CN105176450A - Blending polymer with function of silica gel and acrylate glue and preparation method of blending polymer - Google Patents
Blending polymer with function of silica gel and acrylate glue and preparation method of blending polymer Download PDFInfo
- Publication number
- CN105176450A CN105176450A CN201510575025.9A CN201510575025A CN105176450A CN 105176450 A CN105176450 A CN 105176450A CN 201510575025 A CN201510575025 A CN 201510575025A CN 105176450 A CN105176450 A CN 105176450A
- Authority
- CN
- China
- Prior art keywords
- silica gel
- esters
- polymer
- acrylic acid
- initiator
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention relates to a blending polymer with a function of silica gel and acrylate glue and a preparation method of the blending polymer. The preparation method of the blending polymer comprises the steps that a crosslinked mixture is prepared, wherein the crosslinked mixture is prepared from the following components in percentage by weight: 55 to 65 percent of n-butyl acrylate, 25 to 35 percent of 2-ethylhexyl acrylate, 5 to 10 percent of ethyl acrylate, 2 to 5 percent of crylic acid, 2 to 5 percent of hydroxyethyl acrylate, 0.2 to 1.5 percent of vinyl acetate, 0.2 to 1.5 percent of methylol acrylamide, ethyl acetate, toluene and initiator; the polymer is prepared, and the polymer is of a mixture of silicone rubber and MQ resin; the polymer is blended with the initiator, the crosslinked mixture is added, and the catalyzing is performed so that the polymer is polymerized for crosslinked polymer interpenetration, wherein, the crosslinked mixture and the polymer respectively are 40 to 50% and 50 to 60 % in percentage by weight.
Description
Technical field
The present invention relates to and a kind of there is polymer blend of silica gel and esters of acrylic acid glue function and preparation method thereof.
Background technology
Common esters of acrylic acid glue need be mixed into a certain proportion of silica gel because of application demand, but because silicon is incompatible with acrylic system, can not preserve after common being uniformly mixed for a long time, two kinds of easy layerings of material, cause application performance result undesirable, even can not reach independent vinylformic acid glue, the application performance of silica gel.
Summary of the invention
The object of this invention is to provide a kind of polymer blend with silica gel and esters of acrylic acid glue function; it is easy to preserve; stable performance, and the high peeling force of solvent-type acrylic presser sensor glue, high-temperature stability and the stability of silica gel, the protective value to affixed object can be had simultaneously.
To achieve these goals, the technical solution adopted in the present invention is as follows: comprise crosslinking mixture, polymkeric substance, initiator, described crosslinking mixture, polymkeric substance is respectively 40-50% by weight percentage, 50-60%, wherein, described crosslinking mixture comprises the n-butyl acrylate of 55-65% according to weight percent, the Isooctyl acrylate monomer of 25-35%, the ethyl propenoate of 5-10%, the vinylformic acid of 2-5%, the Hydroxyethyl acrylate of 2-5%, the vinyl acetate of 0.2-1.5%, the n-methylolacrylamide of 0.2-1.5%, ethyl acetate, toluene and initiator, described polymkeric substance is the mixture of silicon rubber and MQ resin.
Further, there is described in the polymer blend initiator used of silica gel and esters of acrylic acid glue function, described crosslinking mixture initiator used is BP amine or azo-bis-isobutyl cyanide.
Further, the solid content described in the polymer blend of silica gel and esters of acrylic acid glue function is 50%-60%.
Further, the polymer blend described in silica gel and esters of acrylic acid glue function also comprises linking agent.
The present invention also comprises a kind of preparation method with the polymer blend of silica gel and esters of acrylic acid glue function, comprises the steps:
Prepare crosslinking mixture, described crosslinking mixture comprises according to weight percent: the n-methylolacrylamide of the Hydroxyethyl acrylate of the ethyl propenoate of the n-butyl acrylate of 55-65%, the Isooctyl acrylate monomer of 25-35%, 5-10%, the vinylformic acid of 2-5%, 2-5%, the vinyl acetate of 0.2-1.5%, 0.2-1.5%, ethyl acetate, toluene and initiator;
Prepare polymkeric substance, described polymkeric substance is the mixture of silicon rubber and MQ resin;
Mixed with polymers initiator is added crosslinking mixture, and make polymer poly merge cross-linked polymer IPN through catalysis, wherein, described crosslinking mixture, polymkeric substance are respectively 40-50%, 50-60% by weight percentage.
