rust-proof effect is poor on the contrary; Can find out at abrasion resistance and extreme pressure property index, the excessive use of extreme pressure anti-wear additives also obtain the more serious index of a galling; Frictional coefficient performance index particularly described in the application, after below the mass percentage that friction improver is reduced to described in the application, can find out from frictional coefficient performance index, fail to realize a good frictional coefficient, also cause the design that cannot realize saving energy and reduce the cost.
As can be seen from comparative example 3; each component cannot realize effective collaborative; the very large index defect that finally caused high-temperature chain lubricating oil 6 to occur, cannot realize the normal lubrication protection to chain, this also show each component effectively collaborative be the key that can obtain an excellent high-temperature chain oil.
Claims (10)
1. a chain greasisng oil recombiner, is characterised in that, in each component total mass of described recombiner for 100%, comprises following component:
2. chain greasisng oil recombiner according to claim 1, be characterised in that, in each component total mass of described recombiner for 100%, the content of softening oil is 40-50 quality %, the content of amine antioxidants is 10-15 quality %, and the content of phenolic antioxidant is 10-15 quality %, and the content of anti-wear agent is 10-15 quality %, the content of friction improver is 2-8 quality %, and the content of ashless anti-rusting additive is 2-8 quality %.
3. chain greasisng oil recombiner according to claim 1 and 2, be characterised in that, described softening oil be the refining base oil of dewaxing, polyalphaolefin, pentaerythritol ester, bis(pentaerythritolester), trimellitate, bis adipate, tricarboxymethyl propane oleate, two different tridecanol dibasic acid esters, bis phthalate, multiple ester, polyoxyethylene glycol, silicone oil one or more.
4. the chain greasisng oil recombiner according to any one of claim 1-3, be characterised in that, described amine antioxidants is right, one or more of p octtttyl diphenylamine, octyl group-butyl pentanoic, alkylation phenyl-a-naphthylamine.
5. the chain greasisng oil recombiner according to any one of claim 1-4, be characterised in that, described phenolic antioxidant is that sulfur-bearing ether phenol, metal organic disulfide are for phosphoric acid salt, containing ester group phenol, containing ester group hindered phenol, 2,6-ditertbutylparacresol, 2, one or more of 6-di-t-butyl mixed ester, 2,6-di-t-butyls-alpha, alpha-dimethyl nitrogen base p-cresol.
6. the chain greasisng oil recombiner according to any one of claim 1-5, be characterised in that, described anti-wear agent is antimony dialkyl-dithiocarbamate, methylene-bis Keywords dibutyl dithiocarbamate, phosphamide compounds, three potassium borate neutral oil dispersion liquids, chlorodiphenyl, acid phosphoric acid ester, acidic phosphite, sulfide fat oil, acid dibutyl phosphite, sulphur phosphoric acid nitrogen containing derivative, tritolyl phosphate, thiophosphoric acid amine salt, isooctyl acid phosphoric acid ester stearylamine salt, tri o cresyl thiophosphate alizarinic acid, sulfide isobutene, dibenzyldisulfide, aminothio ester, lead naphthenate, dibutyl dithiocaarbamate molybdenum, dibutyl dithiocaarbamate antimony, dibutyl dithiocaarbamate is plumbous, borate, boronation oleylamide, A-type organocopper compound, tricresyl phosphate (2, 3-propylene dichloride) one or more of ester.
7. the chain greasisng oil recombiner according to any one of claim 1-6, be characterised in that, described friction improver be polyester type friction improver, oleic acid epoxy ester, tricarbimide trimeric cyanamide, organic boron low friction compound, sulphur molybdenum phosphate, phosphoric acid ester, the metal-salt of sulfuration and many sulfurorganics, organic aliphatic acid, organophosphorus one or more.
8. the chain greasisng oil recombiner according to any one of claim 1-7, be characterised in that, described ashless anti-rusting additive is ammonium phosphate type compound, synthesis barium sulfonate, heavy alkylbenzene sulfonic acid barium, petroleum sodium sulfonate, synthetic sodium sulfonate, sodium heavy alkyl benzene sulfonate, 17 alkenyl imidazoline alkenyl succinates, zinc naphthenate, barium dinonyl napthalene sulphonate, benzotriazole, synthesis sulfonic acid magnesium, alkylphosphonic acid carboxylic acid imidazoline salt, oxidized petrolatum barium soap, alkenyl succinic acid ester, lanolin magnesium soap, dehydrating sorbitol monooleate, triethanolamine oleate ester, sulfonated castor oil, ricinoleic ester potassium, three ancient butylamine, lanolin, metal organic disulfide is for phosphoric acid salt, one or more of metal alkylide sulfonate.
9. the preparation method of the chain greasisng oil recombiner according to any one of claim 1-8, is characterised in that, comprises the step of each component mixing of described recombiner.
10. method according to claim 9, is characterised in that, comprises the following steps:
(1) softening oil is added container;
(2) amine antioxidants, phenolic antioxidant is added, stirring and dissolving;
(3) add anti-wear agent, friction improver, ashless anti-rusting additive, stir, obtain described recombiner.
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1091153A (en) * | 1994-01-06 | 1994-08-24 | 王学绍 | Lubricating oil composition |
| CN1580611A (en) * | 2003-08-13 | 2005-02-16 | 日产自动车株式会社 | Chain driving system |
| CN101117609A (en) * | 2006-08-04 | 2008-02-06 | 中国石油天然气股份有限公司大连润滑油研究开发中心 | High-temperature chain oil and preparation method thereof |
| CN101328445A (en) * | 2007-12-06 | 2008-12-24 | 中国石油化工股份有限公司 | Lubricating anticorrosive oil and use thereof |
| CN102250672A (en) * | 2011-06-07 | 2011-11-23 | 山东源根石油化工有限公司 | Mineral-oil-based high-temperature chain oil and preparation method thereof |
-
2015
- 2015-06-30 CN CN201510373836.0A patent/CN105176638B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1091153A (en) * | 1994-01-06 | 1994-08-24 | 王学绍 | Lubricating oil composition |
| CN1580611A (en) * | 2003-08-13 | 2005-02-16 | 日产自动车株式会社 | Chain driving system |
| CN101117609A (en) * | 2006-08-04 | 2008-02-06 | 中国石油天然气股份有限公司大连润滑油研究开发中心 | High-temperature chain oil and preparation method thereof |
| CN101328445A (en) * | 2007-12-06 | 2008-12-24 | 中国石油化工股份有限公司 | Lubricating anticorrosive oil and use thereof |
| CN102250672A (en) * | 2011-06-07 | 2011-11-23 | 山东源根石油化工有限公司 | Mineral-oil-based high-temperature chain oil and preparation method thereof |
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| CN108587748A (en) * | 2018-06-07 | 2018-09-28 | 芜湖市欧贝润滑剂有限责任公司 | A kind of wear-resistant antirust chain grease |
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