Further, the preparation method of described crosslinking mixture is as follows:
S1: add the n-butyl acrylate of 27.5-32.5%, the Isooctyl acrylate monomer of 12.5-17.5%, the ethyl propenoate of 2.5-5%, the vinylformic acid of 1-2.5%, the Hydroxyethyl acrylate of 1-2.5%, the vinyl acetate of 0.1-0.75%, the n-methylolacrylamide of 0.1-0.75%, ethyl acetate and toluene in a kettle. according to weight percent and be warming up to 75 DEG C-95 DEG C, and then add benzoyl peroxide amine or Diisopropyl azodicarboxylate, and stir uniformly;
S2: according to weight percent add again the n-butyl acrylate of 27.5-32.5%, the Isooctyl acrylate monomer of 12.5-17.5%, the ethyl propenoate of 2.5-5%, the vinylformic acid of 1-2.5%, the Hydroxyethyl acrylate of 1-2.5%, the vinyl acetate of 0.1-0.75%, 0.1-0.75% n-methylolacrylamide, add ethyl acetate and toluene, and to stir uniformly.
Further, in described step S2: the n-methylolacrylamide of the ethyl propenoate of the n-butyl acrylate of described 27.5-32.5%, the Isooctyl acrylate monomer of 12.5-17.5%, 2.5-5%, the vinylformic acid of 1-2.5%, the Hydroxyethyl acrylate of 1-2.5%, the vinyl acetate of 0.1-0.75% and 0.1-0.75%, ethyl acetate, toluene need complete and add in 3 hours.
Further, described " mixed with polymers initiator, linking agent being added crosslinking mixture; make polymer poly merge cross-linked polymer IPN through catalysis " is specially: uniformly initiator is added to polymkeric substance in half an hour, by mixing of crosslinking mixture and polymer uniform, be incubated after 1 hour, be cooled to less than 50 DEG C.
Further, in mixed with polymers initiator " is added crosslinking mixture, makes polymer poly merge cross-linked polymer IPN through catalysis " by described step, while mixed with polymers initiator, mixed cross-linker is gone back.
Further, described initiator is BP amine or azo-bis-isobutyl cyanide.
By such scheme, the present invention at least has the following advantages: of the present invention have silica gel and solve after solvent-type acrylic ester class glue mixing silicon with the polymer blend of esters of acrylic acid glue function and be easy to be divided into the phenomenon being unfavorable for being coated with, and be easy to preserve, stable performance, and the high peeling force of solvent-type acrylic presser sensor glue, high-temperature stability and the stability of silica gel, the protective value to affixed object can be had simultaneously; And this preparation method is simple; easy to operate; both are made to become stable two-phase polymer by reaction; the prepared polymer blend with silica gel and esters of acrylic acid glue function is easy to preserve; stable performance, and the high peeling force of solvent-type acrylic presser sensor glue, high-temperature stability and the stability of silica gel, the protective value to affixed object can be had simultaneously.
Above-mentioned explanation is only the general introduction of technical solution of the present invention, in order to better understand technique means of the present invention, and can be implemented according to the content of specification sheets, be described in detail as follows below with preferred embodiment of the present invention.
Embodiment
Below in conjunction with embodiment, the specific embodiment of the present invention is described in further detail.Following examples for illustration of the present invention, but are not used for limiting the scope of the invention.
A kind of polymer blend with silica gel and esters of acrylic acid glue function of the present invention, comprise crosslinking mixture, polymkeric substance, initiator and linking agent, described crosslinking mixture, polymkeric substance is respectively 40-50% by weight percentage, 50-60%, wherein, described crosslinking mixture comprises the n-butyl acrylate of 55-65% according to weight percent, the Isooctyl acrylate monomer of 25-35%, the ethyl propenoate of 5-10%, the vinylformic acid of 2-5%, the Hydroxyethyl acrylate of 2-5%, the vinyl acetate of 0.2-1.5%, the n-methylolacrylamide of 0.2-1.5%, ethyl acetate, toluene and initiator, described polymkeric substance is the mixture of silicon rubber and MQ resin.
According to the actual requirements, it can not use described linking agent, and this linking agent is conventional linking agent in prior art.Described ethyl acetate and toluene only do chain-transfer agent adjustment polymkeric substance viscosity use, and not actual participation reaction, when reality uses, ethyl acetate is 30-80%, and toluene is 6-15%.Described to have in the polymer blend of silica gel and esters of acrylic acid glue function initiator used in initiator used, crosslinking mixture and be BP amine or azo-bis-isobutyl cyanide.In actual use, in crosslinking mixture, initiator used is 0.3%.This solid content with the polymer blend of silica gel and esters of acrylic acid glue function should between 50%-60%, and need add a certain proportion of solvent during application and do and dilute, so that coating, it can be applicable to stationery adhesive tape.
This preparation method with the polymer blend of silica gel and esters of acrylic acid glue function comprises following three steps,
The first step: prepare crosslinking mixture, described crosslinking mixture comprises according to weight percent: the n-methylolacrylamide of the Hydroxyethyl acrylate of the ethyl propenoate of the n-butyl acrylate of 55-65%, the Isooctyl acrylate monomer of 25-35%, 5-10%, the vinylformic acid of 2-5%, 2-5%, the vinyl acetate of 0.2-1.5%, 0.2-1.5%, ethyl acetate, toluene and initiator.When specifically using, ethyl acetate is 30-80%, and toluene is 6-15%, and initiator is 0.3%.
Wherein, the preparation method of described crosslinking mixture is as follows:
S1: add the toluene of the n-butyl acrylate of 27.5-32.5%, the Isooctyl acrylate monomer of 12.5-17.5%, the ethyl propenoate of 2.5-5%, the vinylformic acid of 1-2.5%, the Hydroxyethyl acrylate of 1-2.5%, the vinyl acetate of 0.1-0.75%, the n-methylolacrylamide of 0.1-0.75%, the ethyl acetate of 15-40% and 1-5% in a kettle. according to weight percent and be warming up to 75 DEG C-95 DEG C, and then add benzoyl peroxide amine or the Diisopropyl azodicarboxylate of 0.3%, and stir uniformly.Ethyl acetate and toluene only do chain-transfer agent adjustment polymkeric substance viscosity use, and not actual participation reaction, benzoyl peroxide amine or Diisopropyl azodicarboxylate are as initiator.
S2: according to weight percent add again the n-butyl acrylate of 27.5-32.5%, the Isooctyl acrylate monomer of 12.5-17.5%, the ethyl propenoate of 2.5-5%, the vinylformic acid of 1-2.5%, the Hydroxyethyl acrylate of 1-2.5%, the vinyl acetate of 0.1-0.75%, 0.1-0.75% n-methylolacrylamide, add the ethyl acetate of 15-40% and the toluene of 5-10%, and to stir uniformly.The toluene of the Hydroxyethyl acrylate of the ethyl propenoate of the n-butyl acrylate of this 27.5-32.5%, the Isooctyl acrylate monomer of 12.5-17.5%, 2.5-5%, the vinylformic acid of 1-2.5%, 1-2.5%, the vinyl acetate of 0.1-0.75%, the n-methylolacrylamide of 0.1-0.75%, the ethyl acetate adding 15-40% and 5-10% need complete and add in 3 hours.Same ethyl acetate and toluene only do chain-transfer agent adjustment polymkeric substance viscosity use, not actual participation reaction.In this step, it raises the viscosity of crosslinking mixture in order to adjust further, with close with the viscosity of follow-up used polymkeric substance.
Second step: prepare polymkeric substance, described polymkeric substance is the mixture of silicon rubber and MQ resin;
3rd step: mixed with polymers initiator is added crosslinking mixture, make polymer poly merge cross-linked polymer IPN through catalysis, wherein, described crosslinking mixture, polymkeric substance are respectively 40-50%, 50-60% by weight percentage.In this step, while mixed with polymers initiator, also can mixed cross-linker.Described initiator is BP amine or azo-bis-isobutyl cyanide.
The concrete operations mode of above-mentioned 3rd step is as follows: uniformly the benzoyl peroxide of 0.3% amine/azo-bis-isobutyl cyanide is added to polymkeric substance in half an hour, by mixing of crosslinking mixture and polymer uniform, is incubated after carrying out after 1 hour, is cooled to less than 50 DEG C.
In actual mechanical process, the order of the above-mentioned the first step and second step can be replaced.The solid content with the polymer blend of silica gel and esters of acrylic acid glue function obtained by above-mentioned preparation method should between 50%-60%, and need add a certain proportion of solvent during application and do and dilute, so that coating, it can be applicable to stationery adhesive tape.
Below by embodiment, the above-mentioned preparation method with the polymer blend of silica gel and esters of acrylic acid glue function is specifically described.
Formula one
There is the polymer blend of silica gel and esters of acrylic acid glue function, comprise crosslinking mixture, the polymkeric substance of 60%, the benzoyl peroxide amine of 0.3% of 40% according to weight percent, wherein,
Described crosslinking mixture comprises according to weight percent:
The preparation method with the polymer blend of silica gel and esters of acrylic acid glue function in this formula comprises:
Prepare crosslinking mixture: add n-butyl acrylate, the Isooctyl acrylate monomer of 12.5%, ethyl propenoate, the vinylformic acid of 1%, Hydroxyethyl acrylate, the vinyl acetate of 0.125%, n-methylolacrylamide, the ethyl acetate of 33%, the toluene of 8% be warming up to 75 DEG C of 0.125% of 1.25% of 2.5% of 32.5% in a kettle. according to weight percent, add the benzoyl peroxide amine of 0.3% again, and stir into the polymkeric substance of certain viscosity uniformly; In reactor, in 3 hours, evenly add n-butyl acrylate, the Isooctyl acrylate monomer of 12.5%, ethyl propenoate, the vinylformic acid of 1%, Hydroxyethyl acrylate, the vinyl acetate of 0.125%, n-methylolacrylamide, the ethyl acetate of 35%, the toluene of 5% of 0.125% of 1.25% of 2.5% of 32.5% according to weight percent;
Prepare polymkeric substance, described polymkeric substance is the mixture of silicon rubber and MQ resin;
Uniformly the benzoyl peroxide amine of 0.3% is added to polymkeric substance in half an hour, by mixing of crosslinking mixture and polymer uniform, is incubated after 1 hour, is cooled to less than 50 DEG C.
Formula two
There is the polymer blend of silica gel and esters of acrylic acid glue function, comprise crosslinking mixture, the polymkeric substance of 60%, the azo-bis-isobutyl cyanide of 0.3% of 40% according to weight percent, wherein,
Described crosslinking mixture comprises according to weight percent:
The preparation method in this formula with the polymer blend of silica gel and esters of acrylic acid glue function comprises:
Prepare crosslinking mixture: add n-butyl acrylate, the Isooctyl acrylate monomer of 13.5%, ethyl propenoate, the vinylformic acid of 1.75%, Hydroxyethyl acrylate, the vinyl acetate of 0.15%, n-methylolacrylamide, the ethyl acetate of 33%, the toluene of 8% be warming up to 75 DEG C of 0.35% of 1.25% of 3.5% of 29.5% in a kettle. according to weight percent, add the Diisopropyl azodicarboxylate of 0.3% again, and stir into the polymkeric substance of certain viscosity uniformly; In reactor, in 3 hours, evenly add n-butyl acrylate, the Isooctyl acrylate monomer of 13.5%, ethyl propenoate, the vinylformic acid of 1.75%, Hydroxyethyl acrylate, the vinyl acetate of 0.15%, n-methylolacrylamide, the ethyl acetate of 35%, the toluene of 5% of 0.35% of 1.25% of 3.5% of 29.5% according to weight percent;
Prepare polymkeric substance, described polymkeric substance is the mixture of silicon rubber and MQ resin;
Uniformly the azo-bis-isobutyl cyanide of 0.3% is added to polymkeric substance in half an hour, by mixing of crosslinking mixture and polymer uniform, is incubated after 1 hour, is cooled to less than 50 DEG C.
Formula three
There is the polymer blend of silica gel and esters of acrylic acid glue function, comprise crosslinking mixture, the polymkeric substance of 50%, the benzoyl peroxide amine of 0.3% of 50% according to weight percent, wherein,
Described crosslinking mixture comprises according to weight percent:
The preparation method in this formula with the polymer blend of silica gel and esters of acrylic acid glue function comprises:
Prepare crosslinking mixture: add n-butyl acrylate, the Isooctyl acrylate monomer of 17.5%, ethyl propenoate, the vinylformic acid of 1%, Hydroxyethyl acrylate, the vinyl acetate of 0.15%, n-methylolacrylamide, the ethyl acetate of 33%, the toluene of 8% be warming up to 75 DEG C of 0.35% of 1% of 2.5% of 27.5% in a kettle. according to weight percent, add the benzoyl peroxide amine of 0.3% again, and stir into the polymkeric substance of certain viscosity uniformly; In reactor, in 3 hours, evenly add n-butyl acrylate, the Isooctyl acrylate monomer of 17.5%, ethyl propenoate, the vinylformic acid of 1%, Hydroxyethyl acrylate, the vinyl acetate of 0.15%, n-methylolacrylamide, the ethyl acetate of 35%, the toluene of 5% of 0.35% of 1% of 2.5% of 27.5% according to weight percent;
Prepare polymkeric substance, described polymkeric substance is the mixture of silicon rubber and MQ resin;
Uniformly the benzoyl peroxide amine of 0.3% is added to polymkeric substance in half an hour, by mixing of crosslinking mixture and polymer uniform, is incubated after 1 hour, is cooled to less than 50 DEG C.
In sum, above-mentioned have silica gel and solve after solvent-type acrylic ester class glue mixing silicon with the polymer blend of esters of acrylic acid glue function and be easy to be divided into the phenomenon being unfavorable for being coated with, and be easy to preserve, stable performance, and the high peeling force of solvent-type acrylic presser sensor glue, high-temperature stability and the stability of silica gel, the protective value to affixed object can be had simultaneously; And this preparation method is simple; easy to operate; both are made to become stable two-phase polymer by reaction; the prepared polymer blend with silica gel and esters of acrylic acid glue function is easy to preserve; stable performance, and the high peeling force of solvent-type acrylic presser sensor glue, high-temperature stability and the stability of silica gel, the protective value to affixed object can be had simultaneously.
The above is only the preferred embodiment of the present invention; be not limited to the present invention; should be understood that; for those skilled in the art; under the prerequisite not departing from the technology of the present invention principle; can also make some improvement and modification, these improve and modification also should be considered as protection scope of the present invention.
Claims (10)
1. one kind has the polymer blend of silica gel and esters of acrylic acid glue function, it is characterized in that: comprise crosslinking mixture, polymkeric substance, initiator, described crosslinking mixture, polymkeric substance is respectively 40-50% by weight percentage, 50-60%, wherein, described crosslinking mixture comprises the n-butyl acrylate of 55-65% according to weight percent, the Isooctyl acrylate monomer of 25-35%, the ethyl propenoate of 5-10%, the vinylformic acid of 2-5%, the Hydroxyethyl acrylate of 2-5%, the vinyl acetate of 0.2-1.5%, the n-methylolacrylamide of 0.2-1.5%, ethyl acetate, toluene and initiator, described polymkeric substance is the mixture of silicon rubber and MQ resin.
2. the polymer blend with silica gel and esters of acrylic acid glue function according to claim 1, is characterized in that: described in there is in the polymer blend of silica gel and esters of acrylic acid glue function initiator used in initiator used, described crosslinking mixture be BP amine or azo-bis-isobutyl cyanide.
3. the polymer blend with silica gel and esters of acrylic acid glue function according to claim 1, is characterized in that: described in there is the polymer blend of silica gel and esters of acrylic acid glue function solid content be 50%-60%.
4. the polymer blend with silica gel and esters of acrylic acid glue function according to claim 1, is characterized in that: described in there is silica gel and esters of acrylic acid glue function polymer blend also comprise linking agent.
5. there is a preparation method for the polymer blend of silica gel and esters of acrylic acid glue function, it is characterized in that: comprise the steps:
Prepare crosslinking mixture, described crosslinking mixture comprises according to weight percent: the n-methylolacrylamide of the Hydroxyethyl acrylate of the ethyl propenoate of the n-butyl acrylate of 55-65%, the Isooctyl acrylate monomer of 25-35%, 5-10%, the vinylformic acid of 2-5%, 2-5%, the vinyl acetate of 0.2-1.5%, 0.2-1.5%, ethyl acetate, toluene and initiator;
Prepare polymkeric substance, described polymkeric substance is the mixture of silicon rubber and MQ resin;
Mixed with polymers initiator is added crosslinking mixture, and make polymer poly merge cross-linked polymer IPN through catalysis, wherein, described crosslinking mixture, polymkeric substance are respectively 40-50%, 50-60% by weight percentage.
6. the preparation method with the polymer blend of silica gel and esters of acrylic acid glue function according to claim 5, is characterized in that: the preparation method of described crosslinking mixture is as follows:
S1: add the n-butyl acrylate of 27.5-32.5%, the Isooctyl acrylate monomer of 12.5-17.5%, the ethyl propenoate of 2.5-5%, the vinylformic acid of 1-2.5%, the Hydroxyethyl acrylate of 1-2.5%, the vinyl acetate of 0.1-0.75%, the n-methylolacrylamide of 0.1-0.75%, ethyl acetate and toluene in a kettle. according to weight percent and be warming up to 75 DEG C-95 DEG C, and then add benzoyl peroxide amine or Diisopropyl azodicarboxylate, and stir uniformly;
S2: according to weight percent add again the n-butyl acrylate of 27.5-32.5%, the Isooctyl acrylate monomer of 12.5-17.5%, the ethyl propenoate of 2.5-5%, the vinylformic acid of 1-2.5%, the Hydroxyethyl acrylate of 1-2.5%, the vinyl acetate of 0.1-0.75%, 0.1-0.75% n-methylolacrylamide, add ethyl acetate and toluene, and to stir uniformly.
7. the preparation method with the polymer blend of silica gel and esters of acrylic acid glue function according to claim 6, is characterized in that: in described step S2: the n-methylolacrylamide of the ethyl propenoate of the n-butyl acrylate of described 27.5-32.5%, the Isooctyl acrylate monomer of 12.5-17.5%, 2.5-5%, the vinylformic acid of 1-2.5%, the Hydroxyethyl acrylate of 1-2.5%, the vinyl acetate of 0.1-0.75% and 0.1-0.75%, ethyl acetate, toluene need complete and add in 3 hours.
8. the preparation method with the polymer blend of silica gel and esters of acrylic acid glue function according to claim 5, it is characterized in that: described " mixed with polymers initiator, linking agent being added crosslinking mixture; make polymer poly merge cross-linked polymer IPN through catalysis " is specially: uniformly initiator is added to polymkeric substance in half an hour, by mixing of crosslinking mixture and polymer uniform, be incubated after 1 hour, be cooled to less than 50 DEG C.
9. the preparation method with the polymer blend of silica gel and esters of acrylic acid glue function according to claim 5, it is characterized in that: in mixed with polymers initiator " is added crosslinking mixture; make polymer poly merge cross-linked polymer IPN through catalysis " by described step, while mixed with polymers initiator, go back mixed cross-linker.
10. the preparation method with the polymer blend of silica gel and esters of acrylic acid glue function according to claim 5, is characterized in that: described initiator is BP amine or azo-bis-isobutyl cyanide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510575025.9A CN105176450A (en) | 2015-09-10 | 2015-09-10 | Blending polymer with function of silica gel and acrylate glue and preparation method of blending polymer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510575025.9A CN105176450A (en) | 2015-09-10 | 2015-09-10 | Blending polymer with function of silica gel and acrylate glue and preparation method of blending polymer |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105176450A true CN105176450A (en) | 2015-12-23 |
Family
ID=54898901
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510575025.9A Pending CN105176450A (en) | 2015-09-10 | 2015-09-10 | Blending polymer with function of silica gel and acrylate glue and preparation method of blending polymer |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105176450A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109251722A (en) * | 2018-10-19 | 2019-01-22 | 兴科电子(东莞)有限公司 | A kind of method for printing solid and preparation method thereof and silica gel is formed on PC film of PC film and the molding of silica gel oil pressure |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0289928A2 (en) * | 1987-05-06 | 1988-11-09 | General Electric Company | Silicone adhesive and organic adhesive composites |
| CN1740258A (en) * | 2005-09-23 | 2006-03-01 | 浙江大学 | Prepn of organosilicon modified pressure-sensitive acrylate adhesive |
| US20060171908A1 (en) * | 2005-02-03 | 2006-08-03 | Akinori Hanatani | Pressure-sensitive adhesive composition applicable to nail and adhesive agent for nail |
| CN101501088A (en) * | 2006-06-06 | 2009-08-05 | 道康宁公司 | A silicone acrylate hybrid composition |
| CN101979454A (en) * | 2010-10-27 | 2011-02-23 | 黑龙江省科学院石油化学研究院 | Method for preparing high-strength heat-resistant silicon resin modified acrylic ester pressure-sensitive adhesive |
| CN102533183A (en) * | 2010-12-09 | 2012-07-04 | 湖北航天化学技术研究所 | Solvent type organosilicon modified acrylate pressure sensitive adhesive, preparation method and application thereof |
| CN102558730A (en) * | 2011-12-22 | 2012-07-11 | 中科院广州化学有限公司 | MQ-silicone resin modified acrylate hybrid material and preparation method and application thereof |
| CN102803420A (en) * | 2009-04-24 | 2012-11-28 | 汉高公司 | Silicone acrylic hybrid polymer-based adhesives |
| CN104449486A (en) * | 2014-12-03 | 2015-03-25 | 新丰杰力电工材料有限公司 | Preparation method and application of high temperature solvent resistant acrylate pressure sensitive adhesive |
-
2015
- 2015-09-10 CN CN201510575025.9A patent/CN105176450A/en active Pending
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0289928A2 (en) * | 1987-05-06 | 1988-11-09 | General Electric Company | Silicone adhesive and organic adhesive composites |
| US20060171908A1 (en) * | 2005-02-03 | 2006-08-03 | Akinori Hanatani | Pressure-sensitive adhesive composition applicable to nail and adhesive agent for nail |
| CN1740258A (en) * | 2005-09-23 | 2006-03-01 | 浙江大学 | Prepn of organosilicon modified pressure-sensitive acrylate adhesive |
| CN101501088A (en) * | 2006-06-06 | 2009-08-05 | 道康宁公司 | A silicone acrylate hybrid composition |
| CN102803420A (en) * | 2009-04-24 | 2012-11-28 | 汉高公司 | Silicone acrylic hybrid polymer-based adhesives |
| CN101979454A (en) * | 2010-10-27 | 2011-02-23 | 黑龙江省科学院石油化学研究院 | Method for preparing high-strength heat-resistant silicon resin modified acrylic ester pressure-sensitive adhesive |
| CN102533183A (en) * | 2010-12-09 | 2012-07-04 | 湖北航天化学技术研究所 | Solvent type organosilicon modified acrylate pressure sensitive adhesive, preparation method and application thereof |
| CN102558730A (en) * | 2011-12-22 | 2012-07-11 | 中科院广州化学有限公司 | MQ-silicone resin modified acrylate hybrid material and preparation method and application thereof |
| CN104449486A (en) * | 2014-12-03 | 2015-03-25 | 新丰杰力电工材料有限公司 | Preparation method and application of high temperature solvent resistant acrylate pressure sensitive adhesive |
Non-Patent Citations (1)
| Title |
|---|
| 叶青萱: "《胶粘剂》", 31 October 1999, 中国物资出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109251722A (en) * | 2018-10-19 | 2019-01-22 | 兴科电子(东莞)有限公司 | A kind of method for printing solid and preparation method thereof and silica gel is formed on PC film of PC film and the molding of silica gel oil pressure |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR101488035B1 (en) | Pressure sensitive adhesive dispersion having high solids and low viscosity and method of making same | |
| CN102850972B (en) | Pressure-sensitive adhesive and preparation method thereof | |
| CN104293249B (en) | Preparation method, pressure sensitive adhesive and the application thereof of pressure sensitive adhesive | |
| CN105950081A (en) | High/low-temperature-alternation-resistant pressure-sensitive adhesive and preparation method thereof | |
| CN109266256B (en) | Medical pressure-sensitive adhesive and preparation method thereof | |
| CN111518491A (en) | High-temperature-resistant acrylate adhesive and high-temperature-resistant PI adhesive tape for OLED | |
| CN102703003A (en) | Silane coupling agent modified resin easy-peel environment friendly water-based pressure-sensitive adhesive | |
| US10604593B2 (en) | Aqueous emulsion, adhesive composition, and aqueous emulsion manufacturing method | |
| CN102703002A (en) | Environment-friendly high temperature-resistant and easily-stripped pressure-sensitive adhesive for electronic industry and preparation method thereof | |
| CN104371607A (en) | Acrylate emulsion pressure-sensitive adhesive with high solid content and low viscosity and preparation method thereof | |
| CN110041860B (en) | Pressure-sensitive adhesive with high peeling force and preparation method thereof | |
| CN104762034B (en) | Low VOC polyacrylate pressure-sensitive sticks agent and preparation method thereof | |
| CN109880555A (en) | Pressure-sensitive polyacrylate emulsion glue, preparation method and its application | |
| CN105175620A (en) | Preparation method of emulsion type pressure-sensitive adhesive | |
| CN113999632A (en) | Water-based acrylate pressure-sensitive adhesive and preparation method thereof | |
| CN113736398A (en) | Electrolyte-resistant solvent type acrylate pressure-sensitive adhesive and preparation method thereof | |
| JP4509279B2 (en) | Method for producing acrylic pressure-sensitive adhesive | |
| CN112694855A (en) | Modified acrylate adhesive, adhesive tape, and preparation method and application method thereof | |
| CN111269350A (en) | Environment-friendly water-based plastic-plastic composite adhesive and preparation method thereof | |
| CN108795340A (en) | Solvent-type acrylic ester pressure-sensitive, preparation method and the application of a kind of macromolecule and high conversion | |
| CN103724521A (en) | Preparation method of single-component polyacrylate pressure-sensitive adhesive for optical protective film | |
| CN105176450A (en) | Blending polymer with function of silica gel and acrylate glue and preparation method of blending polymer | |
| CN102634302A (en) | Environment-friendly strippable pressure-sensitive adhesive for surface protective film | |
| CN103980847A (en) | Self-curing polyacrylate-epoxy resin adhesive as well as preparation method and application of self-curing polyacrylate-epoxy resin adhesive | |
| CN111892679A (en) | Acrylate pressure-sensitive adhesive for foam and preparation process and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20151223 |
|
| WD01 | Invention patent application deemed withdrawn after publication |